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1.
Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   

2.
A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO3 (0.01), N2O5 (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.  相似文献   

3.
Parameterization of evaporation from a non-plant-covered surface is very important in the hierarchy strategy of modelling land surface processes. One of the representations frequently used in its computation is the resistance formulation. The performance of the evaporation schemes using the , , and their combination resistance approaches to parameterize evaporation from bare soil surfaces is discussed. For that purpose, the nine schemes, based on a different dependence of and on volumetric soil moisture content and its saturated value, are used.The tests of performances of the considered schemes are based on time integrations by the land surface module (BARESOIL) using observed data. The 23 data sets at a bare surface experimental site in Rimski anevi, Yugoslavia on chernozem soil, were used for the resistance algorithm evaluation. The quality of the schemes was compared with the observed values of the latent heat flux using several statistical parameters.  相似文献   

4.
Airborne measurements made during August 1985 over Greenland and its environs show that both accumulation-mode (0.1 m D2.0 m) and giant (D2 m) particles were present in relatively high concentrations in arctic haze layers and that the accumulation-mode particles dominated light scattering. Particles with diameters (D) between 1 and 4 m consisted predominately of mixed materials, small and dense inclusions, and probably organic compounds containing sulfur. Many of the particles from 0.1 to 1 m in diameter were also of mixed composition, with sulfuric acid, ammonium sulfate and organics probably the dominant constituents.  相似文献   

5.
Summary ¶In order to better understand land-atmosphere interactions and increase the predictability of climate models, it is important to investigate the role of forest representation in climate modeling. Corresponding to the big-leaf model commonly employed in land surface schemes to represent the effects of a forest, a so called big-tree model, which uses multi-layer vegetation to represent the vertical canopy heterogeneity, was introduced and incorporated into the National Center for Atmospheric Research (NCAR) regional climate model RegCM2, to make the vegetation model more physically based. Using this augmented RegCM2 and station data for China during 1991 Meiyu season, we performed 10 experiments to investigate the effects of the application of the big-tree model on the summer monsoon climate.With the big-tree model incorporated into the regional climate model, some climate characteristics, e.g. the 3-month-mean surface temperature, circulation, and precipitation, are significantly and systematically changed over the model domain, and the change of the characteristics differs depending on the area. Due to the better representation of the shading effect in the big-tree model, the temperature of the lower layer atmosphere above the plant canopy is increased, which further influences the 850hPa temperature. In addition, there are significant decreases in the mean latent heat fluxes (within 20–30W/m2) in the three areas of the model domain.The application of the big-tree model influences not only the simulated climate of the forested area, but also that of the whole model domain, and its impact is greater on the lower atmosphere than on the upper atmosphere. The simulated rainfall and surface temperature deviate from the originally simulated result and are (or seem to be) closer to the observations, which implies that an appropriate representation of the big-tree model may improve the simulation of the summer monsoon climate.We also find that the simulated climate is sensitive to some big-tree parameter values and schemes, such as the shape, height, zero-plane displacement height and mixing-length scheme. The simulated local/grid differences may be very large although the simulated areal-average differences may be much lower. The area-average differences in the monthly-mean surface temperature and heat fluxes can amount to 0.5°C and 4W/m2, respectively, which correspond to maximum local/grid differences of 3.0°C and 40W/m2 respectively. It seems that the simulated climate is most sensitive to the parameter of the zero-plane displacement among the parameters studied.  相似文献   

6.
Summary The effect of the Alpine orography on prototype cold fronts approaching from the west is investigated by three-dimensional numerical model simulations. The numerical experiments cover a range of parameter constellations which govern the prefrontal environment of the front. Especially, the appearance and intensity of prefrontal northern Alpine foehn varies from case to case.The behaviour of a cold front north of the Alps depends much on the prefrontal condition it encounters. It is found that prefrontal foehn can either accelerate or retard the approaching front.An important feature is the pressure depression along the northern Alpine rim that results from the southerly foehn flow. In cases where this depression compensates the eastward directed pressure gradient associated with the largescale flow, the front tends to accelerate and the foehn breaks down as soon as the front passes. In contrast, the foehn prevents the front from a rapid eastward propagation if it is connected with a strong southerly wind component.No-foehn experiments are performed for comparison, where either the mountains are removed, or the static stability is set to neutral. Also shown are effects of different crossfrontal temperature contrasts.List of Symbols c F propagation speed of a front - x, y horizontal grid spacing (cartesian system) - , horizontal grid spacing (geographic system) - t time step - z vertical grid spacing (cartesian system) - cross-frontal potential temperature difference - i potential temperature step at an inversion - E turbulent kinetic energy - f Coriolis parameter - FGP frontogenesis parameter (see section 2.2) - g gravity acceleration (g=9.81 m s–2) - vertical gradient of potential temperature - h terrain elevation (above MSL) - h i height of an inversion (h i =1000 m MSL) - H height of model lid (H=9000 m MSL) - K M exchange coefficient of momentum - K H exchange coefficient of heat and moisture - longitude - N Brunt-Väisäla-frequency - p pressure - Exner function (=T/) - latitude - q v specific humidity - R d gas constant of dry air (R d =287.06 J kg–1 K–1) - density of dry air - t time - T temperature - potential temperature - TFP thermal front parameter (see section 2.2) - u, v, w cartesian wind components - u g ,v g geostrophic wind components - horizontal wind vector - x, y, z cartesian coordinates Abbreviations GND (above) ground level - MSL (above) mean sea level - UTC universal time coordinated With 20 Figures  相似文献   

7.
Thermal comfort of man in different urban environments   总被引：2，自引：4，他引：2  
Summary On July 29, 1985, a hot summer day, biometeorological measurements were performed simultaneously in three different urban structures within the city of Munich and in the trunk space of a nearby tall spruce forest. Based on the results of these experiments the following thermophysiologically relevant biometeorological indices were calculated: Predicted mean vote, skin wettedness and physiologically equivalent temperature. These three indices are derived from different models for the human energy balance. They allow the assessment of the thermal components of the microclimates at the selected sites with regard to application in urban planning. The results quantitatively show the great heat stress in the urban structure street canyon, exposed to south, whereas in the trunk space of the tall spruce forest there is nearly an optimal climate even on hot summer days. Between these extremes the results for street canyon, exposed to north show a little higher heat load than for backyard with trees.
Zusammenfassung An einem heißen Sommertag, dem 29. Juli 1985, wurden in drei Stadtstrukturen in München und im Stammraum eines nahegelegenen Fichtenhochwaldes zeitgleich biometeorologische Messungen durchgeführt. Mit den Meßergebnissen wurden folgende thermophysiologisch relevante biometeorologische Indizes berechnet: Predicted mean vote, Hautbenetzungsgrad und physiologisch äquivalente Temperatur. Diese drei Indizes beruhen auf verschiedenen Modellen zur menschlichen Energiebilanz. Mit den drei Indizes wurden die thermischen Komponenten der Mikroklimate an den ausgewählten Meßplätzen im Hinblick auf Stadtplanungsaufgaben bewertet. Die Ergebnisse zeigen quantitativ die relativ große Hitzebelastung bei der Stadtstruktur Straßenschlucht, nach Süd exponiert, während im Stammraum des Fichtenhochwaldes selbst an heißen Sommertagen nahezu optimale Bedingungen herrschen. Zwischen diesen Extremen liegen die Ergebnisse für die anderen Meßplätze, wobei für Straßenschlucht, nach Nord exponiert die Wärmebelastung etwas höher als für Innenhof mit Bäumen ist.

With 6 Figures  相似文献   

8.
In the summer of 1988/89 flights were carried out in the Coorong coastal area of South Australia to investigate sea-breeze fronts. The flights yielded data sets of the structure of the fronts in the cross-frontal direction with a spatial resolution of approximately 3 m. The study is focused on the budgets of sensible and latent heat in the vicinity of the front and on frontogenesis/frontolysis processes which are closely related to budget considerations.The frontogenesis relationships and the budgets were established on a 2 km length scale by low-pass filtering of the space series. As the wind components were measured with high accuracy, all processes which determine frontogenesis could be evaluated and are displayed in x,z-cross-sections: these are the confluence, shear and diabatic effects, all of which play a role in q/x-, q/z-, /x- as well as /z-frontogenesis. A detailed analysis is given for two different states of frontal development. The presented results shed much light on the governing physical processes in the frontal region with strong emphasis on the effects of confluence-generated updrafts, on shear instabilities causing bulges and clefts in the frontal surface as well as producing the elevated frontal head, and on processes related to differential heating and moistening.  相似文献   

9.
Summary The influence of agricultural management on the CO2 budget of a typical subalpine grassland was investigated at the Swiss CARBOMONT site at Rigi-Seebodenalp (1025m a.s.l.) in Central Switzerland. Eddy covariance flux measurements obtained during the first growing season from the mid of spring until the first snow fall (17 Mai to 25 September 2002) are reported. With respect to the 10-year average 1992–2001, we found that this growing season had started 10 days earlier than normal, but was close to average temperature with above-normal precipitation (100–255% depending on month). Using a footprint model we found that a simple approach using wind direction sectors was adequate to classify our CO2 fluxes as being controlled by either meadow or pasture. Two significantly different light response curves could be determined: one for periods with external interventions (grass cutting, cattle grazing) and the other for periods without external interventions. Other than this, meadow and pasture were similar, with a net carbon gain of –128±17g Cm–2 on the undisturbed meadow, and a net carbon loss of 79±17g Cm–2 on the managed meadow, and 270±24g Cm–2 on the pasture during 131 days of the growing season, respectively. The grass cut in June reduced the gross CO2 uptake of the meadow by 50±2% until regrowth of the vegetation. Cattle grazing reduced gross uptake over the whole vegetation period (37±2%), but left respiration at a similar level as observed in the meadow.  相似文献   

10.
Parameterizing turbulent diffusion through the joint probability density   总被引：3，自引：3，他引：0  
The convective mass flux parameterization often used in meteorological modeling expresses the vertical flux of a transported scalar as proportional to the product of the difference in mean values of the scalar in updrafts and downdrafts and their characteristic velocity. The proportionality factor is a constant to be specified. We show that this proportionality factor also appears in the relaxed eddy accumulation technique of Businger and Oncley. That associates the surface-layer flux of a scalar with the product of the standard deviation of vertical velocity and the mean concentration difference between updrafts and downdrafts.We show that this constant (b) is determined uniquely by the joint probability density (jpd) of vertical velocity and the scalar. Using large-eddy simulation, we generate this jpd for a conservative scalar diffusing through a convective boundary layer. It has quite different forms in top-down and bottom-up diffusion geometries. The bottom-up jpd is fairly well represented by a jointly Gaussian form and implies b ~ 0.6, in good agreement with the surface-layer value reported by Businger and Oncley. The top-down jpd is strikingly non-Gaussian and gives b ~ 0.47. Updrafts carry the bulk of the scalar flux - 70% in the bottom-up case, 60% in the top-down case.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

11.
Summary Mechanisms associated with Alpine lee cyclogenesis during the early phase of their generation are investigated using a variational quasigeostrophic filter technique. It was possible to extract the quasigeostrophic signal from the available analyzed real data set.The results presented here are for the 11–12 March 1982, an example of so-called orographically induced lee cyclogenesis. Non-quasigeostrophic fields, calculated as a difference between observations and the quasigeostrophic fields, show significant magnitudes indicating the possible importance of non-quasigeostrophic processes. A dipole structure in the residual geopotential field was observed, similar to the results of numerical model experiments. Also, a strong upper-level non-quasigeostrophic divergence was found in the Alpine region 24 hours prior to lee cyclogenesis, lasting for 6–12 hours. On the other hand, quasigeostrophic results indicate only a local effect of mountain slopes, suggesting possibly a dominant role of the low-level blocking. A hypothetical scenario of Alpine lee cyclogenesis is proposed, based on results obtained here.With 14 Figures  相似文献   

12.
Summary The evolving modes of the sea-surface temperature (SST) in the Tropical Atlantic on the short interannual (IA) timescale were obtained by performing the extended empirical orthogonal function (EEOF) analyses on this variable separately for the 106-year (1871–1976) and 20-year (1881–1900; 1901–1920; 1921–1940; 1941–1960) periods. The equatorial and inter-hemispheric patterns manifest in the first EEOF mode of each analysis as part of the short IA evolution of the SST anomalies in the Tropical Atlantic. Another outstanding feature of the first EEOF mode of each analysis concerns the propagations of the SST anomalies in the meridional direction within the 20°N–20°S band and in the zonal direction in the sector 40°W–20°W. For all analyses, the SST anomalies propagate northward from the equator to 15°N and southward from 20°N to 15°N, with the same sign anomalies merging approximately at 15°N. On the other hand, the SST anomalies propagate westward in the sector 40°W–20°W with a propagation rate close to that of the phase speed of the fastest baroclinic Rossby wave in the ocean. So, the observed propagations of the SST anomalies in the 20°N–20°S band might result from the combined effect of the surface oceanic currents in this band and the baroclinic Rossby waves in the ocean.  相似文献   

13.
Summary A simple parameterization for the estimation of turbulent kinetic energy (TKE) and momentum flux profiles under near-neutral stratification based on sodar measurements of the vertical velocity variance has been tested using data from the LINEX-2000 experiment. Measurements included operation of a phased-array Doppler sodar DSDPA.90 and of a sonic anemometer USA-1 mounted at a meteorological tower at a height of 90m. Good agreement has been found between the TKE and momentum flux values derived from the sonic and sodar data (with correlation coefficients r>0.90 and a slope of the regression lines of about 1.01.1) suggesting the possible use of sodar measurements of w 2 to derive turbulence parameter profiles above the tower range.  相似文献   

14.
Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both SO and AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m3. In the case of aerosol carbon, we obtained a more gradual increase of AC up to an LWC of 0.5 g/m3. At higher LWCs, _ remained relatively constant at 0.60. As the differences between SO and A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.  相似文献   

15.
The effect of changes in zonal and meridional atmospheric moisture transports on Atlantic overturning is investigated. Zonal transports are considered in terms of net moisture export from the Atlantic sector. Meridional transports are related to the vigour of the global hydrological cycle. The equilibrium thermohaline circulation (THC) simulated with an efficient climate model is strongly dependent on two key parameters that control these transports: an anomaly in the specified Atlantic–Pacific moisture flux (Fa) and atmospheric moisture diffusivity (Kq). In a large ensemble of spinup experiments, the values of Fa and Kq are varied by small increments across wide ranges, to identify sharp transitions of equilibrium THC strength in a 2-parameter space (between Conveyor On and Off states). Final states from this ensemble of simulations are then used as the initial states for further such ensembles. Large differences in THC strength between ensembles, for identical combinations of Fa and Kq, reveal the co-existence of two stable THC states (Conveyor On and Off)—i.e. a bistable regime. In further sensitivity experiments, the model is forced with small, temporary freshwater perturbations to the mid-latitude North Atlantic, to establish the minimum perturbation necessary for irreversible THC collapse in this bistable regime. A threshold is identified in terms of the forcing duration required. The model THC, in a Conveyor On state, irreversibly collapses to a Conveyor Off state under additional freshwater forcing of just 0.1 Sv applied for around 100 years. The irreversible collapse is primarily due to a positive feedback associated with suppressed convection and reduced surface heat loss in the sinking region. Increased atmosphere-to-ocean freshwater flux, under a collapsed Conveyor, plays a secondary role.  相似文献   

16.
Periodicity of annual precipitation in different climate regions of Croatia   总被引：1，自引：1，他引：0  
Summary The periodicity of a 100-year series of annual precipitation over Croatia has been studied by means of power spectrum analysis at 3 stations representing the different climatic regions of Croatia. The annual precipitation variance spectra in the continental lowland (Osijek) and at the north East Adriatic coast (Crikvenica) can be fitted by Markov white noise continuum, but in the transitional region between the Dinaric Alps and the Pannonian lowland (Zagreb-Gri) a non-white noise continuum is necessary. Quasi-periodic oscillations appear in two spectra ranges: short (2.2 and 4.7 years) and medium (25.0 and 33.3 years). These results are compared with those of other authors for other parts of the Europe.With 2 Figures  相似文献   

17.
Influence of heterogeneous land surfaces on surface energy and mass fluxes   总被引：1，自引：0，他引：1  
Summary Land-surface heterogeneity affects surface energy fluxes. The magnitudes of selected land-surface influences are quantified by comparing observations with model simulations of the FIFE (First ISLSCP Field Experiment) domain. Several plausible heterogeneous and homogeneous initial and boundary conditions are examined, although soilmoisture variability is emphasized. It turns out that simple spatial averages of surface variation produced biased flux values. Simulated maximum latent-heat fluxes were approximately 30 to 40 W m–2 higher, and air temperatures 0.4 °C lower (at noon), when computations were initialized with spatially averaged soil-moisture and leaf-area-index fields. The planetary boundary layer (PBL) height and turbulent exchanges were lower as well. It additionally was observed that (largely due to the nonlinear relationship between initial soil-moisture availability and the evapotranspiration rate), real latent-heat flux can be substantially less than simulated latent-heat flux using models initialized with spatially averaged soil-moisture fields. Differences between real and simulated fluxes also vary with the resolution at which real soil-moisture heterogeneity is discretized.With 8 Figures  相似文献   

18.
Summary Interannual modes are described in terms of three-month running mean anomaly winds (u,v), outgoing longwave radiation (OLR), and sea surface temperature (T * ). Normal atmospheric monsoon circulations are defined by long-term average winds (u n,v n) computed every month from January to December. Daily winds are grouped into three frequency bands, i.e., 30–60 day filtered winds (u L,v L); 7–20 day filtered winds (u M,v M); and 2–6 day filtered winds (u S,v S). Three-month running mean anomaly kinetic energy (signified asK L , K M , andK S , respectively) is then introduced as a measure of interannual variation of equatorial disturbance activity. Interestingly, all of theseK L , K M , andK S perturbations propagate slowly eastward with same phase speed (0.3 ms–1) as ENSO modes. Associated with this eastward propagation is a positive (negative) correlation between interannual disturbance activity (K L , K M , K S ) and interannualu (OLR) modes. Namely, (K L , K M , K S ) becomes more pronounced than usual nearly simultaneously with the arrival of westerlyu and negativeOLR (above normal convection) perturbutions. In these disturbed areas with (K L , K M , K S >0), upper ocean mixing tends to increase, resulting in decreased sea surface temperature, i.e.T * 0. Thus, groups (not individual) of equatorial disturbances appear to play an important role in determiningT * variations on interannual time scales. HighestT * occurs about 3 months prior to the lowestOLR (convection) due primarily to radiational effects. This favors the eastward propagation of ENSO modes. The interannualT * variations are also controlled by the prevailing monsoonal zonal windsu n, as well as the zonal advection of sea surface temperature on interannual time scales. Over the central Pacific, all of the above mentioned physical processes contribute to the intensification of eastward propagating ENSO modes. Over the Indian Ocean, on the other hand, some of the physical processes become insignificant, or even compensated for by other processes. This results in less pronounced ENSO modes over the Indian Ocean.With 10 FiguresContribution No. 89-6, Department of Meteorology, University of Hawaii, Honolulu, Hawaii.  相似文献   

19.
This paper describes the similarity between atmospheric fluctuations of carbon dioxide, water vapor and temperature using data which cover a wide range of instability (0.02 < < 10). The is the Monin-Obukhov stability parameter including the humidity effect.The spectral analysis shows that the coherency between fluctuations of carbon dioxide and water vapor or temperature is very close to unity, and the phase difference is basically out of phase for whole frequency ranges analyzed. The stability dependence of the normalized standard deviation of carbon dioxide is very similar to those of water vapor and temperature. The normalized standard deviation is about 2.5 under near neutral conditions, and it decreases with increasing instability following the -1/3; power law as (-)-1/3. The skewness factors of carbon dioxide, water vapor and temperature show a systematic departure with increasing instabilities for 0.02 < s- < 1, and level off at high instabilities for 1 < -\s < 10. The stability dependence of the flatness factors is not so clear as that noted in the standrard deviation and skewness factors. Dissipation rates of carbon dioxide, water vapor and temperature variance are well related to the spectral peak wavelength. This seems to be real since the local production and local dissipation rates are the main terms, almost balancing one another in the variance budget equations for scalar entities.  相似文献   

20.
Summary ¶Two cyclonic vortices close to each other, a binary cyclone or binary system, tend to rotate cyclonically relative to one another and to merge, i.e. the Fujiwhara effect. The point vortex model that represents barotropic binary cyclones predicts their rotation features as follows. The rotation rate is proportional linearly to the sum of the cyclones intensities and inversely to the square of their separation distance while the more intense cyclone rotates slower. Our earlier observational analysis of 1423 mid-latitude binary cyclones (Ziv and Alpert, 1995) showed a reasonable fit to theory, except for the absence of a correlation between individual speeds and intensities within the binary systems, and a reversal of the inverse rotation-separation relationship at the range of 1400–1800km.This study is the first attempt to describe the mid-latitude binary systems using potential vorticity concepts (PV thinking), which implies that a binary interaction takes place between the 3-D flow patterns induced by upper-PV or surface-thermal anomalies rather than by the surface cyclones alone. It is argued that the upper-anomalies dominate the rotation process, and hence the rotational speeds of the interacting surface cyclones are more closely correlated with the relative intensities of their corresponding upper-level anomalies rather than with their own intensities, as reflected in weather charts. Data analysis indicates that mid-latitude binary cyclones are normally associated with at least one upper-PV anomaly. This explains the absence of a correlation between the rotation speed and the intensity of the surface cyclones there.A unique type of a mid-latitude binary system is identified, in which one cyclone coincides with an upper major PV-anomaly and the other moves along the periphery of the former. Such a binary system is entitled here the Contact Binary System (CBS), in contrast with remote interacting systems implied by the point vortex theory.Analytical considerations yield an increase in the rotation rate with separation for CBSs of separation smaller than 1000–1500km, in contrast to the normal decrease with R 2. The contribution of CBSs is suggested here to explain the abnormal increase in rotation rate at 1400–1900km range.  相似文献   

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