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1.
海南岛三亚小东海岸礁礁坪沉积物的稀土元素分布特征 总被引：1，自引：0，他引：1
对海南岛三亚小东海东北岸礁礁坪表面沉积物的稀土元素进行了分析,结果表明,沉积物的∑REE为80.22mg/kg,稀土元素含量球粒陨石标准化分布模式呈现轻稀土富集、重稀土亏损,Eu明显负异常(0.58),Ce无异常,Y/Ho低(27.60)的陆相模式特征.根据小东海礁坪沉积样品稀土元素的空间分布情况可以推测出礁坪珊瑚表面... 相似文献
2.
九龙江河口区稀土元素地球化学特征 总被引：1，自引：0，他引：1
用电感耦合等离子体质谱（ICP-MS）对2007年10月航次采集的九龙江河口区溶解态、悬浮颗粒态、沉积物样品中的稀土元素（REEs）进行了测定,对REEs的地球化学特征进行研究.结果表明,REEs在各相态中的含量范围如下：溶解态的为0.1 ng/dm^3（Eu）～1.96μg/dm^3（Ce）,悬浮颗粒态的为0.28（Tm）～142.83（Ce）mg/kg,沉积物的为0.25（Tm）～99.65（Ce）mg/kg;溶解态、悬浮颗粒态及沉积物中REEs球粒陨石标准化配分曲线均表现为负斜率型,九龙江河口为LREE相对HREE富集型河口.九龙江河口溶解态、悬浮颗粒态、沉积物三相态中REEs含量受流域土壤、地表径流等源区因素影响较大.Ce异常值在各相态中表现为负异常. 相似文献
3.
长江口表层沉积物中稀土元素地球化学特征 总被引：1，自引：1，他引：1
用电感耦合等离子体质谱法测定了2002年8～9月航次丰水期采集的长江口表层沉积物样品,对稀土元素(REEs)在沉积物的中含量分布、配分模式及其与某些常量矿物成份之间的相关关系进行了研究.结果表明,长江口表层沉积物中REEs含量在0.17μg/g(Lu)～78.9μg/g(Ce)之间,含量高低顺序为Ce＞La＞Nd＞Sm＞Yb＞Eu＞Tb＞Lu;用PAAS和世界平均页岩的REEs含量进行Ce、Eu异常值的计算结果表明,长江口沉积物中Ce和Eu均表现出轻微正异常;沉积物中REEs在轻稀土元素(LREE)富集的基础上,表现出中稀土元素(MREE)相对富集的特征,其中用PAAS标准化后MREE富集程度比用世界平均页岩标准化后的结果要明显.通过比较沉积物和悬浮颗粒物的分馏表征值、REEs含量和浓度变化范围等,认为长江口沉积物的主要来源是水体悬浮颗粒物.本文对REEs与Al2O3和Mn的相关性研究还发现,两者与重稀土元素(HREE)有较明显的正相关关系,其中Al2O3与HREE的线性相关性较好. 相似文献
4.
长江水下三角洲表层沉积物稀土元素特征 总被引：1，自引：0，他引：1
长江水下三角洲表层沉积物稀土元素的含量约为160×10-6,重稀土元素的含量约为42×10-6,稀土元素总量约为202×10-6,轻稀土元素的含量约为重稀土元素含量的4倍。现代三角洲的前缘斜坡轻稀土元素、重稀土元素、稀土元素总量依次大于前三角洲、现代三角洲向晚更新世三角洲过渡区及晚更新世三角洲区。三角洲不同区域稀土元素的分布模式相同,均呈现Eu的负异常,δEu介于0.64~0.70之间,平均0.67,在河海相互作用下,随着河流动力的减弱和海洋动力的加强,Eu的负异常加大。南支外Ce的异常与河口锋带有关,晚更新世三角洲Ce的异常与台湾暖流有关。轻稀土元素在现代三角洲前缘斜坡较富集,而重稀土元素在前三角洲区富集,REE在沉积物中的解吸或部分溶解过程是控制长江水下三角洲表层沉积物稀土元素分布特征的主要因素。长江水下三角洲表层沉积的REE受到粒径和盐度的双重控制。 相似文献
5.
太平洋东部深海沉积物稀土元素地球化学 总被引：9，自引：0，他引：9
刘季花 《海洋地质与第四纪地质》1992,12(2):33-42
通过对太平洋东部CC区深海沉积物的稀土元素研究发现:该区沉积物的REE含量较高,普遍具有较小的Eu正异常和较大的Ce负异常;不同类型沉积物中的稀土含量、比值和分布模式存在着差异,这种差异主要取决于沉积物组分的不同;沉积物的来源有自生源、火山源、生物源和陆源,稀土元素主要是通过自生组分富集的,区域上,Ce异常值低处,Eh值高,为强氧化环境区,也是南极底层流的流经路径,是多金属结核富集的有利地区。 相似文献
6.
西南印度洋中脊热液产物稀土元素组成变化及其来源 总被引：1，自引：1，他引：0
对西南印度洋中脊热液区不同热液产物稀土元素(REE)进行了分析,探讨了热液产物形成过程中稀土元素组成变化及其来源。研究结果表明:不同热液产物稀土元素总量变化范围从3.47×10-7到4.80×10-5,轻重稀土比值(LREE/HREE)从2.06到6.16,表明轻重稀土有较大程度分异,δEu异常(δEu=0.86~3.88)和δCe异常(δCe=0.40~0.86)显示热液产物中REE呈Eu富集和Ce亏损特征。稀土元素球粒陨石标准化模式呈现两种类型:(1)呈轻微富集LREE的平坦模式,REE大于2×10-5;(2)呈显著富集LREE和正Eu异常模式,REE小于5×10-7。模式1类似于洋壳火山岩REE配分模式,而模式2与西南印度洋中脊黑烟囱REE模式相似,也与典型洋中脊热液喷口流体和硫化物LREE富集和正Eu异常模式类似。热液产物中稀土元素含量变化和模式特征以及Mg与LREE极强正相关关系可能反映了西南印度洋中脊硫化物形成在热液流体与海水混合沉淀的初始阶段,后期经历了广泛的热液流体再循环和海水蚀变过程。 相似文献
7.
贵州威宁草海第四系窑上组沉积物微量元素地球化学特征及其古环境意义 总被引：5，自引：0，他引：5
分析了贵州威宁草海第四系窑上组剖面微量元素和稀土元素地球化学特征,结合前人研究的介形类、孢粉等资料,探讨了沉积物微量元素垂直变化反映的沉积环境.结果表明,Li、Ba、Sr等14种微量元素有着很好的相关性.∑REE高,δCe、δEu呈现负异常的总体特征,但δCe在第7、11层表现为正异常;轻重稀土分馏较大,具有轻稀土富集... 相似文献
8.
胶州湾在促进青岛市经济发展的同时,人为活动对胶州湾的污染也愈发严重。本文对胶州湾冬季稀土元素(Rare earth elements, REEs)的地球化学特征和人为镧(La)、钆(Gd)污染进行了研究。胶州湾溶解态和酸溶态REEs含量的变化范围分别为：3.5 pmol/L(铕Eu)～359.1 pmol/L(铈Ce)和6.9 pmol/L(铥Tm)～4 861.8 pmol/L(Ce)。由于颗粒物对REEs的吸附,导致溶解态的浓度明显低于酸溶态,溶解态REEs的PAAS(Post-Archean Average Australian Shale,后太古代澳大利亚页岩)标准化配分曲线表现为重稀土富集;(Yb)PAAS/(Nd)PAAS比值平均为4.7±0.7(Yb和Nd为镱和钕,分别代表重稀土元素和轻稀土元素),说明胶州湾溶解态轻稀土和重稀土之间分馏程度较大。酸溶态REEs配分曲线表现为中稀土富集;酸溶态轻中重稀土元素之间分馏程度较低。胶州湾溶解态和酸溶态钇(Y)和钬(Ho)之间也发生了明显分馏。溶解态Ce/Ce*表现为... 相似文献
9.
南海北部陆坡海洋沉积物稀土元素及物源和成岩环境 总被引：13，自引：2，他引：11
通过对0DP184航次1146站位海底岩心沉积物中稀土元素含量及其配分模式的研究,确立了其分配规律,即相对富集轻稀土,Eu亏损等,并且与东海大陆架及中国黄土的稀土分布模式相似,表明本区沉积物物源主要来自陆源,是大陆岩石分化过程的产物。对富集因子的研究也证明了沉积物主要来自陆源。δCe的弱负异常值与∑REE和δEu值一样,主要受陆源源区气候环境变化控制,而与海水关系不大。稀土元素与生物作用基本无关,可能主要是赋存于陆源碎屑矿物的晶格中。通过对岩心沉积物间隙水成分的研究,表明成岩环境主要为还原环境。68m(mcd)以上主要为硫酸盐的还原作用,68m以下主要为甲烷的生物生成作用。 相似文献
10.
对东太平洋CC区中西部33站表层沉积物进行了稀土元素(REE,包括Y)地球化学研究。结果表明,REE在沸石粘土中最富集,在硅质沉积物中含量明显偏低;所有沉积物样品中REE都存在Ce负异常和Eu正异常的轻稀土(LREE)亏损特征,表现为典型受到海水来源物质影响的REE配分模式;硅质粘土中Ce亏损程度、Eu正异常和REE富集程度都比硅质软泥更明显。与东区相比,西区沉积物中LREE、HREE(重稀土和钇元素)和∑REE(稀土元素总量)普遍偏高,LREE与HREE分异更明显,HREE相对更富集,LREE和Ce亏损更显著。研究区表层沉积物中REE主要来自海洋自生物质,同时受到陆源物质、海底火山物质的影响。 相似文献
11.
Size-fractionated uranium isotopes in surface waters in the Jiulong Estuary in China 总被引：1，自引：1，他引：0
L&#; E ZHANG Lei CHEN Min QIU Yusheng XING N YANG Weifeng LI Yanping HUANG Yipu 《海洋学报(英文版)》2008,27(1):29-41
Surface water was collected from the Jiulong Estuary for determination of activity concentrations of uranium isotopes in different size fractions, namely, greater than 53, 10 -53, 2 - 10, 0.4 -2 μm, 10 000 u -0.4 μm and less than 10 000 u fractions by microfihration and cross-flow uhrafiltration technologies. Results indicated that most of the dissolved uranium （ 〈 0.4 μm） exis- ted in the low molecular mass fraction （ 〈 10 000 u）, and the colloidal uranium-238 （10 000 u -0.4 μm） only contributed less than 1% of the dissolved uranium-238. The fractions of colloidal uranium in the dissolved phases decreased with the increasing sa- linity. A positive linear relationship between uranium-238 activities and salinities was observed for the dissolved, colloidal and low molecular mass fractions, indicating a conservative behavior of uranium in the Jiulong Estuary. In the particulate phases （ 〉 0.4 μm）, the partitioning of uranium isotopes among different size fractions was controlled by the partitioning of particle concentrations. In the regions with salinities below 20, the partitioning of uranium-238 among different size fractions was as follows： 10 - 53 μm 〉 2 - 10 μm 〉 0.4 - 2 μm greater than above 53 μm. However, the order at the offshore station with salinities above 30 changed as follows ： 0.4 - 2 μm 〉 10 - 53 μm 〉 2 - 10 μm greater than above 53 μm. The fraction of the 0.4 - 2 μm particles increased at the offshore station, suggesting the increased contribution of the authigenic uranium. The activity ratio of uranium-234 to uranium-238 in the dissolved phases, including the low molecular mass fraction and the colloidal fraction, was larger than unity, showing the occurrence of excess uranium-234. In contrast, the activity ratio of uranium-234 to uranium-238 in all size fractions of the particulate phase was close to the equilibrium value （1.0）. The observed different values of the activity ratio of uranium-234 to uranium-238 in the dissolved phase and the partic 相似文献
12.
JIN Xianglong 《海洋学报(英文版)》2013,32(12):1-3
In China submarine geosciences represents a newly established discipline of oceanography, focusing on the oceanic lithosphere, and its interface with the hydrosphere and biosphere. Recently, supported by the National High Technology Research and Development Program and other high-tech development projects, significant progress has been made in the development of advanced technologies and equipment. This en- ables the scientists in China to carry out explorations of the international seabed area in the Pacific Ocean and on the Southwest Indian Ridge. In addition, they have been active in the research activities associated the mid-ocean ridges and western Pacific marginal seas. It is anticipated that this research field will continue to be highly fruitful in the near future. 相似文献
13.
湄洲湾夏季的初级生产力 总被引：2，自引：3，他引：2
湄洲湾１９９２年夏季的叶绿素ａ，三磷酸腺苷，碳比积累速率，初级生产力的变化范围和均值分别为０．４５－４．７２，１．４９ｍｇ／ｍ＾３；０．１２－１．０７，０．３１μｇ／ｄｍ＾３；０．０６－０．５８，０．３４ｄ＾－１；０．０７－０．３４，０．２１ｍ／（ｍ＾２．ｄ）。叶绿素ａ与三磷酸腺苷之间。初级生产力与碳比积累速率之间均呈正相关关系。叶绿素ａ三磷本能腺苷的比值为４．８，湄洲湾夏季浮游植物的生长受氮不足 相似文献
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Voronova O. S. Zima A. L. Kladov V. L. Cherepanova E. V. 《Izvestiya Atmospheric and Oceanic Physics》2020,56(9):1042-1052
Izvestiya, Atmospheric and Oceanic Physics - The results of satellite wildfire monitoring and estimates for the amounts of emissions of harmful gases and fine aerosols in Siberia from 2001 to 2019... 相似文献
17.
海水中重金属铅的检测方法研究进展 总被引：3，自引：0，他引：3
铅(Pb)是已知毒性最大的重金属污染物之一,它可通过呼吸以及饮食摄入人体.铅是一种慢性的积累性毒物和潜在的致癌、致突变物质.铅的性质与钙类似,在人体骨骼中能够积蓄,主要损害神经系统、造血器官和肾脏 [1].鉴于重金属铅对人体如此严重的生物毒性作用,美国环保总局(EPA)将其列入内分泌干扰物(又称环境激素)名单,因此对环境水体中铅的检测具有重要意义.本文简述了海水中铅的含量及其存在形态,评述了原子光谱法、分子光谱法、质谱法及电化学法在海水中铅含量及其形态分析中的应用. 相似文献
18.
In order to investigate factors controlling nutrient cycling in the shallow and turbid coastal ecosystem of Galveston Bay, data from: (1) the Texas Water Commission (TWC) database 1980–1989, and (2) salinity transects in 1989 and 1993 are presented and analyzed. Statistical regression and time-series analysis were carried out on data acquired by TWC between 1980 and 1989, in an attempt to establish seasonally of nutrient and chlorophyll-a (chl.-a.) concentrations in the bay and to determine factors which regulate these concentrations.A strong seasonality was found for phosphorus and chl.-a. in the upper and mid-bay stations. A recurring maximum for phosphate occurred in September and a chl.-a. maximum occurred regularly in March–April. It is hypothesized that benthic regeneration of phosphorus at the end of summer is responsible for the phosphate maximum. The inverse correlation of the partition coefficient (Kd) for phosphate with the concentration of suspended particulate matter (SPM), coupled to a strong enrichment of phosphate in suspended particles at low SPM concentrations, indicates additional control by geochemical and physical processes such as particle sorting and/or particle-colloid interactions. Nitrate is inversely correlated with salinity at the upper and mid-bay stations, indicating the Trinity River is a major source.Nutrient concentrations in the lower bay (East and West Bay stations) are considerably lower and less predictable, as they are not correlated with salinity or temperature. Data from the 1989 and 1993 transects confirm the yearly maximum in phosphate concentration in late summer months, with peak concentrations in the upper Trinity Bay. It is concluded that despite possible phosphate buffering by physical and geochemical mechanisms, relatively large concentration maxima recur regularly every year during the summer, possibly caused by a benthic source of phosphate. 相似文献
19.
《Deep Sea Research Part I: Oceanographic Research Papers》1999,46(8):1391-1415
The biomass, species and chemical composition of the mesozooplankton and their impact on lower food levels were estimated along a transect across the Arctic Ocean. Mesozooplankton biomass in the upper 200 m of the water column was significantly higher (19–42 mg DW m-3) than has previously been reported for the Arctic Ocean, and it reached a maximum at ca. 87°N in the Amundsen Basin. The lowest values were recorded in the Chukchi Sea and Nansen Basin, where ice cover was lower (50–80%) than in the central Arctic Ocean. In the deeper strata (200–500 m) of the Canadian and Eurasian Basins, the biomass was always much lower (4.35–16.44 mg DW m-3). The C/N (g/g) ratio for the mesozooplankton population was high (6.5–8.5) but within the documented range. These high values (when compared to 4.5 at lower latitudes) may be explained by the high lipid content. Mesozooplankton accounted for approximately 40% of the total particulate organic carbon in the upper 100 m of the water column. Mesozooplankton species composition was homogeneous along the transect, consisting mainly of copepods (70–90% of the total number). It was dominated by four large copepod species (Calanus hyperboreus, C. glacialis, C. finmarchicus and Metridia longa), which together accounted for more than 80% of the total biomass. According to measurements of gut pigment and gut turnover rates, the mesozooplankton on average ingested between 6 and 30% of their body carbon per day as phytoplankton. Microzooplankton may have provided an additional source of energy for the mesozooplankton community. These data emphasize the importance of mesozooplankton in the arctic food web and reinforce the idea that the Arctic Ocean should no longer be considered to be a “biological desert”. 相似文献