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粤中三水盆地长坑赋金硅质岩主要呈层状分布于下石炭统梓门桥组生物碎屑灰岩与上三叠统碳质泥岩（或下石炭统梓门桥组粉砂岩）之间,厚度1—50m,主要由层状、块状及角砾状硅质岩组成。金矿主要呈细脉浸染状产于角砾状硅质岩中。长坑赋金硅质岩层具纹层状构造特征,在其中发现放射虫、微体古生物化石,角砾长轴与硅质纹层平行分布,含有草莓状黄铁矿,这些特征以及长坑金矿床与富湾银矿床成矿时代等资料都表明长坑金矿赋金硅质岩不是简单热水沉积或热液蚀变作用形成的,而是多次硅化作用的产物,至少经历了热水沉积硅化、成岩硅化、金矿成矿热液蚀变硅化及银矿成矿热液蚀变硅化作用的叠加。热水沉积硅质岩形成富金矿源层,为成矿提供了物质基础。 相似文献
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石门雄黄矿区角砾岩硅质岩成因新探 总被引：1，自引：0，他引：1
石门雄黄矿区范围内131处角砾岩、硅质岩露头的产出层位和标高统计表明该区硅质岩和角砾岩的分布主要受奥陶系南津关组(On)和红花园组第二段(Oh~2)两个层位控制。这些地质体的结构构造特征亦表明其为同生或准同生成因;稳定同位素特征表明其成岩流体为海水、大气成因水或原生水。元素含量统计分析表明这些硅质岩和角砾岩是富含As、HB、Ba的地质体,与本区的雄黄一雌黄矿化有密切的成因联系。 相似文献
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东秦岭二郎坪群热水沉积硅质岩的地球化学特征 总被引：7，自引：0，他引：7
东秦岭二郎坪群中广泛发育一套与铜铅锌成矿作用关系密切的硅质岩。区内硅质岩总体属于低硅质硅质岩,SiO2与Al2O3呈负相关,Fe2O3/FeO比值一般小于1,与热水沉积硅质岩的特征一致;南阳盆地以西的硅质岩MnO/TiO2比值小于0.5、Al/(Al Fe)比值接近北太平洋比值,而盆地以东的硅质岩MnO/TiO2比值大于0.5、Al/(Al Fe)比值与日本中部大陆边缘的三叠纪层纹状硅质岩比值类似;硅质岩稀土元素总量较低,重稀土元素有富集的趋势,Ce亏损较明显,Eu显示正异常,表明本区硅质岩主要是热水沉积作用的产物;硅质岩的V、Ni、Cu等微量元素含量具有洋中脊(或远洋盆地)和大陆边缘硅质岩的双重特征。 相似文献
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准噶尔盆地西北缘二叠系风城组内的云质岩、硅质岩是致密油藏重要的储集岩,目前对云质岩和与之伴生的硅质岩成因存在较大争议。通过岩心观察和对硅质岩的主量、微量、稀土及硅同位素的综合研究,以期揭示硅质岩的成因。研究表明,风城组中的硅质岩SiO2含量变化范围为55.15%~85.61%,为不纯的云质硅质岩,其内含有较多热水沉积矿物和碱湖沉积成因的盐类矿物。云质硅质岩主要围绕热液喷口分布,它们常与白云岩呈纹层状、条带状互层。云质硅质岩中硼异常富集,硼含量介于90×10^-6~10000×10^-6之间,平均680×10^-6,与盐类矿物硅硼钠石有关,反映了碱湖沉积成因;Sr/Ba值均大于1,Th/U值多在0.62~2.06之间,Sm/Nd值多在0.20~0.24之间。云质硅质岩的稀土配分显示出Eu负异常、Ce负异常或弱正异常及轻稀土相对重稀土富集的特征。δ^30Si值介于0.39‰~1.88‰之间,其δ^30Si和微量元素特征不反映典型热水成因。云质硅质岩的地质产状和地球化学特征共同表明,风二段和风三段云质硅质岩主要为热水和碱湖的混合沉积成因。硅质岩形成受喷口的位置、热水喷流期和各喷口喷流热水的温度等多方面因素的控制,硅质岩形成时存在多个喷口,在相对封闭的高盐度—碱性还原环境下的热水喷流期,热水与碱湖湖水混合,混合水沉积形成硅质、盐类矿物及白云石,最终形成含盐的云质硅质岩;热水喷流间歇期形成碱湖成因的含盐云质岩。 相似文献
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西秦岭中志留统含铀岩系中硅质岩的岩石学、地球化学及其成因 总被引：5，自引：2，他引：5
根据产状和成因,本文将西秦岭中志留统含铀岩系中的硅质岩分为,(1) 成岩过程中硅化交代碳酸盐岩所形成的硅质岩,产于碳酸盐岩和泥质岩类所组成的透镜层的顶部或碳酸盐岩层内;(2) 早期成岩阶段形成的纹层状硅质岩,主要产于碳酸盐岩和泥质岩透镜层底部或呈薄层夹于粉砂岩、泥质岩层中。根据沉积环境分析及硅质岩的化学成分、REE分布模式和氧同位素组成,提出本区硅质岩形成于受大气淡水影响的局限浅海环境。 相似文献
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贵州遵义二叠系锰矿底部发育一套特殊的硅质岩建造,该套硅质岩环绕锰矿富集区呈墙状产出,习称“白泥塘层”硅质岩或“城墙式”硅质岩,其与锰矿成矿作用之间有着紧密的成因联系。详细地野外地质调查发现,该套硅质岩具有条带状、角砾状和块状构造,其中钢灰色、黑色锰质细脉穿插于条带硅质岩之中,角砾状构造硅质岩多沿锰矿体周边分布。10 件硅质岩样品元素地球化学分析表明 ,硅质岩具有较高的 SiO2（80.55% ～99.56%）和Fe2O3（0.47%～13.76 %）, 较低的Al2O3（0.05%～4.06%）和TiO2（0～0.49%）, 指示其形成过程中陆源碎屑物质参与较少。（La/Ce）比值和Ce 异常值特征指示硅质岩形成于深水裂陷盆地中,环N 境条件为还原状态。Fe-Mn-Al 和SiO2-Al2O3 图解显示, 硅质岩主要落入热水沉积区内或其附近区域。硅质岩Al/（Al+Fe+Mn）均值为0.26、（La/Ce）N 值为1.51～2.34、 Y/Ho 值为 30.64～43.91,Eu/Eu* 值为0.96～1.67,且硅质岩稀土配分模式与热水沉积硅质岩类似,这些特征集中表明硅质岩成岩过程中有明显的热水物质参与,属于热水成因硅质岩,这为遵义二叠系锰矿床热水喷流沉积成因提供了新的佐证。 相似文献
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近几年我们在西天山博罗霍洛山北坡开展科学研究首次发现了西天山的热液沉积岩及其热液沉积型铜矿床,填补了该区这一岩石类型及成矿类型的空白,并为今后西天山寻找铜等多金属矿床拓宽了思路。本文主要对热液沉积岩的特征及其形成环境进行初步探讨。1.热液沉积岩的主要类型本区的热渡沉积岩按成分分为三种主要类型,有的类型在国内属首次发现。(1)硅质岩类:包括微晶硅质岩、碧玉岩、白云石硅质岩、钾长硅质岩和透辉硅质岩等不同类型。微晶硅质岩主要由粒径0.005—0.01mm 的等轴状微晶石英组成,并见有玉髓球粒和胶状构造残余。石英晶粒之间紧密镶嵌,接触边界呈港湾状,晶间无碎屑、泥质或 相似文献
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对广西丹池地区泥盆系浊积岩和硅质岩的沉积特征、岩石化学成分和形成机制的研究表明,它们是在受同生断裂控制的深水拗陷盆地中,由浊流和热水沉积而形成的沉积岩石。相同类型岩石的分布特征表现南盘江晚古生代沉积盆地呈浅海“台地”和深海“槽沟”相间排列的构造格局,其形成和演化与滇黔桂地体和云开地体的碰撞拼贴造山作用以及造山后地壳的蠕散拉伸作用有关。 相似文献
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Silicalites of Hydrothermal Origin in the Lower Cambrian Black Rock Series of South China 总被引：7，自引：0，他引：7
A silicalite bed was found in the hanging wall and foot wall of the sulfide-rich bed of the Lower Cambrian black rock series in South China.Its origin was not described before,On the oxide(SiO2-Al2O3,SiO2-MgO,SiO2-k2o Na2O)diagrams for discriminating silicalites of chemical,biological and volcanic origins(Liu Xiufeng,1991),most of the data points of silicalites fall within the areas representing silicalites of chemical and volcanic origins.On the Al-Fe-Mn diagram for discriminating silicalites of hydrothermal and biological origins(Yamamoto,1987),the data points fall within the areas representing silicalites of hydrotermal and hydrothermal-biological origins.On the SiO2-Al2O3 diagram for discriminating silicalites of hydrothermal and hydrogenous origins(Bonatti,1975),the data points mostly fall within the hydrothermal area.The ratios of SiO2/Al2O3,SiO2/(K2O Na2O),SiO2/MgO,and K2O/Na2O in the silicalites stand between those of volcanic sediments and of seafloor hydrothermal sediments.The total amount of rare-earth elements in the silicalites is low;the North american Shale-normalized REE patterns decline leftward with obvious negative Ce anomaly.The trace elements Mo,Zn,As,Sb,Se,U,and Ba are higher than those in non-hydrothermal sediments and U/Th≥1.The present authors think that the silicalites are derived from seafloor hot brines which had attracted elements from igneous rocks. 相似文献
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E. N. Terekhov A. S. Baluev S. Yu. Kolodyazhnyi M. A. Belokrys 《Lithology and Mineral Resources》2017,52(4):319-333
The paper reports the results of lithogeochemical studies of the Upper Devonian rocks from the Andoma Hill zone of fold-and-fault dislocations (SE Onega region). The rocks are characterized by the negative Eu anomaly (from 0.4 to 0.65) that maks them different from modern sediments of the White Sea. The latter can be regarded as the average composition of mainly Archean (Karelian–Kola) part of the Baltic Shield. In terms of the contents of some trace elements, they also differ from the Vendian rocks of the Zimnii Bereg area. Since the considered rocks are geochemically similar to the Svecofennian metamorphic rocks and Paleoproterozoic granite rapakivi, they could be formed by the erosion of these complexes. The clastic material was transported via a channel confined to the Baltic Shield and Russian Platform junction known as the Polkanov geoflexure. 相似文献
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折腰山矿区含铁硅质岩赋存于含矿岩系与上部岩系间的沉积间断界面。含铁硅质岩矿物主要由细晶石英和赤铁矿组成,二者含量占90%以上,含少量的绢云母、钠长石、绿泥石等。该含铁硅质岩具有低的TiO2、A12O3和高的成矿元素（Fe、Cu、Pb、Zn）含量特征。Al/（Al＋Fe＋Mn）值具有热水沉积岩特征。在Fe-Mn-Al三角图解、Fe-Mn-（Cu＋Co＋Ni）×10三角图解和Zr-Cr图解中,该区含铁硅质岩均落在热水沉积岩区域中,含铁硅质岩的稀土元素总量很低,其北美页岩标准化配分模式为右倾曲线,具有弱的负Eu异常或正Eu异常和负Ce异常。部分样品MnO/TiO2值偏小,U/Th值偏大,Al2O3含量较高,出现负Eu异常,表明该矿区含铁硅质岩也有正常沉积硅质岩成分的加入。结合含铁硅质岩的地质产状、含矿岩系（石英角斑质凝灰岩）和含矿石英的稀土元素特征,认为含铁硅质岩的物源主要为石英角斑质凝灰岩,属于与火山作用有关的非生物成因类型,是该铜多金属矿田重要的找矿标志。 相似文献
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REE data, with major element and other trace element data are reported for a suite of Archean sedimentary rocks (2800 million years old) from Kalgoorlie, Western Australia. The REE patterns fall into two groups with ?LREE/?HREE ratios of 6 and 15, respectively. The first group have either no Eu anomaly relative to chondrites, or a positive Eu anomaly, in contrast to the pronounced Eu depletion (Eu/Eu ~ 0.67) shown by younger (Post-Archean) sedimentary rocks.The problem of positive Eu enrichment relative to chondritic patterns, is examined by analysing a suite of Devonian greywackes, derived from calc-alkaline volcanic rocks. Some of these samples also show positive Eu anomalies, attributable to local accumulation of feldspar. This explanation is preferred to models involving an early anorthositic crust. The group of samples showing heavy REE depletion patterns (complementary to those observed in garnet) appear to be derived from adjacent Na-rich granites which display identical REE patterns. Locally abundant K-rich granites do not appear to have made any contribution to the Archean sedimentary rocks.The majority of the sedimentary rocks have REE patterns indistinguishable from those of recent island arc calc-alkaline rocks, and so could constitute evidence that the Archean crust was principally formed by processes analogous to present day island-arc type volcanism. However, similar REE patterns may be produced by an appropriate mixture of the common bimodal tholeiitic-felsic igneous suite commonly observed in Archean terrains. The REE data presented here do not distinguish between these two models. 相似文献
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贵州水银洞金矿构造蚀变体稀土元素地球化学特征 总被引：3，自引：0，他引：3
水银洞金矿构造蚀变体(SBT)为产出于茅口租(P2m)和龙潭组(P3l)之间不整合面上的一套强硅化灰岩、灰岩角砾岩、硅化粘土岩组合.呆用ICP-MS测定钻孔岩芯中构造蚀变体样品稀土元素组成,对比研究SBT围岩、区域岩浆岩及现代海底热水系统流体稀土元素组成.结果显示,SBT的轻重稀土分馏明显[LREE/HREE=4.92～17.51,(La/Yb)N=5.94～38.37],曲线右倾型;轻稀土分异明显,曲线右倾程度大;重稀土分异不明显,曲线平坦;负Eu(0.61～0.94)、Ce(0.52～1.07)异常明显;SBT及围岩均具有明显W型稀土元素四分组效应,而不同于区域岩浆岩和现代海底热水系统流体,表明热液流体来源以壳源为主. 相似文献
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Rare—Earth Element Geochemistry of Elogites from the Ultra—High Pressure Metamorphic Belt in Central China 总被引：2，自引：1，他引：1
Based on their REE contents and REE patterns,eclogites from the ultra-high pressure metamorphic belt in central China may be roughly divided into xis types including LREE-rich.LREE-rich positive Eu anomaly,LREE-rich negative Eu anomaly,REE pattern-smooth,MREE-rich and HREE-rich.The LREE_rich,LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites are dominant .REE types of eclogites in different areas can be compared and the REE feactures of the same REE type of eclogites in different areas are similar.The results of reconstruction of the primary rocks show that the primary rocks of eclogites possibly are dominated by continental tholeiites which are the product of partial melting of relatively fertile mantle and the rocks of tholeiite crystallization-differentiation.There is perfect evolution relationship among the primary rocks of the LREE-rich, LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites and among those of the REE pattern smooth and MREE-rich types of eclogites,the former three types were deried from continental settings and the latter two from nearly oceanic settings.Meanwhile,it is concluded that the mantle sources of primary rocks of the eclogites are inhomogeneous and the primary rocks of eclogites in this area appear to have undergone varying degree of crustal contamination. 相似文献
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The mammilated chert (MC) studied in this paper is a kind of silica-rich concretion (SiO2 93%) occurring in the Upper Devonian argillaceous silicolites (SiO2≈88%) in Mugui, Guangxi. Impurity components in the MC are relatively low and show systematic variations as compared with
the country rocks. Abundances of Mg, Si, Ti, Fe, Mn, U and Th are characteristically similar to those of recent and fossil
hot-water sediments. Moreover, the MC is also characterized by low REE abundance, LREE > HREE, apparent negative Ce anomaly
and moderate positive Eu anomaly. Oxygen isotope data show that the formation temperature of the MC is about 20 °C, higher
than that of the host rock. The results of geochemical, geological and lithological studies suggest that the MC may have been
formed through metasomatism, filling and crystallization beneath the sedimentary basin during the Devonian period. 相似文献