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1.
Re-Os Dating of Sulfides from the Volcanogenic Massive Sulfide Deposit at Gacun, Southwestern China 总被引：1，自引：0，他引：1
Abstract. The Re-Os isotopic compositions of sulfide ores were analyzed for the Gacun, a volcanogenic massive sulfide deposit in southwestern China, to constrain the timing of mineralization. Sulfide ores from the deposit have a wide range of Re and Os concentrations, varying from 80.2 to 1543.2 ppb and from 0.307 to 8.83 ppb, respectively, and yielded a limited field of high 187 Re/188 Os and high 187 Os/188Os ratios, ranging from 1452 to 3309 and from 5.77 to 13.24, respectively. All sulfide samples yielded an isochron with an age of 217±28 Ma and an initial 187 Os/188 Os ratio of around 0.52±0.73. The Re-Os isochron age agrees with ages previously constrained by the other isotopic dating of the host rocks and fossil strata for the deposit. The rhythmic variation in 187 Os/188 Os and 187 Re/188 Os ratios within massive sulfide zone records a complicated process for ore-forming fluids episodically vented into the brine pool on the Mesozoic seafloor. 相似文献
2.
半封闭硝酸溶解体系ICP-MS快速测定辉钼矿的Re-Os年龄及Re含量 总被引：4，自引：4，他引：0
Re-Os法能够直接厘定内生金属矿床成矿时代,但是封闭Carius管法化学流程复杂,且有一定的危险性。本文建立了一种简便快速测定辉钼矿Re-Os年龄及其Re含量的方法。用3 mL浓硝酸在10 mL比色管中溶解5~15 mg辉钼矿样品,将溶液中的钼酸沉淀分离后稀释定容,直接采用质谱测量187和185质量数比值(M187/M185)。利用辉钼矿Re-Os年龄标准物质JDC和HLP的M187/M185值与其年龄的正相关线性关系计算未知辉钼矿样品的Re-Os年龄,并通过185Re计数利用相对法计算Re含量。本方法应用于测量13.26~2130 Ma的辉钼矿,Re-Os年龄的测定值与推荐值的相对偏差多数在0.36%~7.42%之间,由于放射性积累较多,长年龄样品测量的准确度较高。与传统Carius管法相比,该方法不需要加入稀释剂,省去了封闭和打开Carius管环节以及Re-Os分离纯化流程,适合于辉钼矿Re-Os年龄的初步分析。 相似文献
3.
Rhenium-Osmium (Re-Os) isotopic dating applied to the geochronology of hydrocarbon accumulation has been the forefront of international research in the last 10 years and has achieved significant achievements. However, our current researches are lacking in Re-Os isotopic chronology on the geochronology of hydrocarbon accumulation. The successful application of the Re-Os geochronology has enabled the determination of accurate and precise depositional ages for Organic-Rich Sedimentary rocks (ORS), the establishment of timing constraints of oil generation or migration, and the fingerprinting of the source of oil. On the basis of literatures study both at home and abroad, this article mainly dealt with the principle of Re-Os isotopic dating and analyzed the accumulation processes of Re and Os in a seawater-sediment system. Meanwhile, the test samples, sample preparation and analytical methodology of Re-Os isotopic dating were summarized. The results revealed that the initial 187Os/188Os ratio could constrain the age of oil generation or migration, and effectively evaluated the relationship between source rock and oil. The radiogenic 187Os/188Os ratio showed a positively correlated relationship with source rock age. This article proposed that hydrocarbon mature, biodegradation and water washing had minimal or no effect on data scatter about Re-Os isochron. However, the effects of postdepositional mobility of Re and Os, variations in the initial 187Os/188Os ratio, and thermochemical sulfate reduction could result in data scatter. The reproducibility and accuracy of Re-Os age was also closely related to the sample particle size and sample amount. Compared with other isotopic dating, the biggest advantage of Re-Os isotopic dating is to study geological body related to accumulation process, and to obtain direct evidence of hydrocarbon accumulation period. From what was discussed above, the article discussed the existing problems and put forward the future hot research and development direction of Re-Os isotope system, so as to promote the deep development of relative theory and technology of Re-Os isotopic dating. 相似文献
4.
含辉钼矿全岩样品Re-Os同位素定年研究:在北京大庄科钼矿床中的应用 总被引：1，自引：1，他引：0
采用硝酸在比色管中对辉钼矿样品中Re含量进行初测的方法,测得辉钼矿标准样品JDC Re含量与推荐值在误差范围内基本一致,与传统的Carius管法相比,该方法具有简便快速的特点。传统的辉钼矿Re-Os同位素定年分析对象为辉钼矿单矿物,根据所测得的187Re/187Os值获得辉钼矿的Re-Os年龄,Re、Os在辉钼矿中大量富集,而在硅酸盐矿物中几乎没有,探索性地对含有辉钼矿的全岩样品进行Re-Os同位素定年,虽然所得Re、Os含量偏低,但187Re/187Os值不会变。该方法省去了选样过程花费的大量时间,避免了选样过程中可能造成的交叉污染。采用同位素稀释Carius管逆王水法探索性地对北京大庄科钼矿床中含辉钼矿全岩样品进行Re-Os同位素年龄测定,获得了(137.6±3.7)Ma精确的等时线年龄,与挑选出辉钼矿单矿物样品的Re-Os同位素等时线年龄(136.8±2.6)Ma吻合较好,直接厘定了大庄科钼矿的成矿时代。该年龄与矿区汉家川石英二长岩锆石U-Pb年龄一致,表明大庄科钼矿的形成与汉家川石英二长岩关系较为密切,为中国东部第二期大规模成矿作用的产物,形成于中国东部岩石圈伸展环境。 相似文献
5.
Carius管直接蒸馏快速分离锇方法研究 总被引：18，自引：10，他引：8
建立了Carius管直接蒸馏快速分离锇的方法。采用一次性的常规硅胶管和细聚四氟乙烯管来封闭Carius管及作为通气管,将常规的把样品溶液转入蒸馏瓶中进行蒸馏的方法改进为从Carius管内直接蒸馏分离锇,简化了实验流程,缩短了锇的分离时间,同时节省了大量清洗蒸馏器皿的时间及清洗试剂。用电感耦合等离子体质谱法测定铼-锇同位素的模式年龄,结果表明,通气流量为30~80 mL/min时,蒸馏30 min,对铼-锇定年标准物质GBW04435(HLP)的7次测定平均值为(221.3±0.4)Ma,标准物质GBW04436(JDC)的2次测定平均值为(139.7±0.2)Ma,分别与模式年龄的标准值(221.4±5.6)Ma、(139.6±3.8)Ma在不确定度范围内一致。方法具有批量分析样品铼-锇同位素的应用前景。 相似文献
6.
翠宏山钨钼多金属矿床是小兴安岭-张广才岭成矿带内一个重要的矽卡岩型矿床,钨、钼、锌均达大型规模。为确定该矿床的形成时代,对取自岩体内接触带钨钼矿体的7件辉钼矿样品进行了Re-Os同位素测年研究。结果表明:辉钼矿中Re质量分数为（0.376 9～0.973 7）×10-6,Os质量分数为（1.272～3.234）×10-9;获得的模式年龄为(199.0±3.1)～(203.9±3.8) Ma,加权平均年龄为（201.6±1.4）Ma(MSWD=0.80),等时线年龄为（198.9±3.7）Ma(MSWD=0.83)。结合区域成矿作用分析认为:翠宏山多金属矿床的形成时代为早侏罗世,与成矿带内的霍吉河和鹿鸣等斑岩型（细网脉型）钼矿床同属燕山早期大规模构造-岩浆-成矿事件的产物。根据本次辉钼矿Re-Os定年结果,结合前人在矿区内所测多个花岗岩体的锆石U-Pb年龄认为:与翠宏山多金属矿床具成因联系的岩体应为二长花岗岩、碱长花岗岩,成岩成矿作用与古太平洋板块俯冲有关。辉钼矿中Re质量分数、成矿岩体的物质源区综合研究表明,翠宏山多金属矿床的成岩成矿物质具有壳幔混源特征。 相似文献
7.
We present a detailed study of Re-Os age determinations for eight natural molybdenite samples of like polytype (2H), spanning a range of age, natural grain size and deposit type. The focus of the study is to critically evaluate the effects of sampling, sample preparation and aliquant size on the accuracy and reproducibility of Re-Os ages for these molybdenite samples. We find that for some molybdenite samples, analysis of small sample aliquants (<20 mg) may not yield accurate or reproducible Re-Os ages, whereas analysis of larger aliquants from the same mineral separate do yield reproducible Re-Os dates. Such an observation is best explained if Re and 187Os are internally decoupled within molybdenite grains. This finding is supported from spot analyses by laser ablation MC-ICP-MS analyses presented here and is consistent with previously published observations.The degree of decoupling between Re and 187Os appears to increase both as a function of increasing grain size, and increasing age of molybdenite. From detailed dating of individual molybdenite mineral separates, we provide approximate minimum aliquant amounts required for reproducible Re-Os age dating, as a function of molybdenite age and grain size. Geologically younger, naturally fine-grained molybdenite samples appear to show little Re and 187Os decoupling, and reproducible ages can be determined from some samples with as little as 1 mg of aliquant. Geologically old, and coarse-grained molybdenite samples may require as much as 40 mg of aliquant from a much larger mineral separate to overcome Re and 187Os decoupling. The mechanism(s) of Re and 187Os decoupling within molybdenite is not constrained by this results of this study, but the observation that the degree of decoupling increases with grain size (distance) and age (time/geologic history) may suggest primary diffusive control. Assuming that Re and 187Os decoupling in molybdenite results primarily from diffusion of 187Os, apparent diffusion coefficients are calculated (D = x2/t). Estimates of D for Os made in this way range from 2.8 × 10−26 to 2.1 × 10−21 m2/s, which are broadly similar to experimentally derived diffusion coefficients for Os in Fe-sulfide minerals and for Re in molybdenite at temperatures <500°C. 相似文献
8.
The geochemistry of Re-Os and the recent use of Re as a non-traditional stable isotope both need accurate and precise quantification of 187 Re/185 Re ratios. This paper reports rhenium isotopic data obtained from the analysis of a standard solution and geological samples by MC-ICP-MS. We show that measured isotopic ratios are modified by matrix effects that cannot be accounted for by the standard solution bracketing technique. The bias resulting from measurements on a spiked (185 Re-enriched) sample is shown to alter the apparent Re concentration by several percent. When spiking samples and calibrators with tungsten, simultaneous measurement of tungsten and rhenium isotopes compensates for the matrix-induced modification of mass bias. Rhenium and tungsten are shown to have different fractionation factors. This may be due to the fact that the two elements fractionate in a different but systematic way, or that the reference isotopic ratios used for elemental Re and W are incoherent with one another. The consistency of fractionation through time can be used to obtain an empirical relationship between W and Re measured ratios from a standard solution to obtain a sample's fractionation-corrected 187 Re/185 Re spiked ratio on samples containing pg g−1 levels of Re, even if some matrix capable of affecting mass bias remains in the final solution. 相似文献
9.
辉钼矿Re-Os同位素定年方法的改进与应用 总被引：13，自引：9，他引：4
公认的Re-Os同位素定年代表物辉钼矿,目前已在金属硫化物矿床年代学研究领域获得了广泛的应用。本研究采用浓HNO3分解辉钼矿样品,大大地简化了Re和Os的化学制备过程,并根据辉钼矿中正常Os含量水平相对放射成因187Os可以忽略的特点,以正常Os标准为稀释剂,实现了仪器测量过程中Os同位素质量分馏的在线校正,改善了分析数据的质量。该方法经辉钼矿国家标准物质进行验证,获得了满意的Re、Os含量及Re-Os年龄数据,并且在南岭地区与连阳复式岩体相关的姓坪夕卡岩型钼矿床成矿年龄研究中获得了成功应用。在实际应用中,为了获得有意义的能反映真实地质事件的年龄数据,辉钼矿样品不仅要有足够的取样量,而且还要保证粒度细、混合均匀。 相似文献
10.
河北省安妥岭钼矿床地质特征及辉钼矿Re-Os同位素年龄 总被引：1，自引：0，他引：1
河北省安妥岭钼矿床位于太行山北段,是燕辽钼矿带内著名的钼矿床之一。辉钼矿化呈脉状、薄膜状、浸染状分布于斑岩体及其外接触带中,围岩蚀变为硅化、黄铁矿化、绢云母化、黄铁绢英岩化、青磐岩化等,具有斑岩型钼矿床的基本特征。对矿床中5件辉钼矿样品进行了Re-Os同位素分析,获得模式年龄为(145.7±2.4)～(148.8±2.6) Ma,平均模式年龄为(146.9±1.0) Ma,等时线年龄为(147.3±3.7) Ma,MSWD值为1.5, 187Os初始值为(-0.4±2.6) ng/g,表明钼成矿时代为晚侏罗世,属燕山中晚期构造-岩浆-流体活动的产物。样品Re含量为50.42×10-6～104.9×10-6,黄铁矿单矿物δ34S的变化范围为0.7‰～2.8‰,结合已有的Pb同位素结果,推断成矿物质为壳幔混源,矿床形成于中国北方中生代第二期大规模成矿作用期,处于中国东部构造体制转折阶段。 相似文献
11.
大颗粒辉钼矿Re-Os同位素失耦现象及187Os迁移模式研究 总被引：10，自引：4，他引：6
对采自西华山钨矿的大颗粒辉钼矿样品的不同部位进行了取样,并对其年龄分别进行精确厘定,得到了不同的Re-Os模式年龄值,验证了失耦现象的存在.从原理上对失耦现象及其成因进行了解释,并在前人成果的基础上,探索性地提出了187Os可能的迁移模型.取样方式的不同会对辉钼矿的模式年龄产生很大影响,因此,在实际应用中一定要严格遵循"多取样,细磨碎"的原则,这对于能获得科学真实的与地质背景相符的Re-Os同位素地质年龄,从而深入探讨矿床成矿作用具有重要意义. 相似文献
12.
Re-Os同位素定年方法进展及ICP-MS精确定年测试关键技术 总被引：8，自引：0，他引：8
本文介绍了Re-Os同位素定年的基本原理、技术发展及应用现状;综述了样品分解和Re-Os分离富集的主要方法,重点对ICP-MS法进行Re-Os同位素定年做了较详尽的介绍,包括质量分馏校正、干扰校正、含量初测、取样量的确定、稀释剂的稀释比及稀释剂加入量等,以确保高精度测试;评述了ICP-MS最常见的测定对象-辉钼矿中Re-Os的失耦现象及降低其对Re-Os同位素定年影响的对策,文中描述了由测定同位素比值计算含量时的误差传递公式并重申了最佳稀释比。最后,指出了Re-Os同位素定年方法研究中应该关注的工作方向。 相似文献
13.
Tarun K. Dalai Katsuhiko Suzuki Masao Minagawa Yoshiyuki Nozaki 《Chemical Geology》2005,220(3-4):303-314
Concentrations of Re and Os, and the isotopic composition of Os have been measured in the Japan Sea sediments to assess the response of the Japan Sea to glacial–interglacial climate change and associated weathering fluxes. The osmium concentrations in the sediment samples analyzed vary from 59 to 371 pg/g, and 187Os/188Os from 0.935 to 1.042. Only 187Os/188Os of sediment samples from dark laminations deposited under suboxic to anoxic conditions and having elevated concentrations of Re and Os, and with ≥ 80% hydrogenous Os are explained in terms of seawater composition. Lower 187Os/188Os were observed for sediments deposited during the last glacial maximum (LGM) when planktonic foraminifera from the Japan Sea recorded lighter oxygen isotopic composition. Decrease in dissolved Os fluxes from continents and/or change in the composition of the dissolved load to the Japan Sea are suggested as the driving mechanisms for the observed lower LGM 187Os/188Os. The results of this study, coupled with lower 187Os/188Os during the last glacial observed at other sites from ocean basins with different lithology and contrasting sediment accumulation rates, suggest that this trend is characteristic of the global oceans.
Data from this study show that the Japan Sea recorded higher 187Os/188Os during the current interglacial coinciding with excursions of oxygen isotopic compositions of planktonic foraminifera to heavier values. This is explained in terms of preferential release of 187Os during deglacial weathering and/or higher continental Os flux driven by warm and wet climate. This study demonstrates that Os isotopic composition of reducing margin sediments has immense potential to track variations in the seawater composition. In addition, 187Os/188Os of reducing sediments may be used to draw inferences about local paleoceanographic processes in semi-enclosed basins such as the Japan Sea. 相似文献
14.
含有普通锇的辉钼矿Re-Os同位素定年研究 总被引：14，自引：3，他引：11
通过大量数据统计,表明较高比例的辉钼矿中存在普通锇。普通锇可能以类质同像形式存在于辉钼矿样品中,理论上辉钼矿中可能含有较高含量普通锇。辉钼矿样品含有较高含量普通锇可能对Re-Os定年结果产生很大影响,从原理上并结合实例证实了普通锇含量对辉钼矿Re-Os年龄影响程度。对于一般辉钼矿样品来讲,如果187Os总量(放射成因187Os与非放射成因187Os之和)与普通锇比值小于20,需要考虑普通锇对Re-Os模式年龄的影响,并提出了对于含有普通锇辉钼矿模式年龄的计算方法。先做出187Os/188Os-187Re/188Os等时线,求得初始187Os/188Os值,再根据初始187Os/188Os值和单个样品的普Os含量求得非放射成因的普Os中187Os的量。最后根据Re含量以及放射成因187Os含量得到模式年龄。 相似文献
15.
A double spike for osmium analysis of highly radiogenic samples 总被引：1，自引：0，他引：1
Richard Markey Judith L. Hannah John W. Morgan Holly J. Stein 《Chemical Geology》2003,200(3-4):395-406
Geologic samples containing highly radiogenic Os (molybdenites and low-level, highly radiogenic (LLHR) samples) have no internal means by which to correct for mass fractionation during isotopic measurement by mass spectrometry. We describe a double spike for use with highly radiogenic samples, created by combining isotopically enriched 188Os and 190Os. Spiking molybdenite and other highly radiogenic minerals with this tracer allows for a fractionation correction, as well as a more reliable determination of common Os relative to analysis using single spikes.
The precise isotopic composition of the double spike is determined by a calibration against natural Os, in which two separate measurements are necessary: one each for the pure double spike and the spike–standard mixture. An estimate of the true composition of the spike is obtained by least squares approximation, and the errors are obtained by Monte Carlo methods. Sample analyses are then much more straightforward than the calibration because isotopic compositions of all components are known a priori.
Results obtained with a mixed Re-double Os spike demonstrate an improved reproducibility over individual 185Re and 190Os spikes. For an Archean in-house molybdenite standard we now observe a reproducibility of 0.08%. The ability to make a fractionation correction is essential for Os measurements made by ion counting. With the double Os spike, young samples and those with low Re contents (i.e., LLHR) can now be accurately analyzed. The 188Os–190Os double spike also allows a determination of the common Os contents of highly radiogenic samples. Common Os is poorly determined for ancient samples with high concentrations of 187Os, which fortunately are not sensitive to estimates of common Os. Common Os can be reasonably well determined for younger samples and those with low Re contents. We report a common Os concentration of 0.4±0.1 ppb for an 11 Ma molybdenite. Consideration of common Os content is important for age determination of young samples and LLHR samples, and is not possible by other published means of Os analysis. 相似文献
16.
Re-Os同位素定年在石油生成及富有机质沉积岩的绝对定年方面取得了良好的应用效果,并且石油的Os同位素初始值还可以作为油源示踪的指标。分析了Re-Os同位素定年方法在富有机质体系中应用的原理,探讨了影响同位素体系封闭性的各种因素,指出熟化作用、生物降解及水洗作用、脱沥青作用不会影响Re-Os同位素体系的封闭性,而硫酸盐热化学还原作用、成矿流体作用及幔源岩浆混染会扰动Re-Os同位素体系。目前石油系统中Re-Os同位素研究存在的主要问题可归结为2个方面:1石油系统有机质中Re-Os同位素的地球化学行为;2Re-Os同位素年龄的精度及其指示意义。对于这2个方面,开展有机相及现代海藻与Re-Os同位素相关性的研究将有助于了解Re和Os在有机质中的具体富集形式;对控制Re-Os同位素分馏的因素(如沉积环境及有机质类型)的研究将会有助于鉴别哪些地层以及什么样的样品能用来进行Re-Os定年。 相似文献
17.
Measurement of SIMS Instrumental Mass Fractionation of Pb Isotopes During Zircon Dating 总被引：8，自引：0，他引：8
Richard A. Stern Simon Bodorkos Sandra L. Kamo Arthur H. Hickman Fernando Corfu 《Geostandards and Geoanalytical Research》2009,33(2):145-168
An igneous zircon reference material (OG1) was characterised for U-Pb isotopes by ID-TIMS, and utilised to evaluate SIMS (SHRIMP) instrumental mass fractionation (IMF) of radiogenic Pb isotopes (207 Pb*/206 Pb*). The TIMS 207 Pb*/206 Pb* reference value for OG1 was 0.29907 ± 0.00011 (95% confidence limit), 3465.4 ± 0.6 Ma. The high 207 Pb* (∼ 30 μg g−1 ), negligible common Pb, and isotopic homogeneity permitted precise (± 1–2‰) 207 Pb*/206 Pb* measurements within the analytical sessions. External reproducibility of mean 207 Pb*/206 Pb* ratios between sessions was demonstrated for one instrument, yielding a mean IMF of +0.87 ± 0.49‰. The mean 207 Pb*/206 Pb* ratios between instruments were dispersed beyond uncertainties, with session IMF values from +3.6 ± 1.7‰ to −2.4 ± 1.3‰, and a grand mean IMF value (twenty-six sessions) of +0.70 ± 0.52‰, indicating a tendency towards elevated 207 Pb*/206 Pb*. The specific causes of variability in IMF are unclear, but generally reflect subtle differences in analytical conditions. The common practice in SIMS of assuming that IMF for Pb+ is insignificant could result in systematic age biases and underestimated uncertainties, of critical importance for precise correlation of Precambrian events. Nevertheless, a zircon RM such as OG1 can be readily incorporated into routine dating to improve 207 Pb*/206 Pb* accuracy and external reproducibility. 相似文献
18.
Reproducibility of Re-Os molybdenite ages depends on sample size and homogeneity, suggesting that Re and Os are decoupled within individual molybdenite crystals and do not remain spatially linked over time. In order to investigate the Re-Os systematics of molybdenite at the subgrain (micron) scale, we report LA-ICP-MS Re-Os ages for an Archean molybdenite crystal from Aittojärvi, Finland, analyzed in situ in a white aplite matrix. A related Aittojärvi molybdenite (A996D), in the form of a very fine-grained mineral separate, is used as one of our in-house NTIMS standards, and thus its age of 2760 ± 9 Ma is well established. Measurements of (187Re + 187Os)/185Re on micron scale spots along 200 μm traverses across the crystal yield a wide range of ages demonstrating that, in this case, microsampling of molybdenite does not produce geologically meaningful ages. Experimentation with mineral separations and sample size over a 7-yr period predicted that this would be the outcome. We suggest that 187Os is more likely to be the mobile species, based on its charge and ionic radius, and that 187Os becomes decoupled from parent 187Re with time on the micron and larger scale. Incompatible charge and ionic radius for Os ions formed during reduction of molybdenite-forming fluids may explain the widely observed absence of common (initial) Os in molybdenite. Geologically accurate ages for molybdenite can only be obtained for fully homogenized crystals (or crystal aggregates) so that any post-crystallization 187Re-187Os decoupling is overcome.A growing number of geologically accurate ID-NTIMS 187Re-187Os ages for homogenized molybdenite suggest that postcrystallization mobility of radiogenic 187Os must be limited to within the molybdenite mineral phase. We suggest that radiogenic 187Os may be stored in micron scale dislocations, kink bands, and delamination cracks produced by deformation, and that the unusual structure and deformation response of molybdenite results in an increased chemical stability in this mineral. Migration of 187Os into adjacent silicate phases is highly unlikely, but other contacting sulfides may take in Os. In an example from a Proterozoic skarn deposit at Pitkäranta (western Russia), we demonstrate minor loss of radiogenic 187Os from molybdenite and a corresponding gain in adjacent chalcopyrite such that the molybdenite age is not perceptibly disturbed, whereas the resulting chalcopyrite ages are impossibly old. Therefore, it is unadvisable to perform Re-Os analytical work on any sulfide in contact or intimate association with molybdenite. In addition to large errors in the age, if the isochron method is employed, initial 187Os/188Os ratios could be erroneously high, leading to seriously errant genetic interpretations. 相似文献
19.
Proterozoic melting in the northern peridotite Massif, Zabargad Island: Os isotopic evidence 总被引：1，自引：0，他引：1
The geodynamic history of the three Zabargad peridotite bodies is the key to their significance as samples of the upper mantle. Currently, there are two main hypotheses that differ greatly in their implications for the origin and age of the peridotite complex as a whole. In the first, the Zabargad peridotite bodies all represent young asthenospheric mantle that was juxtaposed with ancient crustal gneisses during the opening of the Red Sea. In the second, the complex may represent a single package of residual mantle and lower crust of Pan-African age that was uplifted during the Miocene. In order to distinguish between these two models, we have analysed five samples of Zabargad peridotite and two pyroxenites for Os isotopes. The 187 Os/188 Os results range from 0.1198 to 0.1320 and correlate with Al2 O3 , allowing an age inference for the northern body, based on the Os isotopic evolution curve for the bulk Earth, of 1.4±0.3 Gyr. This is at least as old as the previously inferred Pan-African age and may be older, and agrees with previous suggestions that the northern and central peridotite bodies probably represent ancient continental lithospheric mantle, while the southern body represents recent asthenospheric mantle. Our results from both central and southern bodies are consistent with either crustal age hypothesis. 相似文献
20.
铼-锇同位素测年法研究综述 总被引：1，自引：0，他引：1
Re-Os同位素测年的最合适的对象为辉钼矿,定年是基于放射性的187Re通过β衰变成为187Os而引起锇同位素异常来计算地质年代的。在目前的测试研究中,较常用的方案为Carius管溶样法-蒸馏分离Os-萃取分离Re-TJA PQ ExCell ICPMS测定同位素比值。在我国有许多成功用Re-Os同位素测定钼矿床成矿年龄的范例,对认识矿床特征及成因、总结区域的成矿演化规律、解决相关地质问题具有重要的理论意义,而且对于指导矿床的预测和勘查具有很高科学价值。 相似文献