Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

Modeling spatially non-stationary land use/cover change in the lower Connecticut River Basin by combining geographically weighted logistic regression and the CA-Markov model   总被引：2，自引：0，他引：2  

Hui Wang  Scott R. Stephenson  Shijin Qu 《International journal of geographical information science》2019,33(7):1313-1334

Simulating land use/cover change (LUCC) and determining its transition rules have been a focus of research for several decades. Previous studies used ordinary logistic regression (OLR) to determine transition rules in cellular automata (CA) modeling of LUCC, which often neglected the spatially non-stationary relationships between driving factors and land use/cover categories. We use an integrated geographically weighted logistic regression (GWLR) CA-Markov method to simulate LUCC from 2001–2011 over 29 towns in the Connecticut River Basin. Results are compared with those obtained from the OLR-CA-Markov method, and the sensitivity of LUCC simulated by the GWLR-CA-Markov method to the spatial non-stationarity-based suitability map is investigated. Analysis of residuals indicates better goodness of fit in model calibration for geographically weighted regression (GWR) than OLR. Coefficients of driving factors indicate that GWLR outperforms OLR in depicting the local suitability of land use/cover categories. Kappa statistics of the simulated maps indicate high agreement with observed land use/cover for both OLR-CA-Markov and GWLR-CA-Markov methods. Similarity in simulation accuracy between the methods suggests that the sensitivity of simulated LUCC to suitability inputs is low with respect to spatial non-stationarity. Therefore, this study provides critical insight on the role of spatial non-stationarity throughout the process of LUCC simulation.  相似文献   

微生物勘探技术在潮汕坳陷油气勘探中的应用初探     

赵忠泉  孙鸣  万晓明  陈胜红  赵静  宋立军  李辉  强昆生  梁永兴 《中国地质》2020,47(3):645-654

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。  相似文献   

Numerical Simulation on Flow Past Two Side-by-Side Inclined Circular Cylinders at Low Reynolds Number     

Liu  Cai  Gao  Yang-yang  Qu  Xin-chen  Wang  Bin  Zhang  Bao-feng 《中国海洋工程》2019,33(3):344-355

A series of three-dimensional numerical simulations is carried out to investigate the effect of inclined angle on flow behavior behind two side-by-side inclined cylinders at low Reynolds number Re=100 and small spacing ratio T/D=1.5 (T is the center-to-center distance between two side-by-side cylinders, D is the diameter of cylinder). The instantaneous and time-averaged flow fields, force coefficients and Strouhal numbers are analyzed. Special attention is focused on the axial flow characteristics with variation of the inclined angle. The results show that the inclined angle has a significant effect on the gap flow behaviors behind two inclined cylinders. The vortex shedding behind two cylinders is suppressed with the increase of the inclined angle as well as the flip-flop gap flow. Moreover, the mean drag coefficient, root-mean-square lift coefficient and Strouhal numbers decrease monotonously with the increase of the inclined angle, which follows the independent principle at small inclined angles.

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Differential physiological responses of the coastal cyanobacterium <Emphasis Type="Italic">Synechococcus</Emphasis> sp. PCC7002 to elevated <Emphasis Type="Italic">p</Emphasis>CO<Subscript>2</Subscript> at lag,exponential, and stationary growth phases     

Shanli Mou  Gang Li  Hongmei Li  Fazhong Li  Zhisheng Shao  Jinsong Li  Changfeng Qu  Yongyu Zhang 《中国科学:地球科学(英文版)》2018,61(10):1397-1405

We studied the effects of expected end-of-the-century pCO₂ (1000 ppm) on the photosynthetic performance of a coastal marine cyanobacterium Synechococcus sp. PCC7002 during the lag, exponential, and stationary growth phases. Elevated pCO₂ significantly stimulated growth, and enhanced the maximum cell density during the stationary phase. Under ambient pCO₂ conditions, the lag phase lasted for 6 days, while elevated pCO₂ shortened the lag phase to two days and extended the exponential phase by four days. The elevated pCO₂ increased photosynthesis levels during the lag and exponential phases, but reduced them during the stationary phase. Moreover, the elevated pCO₂ reduced the saturated growth light (Ik) and increased the light utilization efficiency (α) during the exponential and stationary phases, and elevated the phycobilisome:chlorophyll a (Chl a) ratio. Furthermore, the elevated pCO₂ reduced the particulate organic carbon (POC):Chl a and particulate organic nitrogen (PON):Chl a ratios during the lag and stationary phases, but enhanced them during the exponential phase. Overall, Synechococcus showed differential physiological responses to elevated pCO₂ during different growth phases, thus providing insight into previous studies that focused on only the exponential phase, which may have biased the results relative to the effects of elevated pCO₂ in ecology or aquaculture.  相似文献   

Study on the Anisotropy of the Underground Medium in Hohhot     

Zhang Hui  Zhai Hao  Han Xiaoming 《中国地震研究》2018,32(1):80-88

In this paper, the data of earthquake events of magnitude M_S6.0 and above produced in Hohhot Seismic Station from 2008 to 2015 and the data of M_L ≥ 1.0 seismic events from 2015 to 2016 in Horinger Seismic Station and the surrounding mobile stations in southern Hohhot are selected. Using Splitlab and SAM software, the spin-correlation method, the least-energy method and the cross-correlation coefficient method are used to analyze the teleseismic and near-seismic phases (SKS, S). The results of this study are in good agreement with the results previously obtained by other researchers. The study of teleseismic SKS splitting reflects the characteristics of the anisotropy of the upper mantle beneath Hohhot, that is, the anisotropy of the upper mantle shows NW, which reflects "fossil" Anisotropy, mainly in the continental structure of stable units and preserves the history of mantle deformation information. The crustal anisotropy reflected by the near-earthquake S-wave splitting study is similar to that of the active fault zone, trending NE as a whole and is consistent with the tectonic stress field background of the northeastern margin of Ordos block.  相似文献   

Focal Mechanism and Focal Depth of the May 22, 2016 MS4.6 Earthquake in Chaoyang, Liaoning     

Zhao Xing  Zhang Fan  Han Xiaoming  Wang Shubo  Wei Jianmin 《中国地震研究》2018,32(1):100-112

An earthquake with M_S4.6 occurred at 17:08 p.m., May 22, 2016 in Chaoyang County, Liaoning Province. We used the P-wave first motion method, TDMT method, and CAP method to determine the focal mechanisms and the PTD method and sPn-Pn method to determine the focal depth. The focal mechanism results of the three methods are consistent. The depth results of the CAP method, PTD method and sPn-Pn method are close. We used the double difference location method to relocate earthquakes in 2009-2016, and obtained the strikes and dip angles of the small earthquake distributions with the help of simulated annealing algorithm and gauss Newton algorithm fitting. According to the focal mechanism results, the depth results, the characteristics of small earthquake distributions and the structural characteristics of the source area, the seismogenic fault strike is NEE and the main pressure force direction is NNW. The earthquake focal mechanism is for a normal fault type with a little left-lateral strike slip motion.  相似文献   

An acoustic-wave theory for casing bond evaluation using viscoelastic slip boundary modeling     

Xiaoming Tang  Can Jiang  Yuanda Su  Xuelian Chen 《中国科学:地球科学(英文版)》2018,61(8):1057-1064

Slip boundary condition is commonly utilized to model elastic wave propagation through layered earth media. The same approach is used here to characterize acoustic wave propagation along a cased borehole with various cement bond conditions. By modeling the cement layer between casing and formation as a viscoelastic slip interface with complex coupling rigidity parameters, one can not only reduce the complexity in the classical elastic wave modeling of the problem, but also efficiently model various complicated wave phenomena that are difficult for the existing modeling. More specifically, the new theory can well describe the effect of the cement bond condition change and the location of the change (i.e., whether it is in the first interface between casing and cement, or the second interface between cement and formation) on the acoustic waves, demonstrating the good modeling capability and predicting power. Application of the theory to field data shows that the theory can correctly model the acoustic wave characteristics and interpret the cement bond condition, thus providing a useful fundament theory for casing bond evaluation using acoustic logging.  相似文献   

中国银行业基层网点的空间演化机制     

姚晓明  朱晟君 《地理研究》2020,39(2):384-398

中国银行业改革持续深化,不同类型银行的业务限制和地域限制逐步取消,银行间竞争日益激烈,重新调整网点布局已成为各家银行应对措施之一。重点关注2007—2016年中国银行业基层网点的空间演化路径,在借鉴演化经济地理研究中产业关联思想的基础上,提出地方产业基础的金融关联度和区域间投资的金融关联度两个重要变量,以此构建解释框架。考虑到中国银行业渐进式的改革历程,按银行所有制及银行规模分组进行比较分析。研究发现：① 地方银行市场竞争越激烈会显著提升产业基础、投资流向的金融关联度在银行网点布局决策中的重要性,银行网点会向金融关联度高的地区集聚;② 各影响因素的作用机制随地方银行市场环境和银行成长过程发生变化,表现出阶段性特征;③ 银行的个体异质性也是影响银行网点空间演化路径的因素之一。  相似文献   

包兰铁路沙坡头段不同编制结构的枝条阻沙栅栏防护效应风洞模拟     

康文岩  王立  屈建军  卢琴春 《中国沙漠》2020,40(2):94-99

对包兰铁路沙坡头段枝条阻沙栅栏流场结构进行风洞模拟试验。结果表明:气流在经过横向、竖向阻沙栅栏时均出现了明显的流速分区。气流在经过阻沙栅栏时速度会减弱,但是竖向枝条阻沙栅栏的综合阻风防沙效果明显优于横向阻沙栅栏,同时竖向枝条阻沙栅栏制作上具有工序简单、原材料广泛及不受枝条长度限制的特性,因此,在防沙治沙应用中,竖向枝条阻沙栅栏更适合推广。虽然孔隙度是阻沙栅栏设计的重要技术参数,但栅栏结构对风沙流场产生直接影响,是决定着其对风沙活动防护效应高低的关键因子。  相似文献