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1.
Alkalinity, dissolved inorganic carbon (DIC), and 13C profiles from seep sites on the northwestern Gulf of Mexico upper slope show anomalously negative 13C values of up to –4.5 PDB, increased levels of DIC of up to 2.45 mmole/liter, and slight alkalinity rises of up to 2.54 meq/liter, relative to water column profiles from a seep-free site (0.63, 2.04 mmole/liter, and 2.39 meq/liter). The observed DIC enrichments coupled with the13C-depletions are attributed to the release of CO2 by microbial oxidation of crude oil in the seep environment, and its migration into the water column. The 13C composition of the migrating CO2 is estimated to be –26.0 on the basis of dissolved carbon inventory. Manifestation of DIC and 13C anomalies in the water column caused by hydrocarbon seepage holds promise to be useful for hydrocarbon reconnaissance surveys over large offshore tracts on account of the simplicity of sampling acquisition, and rapidity of analytical techniques in the laboratory.  相似文献   

2.
The 18O and 13C compositions of glacial- to Holocene-aged benthic foraminifera in a core collected from the eastern Arabian sea (water depth 1230 m) were determined to investigate glacial—interglacial variations in the intermediate depth water chemistry of the North Indian Ocean. In addition, we determined the 13C composition of Holocene benthic foraminifera from seven cores for which the 18O and 13C of benthic foraminifera from last glacial maximum (LGM) were reported by Kallel et al. (1988). The 13CDIC in the intermediate waters was generally depleted by 0.3–0.4 during the last glacial maximum compared to Holocene.  相似文献   

3.
Microbial Diversity in Nankai Trough Sediments at a Depth of 3,843 m   总被引：6，自引：0，他引：6  
Dense populations of bivalves, primarily Calyptogena sp., were observed at cold seeps of the Nankai Trough. Bacterial input to the sediment was estimated through determination of phospholipid ester-linked fatty acid (PLFA) and DNA profiles. Results indicated a bacterial biomass of 109 cells (g dry wt)-1 while individual fatty acid profiles revealed a predominance of monounsaturated fatty acids, mainly 18:1 isomers. The presence of these fatty acids can be interpreted to reflect a response to low temperature and a predominance of psychrophilic bacteria. DNA fragments encoding bacterial ribosomal RNA small-subunit sequences (16S rDNA) were amplified by the polymerase chain reaction method using DNA extracted directly from the sediment samples. From the sequencing results, at least 19 kinds of bacterial 16S rDNAs related to mostly the Proteobacteria and a few gram-positive bacteria were identified. These results suggest that the bacterial community in the Nankai Trough sediments consists of mainly bacteria belonging to the Proteobacteria , , and subdivisions. Bacteria belonging to the and subdivisions, which are known to include epibiont and sulfate reducing bacteria, respectively, were mostly detected in the sediment obtained from inside the area of the Calyptogena community, and the -Proteobacteria may function to supply reduced sulfur to bacterial endosymbionts of Calyptogena.  相似文献   

4.
Carbon and nitrogen stable isotope ratios (13C and 15N) of surface sediments were measured within Osaka Bay, in the Seto Inland Sea in Japan, in order to better understand the sedimentation processes operating on both terrestrial and marine organic matter in the Bay. The 13C and 15N of surface sediments in the estuary of the Yodo River were less than –23 and 5 respectively, but increased in the area up to about 10 km from the river mouth. At greater distances they became constant (giving 13C of about –20 and 15N about 6). It can be concluded that large amounts of terrestrial organic matter exist near the mouth of the Yodo River. Stable isotope ratios in the estuary of the Yodo River within 10 km of the river mouth were useful indicators allowing study of the movement of terrestrial organic matter. Deposition rates for total organic carbon (TOC) and total nitrogen (TN) over the whole of the Bay were estimated to be 63,100 ton C/year and 7,590 ton N/year, respectively. The deposition rate of terrestrial organic carbon was estimated to be 13,200 (range 2,000–21,500) ton C/year for the whole of Osaka Bay, and terrestrial organic carbon was estimated to be about 21% (range 3–34) of the TOC deposition rate. The ratio of the deposition rate of terrestrial organic carbon to the rate inflow of riverine TOC and particulate organic carbon (POC) were estimated to be 19% (range 3–31) and 76% (range 12–100), respectively.  相似文献   

5.
Ishiwatari  R.  Hirakawa  Y.  Uzaki  M.  Yamada  K.  Yada  T. 《Journal of Oceanography》1994,50(2):179-195
Organic geochemical study of bulk organic matter (OM), hopanoid hydrocarbon and normal hydrocarbon (C23C35) was conducted for a 936-cm-long sediment core sample from the Oki Ridge of the Japan Sea (Core KH-79-3, C-3; 37°03.5 N, 134°42.6E, water depth 935 m). Stable carbon isotopic ratios were also measured for both bulk OM and individual hydrocarbons. The following results were obtained: (1) The weight ratios of total organic carbon to total nitrogen range from 6.2 to 9.4 in the core. The 13C values of bulk OM range from –25.1–20.7%.. The 13C values of OM in the sections of 140190 cm are lower (–25–24) than those in the other sections (–23–21). This result indicates that OM in the core except for the 140190 cm sections is essentially of marine origin. (2) The 13C value of diploptene (a hopanoid hydrocarbon) in the last glacial maximum (LGM), is –66.3 (vs. PDB), which indicates it originating in methanotrophic bacteria. This result provides evidence to support for the previous ideas (Oba et al., 1980, 1984; Masuzawa and Kitano, 1984) that the bottom waters in the Japan Sea were anoxic in LGM. (3) Long chain (C23C35) n-alkanes of higher-plant wax origin were found throughout the core. Their concentration is high in 140190 cm in depth, suggesting that eolian dust load was high in LGM. (4) The n-alkane/TOC ratio increases with decreasing 13C values of bulk OM. This result indicates that the load of terrestrial (probably eolian dust-derived) OM to the Japan Sea became higher in colder climates. (5) The CPI values of long-chain n-alkanes are different in different 13O stages of paleoclimate, probably reflecting variations in species of terrestrial higher plants as a result of climatological adaptations.  相似文献   

6.
Nitrogen isotope compositions of particulate organic matter and nitrate were analyzed for seawater sampled at five stations at the Alaskan Gyre, Western Subarctic Gyre and East China Sea, focusing on the samples from the surface to 5000 m water to characterize the nitrogen cycling in the subarctic North Pacific Ocean and its marginal sea. The 15N of particulate organic matter showed little agreement with a conceptual closed model that interprets isotopic variation as being caused by isotope discrimination on nitrate utilization. The 15N and 13C of particulate organic matter varied with the water depth. A correlation between isotope compositions and C/N elemental ratio was found generally at all stations, although some irregular data were also found in deep layers. We developed a hypothetical nitrogen balance model based on N2 fixation and denitrification in seawater and attempted to apply it to distinguish nutrient cycling using both 15N-NO3 – and N* variation in seawater. This model was applied to the observed data set of 15N-NO3 – and N* in the North Pacific water and estimated the 15N-NO3 – of primordial nitrate in the North Pacific deep water as 4.8. The North Pacific intermediate water for all stations showed similar 15N-NO3 – and N* values of 6 and –3 µmol/kg, respectively, suggesting a similar nitrogen biogeochemistry. In the East China Sea, analysis showed evidence of water exchange with the North Pacific intermediate water but a significant influence of nitrogen from the river runoff was found in depths shallower than 400 m.  相似文献   

7.
The chemical states of iron in near-shore and deep-sea sediments were investigated by means of57Fe Mössbauer spectroscopy in combination with selective and nonselective chemical leachings. As far as a limited number of the sediments analyzed are concerned, Mössbauer spectra of near-shore sediments consist of high-spin paramgnetic ferrous (=1.13 mm/s, Eq=2.65 mm/s) and paramagnetic ferric (=0.35 mm/s, Eq=0.64 mm/s) components, while those of deep-sea sediments are composed of high-spin paramagnetic ferrous, paramagnetic ferrous, paramagnetic ferric and magnetic ferric (0.4 mm/s,H510 KG) components. The Fe2+/Fe3+ ratios of deepsea sediments are much smaller than those in near-shore sediments, while the total contents of iron in the former are much higher than those in the latter. This is principally due to the high contents of authigenic ferric oxides in deep-sea sediments. Further, in the aluminosilicate fraction, the Fe2+/Fe3+ ratios of deep-sea sediments are also smaller than those of near-shore sediments. This is probably attributed to high contents of clay minerals and authigenic aluminosilicates in deep-sea sediments relative to near-shore ones. The magnetic components in deepsea sediments are attributable to hematite, magnetite and/or maghemite.  相似文献   

8.
In the southeastern Yellow Sea, active seepage of hydrocarbon gases has been observed by high-resolution (3.5 kHz) seismic profiling both in 1987 and 2001, occurring through a large number of plumes from the topmost pre-Holocene sedimentary layer. It is strong enough to compensate for current speed, extending vertically up to the sea surface. The gas seepage often appears to be explosive to form craters and diapirs, although pockmarks are rare due to the redistribution of mobile palimpsest sands. In core-top seawater and sediments, the gases are characterized by high amounts of C2, homogenous 13C1 values and a large difference (19.7 on average) between 13C1 (–55.2 to –53.6 PDB) and 13C2 (–36.8 to –32.5 PDB) values. The gases are considered to be generated with a smaller amount of C1 at the early thermal cracking stage of labile source materials, after which the C2 gas is enriched in 13C by diffusion or biological alternation at the generation or accumulation site. The homogenous 13C1 values may be one of the geochemical characteristics of gases acquired at depth which are less altered in the case of rapid diffusive gas migration to the seafloor.  相似文献   

9.
Marine isotope stages (MISs) 1 to 5 were identified in the planktonic 18O record in sediment core DP00-02 just south of the Antarctic Polar Front in the Drake Passage, Antarctica. The oxygen isotope record, based on Neogloboquadrina pachyderma sinistral, is correlated with the contemporaneous global 18O stratigraphy. Marked deviations from the global climate curve suggest a local/regional overprint, particularly during MIS 3 which is considered a colder time period in the ocean record than MIS 1 and MIS 5 during the last interglacial. The comparison shows that negative 18O shifts in core DP00-02 during MIS 3 are larger than mean global changes which show a shift equal to or smaller than 0.5. The isotope shift, exceeding the glacial-interglacial ice volume effect, probably resulted from changes in the isotope composition of seawater, which is linearly related to decreases in salinity rather than to increases in sea-surface temperature. Increased ice-rafted debris (IRD) content during this interval indicates a strong influx of IRD from melting ice shelves and icebergs, which may be related to upwelling of warmer circumpolar deep water.  相似文献   

10.
Over 20 occurrences of discontinuous limestone blocks, locally called calcari aLucina, were mapped in the Tuscan—Romagna region of the northern Italian Apennines. The limestones, consisting of a variable mixture of authigenic carbonates (calcite, dolomite, and aragonite), sulfides (primarily pyrite), and allogenic silicates, occur in association with turbidite and hemipelagite units that were deposited in foredeep basins during early to late Miocene times. The limestone blocks are interpreted to represent relicts of carbonate buildups formed around methane-rich fluid vents on the basis of their (1) striking petrographic similarities to carbonates from cold vents in the modern oceans; (2) unique chemosynthetic-like fauna, and (3) anomalously negative 13C values ( 13C = – 16 to – 58 PDB). The contemporaneous tectonism of the Apennine orogeny is likely to be the primary cause for the expulsion of the methane-rich fluids to the seabed in a manner analogous to the fluid-flow processes occurring at modern accretionary prisms.  相似文献   

11.
Two independent methods of paleobathymetry, applicable to hydrocarbon-derived carbonates, are explored in this study. The oxygen isotope method exploits the temperature decline with depth that leaves a measurable imprint on the 18O composition of pristine products of venting comprised of aragonites and dolomites. The other method makes use of the bathymetric preferences of benthic foraminiferal taxa entrapped in the carbonate buildups. These two methods were tested on the calcari aLucina limestones hosted in turbidites and mudstones infilling the Miocene-age Marnoso-arenacea basin. The limestone blocks, rich in fossils of chemosymbiotic-like fauna, preserve a 10-Ma record of hydrocarbon venting from Langhian to lower Messinian times. Our results indicate that carbonate accretion and lithification occurred at upper bathyal depths in waters not shallower than 200–250 m. The 18O of venting products contains the imprints of profound hydrographic changes that occurred in the ancient Mediterranean basin from the lower Serravallian to the lower Messinian.  相似文献   

12.
Numerical solutions are examined for isolated, intense vortices as influenced by western bounding bottom topography through the use of a rigid-lid, two-layer primitive -plane numerical model. Systematic studies are made of the sense of rotation (cyclonic/anticyclonic), the consequence of varying the gradient of bottom slope, and the different vertical shear in a two layer ocean. In the basin with a bottom slope, the nearly barotropic anticyclonic vortex forms a modon-like vortex for S with fixedRo 2<O(1) (where is the ratio between the variation of the Coriolis parameter across the eddy to the Coriolis parameter in the center, S the topographic effect and,Ro 2 the Rossby number in the lower layer) and its generation is due to a compound effect of the planetary beta, topographic beta, avvection, and mirror image. The formation of the modon-like vortex and the propagation of the original vortex onto the bottom slope depends on the strength of slope gradient and the baroclinicity of the vortex. The nearly barotropic anticyclonic vortex evolves into the stronger upper ocean one with increasing S: the gradient of the bottom slope becomes steeper. Then the original vortex lives longer because the barotropic component of the energy is converted to the baroclinic one and it moves toward southeast in forming a modon-like vortex in the lower layer. The evolution of a vortex in the model results are compared to observational results of a Kuroshio warm core ring (KWCR) obtained from hydrographic data (June, 1985) and from NOAA satellite infrared images (April, 1985 to July, 1985). It is shown that a KWCR (June, 1985) is influenced by the western continental slope/shelf of the East Japan.  相似文献   

13.
Observational data on air-sea boundary processes at the Shirahama Oceanographic Tower Station, Kyoto University, obtained in November, 1969, was analyzed and presented as an example representing the structure of growing wind-wave field. The condition was an ideal onshore wind, and the data contained continuous records of the wind speed at four heights, the wind direction, the air and water temperatures, the tides, and the growing wind waves, for more than six hours. The main results are as follows. Firstly, in both of the wind speed and the sea surface wind stress, rather conspicuous variations of about six-minute period were appreciable. Secondly, the three-seconds power law and its lemma expressed byH *=BT *3/2 and=2BT *–1/2, respectively, are very well supported by the data, whereH *(gH/u * 2) andT *(gT/u *) are the dimensionless significant wave height and period, respectively, the wave steepness,u * the friction velocity of air,g the acceleration of gravity, andB=0.062 is a universal constant. Thirdly, the spectral form for the high-frequency side of the spectral maximum is well expressed by the form of()= sgu*–4, where is the angular frequency and() the spectral density. The value of s is determined as 0.062±0.010 from the observational data. There is a conspicuous discrepancy between the spectral shape of wind waves obtained in wind-wave tunnels and those in the sea, the former containing well-defined higher harmonics of the spectral peak, and consequently there is an apparent difference in the values of s also. However, it is shown that the discrepancy of s may be eliminated by evaluating properly the energy level of the spectral form containing higher harmonics.  相似文献   

14.
Stable isotope measurements on molluses from raised marine deposits, and on foraminifera in a piston core, define a series of light isotope events. A major event is14C dated at ca. 10.3 ka and is correlated with a marked isotopic excursion in HU77-021-156. This event is followed by a dramatic rise in diatom and, slightly later, in benthic foraminiferal abundances. Molluses record another light event around 8 ka. Major fluctuations in both 18O and 13C around 10.3 ka suggests that the Hudson Strait ice stream may have responded to the Younger Dryas climatic oscillation.  相似文献   

15.
Effects of the Ekman friction on the prograde (eastward) flows past a cylinder on a-plane are investigated when (=R 2/U, whereR is the cylinder radius andU the freestream speed)O(1) and(=2E k 1/2/R 0·O(1) where is the non-dimensional beta parameter and the ratio of the square root of the Ekman numberE k multiplied by 2 to the Rossby numberRo multiplied by the aspect ratio(=H/R, whereH is the fluid depth). Previous studies without the Ekman friction have shown that the-effect inhibits flow separation for pragrade flows through the asymptotic boundary condition by shifting the region of the adverse pressure gradient toward the rear stagnation point. It is found that the Ekman friction alleviates this-effect on the exterior flow. In the Ek 1/4-boundary layer, on the other hand, Ekman friction suppresses the vorticity advection along the wall, which tends to make the boundary layer thickness thin and delay the flow separation. The Ekman friction thus affects flow separation in a complicated manner. Details of the boundary layer structures and the separation angles are described for 0.3< <4.0 and 0.1<<1.5.  相似文献   

16.
A coastal ocean -coordinate model of Monterey Bay (MOB) with realistic bottom topography and coastlines is developed using the Princeton Ocean Model (POM) and grid generation technique (GGT) to study the horizontal pressure gradient errors associated with the MOB steep topography. The submarine canyon in MOB features some of the steepest topography encountered anywhere in the world oceans. The MOB grids are designed using the EAGEAL View and GENIE++ grid generation systems. A grid package developed by Ly and Luong (1993) is used in this study to couple grids to the model. The MOB model is tested with both orthogonal and curvilinear nearly-orthogonal (CNO) grids. The CNO grid has horizontal resolution which varies from 300 m to 2 km, while the resolution of the orthogonal grid is uniform with x = 1.25 km and y = 1.38 km. These grids cover a domain of 180 × 160 km with the same number of grid points of 131 × 131. Vertical resolutions of 25, 35 and 45 vertical sigma levels are tested. The error in the MOB are evaluated in terms of mean kinetic energy and velocity against various grids, vertical, horizontal resolution and distributions, and bottom topography smoothing. Simulations with various grids show that GGT can be used as another tool in reducing -coordinate errors in coastal ocean modeling besides increasing resolution and smoothing bottom topography. Topographical smoothing not only reduces topographic slope, but changes realistic topography. A CNO grid with a high grid density packed along steep slopes and Monterey Submarine Canyon reduces the errors by 40% compared to a rectangular grid with the same number of grid points. The CNO grid is more efficient than the rectangular grid, since it has most of its grids over water. The simulations show that the presented MOB -coordinate model can be used with a confidence regarding horizontal pressure gradient error.  相似文献   

17.
Geochemical properties of gas hydrate accumulation associated with an active gas vent on the continental slope offshore northeast Sakhalin Island in the Sea of Okhotsk have been investigated. The pore water chemistry data suggest that the gas hydrates (GHs) were formed in an environment of upward-migrating fluid combined with a mechanism of pore water segregation. The upward infiltration of water enriched mainly by Cl– and K+ species appears to occur on the background of earlier diagenesis processes within the gas vent sediments. The GHs were formed from water with chlorinity ranging from 530 to 570 mM. The 18O and D of GH water varied from –1.4 to –1.8 and from –13 to –18, respectively, representing a mix of seawater and infiltrating fluid water. A complex interaction of pore water, water of ascending fluid and segregated pore water during hydrate formation is also supported by water content measurements and observed gas hydrate structure. The direction of segregated water is opposite to upward fluid migration. Decreasing activity of the gas vent is inferred by comparing the present top of the recovered hydrate layer with previous observations.  相似文献   

18.
Salinity, preformed phosphate and AOU distribution on the sigma-t surfaces of 26.8 and 27.3 of the central North Pacific Ocean, as well as the topography of these density surfaces, were studied. The direction of water flow suggested by the AOU distribution on these density surfaces was compared to that indicated by the acceleration potential contours on the t =125 cl/ton and t =80cl/ton surfaces drawn by Joseph L.Reid, Jr. The disagreements were explained in terms of mixing and possible gradients of primary production at the sea surface. On the 26.8 sigma-t surface a southward flow connecting the westward flow south of the Aleutian chain and the eastward flow farther south, between 175E and 180 is suggested by the AOU distribution but is not implied by the acceleration potential contours. If the circulation pattern at this density surface is similar to that at the sea surface, this southward flow is very likely to be real.  相似文献   

19.
Petrographic and geochemical analyses performed on a North Sea core from the Gryphon Field reveal the presence of palaeo-degassing features surrounded by injected sandstones in the Eocene interval. The injected sandstones are oil-stained and poorly cemented by carbonate and quartz. 18O isotope analyses indicate that carbonate cementation occurred during shallow burial (likely less than about 300 m). Depleted 13C (around –30 V-PDB) carbonate cement suggests that bicarbonate was derived from the microbial oxidation of oil and gas. Late quartz overgrowths enclose oil present in the injected units. The tubular degassing conduits are composed of zoned cements and have 18O and 13C isotope values similar to the injected sandstones, indicating that oil and gas seepage induced the precipitation of authigenic carbonate in the shallow subsurface. Oil inclusions in inter- and intra-crystal cement sites in both injected sandstones and degassing conduits indicate that oil seepage was an ongoing feature at shallow burial. A proposed model involves oil and gas seepage and the formation of the degassing conduits, followed by a sand injection phase. It seems likely that oil and gas continued to leak towards the seabed by exploiting the network of permeable injected sandstones and the horizons of porous degassing features.  相似文献   

20.
Hydrocarbon gases were determined in sediments from three mud volcanoes in the Sorokin Trough. In comparison to a reference station outside the mud volcano area, the deposits are characterized by an enrichment of high-molecular hydrocarbons (C2–C4), an absence of unsaturated homologues, a predominance of iso-butane in comparison with n-butane, and the presence of gas hydrate. The molecular composition of the hydrocarbon gases suggests their deep sources and thermogenic origin. In the pelagic sediments at the reference station, the methane concentration is relatively low (up to 49 ml/l); maximum concentrations are reached in deposits of the Dvurechenskii mud volcano (up to 400 ml/l). It was the first time that gas hydrate was sampled at the Dvurechenskii mud volcano. The gas extracted by dissociation of hydrate samples was dominated by methane (99.5%) with low amounts of ethane and propane (less than 0.5%). The isotopic composition of the methane varies between –62 and –66 PDB in 13C, and between –185 and –209 SMOW in D, indicating a mainly biogenic origin with an admixture of thermogenic gas.  相似文献   

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