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1.
Particulate and dissolved organic and inorganic carbon concentrations were measured in the Yang Tze (Changjiang) and Huanghe (Yellow) river estuaries, during two different seasons. During the winter, the organic matter in the suspended load of both estuarine systems was dominantly of terrestrial origin, while in the summer, there were significant contributions from aquatic production. In these turbid rivers, there is a strong positive correlation between the concentrations of total suspended matter and particulate organic carbon, probably because biological production is inhibited when turbidity exceeds a certain limit. Dissolved organic carbon (DOC) does not exhibit a conservative behavior in these estuarine systems. High dissolved organic carbon values in bottom water samples suggest remobilization of DOC from near-surface, bottom sediments. Dissolved inorganic carbon concentrations were very high in the Huanghe River, and the trend in the calculated saturation indices for calcite suggests precipitation of carbonate in this estuarine system. There is no such evidence for carbonate precipitation in the Yang Tze River.  相似文献   

2.
The spectral absorption properties of chromophoric dissolved organic matter (CDOM) and their distributions in two Chinese estuaries, the Yangtze River Estuary and the Jiulong River Estuary, were studied during August 2003 (wet season) and during different seasons between 2003−2005, respectively. The CDOM concentrations (a355) of fresh end members in the Jiulong River Estuary varied seasonally, while its quality remained relatively stable. However, the a355 of the marine end members exhibited less variability. Application of a conservative mixing model indicated that CDOM behaved conservatively in the Yangtze River Estuary. No photobleaching removal was observed at high salinity region of this estuary. Although CDOM showed conservative behavior for many cruises in the Jiulong River Estuary, there was evidence for removal in the low salinity regions during some cruises. Laboratory mixing experiments and a salt addition experiment suggested that particle sorption of CDOM maybe the possible reason for the removal. These results showed that absorption properties of CDOM can be used as a tool to observe the quantitative and qualitative dynamics of DOM during estuarine mixing.  相似文献   

3.
Estuaries are often seen as important filters between land and the sea for inorganic and organic nutrients. This paper aims at estimating the estuarine fluxes of dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP) and dissolved silicate for the major oligothrophic and pristine rivers running into the Bothnian Bay (BB) and the Bothnian Sea (BS), the northern subarctic subbasins of the Baltic Sea. Long-term data sets for these rivers and their estuaries as well as for the BB and BS were analyzed to assess whether these estuaries are sinks for inorganic nutrients. Most studied estuaries can be characterized as salt wedge estuaries with little exchange between the fresh seaward-flowing river water and the inward-flowing seawater. Estimates of water transit times ranged between 1 and 14 days. In most estuaries of the BB, N-depleted river water meets P-depleted seawater during the growth period. These findings were corroborated by mixing diagrams showing that the inner areas of the estuaries were N-depleted in summer. In the BS, on the other hand, both rivers and seawater were mostly N-depleted during summer. Thus, for most estuaries of this region of the Baltic Sea, primary productivity is presumably lower than or equal to that of offshore. The low productivity is also reflected in the sediments. The coastal sediments did not differ from the offshore stations in accumulation rates as well as the content of organic matter and nutrients, indicating that estuarine nutrient burial is not always higher as normally observed in other temperate systems. Finally, the estuaries of the pristine rivers in the northernmost part of the BB import DIN during summer, whereas the estuaries of the rivers in the BS import DIP during winter, from the sea.  相似文献   

4.
Although it is well-known that reactions occur within estuaries to alter the flux of dissolved aluminum from rivers into the oceans, the nature and relative importance of these reactions are not well defined. In this study we show that sediment-water interactions can have a significant influence on dissolved Al distributions in estuaries. Undisturbed sediments will act as a sink for dissolved Al because of diffusion across the sediment-water interface and reaction of Al within the sediment. Resuspension of sediments will cause a release of dissolved Al into relatively Si-depleted estuarine waters.Flocculation of colloidal material may cause a net consumption of dissolved Al in estuaries. Our results indicate, however, that this process may not, in many cases, be the primary cause for curvature in Al-Cl? profiles. An alternative model, whereby Al is displaced from organic matter complexes and adsorption sites in the estuarine zone and reacts with Si and cations in solution, is consistent with the data presented in this study as well as many other studies. In this case, the extent of net Al removal in estuaries will be determined by both the amount and nature of the dissolved organic matter present.  相似文献   

5.
The use of dissolved organic matter fluorescence as a tracer of river-sea mixing was examined in two South Carolina estuaries. Fluorescence declined linearly with seawater dilution in laboratory mixing studies, and also behaved conservatively in an estuary where a single river emptied into a bay. Fluorescence-salinity relationships were also studied in another estuary where a piedmont river (high suspended sediment, low fluorescence) and a coastal plains river (low sediment, high fluorescence) mixed with ocean water. The factor of 2 or greater difference in fluorescence between the two rivers allowed their relative contribution to the estuarine water mass to be distinguished. Petroleum hydrocarbons, measured in estuarine water at 0·7-1·8 μg l−1 concentrations, contributed negligibly to water fluorescence.  相似文献   

6.
《Marine Chemistry》2001,73(3-4):253-271
The influence of mangrove-fringed tropical estuaries on coastal carbon budgets has been widely recognised. However, a quantitative differentiation between riverine and mangrove-derived inputs to the dissolved (DOM) and microparticulate organic matter (POM) pool of these environments has been hitherto not possible. Based on lignin-derived phenols and stable carbon isotopes a chemical signature for mangrove, terrestrial and marine-derived organic matter was established for a mangrove estuary in North Brazil. A mixing model was applied to calculate the contribution of each of the three sources to the DOM and POM pool in the estuary throughout 18 tidal cycles in the course of one year. Best source assignment for POM was reached with the yield of lignin phenols and δ13C as paired indicators, while the origin of DOM was best identified by the yield of lignin phenols and the acid to aldehyde ratio of vanillyl phenols. Although only about 6% of the fluvial catchment area is covered by mangroves, their contribution to the estuarine DOM and POM pool generally exceeded several times the terrigenic input from the hinterland. This outwelling of mangrove-derived organic matter was enhanced during the rainy season. DOM and POM were exported from the mangrove to the estuary in similar proportions. Most mangrove-POM was rapidly removed from the water column, while mangrove-DOM behaved conservatively. In contrast, terrestrial DOM was almost entirely removed in the outer part of the estuary, which was accompanied by a concomitant increase in terrestrial POM. This seems to be the result of a geochemical barrier zone for this type of DOM in the estuary. Generally, a high proportion of mangrove-DOM was present in the outer part of the estuary, even at high tide. This indicates DOM outwelling from mangroves in adjacent bays or estuaries and points to similar driving forces controlling this process on a regional scale. Mangroves probably play a more important role than rivers for marine carbon budgets along the North Brazilian coast south of the Amazon estuary.  相似文献   

7.
The inner part of the Ariake Sea is one of the most productive estuarine systems in Japan. To examine potential food items for estuarine organisms, we conducted monthly observations of the dynamics of particulate organic matter along the macrotidal Chikugo River estuary in 2005 and 2006. In the neighboring macrotidal Midori and Kuma River estuaries, comparative observations were made. High turbidity and strong vertical mixing were observed only at low salinities (<10) in the Chikugo River estuary. In contrast, the Midori and Kuma River estuaries were characterized by less turbid and less mixed waters. Concentrations of particulate organic carbon often exceeded 5?mg?l?1 in or close to the estuarine turbidity maximum (ETM) of the Chikugo River estuary. However, such high concentrations were rarely observed in the other two estuaries. The observed differences could be attributable to different hydrodynamic processes related to the different lengths of tidal reaches: 23, 8, and 6?km in the Chikugo, Midori, and Kuma Rivers, respectively. In the Chikugo River estuary, spatiotemporal changes of chlorophyll a suggested that phytoplankton occurred abundantly up- and/or downstream from the ETM especially during the warm season. In contrast, pheophytin (i.e., plant detritus) always accumulated in or close to the ETM. Carbon stable isotope ratios and carbon to nitrogen ratios indicated that the plant detritus was derived from phytoplankton and terrestrial plants. The Chikugo River estuary has a high potential to support the production of estuarine organisms through abundant plant detritus in the well-developed ETM all the year round.  相似文献   

8.
The contribution of organic matter (humic compounds) to the alkaline reserve of seawater in the Sea of Japan, in the Razdol’naya River estuarine waters, and in the interstitial waters of the sediments of the Sea of Okhotsk was characterized using two procedures for alkalinity measurements: the method by Bruevich and that of the sample equilibrium with air. It was found that the surface waters of the Sea of Japan contained about 20 μmol/kg of alkalinity of organic origin, and this value twofold decreased with depth. For most of the actual cases of the calculations of the seawater carbonate system, this value may be neglected. Meanwhile, the contribution of organic alkalinity to the Razdol’naya River waters amounts to nearly 120 μmol/kg. It was shown that, if this value in the calculation of the carbonate system of the Razdol’naya River estuary-Amur Bay is neglected, this may cause gross errors in the values of the partial pressure of carbon dioxide (the error might be over 1500 μatm) and in the dissolved inorganic carbon (an error over 150 μmol/kg). The maximum absolute contribution of the humic matter (over 300 μmol/kg) was found for the interstitial waters in selected sediments of the Sea of Okhotsk. In the interstitial waters of these sediments, humic matter concentrations as high as 300 mg/l were detected. The data obtained show that the determination of the amount of humic matter must be an indispensable condition for an adequate analysis of estuarine carbonate systems and of the interstitial water in reduced marine sediments.  相似文献   

9.
The geochemistry of dissolved copper-organic complexes was investigated in the estuarine waters of Narragansett Bay. A transect survey was conducted in August 1980, while one mid-bay station was monitored from March through August of that year. The transect data indicated that most of the copper-organic complexes enter the bay via sewage effluent which is discharged into the Providence River at the head of the bay. Organic copper concentrations in the estuary ranged from 0.12 to 2.30 μg kg?1 and comprised from 14 to 70% of the total dissolved copper. The concentration of copper-organic complexes was not directly related to the amount of dissolved organic matter; and recently generated organic material from phytoplankton production within the bay had a negligible influence on the fraction of dissolved copper which was organically bound.The major source of total copper to the bay is anthropogenic inputs from sewage effluents. Particulate and dissolved copper concentrations ranged from 0.06 to 2.42 and 0.23 to 16.4 μg kg?1, respectively, giving average values of about 40% particulate and 60% dissolved copper. Particulate copper concentrations decreased rapidly from the upper to the lower bay as a result of both removal and dilution. About 75% of the dissolved copper entering the bay is rapidly removed in the Providence River and upper bay, and the remaining portion (which is largely organic copper) follows conservative mixing in the mid to lower bay. The data suggest that copper binding by dissolved organic matter may be an important control on the riverine flux of dissolved copper through estuaries into coastal and oceanic waters.  相似文献   

10.
Between 2003 and 2007, a series of field studies were performed in a typical small coastal plain type estuary (Eprapah Creek) located on the Southeast coast of Australia. The aim of these field studies was to investigate the turbulence and turbulent mixing properties in the estuarine zone. During these studies, high frequency turbulence and physio-chemistry data were collected continuously over a relatively long duration (up to 50 h). This article provides a summary of the key outcomes of these studies, highlighting the implications that these findings have on the modelling of small estuaries. The studies showed that the response of the turbulence and water quality properties were distinct under spring and neap tidal forcing and behaved differently in the middle and upper estuarine zones. The behaviour of turbulence properties to spring tidal forcing differed from that observed in larger estuaries and seemed unique to small estuarine systems. An investigation of several key turbulence parameters used in the modelling of estuarine mixing showed that many assumptions used in larger estuaries must be applied with caution or are simply untrue in small estuaries. For example the assumption that the mixing coefficient parameters are constant over the tidal cycle in a small estuary is simply untrue. These distinctions between the turbulence and mixing properties in small and large estuarine systems highlight the need for the continued study of small estuaries, so this type of system can be properly understood.  相似文献   

11.
本文对河口细颗粒泥沙絮凝作用的研究工作进行了综合评述．对盐度、有机物、水流切应力及悬浮颗粒的表面电荷等因素对河口细颗粒泥沙絮凝作用的影响规律及絮凝机理进行了总结和探讨．  相似文献   

12.
The diversity of small-scale wetlands, high salinity tidal creeks, salt marshes, estuaries, and a wide and shallow shelf with the Gulf Stream close to the break makes the coastal zone of south-eastern North Carolina (U.S.) a natural laboratory for the study of the cycling of nitrogen (N) and phosphorus (P) in coastal and shelf waters. We assessed the summer concentrations, forms, and ratios for each N (total dissolved N, nitrate + nitrite, ammonium and dissolved organic N) and P (total dissolved P, o-phosphate and dissolved organic P) pool as these nutrients travel from tidal creeks, salt marshes and two large estuaries to Long and Onslow Bays. Additionally, we measured ancillary physical (temperature, salinity and turbidity) and chemical (dissolved oxygen, chlorophyll a and pH) water properties. Highest concentrations of all individual N and P compounds were found in the upper parts of each tributary and were attributed to loads from agricultural and urban sources to the coastal watersheds, continuing downstream to receiving estuaries. In all areas, dissolved organic N and P species were predominant constituents of the total dissolved N and P pools (64–97% and 56–93%, respectively). The lower parts of estuaries and surface shelf waters were characterized by oceanic surface values, indicating removal of N and P downstream in all tributaries. The different watershed and hydrological characteristics also determined the different speciation of N and P pools in each estuary. Despite a high level of anthropogenic pressure on the uppermost coastal waters, there is self-regulation in this coastal ecosystem with respect to human perturbations; i.e. significant amounts of the N and P load are retained within estuarine and nearshore waters without reaching the shelf.  相似文献   

13.
The mixing behaviour of iron, manganese, phosphate and humic acid in a Delaware salt marsh creek was studied using field data, laboratory mixing experiments, and geochemical mass balance equations. Property-salinity diagrams for field data indicated that the removal of iron is 56–70% in the 0–10‰ salinity range. A proposed mechanism of removal is the flocculation of colloidal iron, perhaps with humic acid. Phosphate, however, undergoes 195% addition in the same low salinity region, which may be due to release of phosphate from resuspended sediments. Dissolved manganese is conserved, as is humic acid throughout the salt marsh mixing zone. Within the uncertainty of the data the maximum possible removal of humic acid is 23%.Laboratory mixing experiments that simulated salt marsh mixing along the same salinity gradient as observed in the field (5–25‰) showed only small-scale additions and removals compared to the field results. Such small-scale changes occurred largely at salinities >10‰ in the laboratory experiments, whereas most removals and additions occurred at salinities <10‰ in the field. Mixing studies also showed little difference between prefiltered and unfiltered mixes. The studies suggest that simple mixing of salt marsh waters, with or without suspended material, does not strongly influence the observed behaviour of dissolved constituents in salt marshes, and that other processes (e.g. sediment or intertidal exchange) must dominate their behaviour.  相似文献   

14.
Human encroachment on the coastal zone has led to concern about the impact of anthropogenic nitrogen (N) on estuarine and continental shelf waters. Western North Atlantic watershed budgets suggest that the export of human-derived N from estuaries to shelf waters off the east coast of the US may be significant; however, models based on water inputs and estimates of upwelling of deepwater nutrients to surface waters of the mid-Atlantic bight indicate that estuarine N may be a relatively minor component of the overall shelf N budget. Stable N isotope ratios could provide a means to assess the relative input of anthropogenic N to shelf waters, particularly since dissolved N from human sources has elevated δ15N values (range: 7–30‰). We collected particulate material from surface shelf waters off the US east coast from 2000 to 2005 at near-shore sample sites proximal to the mouth of six estuaries and corresponding sites farther offshore. Near-shore (mean 33.7 km from estuary mouth) δ15N values ranged from 5.5 to 7.7‰ Offshore values (mean 92.4 km from estuary mouth) were consistently lower than near-shore sites (average 4.7 ± 1.0‰ versus 6.8 ± 1.1‰), suggesting different N sources to near and offshore stations. Near-shore regions are often more productive, as mean monthly chlorophyll-a concentrations from the sea-viewing wide field-of-view sensor (SeaWiFS) were significantly higher at near-shore sites near the mouth of three of the six estuaries. A mass balance using a concentration-dependent mixing model with chlorophyll-a concentrations as a surrogate for dissolved inorganic nitrogen can account for all of the nitrogen at near-shore sites south of Cape Cod with estuarine nitrogen estimated to contribute 45–85% of the nitrogen to the near-shore surface particulate material. Our results support the hypothesis that estuarine nitrogen is influencing continental shelf ecosystems, and also provide preliminary evidence of the spatial extent of its influence on shelf waters in the mid-Atlantic bight.  相似文献   

15.
目前,溶解有机碳(DOC)遥感反演研究主要集中在河口及陆源影响较大的边缘海区,大多数是利用DOC与有色溶解有机物(CDOM)或DOC与盐度的经验关系获取。为了较好的理解DOC的遥感反演机理,收集了全球主要大河(流量排名前25中16条)及边缘海DOC与CDOM浓度与保守性分布状况,发现大多数河口CDOM呈现保守性分布,DOC呈现非保守性分布。基于DOC与CDOM保守性行为的主要影响因素分析以及研究海区的生物地球化学特征,论述了DOC遥感反演算法的研究进展,提出了DOC遥感反演需要考虑DOC受不同主要控制因素(如保守混合与生物作用等)的影响,并对这些控制因素进行量化。  相似文献   

16.
DOC遥感研究进展——基于全球大河DOC与CDOM保守性特征   总被引：1，自引：1，他引：0  
潘德炉  刘琼  白雁 《海洋学报》2012,34(4):1-11
目前,溶解有机碳(DOC)遥感反演研究主要集中在河口及陆源影响较大的边缘海区,大多数是利用DOC与有色溶解有机物(CDOM)或DOC与盐度的经验关系获取。为了较好的理解DOC的遥感反演机理,收集了全球主要大河(流量排名前25中16条)及边缘海DOC与CDOM浓度与保守性分布状况,发现大多数河口CDOM呈现保守性分布,DOC呈现非保守性分布。基于DOC与CDOM保守性行为的主要影响因素分析以及研究海区的生物地球化学特征,论述了DOC遥感反演算法的研究进展,提出了DOC遥感反演需要考虑DOC受不同主要控制因素(如保守混合与生物作用等)的影响,并对这些控制因素进行量化。  相似文献   

17.
In seawater and lake water the complexation of several heavy metals, present in the dissolved state at relevant trace levels, with humic substances isolated from two marine and an estuarine sediment has been studied by differential pulse anodic stripping voltammetry (DPASV) at a hanging mercury drop electrode (HMDE). Taking Zn(II) as an example, the aim of this study was to gain direct information on the general level of importance of humic substances for the speciation of certain heavy metals in fresh and saline waters.In seawater humic acids originating from different sediments have very similar complexing properties for Zn(II), decreasing slightly in the order HAN > HAL > HAM. In lake water HAL is most efficient for complexing Zn(II), followed by HAN and HAM.In both types of natural waters, the sedimentary fulvic acid is less efficient in complexing Zn(II) than the respective humic acid from the same site. In general, the complexing efficiency decreases in the order EDTA > NTA > humic acids > fulvic acid.The problem of humic acid adsorption at the electrode, which somewhat limits the investigation of Pb(II) and Cd(II), and the impact of pH on the amount of complexed Zn(II) are also discussed.The findings provide further direct evidence for the conclusion previously drawn from existing complexation data that because of the rather low levels of dissolved humics in large parts of the oceans, the complexation efficiency of humics for Cd, Pb and Zn is too low to affect the speciation pattern of these three heavy metals.  相似文献   

18.
Historical data of total dissolved inorganic carbon (CT), together with nitrate and phosphate, have been used to model the evolution of these constituents over the year in the Atlantic water of the Norwegian Sea. Changes in nutrient concentration in the upper layer of the ocean are largely related to biological activity, but vertical mixing with the underlying water will also have an impact. A mixing factor is estimated and used to compute the entrainment of these constituents into the surface water from below. After taking the mixing contribution into account, the resulting nutrient concentration changes are attributed to biological production or decay. The results of the model show that the change in CT by vertical mixing and by biological activity based on nutrient equivalents needs another sink to balance the carbon budget. It cannot be the atmosphere as the surface water is undersaturated with respect to carbon dioxide and is, thus, a source of CT in this region. Inasmuch as the peak deficit of carbon is more than a month later than for the nutrients, the most plausible explanation is that other nitrogen and phosphate sources than the inorganic salts are used together with dissolved inorganic carbon during this period. As nitrate and phosphate show a similar trend, it is unlikely that the explanation is the use of ammonia or nitrogen fixation but rather dissolved organic nitrogen and phosphate, while dissolved organic carbon is accumulating in the water.  相似文献   

19.
The East Asian marginal seas are important sinks of terrigenous materials transported by large rivers. In this study two cores from the Changjiang (Yangtze River) and Zhujiang (Pearl River) estuaries and one core from the inner shelf off of Hong Kong were investigated to examine the burial of organic matter during the postglacial period and its possible links with paleoenvironmental changes. Based on a simple two end-member mixing model, the terrestrial organic matter supplied primarily from the Zhujiang and Changjiang dominates the estuarine areas while marine organic matter contributes more to the inner-mid shelf. The competing contributions of terrestrial and marine organic matter are responsible for the downcore variations of organic elemental compositions. The overall decreasing shifts of total organic carbon concentrations and total organic carbon to total nitrogen ratios in the Zhujiang estuarine sediments since 6.5 kaBP seems to support the notion that depth profiles of organic matter compositions deposited in the Zhujiang Estuary can aid in the reconstruction of monsoon history in the Holocene. Nevertheless, organic matter compositions in the Changjiang Estuary and inner shelf off of southeastern Hong Kong respond in a different and more complex way to freshwater discharges or precipitation changes (monsoon variability) in the catchments, owing to complex controls of deposition and preservation of organic matter in these estuarine and shelf environments. Caution is therefore needed in using organic elemental and isotopic compositions to decipher paleoenvironmental changes in East Asian continental shelves where intense river–sea interactions occur and sedimentary environments change drastically.  相似文献   

20.
The ‘dissolved’ iron (that passed through a 0·4-μm filter) varied nonconservatively with salinity in the Connecticut River estuary. However, the total iron appeared to be conservative. Measurements of Fe(II) and Fe(III) showed that oxidation of Fe(II) was not a factor in the decrease of ‘dissolved’ iron in the low salinity region. A solubility model and analyses based on different pore-size filters indicated that a substantial amount of the ‘dissolved’ iron in the low salinity region was colloidal iron. The coagulation of fine colloidal particles led to the non-conservative behavior of ‘dissolved’ iron during estuarine mixing, but it did not necessarily lead to removal of total iron from the waters. Particulate iron was 80–90% of the total iron and it covaried with the total suspended matter during mixing and sediment resuspension. The residence time of water in the Connecticut River estuary was too short to allow removal of iron from the water column within the estuary.  相似文献   

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