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原生晕方法对于研究隐伏金矿体存在的可能性,矿体的规模、埋藏深度及其剥蚀深度都具有很大的指导意义。系统研究了安徽上成金矿床深部的原生晕结构特征,结果表明,矿区Ⅲ号矿体的轴向分带序列为Ag-Hg-Pb-Zn-Cu-Au-Sb1-As-Bi-Co-Mo-W-Sn-B-Sb2,呈现"反分带"特征;地球化学参数A1、A2曲线变化趋势为由降到升;原生叠加晕结构显示在Ⅲ号矿体尾部出现前、尾晕共存。同时,主成矿元素Au在原生晕浓度分带水平投影图上表现出向北西侧伏的特征。综合原生晕特征可以推断,在-60m中段最西端的北西侧深部应有隐伏矿体发育。依据微量元素的多元统计分析结果,可分为如下3类:①成矿元素及与成矿密切相关的元素Au、As、Bi、Cu、Co、Ag、Pb、Zn;②高温热液矿化元素W、Sn、Mo、B;③低温热液矿化元素Sb、Hg。 相似文献
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为预测湖南临湘虎形山钨矿床主矿体的深部变化趋势,在矿床地质特征和矿床成因研究的基础上,开展了野外地质调查和原生晕地球化学研究。微量元素统计分析表明,矿体的前缘晕元素为Ag、Zn、Au、Pb、Be、As、Cu,近矿元素为W、Bi,尾晕元素Sb、Sn、Mo。24号勘探线的钻孔原生晕数据表明,矿体自上而下其原生晕轴向分带序列为:Ag-Zn-Au-Pb-Be-As-Cu-W-Bi-Sb-Sn-Mo,具有"头尾晕共存"和"反分带"特征。结合矿体原生晕轴向分带模式,预测矿体向深部(-350 m以下)有一定的延伸或深部有盲矿体的存在。 相似文献
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为预测和评价贵州普安泥堡金矿床的成矿潜力,采用原生晕地球化学方法对10460勘探线所控制的Ⅲ-1号矿体进行原生晕轴向分带特征研究。采集了该勘探线上6个钻孔矿体附近的构造蚀变岩石样品进行ICP-AES分析。通过对各元素进行相关性分析及因子分析,选取原生晕地球化学特征研究的指示元素为Au、As、Ag、Cu、Hg、Mo、Co、Cd、Sb。综合原生晕分带图及指示元素分带序列分析,判断Ⅲ-1矿体原生晕出现了明显的分带异常,其由浅部到深部总体表现为:前缘晕元素+尾晕元素—近矿晕—前缘晕元素+近矿晕元素+尾晕元素的元素异常分布序列,指示在深部存在一个或多个隐伏矿体,是造成元素异常叠加共存与轴向分带序列异常的原因。 相似文献
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迄今为止文献中未见有铂矿原生晕研究的报道,通过对大岩子矿区地表和不同中段坑道原生晕的研究,发现在铂-钯矿体周围有清晰的F、Sb、Cd、Hg、As、Ag、Au、Pd、Pt、Cu、Ni元素的原生晕,其中F、Sb、Cd、Hg、As为前缘指示元素,Au、Ag为近矿指示元素,Pt、Pd、Cu、Ni为成矿指示元素.元素的垂直分带序列为(地表至矿体):(F、Sb、Cd、Hg、As)-(Ag、Au)-(Pd、Pt)-(Cu、Ni).地表岩石地球化学测量发现的Ⅲ号Pd、Pt异常带,具有多元素异常组合特征,判断为矿致异常,推测在该异常带下方可望找到隐伏矿体.坑道原生晕研究发现,在PD4中段出现浓集中心醒目、浓度分带清晰的F原生晕,推测在PD4中段下方可能存在新的盲矿体. 相似文献
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为预测范庄银矿床M_(23)主矿体的深部变化趋势,在对矿区地质特征和矿床成因研究的基础上,开展了野外地质调查及地球化学研究。结果发现矿体具有明显的侧伏现象。微量元素统计分析表明,Cu、Sb、As为矿体的近矿指示元素,矿体具有多期次的特点。M_(23)矿体化探数据表明,矿体自上而下其原生晕轴向分带序列为:Au-Bi-Cu-As-Zn-Pb-Sb-Mo-Ag-Sn-W-Hg,具有明显的"头尾晕共存"和"反分带"特征。结合矿体剥蚀系数的变化规律,预测在M_(23)矿体向深部(696 m以下)有较大延深(伸)或有深部有盲矿体存在,钻探验证(见矿高程370 m)说明矿床深部有较大的增储潜力。 相似文献
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胶西北上庄金矿床原生晕轴(垂)向分带特征及深部矿体预测的勘查地球化学标志 总被引：2，自引：0，他引：2
文章应用格里格良原生晕分带指数方法,系统研究了上庄金矿单个矿体、矿区等不同取样系统的原生晕轴(垂)向分带特征.结果表明,上庄金矿床原生晕轴(垂)向分带序列及原生晕叠加模式在矿区范围内比较相似,因此,可利用典型矿体原生晕轴(垂)向分带规律来指导矿床内深部矿体的预测.适用于该矿区-750 m以上的原生晕轴(垂)向分带序列为B-(Hg W Bi)-(As Mn Co)-Zn-(Au Ag)-Pb-Mo.典型矿体原生晕叠加模式显示,沿垂直方向矿体间断部位原生晕出现头、尾晕同位叠加以及头、尾、近矿晕同位叠加2种情况,并均呈现出地球化学参数的剧烈波动.其中,前者是下部有盲矿体存在的反映,而后者则有可能既是深部有盲矿体存在,也是2个矿化带或大矿体间有小矿体存在的反映.依此认识对深部矿体开展了预测,部分靶区已获得成功验证. 相似文献
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对山西省胡家峪桐木沟铜矿床3号主矿体定位规律及深部原生晕特征进行研究。结果表明：3 号主矿体赋存于篦子沟组硅化大理岩与碳质板岩接触带上,倾向SE,向NE侧伏。篦子沟组层内剥离断层作为控矿构造为成矿流体的运移及矿质卸栽提供空间,控矿断裂面沿倾向方向由缓到陡的部位易于成矿。目前开拓的525 m。445 m中段正处在断裂面产状变缓部位,向深部断裂面产状有变陡的可能;其矿体原生晕轴向分带序列为(Sn－W－Sb)－(Mn－V－B－As－Ni)－(Pb－Ti－Ag－Co－Mo－Bi－Zn－Hg－cu－Au)。地球化学参数n总体表现为“升”,前缘晕元素的分布向下富集,原生晕特征显示3号矿体向下部还有延伸,并据此圈定出深部矿体的预测靶区。445 m中段出现Cu、M0矿化叠加现象,且发现强烈绢英岩化的斑状花岗闪长岩,推测深部可能存在斑岩型Cu、Mo矿化,深部前缘晕元素富集是含Mo热液叠加的表征,因而深部也同时作为寻找Mo矿化的远景区。 相似文献
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通过对安徽庐江黄屯铜金矿床18号勘探线上的4个钻孔岩心进行系统取样和分析,研究了18号勘探线剖面地质特征及原生晕分带特征,探讨了该矿床的地球化学异常模式及矿床成因。黄屯铜金矿床的特征元素组合为Au、Ag、Cu、As、Sb、Bi、W,原生晕垂向分带序列为（Sb、As）-（Ag、Au、Cu）-（Bi、W）。18号勘探线剖面地质特征和原生晕形态特征显示,在ZK18-1钻孔和ZK18-2钻孔之间可能存在隐伏断层,造成铜金矿体和地层错动。在TK02钻孔底部发育热液矿床前缘晕元素组合异常,指示深部可能存在隐伏矿体。综合研究认为,黄屯铜金矿床的成矿物质可能主要来源于火山热液和闪长玢岩,该矿床为火山-次火山热液型矿床。 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献