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1.
The Ditrău Alkaline Massif is an intrusion into the Bucovina nappe system that is part of the Mesozoic crystalline zone located in Transylvania, Romania, in the Eastern Carpathians. Nepheline syenites are the most abundant rocks in the central and eastern part of the Massif, and represent the last major intrusion of the complex. Fluid inclusions in nepheline, aegirine and albite were trapped at magmatic conditions on or below the H2O-saturated nepheline syenite solidus at about 400–600 °C and 2.5–5 kbars. Early nepheline, and to a lesser extent albite, were altered by highly saline fluids to produce cancrinite, sodalite and analcime, during this process cancrinite also trapped fluid inclusions. The fluids, in most cases, can be modeled by the H2O–NaCl system with varying salinity; however inclusions with more complex fluid composition (containing K, Ca, CO3, etc., in addition to NaCl) are common. Raman spectroscopic analyses of daughter minerals confirm the presence of alkali-carbonate fluids in some of the earliest inclusions in nepheline, aegirine and albite.

During crystallization, the melts exsolved a high salinity, carbonate-rich magmatic fluid that evolved to lower salinity as crystallization progressed. Phases that occur early in the paragenesis contain high-salinity inclusions while late phases contain low-salinity inclusions. The salinity trend is consistent with experimental data for the partitioning of chlorine between silicic melt and exsolved aqueous fluid at about 2.0 kbars. The activity of water (aH2O) in the melt increases during crystallization, resulting in the formation of hydrous phases during late-stage crystallization of the nepheline syenites.  相似文献   


2.
辽宁赛马岩体是我国典型的产铀碱性杂岩体,但其稀土矿化机制尚不明确.通过光学显微镜、扫描电镜和电子探针分析,得知该岩体从霞石正长岩经霓霞正长伟晶岩至晚期异霞正长岩,代表性稀土矿物层硅铈钛矿[Na2Ca4REETi(Si2O72OF3]不断富集,Nb、Zr和REE(特别是HREE)等高场强元素含量不断升高,部分颗粒具Zr、REE等元素成分环带,以上成分变化与稀土等不相容元素性质、碱性岩浆成分和岩浆结晶分异过程密切相关.此外,层硅铈钛矿经历了一系列的热液蚀变,蚀变部分Ti、Ca、Sr、Na含量增加而Zr、REE含量降低,最终形成由残余层硅铈钛矿+方解石+萤石+铈硅磷灰石组成的假晶,可能与富碱质、F和CO2的自交代流体作用有关.该研究揭示了碱性岩浆演化过程中,层硅铈钛矿成分变化及热液蚀变组合对指示岩浆结晶分异程度、探究稀土元素分馏及其热液活动性的具有重要意义.   相似文献   

3.
辽宁赛马碱性岩体早年因产铀矿而闻名,该岩体主要由响岩、霞石正长岩和异霞正长岩组成,其中铀、锆和稀土等元素矿化主要集中于异霞正长岩岩浆阶段。异性石是异霞正长岩中特征的锆-稀土矿物,主要分为两期,晚期异性石表现出更加富集Nb、REE等高场强元素的特点。早期异性石经历了一系列的热液蚀变,根据蚀变强弱程度,蚀变矿物组合可分为:(1)异性石+钠锆石+霓石±钠沸石;(2)异性石+钠锆石+锆石+钠沸石±霓石;(3)异性石假晶,假晶主要由残余异性石+钠锆石+锆石+钠沸石+霓石+钾长石+铈硅磷灰石组成。相比于岩浆锆石,蚀变组合中次生锆石具有富Ca、Al、Fe的特点,与异性石本身化学成分和流体性质密切相关。通过对异性石及其蚀变组合的精细矿物学研究,我们得知假晶的形成可能是异性石"溶解-再沉淀"的结果,致使假晶形成的流体至少包括:(1)占主导的富Na(±K)、Al、F的自交代流体;(2)少量晚期富Ca流体。假晶中次生锆石和铈硅磷灰石的结晶说明了Zr和REE等高场强元素的热液活动性,自交代碱性流体和富Ca流体在此过程中起到"搬运"和"提纯"的作用,这对认识碱性岩稀有、稀土成矿机制具有重要的指示意义。  相似文献   

4.
J. G. Liou 《Lithos》1971,4(4):389-402
The stability fields of analcime and analcime+quartz have been investigated using conventional hydrothermal techniques, over the approximate range of conditions 160–600 °C and 500–5000 bars fluid pressure. The dehydration of analcime (Na2Al2Si3·3O11·6 · nH2O) to albite, nepheline and H2O occurs at temperatures of 492±5 °C at 500 bars, 538±5 °C at 1000 bars, 578±5 °C at 2000 bars and 598±5 °C at 3000 bars. In the presence of quartz, analcine dehydrates to highly disordered albite and H2O at about 200 °C and 2000 bars, 196°±5 °C and 3000 bars, about 190 °C and 4000 bars, and 183±5 °C at 5000 bars Pfluid. The synthetic phase equilibria appear to be compatible with field observations that primary analcimes occur as phenocrysts or in groundmass in some volcanic and hypabyssal rocks and secondary analcimes in sedimentary, hydrothermally altered and low-grade metamorphic rocks.  相似文献   

5.
琼西南东方中沙农场发育有基性岩脉,主要由斜长石、单斜辉石和少量角闪石组成。其LA-ICP-MS锆石U-Pb年代学测试表明,该岩脉形成年龄为(242.2±2.6) Ma,和东部地区辉绿岩脉的形成年龄一致。该基性岩脉w(SiO2)=52.39%~53.44%,w(K2O+Na2O)=5.02%~5.71%,具富钾(w(K2O)=2.45%~3.29%)和高K2O/Na2O值 (0.91~1.63) 特征。该基性岩脉富集轻稀土元素和大离子亲石元素(LIL),轻微Eu负异常(δEu=0.76~0.84),Sr、P弱负异常,明显亏损高场强元素Nb、Ta、Ti。海南约240 Ma的基性岩脉可能来源于被流体交代的地幔源区,形成于华南-印支陆块碰撞后伸展构造环境。  相似文献   

6.
以地质和成矿学论点为依据,内岛弧、大陆边缘及内大陆构造域的火山深成岩带的形成作用具有其共同性;矿石-岩浆系可划分数个级别.金-银矿化的矿物-地球化学特点与局部或整体矿石-岩浆系中含矿岩浆岩岩石化学特点之间存在有可比性.通过含矿脉体-交代岩带的形态、构造、结构特点、物质组成变化的研究表明,产出在单独的矿石-岩浆系,特别是高等温线部位的矿床,其垂向成矿规模最大.在地球物理、地质学、岩石学、物理化学和实验研究的基础上建立同火山作用的金-银成矿系模型是可行的.  相似文献   

7.
Sulfate fluids are common fluids in nature, and their salinity studies can provide important information for the evolution of ore-forming fluids, migration and enrichment of ore-forming elements, and the classification of deposit types. Considerable research has been carried out to investigate the solubility of Na2SO4 and K2SO4 in hydrothermal fluids, however most of the literature reported experimental data were under saturated vapor pressure or the water supercritical region. A few data have been reported for the low temperature hydrothermal mineralization region. Thermodynamic model is a useful method to study the properties of hydrothermal geofluids, especially for mineral solubility. Pitzer interaction model is one of the most widely used model to calculate the thermodynamic properties of hydrothermal fluids, but few work have ever been carried out to calculate the solubility of sulfate at high temperature and pressure. With Pitzer specific interaction model, using the literature reported density data of Na2SO4 and K2SO4 solutions at high temperature and pressure, the pressure effect on Pitzer activity coefficient of sulfate and the standard partial molar volume change during sulfate dissolution process were evaluated and related parameters were obtained. The standard partial molar volumes of Na2SO4 and K2SO4 calculated with these parameters agreed well with those reported in the literature. Combined with the relevant parameters in the literature under saturated vapor pressure, a thermodynamic model for Na2SO4 and K2SO4 solubility calculation with temperature up to 250 ℃ and pressure up to 40 MPa was developed. The model gave very good agreement with the experimental solubility data. With this model, Na2SO4 and K2SO4 solubility was calculated at high temperature and pressure. The calculation results showed that pressure had a positive effect on both the average activity coefficient and solubility product of Na2SO4 and K2SO4, but the solubility of Na2SO4 and K2SO4 decreased with pressure due to the larger change of the average activity coefficient with pressure. And as the temperature increased, the degree of such reduction became larger. The results herein can provide instructions for the compositional analysis of sulfate fluid inclusions.  相似文献   

8.
SHRIMP锆石U-Pb年龄测定表明,辽东半岛弟兄山岩体的侵位时代为三叠纪(205.2±2.1 Ma),是华北东部三叠纪花岗岩的一部分.全岩岩石化学分析结果显示,弟兄山花岗岩具有高SiO2、Al2O3、K2O,低TiO2、Na2、MnO和CaO的特征,K2O+Na2变化范围为7.88%~9.28%,K2O/Na2 ≥ 1.16~1.46;CaO/Na2=0.08~0.23,铝指数A/CNK=0.95~1.10,并且在矿物组合中出现白云母,属准铝-过铝质花岗岩.在SiO2-Zr图解中,所有样品点均落在S型花岗岩区域中.以上特征均显示该花岗岩为准铝-过铝质S型花岗岩.稀土曲线和稀土参数表现出强烈的轻、重稀土分异特征和明显的Eu负异常特征,反映源区岩浆形成后发生过斜长石或其他富Ca矿物的分离结晶作用,是典型准铝-过铝质花岗岩的稀土元素特征.在原始地幔标准化的微量元素蛛网图上,所有花岗岩均富集Rb、Th,明显亏损Nb、Ta、Sr和Ti.所有样品的Rb=133×10-6~360×10-6,绝大多数样品高于花岗岩的平均值(200×10-6);Sr(25×10-6~135×10-6)和Ba(48×10-6~507×10-6)明显低于花岗岩的平均值(Sr 300×10-6,Ba 830×10-6),Ba、Sr亏损反映岩浆经历了较为完全的分离结晶作用;大离子亲石元素Rb、Th富集,Nb和Ta亏损显示陆壳物质为岩浆的源岩.上述特征表明岩浆物质来源于陆源碎屑岩石.结合区域构造演化历史,认为弟兄山岩体是库拉-太平洋板块向欧亚大陆俯冲的产物,是印支晚期华北岩石圈处于弱伸展状态背景的响应.  相似文献   

9.
青海玉树县南洞卡组粗面安山岩的SiO2含量为55.92%~57.85%,高Na2O、MgO和Al2O3,低K2O、TiO2和 P2O5,铝饱和指数A/CNK=0.98~1.08,具有准铝-弱过铝质的特点。岩石K2O含量低,Na2O/K2O=12.60~15.97,显示出钠质粗面安山岩特征。SiO2-K2O图解和里特曼指数(2.89~3.25),说明岩石属于钙碱性系列。稀土配分模式为轻稀土弱富集右倾型,铕弱负异常(σEu=0.90~0.96)。微量元素蛛网图显示,岩石富集Rb、Th和U等元素,亏损高场强元素Nb、Ta和大离子亲石元素Ba,样品Ce/Pb、Nb/U 并未随着MgO含量的升高而升高,样品的La/Nb、Zr/Nb、Ba/Nb比值均表现出良好的稳定性,表明岩浆在上升过程中遭受地壳物质混染的可能性不大,可能是其源区特征的反映。研究表明岩浆经历了橄榄石和单斜辉石的结晶分异,且受到俯冲板片熔体对源区的改造作用。结合234 Ma的形成年龄,说明该粗面安山岩是金沙江洋盆向西俯冲消减和斜向碰撞的地质记录,其形成时代和地球化学特征也为江达-维西火山弧的形成演化及成矿作用研究提供依据。  相似文献   

10.
Peter C. Rickwood 《Lithos》1989,22(4):247-263
Use of some petrologic diagrams applied to analyses of volcanic rocks is unnecessarily difficult due to lack of data for construction of discriminant lines between rock series. Coordinates are provided for sufficient points to enable accurate plotting of the boundary lines within seven diagrams, viz.: (1) TAS - total alkalies (Na2O+K2O) vs. SiO2; (2) K2O vs. SiO2; (3) AFM; (4) Jensen; (5) KTP - K2O---TiO2---P2O5; (6) FMS - (FeO*/MgO) vs. SiO2; and (7) TAKTIP - K2O/(Na2O+K2O) vs. TiO2/P2O5. Different versions of these boundaries are collated to indicate their variable position, and it is demonstrated that inter-laboratory analytical precision suffices to account for almost all of their spread on the TAS and K2O vs. SiO2 diagrams.  相似文献   

11.
赣北鄱阳湖地区土塘剖面发育第四纪红土,自下而上可分为强网纹红土层、弱网纹红土层、微网纹红土层、均质红土层和下蜀黄土层。基于常量元素、粒度分析数据以及前人年代框架,初探土塘剖面化学风化特征及其古气候意义。(1)土塘剖面粒度组分均一,常量元素含量相近,风化淋溶强烈。(2)土塘剖面各地层间化学风化强度存在差异:下蜀黄土层为初期的去Na、Ca阶段;均质红土层为中期的去K阶段;微网纹红土层由去K阶段向去Si阶段过渡;网纹红土层已完全进入晚期去Si阶段。剖面常量元素的相对迁移能力为:Na2O>MnO2>CaO>P2O5>MgO>K2O>SiO2>Al2O3>TiO2>Fe2O3。(3)中更新世以来赣北鄱阳湖地区气候总体上由暖湿趋于干冷,期间伴随多个明显的干湿旋回佐证强烈的淋溶与干湿交替作用是网纹红土发育的重要驱动因子。  相似文献   

12.
通过对长春地区HDBZK-1孔沉积序列的热释光测年和沉积物粒度分析,选取对气候变化较为敏感的K2O、Na2O、MgO、CaO、Al2O3等氧化物及K2O/ Na2O、Al2O3/(Al2O3+CaO+Na2O)作为环境代用指标,并与孢粉分析资料相结合,分析了长春地区中更新世晚期(约280~120 kaB.P.)的气候环境变化。结果表明:该区中更新世晚期总体经历了4次明显的冷干-暖湿气候变化,即寒冷干旱(281.6~244.0 kaB.P.)-温凉稍湿(244.0~215.0 kaB.P.)-寒冷干旱(215.0~ 131.8 kaB.P.)-以淡水藻类花粉突然增多为明显标志的暖湿(131.8~126.4 kaB.P.);这与深海氧同位素曲线所反映的气候变化旋回有较好的对应关系。  相似文献   

13.
青藏高原北部白榴碧玄岩年代学及地球化学研究   总被引:1,自引:0,他引:1  
杨迪  丁林 《地质科学》2013,48(2):449-467
本文在可可西里北部边缘银顶山地区首次发现含橄榄石的高镁高钾质超基性火山岩。火山岩在阿尼玛卿-昆仑-木孜塔格缝合带南侧呈熔岩残丘形式产出,分布面积约为0.2 km2,其形成时代为上新世(5~4 Ma),是岩浆的快速侵位-喷溢的结果。斑晶主要为橄榄石(10%~12%)+白榴石(21%~27%)+霞石(13%~16%)±透辉石(29%~31%),基质主要为透辉石+云母+Fe-Ti氧化物+玻璃,定名为白榴碧玄岩。对3个样品51个点的橄榄石电子探针数据计算显示,橄榄石牌号为Fo74-87Fa13-26,属贵橄榄石,岩石中的橄榄石均不存在扭折带,表明这些橄榄石很可能是岩浆结晶的产物,而非岩浆捕获体。通过计算,银顶山地区橄榄石的结晶温度大约在1 226 ℃~1 234 ℃左右。白榴碧玄岩的化学组分:SiO2<45%,MgO>10%, Na2O+K2O>8%,Mg#(68.84~70.80),而Cr(149×10-6~156×10-6)和Ni(138×10-6~151×10-6),87Sr/86Sr(约0.708 6)和143Nd/144 Nd(约0.512 4),处于EMII源区范围内。初步认为藏北地区上新世超基性火山岩来自于较深的源区,最有可能是软流圈顶部地幔的局部熔融,并受到俯冲地壳物质的交代。  相似文献   

14.
At Gordon Butte (Crazy Mountains, Montana), agpaitic nepheline-syenite pegmatites intrude potassic alkaline rocks (principally, malignites and nepheline microsyenites). All pegmatite veins are composed predominantly of potassium feldspar, nepheline, prismatic aegirine, barytolamprophyllite, wadeite, eudialyte, loparite-(Ce) and altered rinkite ("vudyavrite") embedded in spherulitic and fibrous aegirine. Well-differentiated veins contain "pockets" filled with calcite, fluorapatite, mangan-neptunite, Mn-Ti-enriched prismatic aegirine, calcium catapleiite, and an unidentified Ca-Ti silicate. The potassium feldspar corresponds to Ba-rich sanidine with relatively low Na contents. The nepheline contains low levels of SiO2 and elevated Fe contents. The compositions of nepheline cluster in the lower portion of the Morozewicz-Buerger convergence field, indicating low-temperature crystallization and/or chemical re-equilibration of this mineral. The association of sanidine with nearly stoichiometric nepheline is unusual for agpaitic rocks and probably reflects inhibition of Al/Si ordering in the feldspar by Ba. At least four types of clinopyroxene can be distinguished on the basis of their morphology and composition. All these types correspond to Al- and Ca-poor aegirine (typically <0.6 and 2.6 wt% Al2O3 and CaO, respectively). The overall evolutionary trend of clinopyroxene in the Gordon Butte rocks is from Fe-poor diopside to aegirine-augite in the malignites and nepheline microsyenites, and culminates with the pegmatitic aegirine. This trend is characteristic for potassic alkaline complexes and results from preferential partitioning of Fe2+ into biotite during the magmatic crystallization. Barytolamprophyllite in the pegmatites is primary (as opposed to deuteric); only a few crystals contain a core composed of lamprophyllite. The evolutionary history of the Gordon Butte pegmatites can be subdivided into primary, agpaitic, and deuteric stages. The earliest paragenesis to crystallize included accessory zircon and thorite. Sr-rich loparite also precipitated relatively early serving as a major repository for Sr, REE, and Nb. During the agpaitic stage, diverse titano- and zircono-silicates (barytolamprophyllite, eudialyte, wadeite, and rinkite, among others) consumed most of the Ba, Sr, Ti, Zr, and Nb still remaining in the melt. The final stage in the evolution of the pegmatites involved interaction of the earlier-formed mineral assemblages with deuteric fluids. In common with the Rocky Boy pegmatites, Sr-REE-Na-rich fluorapatite, Ba-Fe titanates and REE-bearing carbonates (ancylite, calcio-ancylite, and bastnäsite-parisite series) are chief products of the deuteric stage. The alteration of the primary mineral assemblages by deuteric fluids also produced muscovite-zeolite pseudomorphs after nepheline, replacement of wadeite and eudialyte by catapleiite-group minerals, re-deposition of Ba in the form of hyalophane, baotite, and benitoite, and cation leaching from rinkite, eudialyte, and loparite. The mineralogy of the pegmatites from Gordon Butte, other potassic complexes, and sodic agpaitic occurrences is compared in detail.  相似文献   

15.
为探讨松辽盆地北部林西组地球化学特征、沉积环境及构造背景,对该区黑富地1井所钻遇的上二叠统林西组暗色泥质板岩进行主量元素、微量元素和稀土元素测试分析,结果表明:样品主量元素平均质量分数SiO2为65.05%、Al2O3为17.23%、CaO为2.58%、Na2O为2.84%、K2O为3.29%,K2O/Na2O值为0.20~3.48,A12O3/(CaO+Na2O)值为0.41~8.01;稀土元素w(∑REE)值介于80.68×10-6~215.59×10-6之间,平均值为173.41×10-6,δEu值介于0.61~0.88之间,平均值为0.70,表现为Eu的负异常,δCe值介于0.91×10-6~1.01×10-6之间,为微弱的Ce负异常,LREE富集,HREE亏损;微量元素以亏损Nb、Ta、Sr,相对富集Rb、Ba、La、Ce、Pb、Nd、Sm为特征。样品元素分析和物源w(TiO2)-w(Ni)、La/Th-w(Hf)等判别图解表明,林西组沉积物源具有多样性,主要来源于上地壳长英质物源,还有少量来自中、基性岩火成岩物源区。样品微量元素标准化蛛网图,稀土元素球粒陨石标准化配分模式图,K2O/Na2O-w(SiO2)、Th-Co-Zr/10、F2-F1构造背景判别图及地球化学参数对比结果表明,松辽盆地北部林西组物源构造背景主要为活动大陆边缘和大陆岛弧,可能形成于靠近大陆岛弧的活动大陆边缘构造背景。林西组应形成于海陆过渡相到陆相环境,水体由半咸水逐渐转变为淡水。  相似文献   

16.
Trevor H. Green  John Adam 《Lithos》2002,61(3-4):271-282
The solubility of Ti- and P-rich accessory minerals has been examined as a function of pressure and K2O/Na2O ratio in two series of highly evolved silicate systems. These systems correspond to (a) alkaline, varying from alkaline to peralkaline with increasing K2O/Na2O ratio; and (b) strongly metaluminous (essentially trondhjemitic at the lowest K2O/Na2O ratio) and remaining metaluminous with increasing K2O/Na2O ratio (to 3). The experiments were conducted at a fixed temperature of 1000 °C, with water contents varying from 5 wt.% at low pressure (0.5 GPa), increasing through 5–10 wt.% at 1.5–2.5 GPa to 10 wt.% at 3.5 GPa. Pressure was extended outside the normal crustal range, so that the results may also be applied to derivation of hydrous silicic melts from subducted oceanic crust.

For the alkaline composition series, the TiO2 content of the melt at Ti-rich mineral saturation decreases with increasing pressure but is unchanged with increasing K content (at fixed pressure). The P2O5 content of the alkaline melts at apatite saturation increases with increased pressure at 3.5 GPa only, but decreases with increasing K content (and peralkalinity). For the metaluminous composition series (termed as “trondhjemite-based series” (T series)), the TiO2 content of the melt at Ti-rich mineral saturation decreases with increasing pressure and with increasing K content (at fixed pressure). The P2O5 content of the T series melts at apatite saturation is unchanged with increasing pressure, but decreases with increasing K content. The contrasting results for P and Ti saturation levels, as a function of pressure in both compositions, point to contrasting behaviour of Ti and P in the structure of evolved silicate melts. Ti content at Ti-rich mineral saturation is lower in the alkaline compared with the T series at 0.5 GPa, but is similar at higher pressures, whereas P content at apatite saturation is lower in the T series at all pressures studied. The results have application to A-type granite suites that are alkaline to peralkaline, and to I-type metaluminous suites that frequently exhibit differing K2O/Na2O ratios from one suite to another.  相似文献   


17.
对松辽盆地北部地区黑富地l井钻遇的上二叠统林西组碎屑岩样品进行微体化石以及主量元素、微量元素和稀土元素测试分析,进而探讨该区林西组时代、地球化学特征、沉积环境及构造背景.获得的Protohaploxypinus fertilis-Piceaepollenites opimus-Alisporites communis孢...  相似文献   

18.
江西相山矿田主要铀矿化类型及其地球化学特征对比研究   总被引:1,自引:0,他引:1  
江西相山矿田发现近30个铀矿床,矿化与浅成超浅成侵入岩(次火山岩)关系密切,不管是划归火山岩型还是斑岩型矿床类型,均属于热液型矿床。从热液矿床的成矿构造特点分析,相山矿田铀矿化主要有隐爆碎屑岩型和蚀变岩型两大类,后者主要有水云母化蚀变岩型和钠长石化蚀变岩型。通过收集资料,结合笔者完成的有关课题成果数据,对各铀矿化类型进行了地球化学的对比研究,结果表明:隐爆碎屑岩型矿石品位较高,U含量大多大于1%,SiO2、Na2O含量较低,P2O5含量较高,K2O/Na2O比值平均11.51,主要伴生元素有Hf、Sb、Cu、Pb、Zn、Zr等;水云母化蚀变岩型矿化的K2O/Na2O比值平均4.83,伴生元素有W、Pb、Mo、Th、Sb等;钠长石化蚀变岩型矿化的K2O/Na2O比值平均0.19,U与CaO、P2O5关系密切,伴生元素有Sr、Zr、Hf、Sc、W等。从钠长石化蚀变岩型,到水云母化蚀变岩型,到隐爆碎屑岩型,即随矿化岩石U品位的增高,稀土配分曲线呈现出从右倾向左倾有规律的变化。  相似文献   

19.
利用岩石化学中各种氧化物及相关比值在陆相盆地沉积作用中的不同表现性质, 讨论了上黑龙江盆地绣峰组Ⅳ级层序形成的气候、水体、沉积体系及基准面变化特征.绣峰组Ⅳ级层序自下部向中部Fe2O3、Fe3+/Fe2+、K2O、Na2O等值逐渐减小; MnO、FeO、MgO、LOS等含量逐渐增高; 层序中部向上部Fe2O3、K2O、Na2O等值逐渐增大, MnO、FeO等含量逐渐减少, 显示了绣峰组Ⅳ级层序在气候旋回控制下由水体加深、气候潮湿向水体变浅、气候干旱演变的中期基准面对称旋回特征.这一研究成果为陆相盆地高频层序划分提供了新思路.   相似文献   

20.
普朗铜矿床是格咱岛弧产出的超大型斑岩型铜矿床,以往较多关注于含矿的石英二长斑岩,而对矿区出露的闪长岩、花岗闪长斑岩研究相对薄弱.对普朗矿区的闪长岩和花岗闪长斑岩开展了地球化学和锆石年代学分析,结果显示,闪长岩SiO2含量为62.46%~62.25%,K2O含量为5.53%~6.27%,MgO含量为3.58%~3.69%,(Na2O+K2O)总碱含量为7.93%~8.72%,K2O/Na2O>2,属中性超钾质碱性岩;花岗闪长斑岩SiO2含量为66.00%~66.98%,K2O含量为4.06%~4.19%,MgO含量为2.04%~2.17%,(Na2O+K2O)总碱含量为7.60%~7.81%,K2O/Na2O>1,属酸性钾质碱性岩.花岗闪长斑岩与中甸地区火山岩具有一致的Sr-Nd同位素特征,而闪长岩εNd(t)值变化范围大,二阶段模式年龄分散(369 Ma、913 Ma、1 138 Ma),指示有富集组分的混入.闪长岩LA-ICPMS锆石U-Pb年龄为227.0±2.9 Ma;花岗闪长斑岩LA-ICPMS锆石U-Pb年龄为211.5±3.7 Ma.结合岩石主量、微量元素、全岩Sr-Nd同位素及锆石U-Pb年龄,提出甘孜-理塘洋在长时期的西向俯冲(约25 Ma)过程中,普朗矿区(局部)可能发生过由挤压向伸展构造体制的转换,激发幔源的岩浆活动,导致钾质碱性小岩体侵位,该过程对该超大型斑岩铜多金属矿的形成具有重要意义.   相似文献   

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