Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

微生物勘探技术在潮汕坳陷油气勘探中的应用初探     

赵忠泉  孙鸣  万晓明  陈胜红  赵静  宋立军  李辉  强昆生  梁永兴 《中国地质》2020,47(3):645-654

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。  相似文献   

航空重力垂直梯度探测潜艇方法研究     

张志强  郑晗  崔银锋 《海洋测绘》2019,39(4):6-9

航空重力梯度测量属于被动探测,抗干扰能力强,如果能和其他探潜手段相配合将极大地提高航空搜潜的效率。针对航空重力梯度测量是否能够用于探测潜艇的问题,依据俄亥俄级弹道导弹核潜艇的结构特点,建立了适用于重力梯度计算的潜艇模型,分别给出了潜艇外壳、内部质量亏损产生的重力垂直梯度的计算方法,并对不同精度重力梯度仪可探测的潜艇重力垂直梯度值进行了计算,从航空反潜的角度对探测潜艇效果进行了分析。经计算表明,如航空重力梯度仪精度达到10~(-2) E,将具备一定的实际探潜效能;如精度达到10~(-4) E,反潜机搜索宽度可与现有航空磁性探潜相当。  相似文献   

The Influence of Two Kinds of El Niño Events on the Strong Tropical Cyclone Generation and Strength in the Pacific Ocean     

Xingchi Wang  Shuzong Han  Xin Wang  Yujie Dong 《中国海洋大学学报(英文版)》2018,17(5):1011-1018

This paper focuses on the effects of two types of El Niño events on tropical cyclone activity. We classified El Niño events from 1961 to 2015 according to their sea surface temperature (SST) anomalies into an eastern type and a central type. Then we selected strong tropical cyclones to statistically analyze the tropical cyclone characteristics during different events and their effects, as well as to study the possible mechanisms related to thermodynamic and dynamic factors. The tropical cyclone generation areas were found to be very similar during the two kinds of events. The average number of tropical cyclone in the eastern event is more than that in central event, and the hurricane in northeastern Pacific (HNP) has more energy than the typhoon in northwestern Pacific (TNP) in all cases. The seasonal distribution of the TNP high-incidence centers during central El Niño events is opposite to that of the HNP. The TNP accumulated cyclone energy (ACE) intensity is similar in the fall and summer, and the HNP ACE intensity in the summer is greater than that in the fall. The SSTs are consistent with the TNP and HNP movement trends. The Walker circulation intensity was strongly affected by the eastern events, but it quickly returned to its normal state, while the intensity was slightly reduced in the central events, and it slowly returned to its normal state. The vertical velocity distributions in the Pacific are different at different stages of both events, and the distributions of vertical velocity anomalies for typhoons and hurricanes are consistent.  相似文献   

中国银行业基层网点的空间演化机制     

姚晓明  朱晟君 《地理研究》2020,39(2):384-398

中国银行业改革持续深化,不同类型银行的业务限制和地域限制逐步取消,银行间竞争日益激烈,重新调整网点布局已成为各家银行应对措施之一。重点关注2007—2016年中国银行业基层网点的空间演化路径,在借鉴演化经济地理研究中产业关联思想的基础上,提出地方产业基础的金融关联度和区域间投资的金融关联度两个重要变量,以此构建解释框架。考虑到中国银行业渐进式的改革历程,按银行所有制及银行规模分组进行比较分析。研究发现：① 地方银行市场竞争越激烈会显著提升产业基础、投资流向的金融关联度在银行网点布局决策中的重要性,银行网点会向金融关联度高的地区集聚;② 各影响因素的作用机制随地方银行市场环境和银行成长过程发生变化,表现出阶段性特征;③ 银行的个体异质性也是影响银行网点空间演化路径的因素之一。  相似文献   

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究          下载免费PDF全文

常俊男  田晓清  樊成奇  黄金昌  陆亚男  韩清华 《极地研究》2020,32(1):60-67

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。  相似文献   

Influence of Stress on Void Ratios of Compacted Crushed Rock Masses in Coal Mine Gobs     

Hu  Shengyong  Han  Dandan  Feng  Guorui  Zhang  Ao  Hao  Guocai  Hu  Lanqing  Zhu  Liping  Li  Bo 《Natural Resources Research》2020,29(2):1361-1373

The transfer and evolution of stress among rock blocks directly change the void ratios of crushed rock masses and affect the flow of methane in coal mine gobs. In this study, a Lagrange framework and a discrete element method, along with the soft-sphere model and EDEM numerical software, were used. The compaction processes of rock blocks with diameters of 0.6, 0.8, and 1.0 m were simulated with the degrees of compression set at 0%, 5%, 10%, 15%, 20%, and 25%. This study examines the influence of stress on void ratios of compacted crushed rock masses in coal mine gobs. The results showed that stress was mainly transmitted downward through strong force chains. As the degree of compression increased, the strong force chains extended downward, which resulted in the stress at the upper rock mass to become significantly higher than that at the lower rock mass. It was determined that under different degrees of compression, the rock mass of coal mine gobs could be divided, from the bottom to the top, into a lower insufficient compression zone (ICZ) and an upper sufficient compression zone (SCZ). From bottom to top, the void ratios in the ICZ sharply decreased and those in the SCZ slowly decreased. Void ratios in the ICZ were 1.2–1.7 times higher than those in the SCZ.

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南极半岛邻近海域夏季POC分布特征及其影响因素          下载免费PDF全文

张一成  韩正兵  杨洋  潘建明  张海峰  李栋  赵军  朱秋红  范高晶  张海生 《极地研究》2020,32(1):47-59

海水中的颗粒有机碳(POC)与生物的生命过程、初级生产力关系密切,是海洋食物链中重要的物质基础和能量来源,因此POC的分布特征可以有效反映其生物地球化学环境。利用中国第33次南极考察期间(2016年12月至2017年1月)在南极半岛邻近海域采集的海水颗粒物样品,研究POC的空间分布特征及其影响因素。结果表明,斯科舍海0—200 m的POC浓度范围为7.44—193.52μg·L~(-1),平均浓度为(48.84±35.09)μg·L~(-1);南斯科舍海岭0—200 m的POC浓度范围为9.13—62.17μg·L~(-1),平均浓度为(29.76±14.12)μg·L~(-1);鲍威尔海盆0—200 m的POC浓度范围为5.87—270.72μg·L~(-1),平均浓度为(48.57±38.92)μg·L~(-1)。表层POC高值出现在斯科舍海区和鲍威尔海盆区,而低值出现在海岭区,与叶绿素a(Chla)的变化趋势一致,与营养盐的变化趋势相反。垂向分布上,各个区域POC平均浓度随深度的增加而减少,鲍威尔海盆和斯科舍海POC最高值都出现在25 m层。分析结果表明光合浮游植物是研究海域POC的主要来源, POC的主要影响因素为温度、水团混合以及海冰环境。斯科舍海与鲍威尔海盆整体非生命POC占比高,可能是由于高磷虾生物量、海冰碎屑以及陆源输入的干扰;南斯科舍海岭整体非生命POC占比低。  相似文献   

全球粮食安全格局的时空演化     

蔡建明  马恩朴  林静  廖柳文  韩燕 《地理学报(英文版)》2020,30(2):179-196

Food security is the primary prerequisite for achieving other Millennium Development Goals(MDGs).Given that the MDG of“halving the proportion of hungers by 2015”was not realized as scheduled,it will be more pressing and challenging to reach the goal of zero hunger by 2030.So there is high urgency to find the pattern and mechanism of global food security from the perspective of spatio-temporal evolution.In this paper,based on the analysis of database by using a multi-index evaluation method and radar map area model,the global food security level for 172 countries from 2000 to 2014 were assessed;and then spatial autocorrelation analysis was conducted to depict the spatial patterns and changing characteristics of global food security;then,multi-nonlinear regression methods were employed to identify the factors affecting the food security patterns.The results show:1)The global food security pattern can be summarized as“high-high aggregation,low-low aggregation”.The most secure countries are mainly distributed in Western Europe,North America,Oceania and parts of East Asia.The least secure countries are mainly distributed in sub-Saharan Africa,South Asia and West Asia,and parts of Southeast Asia.2)Europe and sub-Saharan Africa are hot and cold spots of the global food security pattern respectively,while in non-aggregation areas,Haiti,North Korea,Tajikistan and Afghanistan have long-historical food insecurity problems.3)The pattern of global food security is generally stable,but the internal fluctuations in the extremely insecure groups were significant.The countries with the highest food insecurity are also the countries with the most fluctuated levels of food security.4)The annual average temperature,per capita GDP,proportion of people accessible to clean water,political stability and non-violence levels are the main factors influencing the global food security pattern.Research shows that the status of global food security has improved since the year 2000,yet there are still many challenges such as unstable global food security and acute regional food security issues.It will be difficult to understand these differences from a single factor,especially the annual average temperature and annual precipitation.The abnormal performance of the above factors indicates that appropriate natural conditions alone do not absolutely guarantee food security,while the levels of agricultural development,the purchasing power of residents,regional accessibility,as well as political and economic stability have more direct influence.  相似文献   

黄渤海带鱼(Trichiurus lepturus)渔业生物学参考点估计研究     

纪毓鹏  刘群  廖宝超  张清清  韩亚楠 《海洋学报(英文版)》2019,38(10):20-26

It is important to find a reliable method to estimate maximum sustainable yield(MSY) or total allowable catch(TAC) for fishery management, especially when the data availability is limited which is a case in China. A recently developed method(CMSY) is a data-poor method, which requires only catch data, resilience and exploitation history at the first and final years of the catch data. CMSY was used in this study to estimate the biological reference points for Largehead hairtail(Trichiurus lepturus, Temminck and Schlegel) in the Yellow Sea and Bohai Sea, based on the fishery data from China Fishery Statistical Year Books during 1986 to 2012. Additionally,Bayesian state-space Schaefer surplus production model(BSM) and the classical surplus production models(Schaefer and Fox) performed by software CEDA and ASPIC, were also projected in this study to compare with the performance of CMSY. The estimated MSYs from all models are about 19.7×104–27.0×104 t, while CMSY and BSM yielded more reasonable population parameter estimates(the intrinsic population growth rate and the carrying capacity). The biological reference points of B/BMSY smaller than 1.0, while F/FMSY higher than 1.0 revealed an over-exploitation of the fishery, indicating that more conservative management strategies are required for Largehead hairtail fishery.  相似文献