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1.
The performances of three semi-analytical retrieval models for water inherent optical properties were validated in the coastal Yellow Sea and East China Sea, including the Quasi-Analytical Algorithm (QAA), the Garver-Siegel-Maritorena model (GSM) and the Over Constrained Linear Matrix (LM). The model-retrieved parameters, namely absorption coefficients of phytoplankton (a ph), colored dissolved and detrital particulate matter (a dg), total absorption coefficients (a t), and backscattering coefficient of particles (b bp), were compared. The bio-optical datasets collected from a Yellow Sea and East China Sea cruise in April and September 2003 were used in the study. The QAA model performed the best in retrieval for all the coefficients, showing log-transformed root mean square errors of 0.306 for a ph, 0.268 for a dg, 0.144 for a t, and 0.273 for b bp at 443 nm. The LM model showed a slightly larger deviation than the QAA model with a similar error trend for absorption coefficients, but it returned the largest uncertainties for b bp, with log-transformed root mean square error up to 0.646. The GSM model, however, yielded the largest and fluctuating errors along with wavelength for absorption coefficient retrievals. Substituting the fitting parameters from measured data for the empirical spectral parameters, all three models returned better results. These improvements demonstrated that semi-analytical algorithms designed for ocean water need regional modifications before applying to coastal areas. The QAA algorithm may be the most suitable model for retrieval for the Yellow Sea and East China Sea, and future model refinements should concentrate on regional modeling of inherent optical properties.  相似文献   

2.
海水石油类物质吸收系数遥感化提取算法研究   总被引：2，自引：0，他引：2  
Establishing the remote sensing algorithm of retrieving the absorption coefficient of seawater petroleum substances is an efficient way to improve the accuracy of retrieving a seawater petroleum concentration using a remote sensing technology. A remote sensing reflectance is a basic physical parameter in water color remote sensing. Apply it to directly retrieve the absorption coefficient of seawater petroleum substances is of potential advantage. The absorption coefficient of waters containing petroleum [ACWCP, a_o(λ)], consists of the absorption coefficient of pure water [ACPW, a_w(λ)], plankton [ACP, a_(ph)(λ)], colored scraps [ACCS, a_(d,g)(λ)], and petroleum substance [ACPS, a_(oil)(λ)]. Among those, ACCS consists of the absorption coefficient of nonalgal particle [ACNP, a_d(λ)] and colored dissolved organic matter [ACCDOM, a_g(λ)]. For waters containing petroleum, the retrieved ACCS using the existing method is a combination absorption coefficient of ACNP,ACCDOM and ACPA [CAC, a_(d,g,oil)(λ)]. Therefore, the principle question is how to extract ACPS from CAC.Through the analysis of the three proportion tests conducted between the year of 2013 and 2015 and the corresponding remote sensing data, an algorithm of retrieving the absorption coefficient of petroleum substances is proposed based on remote sensing reflectance. First of all, ACPS and CAC are retrieved from the reflectance using the quasi-analytical algorithm(QAA), with some parameter modified. Secondly, given the fact that the backscatter coefficient [BC, b_(bp)(555)] of total particles at 555 nm can be obtained completely from the reflectance, the relation between BC and ACNP in petroleum contaminated water can be established. As a result, ACNP can be calculated. Then, combining the remote sensing retrieving algorithm of a_g(440), the method of achieving the spectral slope of the absorption coefficient can be established, from which ACCDOM,can be calculated. Finally, ACPS can be computed as the residual. The accuracy of ACPS based on this algorithm is 86% compared with the in situ measurements.  相似文献   

3.
Remote sensing reflectance [R rs(λ)] and absorption coefficients of red tides were measured in Isahaya Bay, southwestern Japan, to investigate differences in the optical properties of red tide and non-red tide waters. We defined colored areas of the sea surface, visualized from shipboard, as “red tides”. Peaks of the R rs(λ) spectra of non-red tide waters were at 565 nm, while those of red tides shifted to longer wavelengths (589 nm). The spectral shape of R rs(λ) was close to that of the reciprocal of the total absorption coefficient [1/a(λ)], implying that the R rs(λ) peak is determined by absorption. Absorption coefficients of phytoplankton [a ph(λ)], non-pigment particles and colored dissolved organic matter increased with increasing chlorophyll a concentration (Chl a), and those coefficients were correlated with Chl a for both red tide and non-red tide waters. Using these relationships between absorption coefficients and Chl a, variation in the spectrum of 1/a(λ) as a function of Chl a was calculated. The peak of 1/a(λ) shifted to longer wavelengths with increasing Chl a. Furthermore, the relative contribution of a ph(λ) to the total absorption in red tide water was significantly higher than in non-red tide water in the wavelength range 550–600 nm, including the peak. Our results show that the variation of a ph(λ) with Chl a dominates the behavior of the R rs(λ) peak, and utilization of R rs(λ) peaks at 589 and 565 nm may be useful to discriminate between red tide and non-red tide waters by remote sensing.  相似文献   

4.
The variety in shape and magnitude of thein vivo chlorophyll-specific absorption spectra of phytoplankton was investigated in relation to differences in pigment composition off Sanriku, northwestern North Pacific. Site-to-site variations of the absorption coefficients,a ph * (λ), and pigment composition were clearly observed. At warm-streamer stations, higher values ofa ph * (440) anda ph * (650) were found with relatively high concentrations of chlorophyllb (a green algae marker). At stations located in the Oyashio water (cold streamer),a ph * (440) values were lower and fucoxanthin (a diatom marker) concentrations were higher, compared to the other stations. The peak in the absorption spectra at the Oyashio stations was shifted toward shorter wavelengths, which was probably due to the presence of phaeopigments. In a Kuroshio warm-core ring, the magnitude ofa ph * (440) was in between those at the warm-streamer and Oyashio stations, and the diagnostic pigment was peridinin (a dinoflagellate marker). These findings indicated that major differences in phytoplankton absorption spectra of each water mass were a result of differences in the phytoplankton pigment composition of each water mass, which was probably related to the phytoplankton community.  相似文献   

5.
Spectral absorption coefficients of total particulate material and detritus were measured throughout the euphotic zone along the equator between 165°E and 150°W and during time-series for each of these two longitudes in October 1994 (JGOFS-FLUPAC cruise). The sum of pigments obtained by spectrofluorometry (tChla=DV−chla+Chla) was used for normalization (and was also compared to fluorometric and HPLC measurements as an intercalibration study). In order to assess the specific absorption coefficient of photosynthetically active pigments (aps) from the pigment-specific absorption coefficient for phytoplankton (aph*), we made a multiple regression analysis of measured phytoplankton absorption spectra onto publishedin vivo spectra of pure pigments. This made it possible to calculate the concentrations of photoprotective carotenoids (tPPC) when HPLC measurements were not available and thus to subtract their contribution to absorption from the total phytoplanktonic absorption coefficient (aph). Methodological uncertainties in both coefficients used for calculating absorption coefficients and in pigment measurements are discussed. Pigments and absorption measurements made during the cruise enabled us to describe two typical trophic regimes in the equatorial Pacific ocean: oligotrophic waters of the ”warm pool“ west of 170°W and high-nutrient, low-chlorophyll waters (HNLC) of the upwelling east of 170°W. The vertical decreasing gradient of aph* from the surface to the deep chlorophyll maximum (DCM) was due to a high tPPC/tChla ratio at the surface and was higher in the oligotrophic (0.14-0.065 m2 mg (tChla)−1 biomass dominated byProchlorococcus, rich in zeaxanthin) than in the mesotrophic area (0.07-0.06 m2 mg (tChl a)-' biomass dominated by picoeucaryotes). Below the DCM,aph* reached a similar minimum value in both oligotrophic and mesotrophic areas.a*ps varied less than a*ph from the surface layer to the DCM in both oligotrophic and mesotrophic areas. The difference in a*ph and a*ps from west to east of the transect could be interpreted as a shift in the phytoplankton composition, with a dominance of procaryotes in the west and a dominance of eucaryotes in the upwelling area. Higher aps in well-lit typical oligotrophic waters indicated that phytoplankton communities dominated byProclorococcus might be more efficient for capturing light usable for photosynthesis than those present in the HNLC situation.  相似文献   

6.
We have estimated the spatial variability of phytoplankton specific absorption coefficients (a* ph ) in the water column of the California Current System during November 2002, taking into account the variability in pigment composition and phytoplankton community structure and size. Oligotrophic conditions (surface Chl < 0.2 mg m−3) dominated offshore, while mesotrophic conditions (surface Chl 0.2 to 2.0 mg m−3) where found inshore. The specific absorption coefficient at 440 [a* ph (440)] ranged from 0.025–0.281 m2mg−1 while at 675 nm [a* ph (675)] it varied between 0.014 and 0.087 m2mg−1. The implementation of a size index based on HPLC data showed the community structure was dominated by picoplankton. This would reduce the package effect in the variability of a* ph (675). Normalized a ph curves were classified in two groups according to their shape, separating all spectra with peaks between 440 and 550 nm as the second group. Most samples in the first group were from surface layers, while the second group were from the deep chlorophyll maximum or deeper. Accessory photoprotective pigments (APP) tended to decrease with depth and accessory photosynthetic pigments (APS) to increase, indicating the importance of photoprotective mechanisms in surface layers and adaptation to low light at depth. Samples with higher ratios of APP:APS (>0.4) were considered as phytoplankton adapted to high irradiances, and lower ratios (<0.26) as adapted to low irradiances. We found a good relationship between APP:APS and a* ph (440) for the deeper layer (DCM and below), but no clear evidence of the factors causing the variability of a* ph (440) in the upper layer.  相似文献   

7.
Traditional field techniques to monitor water quality in large estuaries, such as boat-based surveys and autonomous moored sensors, generally provide limited spatial coverage. Satellite imagery potentially can be used to address both of these limitations. Here, we show that satellite-based observations are useful for inferring total-suspended-solids (TSS) concentrations in estuarine areas. A spectra-matching optimization algorithm was used to estimate the particle backscattering coefficient at 400 nm, bbp(400), in Chesapeake Bay from Sea-viewing Wide-Field-of-view Sensor (SeaWiFS) satellite imagery. These estimated values of bbp(400) were compared to in situ measurements of TSS for the study period of September 1997–December 2003. Contemporaneous SeaWiFS bbp(400) values and TSS concentrations were positively correlated (N = 340, r2 = 0.4, P < 0.0005), and the satellite-derived bbp(400) values served as a reasonable first-order approximation for synoptically mapping TSS. Overall, large-scale patterns of SeaWiFS bbp(400) appeared to be consistent with expectations based on field observations and historical reports of TSS. Monthly averages indicated that SeaWiFS bbp(400) was typically largest in winter (>0.049 m−1, November–February) and smallest in summer (<0.031 m−1, June–August), regardless of the amount of riverine discharge to the bay. The study period also included Hurricanes Floyd and Isabel, which caused large-scale turbidity events and changes in the water quality of the bay. These results demonstrate that this technique can provide frequent synoptic assessments of suspended solids concentrations in Chesapeake Bay and other coastal regions.  相似文献   

8.
We measured the absorption coefficients of suspended particles (ap(λ)) during three cruises from coastal waters to open ocean in the northern South China Sea (NSCS). The absorption contributions of phytoplankton (aph(λ)) and nonalgal particles (aNAP(λ)) were determined using the methanol extraction method. Based on the dataset of about 360 samples, we examined the spectral relationships of the particle absorption coefficients. The results show that ap(λ) spectra are well linearly correlated with ap(443) over the wavebands between 420–650 nm; aph(λ) could be well expressed as the second-order quadratic equations of aph(443) among the blue-green wavebands, and aNAP(λ) follows the general exponential function. Based on these spectral relationships, a model was proposed for partitioning the total particulate absorption coefficients into the contributions of phytoplankton and nonalgal particles using the nonlinear optimization method. The model was validated by comparing the computed results with in situ absorption coefficients. In some wavebands, such as 412 nm, 443 nm, 490 nm and 683 nm, we obtained good correlations with the percentage root mean square error (RMSE) values being controlled within 25% and the slopes being closer to 1.0. For samples from coastal waters, the discrepancy was a little large, which might be due to the higher absorption contributions from certain pheopigments. Overall, this model provides us much insight into phytoplankton absorption retrieval from in situ measurements and remote sensing ocean color data.  相似文献   

9.
Advanced remote sensing techniques and regional algorithms are combined to produce and analyze a 12-year multi-sensor time series of bio-optical properties for the Adriatic Sea. First, a multi-sensor series of normalized water-leaving radiance LWN is created with an optically-based merging technique applied to SeaWiFS and MODIS data, then distributions of inherent optical properties (IOPs) are obtained with a semi-analytical bio-optical model. Additionally, Chla is computed by two regional empirical algorithms associated with two classes of optical properties representative of open ocean waters and Adriatic coastal regions (Classes 1 and 2, respectively). The domain of applicability of each algorithm is dynamically determined on the basis of the LWN input spectrum by a novelty detection approach. The various satellite products are validated using a comprehensive bio-optical time series collected in the northern Adriatic. At the basin level, the frequency of occurrence of Classes 1 and 2 are 61% and 10%, respectively, with Class 2 waters particularly located in the northern part and characterized by higher levels of Chla and IOPs. The annual cycle of Chla over the 12-year period exhibits significant variations in amplitude and phase; moreover, the annual cycle shows a reduced amplitude during a period centered on 2004 for a time interval that varies with the region. In the northern Adriatic, the overall level of Chla appears lower between 2003 and 2008 compared to the beginning of the series.  相似文献   

10.
近年来, 渤海夏季低氧现象频发, 引起了人们的广泛关注。然而对该海域低氧形成的机制还未得到充分认识。研究基于在秦皇岛外海的现场观测, 分析了海水中颗粒物吸收光谱特征及其与不同粒径浮游植物叶绿素a (chl a)组成、环境因子的关系, 评估了夏季底层水体脱氧过程中有机物来源与特征。结果显示,夏季秦皇岛外海微型浮游植物chl a占总量的80%。表层水体中, 总颗粒物吸收光谱[ap(l)]特征由浮游植物色素吸收光谱[aph(l)]主导, 在中、底层水体中则由碎屑颗粒物吸收光谱[ad(l)]主导。垂向上, ap(440)和ad(440)均表现为表层<中层<底层。结果还表明, 浮游植物粒径主导秦皇岛外海chl a的光吸收效率, 即a*ph(440)。基于三粒级chl a含量, 可利用多元回归预测aph(440)。碎屑颗粒物的吸收光谱同样受浮游植物群落、有机质相对含量等的影响。研究结果表明初级生产产生的微型颗粒有机物是底层水体脱氧的主要底物。  相似文献   

11.
Phytoplankton absorption and pigment characteristics of a red tide were investigated in coastal waters of the southern Benguela. Diagnostic indices indicated that dinoflagellates were the dominant phytoplankton group, with diatoms and small flagellates being of secondary importance. Very high biomass was observed close to the coast where chlorophyll a concentrations of up to 117 mg m–3 were measured. Both measured (a ph) and reconstructed pigment absorption (a pig) displayed an increasing trend with chlorophyll a, while the package effect index (Q* a) decreased, indicating increased packaging with an increase in biomass. Proportioning of the total pigment absorption between 400 and 700 nm revealed that chlorophyll a accounted for 39–65% of the absorption, while photosynthetic carotenoids (15–30%) and chlorophyll cs (15–30%) were also prominent in absorbing light for photosynthesis.  相似文献   

12.
Abstract. Biomass and primary production rates derived from photosynthesis-light curves on picoplankton (< 1 um fraction) and total phytoplankton were compared for the Strait of Messina. Picoplankton biomass ranged between 0.063 and 0.094 mg Chi a m-5 and accounted for 56–63 % of the total. Total primary production rates were between 0.22 and 1.56 mg C-m-2-h-1 of which the picoplankton contribution ranged from 24 to 43%. In this turbulent nearshore environment, the contribution of picoplankton to total phytoplankton production is considerably less than in calmer open-ocean waters. Carbon assimilation numbers (Pmb), the initial slope (a), adaptation parameter (Ik), optimal irradiance (Im) and compensation intensity (Lm,) for the picoplankton were lower than for the > 1 μm fraction. Fitted respiration (RmB) for the picoplankton was, however, on the average higher (10.3 % of PmB) than for the > 1 μrn fraction (6.6 %). Assimilation numbers for the > 1 μm fraction in the southern stations were of higher magnitude (8.5–12.0 mg C mg Chi a-1 h-1) than in the northern station, possibly due to the impact of upwelled water flowing southward along the Sicilian coast.  相似文献   

13.
An aggregate flux event was observed by ship and by four underwater gliders during the 2008 sub-polar North Atlantic spring bloom experiment (NAB08). At the height of the diatom bloom, aggregates were observed as spikes in measurements of both particulate backscattering coefficient (bbp) and chlorophyll a fluorescence. Optical sensors on the ship and gliders were cross-calibrated through a series of simultaneous profiles, and bbp was converted to particulate organic carbon. The aggregates sank as a discrete pulse, with an average sinking rate of ∼75 m d−1; 65% of aggregate backscattering and 90% of chlorophyll fluorescence content was lost between 100 m and 900 m. Mean aggregate organic carbon flux at 100 m in mid-May was estimated at 514 mg C m−2 d−1, consistent with independent flux estimates. The use of optical spikes observed from gliders provides unprecedented coupled vertical and temporal resolution measurements of an aggregate flux event.  相似文献   

14.
Relationships between the surface concentrations of phytoplankton pigments (C ph), total suspended matter (C sm), particulate organic carbon (C poc), and total suspended phosphorus (C sp), on the one hand, and the relative water transparency determined through the Secchi disc depth (z d), on the other, are analysed using the data compiled in the Guinean coastal waters (Tabunsu and Tonkima river estuaries) during November–December 1990. The functions ofC ph,C sm=f(z d) are matched up with the experimentally derived data, as well as with the model bio-optical state of seawater. The general regression equation has been calculated using the data characteristic of various types of water.Translated by Vladimir A. Puchkin.  相似文献   

15.
Satellite image studies and recent in situ sampling have identified conspicuous phytoplankton blooms during spring and summer along the Patagonia shelf-break front. The magnitudes and spectral characteristics of light absorption by total particulate matter (phytoplankton and detritus) and colored dissolved organic matter (CDOM) have been determined by spectrophotometry in that region for spring 2006 and late summer 2007 seasons. In spring, phytoplankton absorption was the dominant optical component of light absorption (60–85%), and CDOM showed variable and important contributions in summer (10–90%). However, there was a lack of correlation between phytoplankton biomass (chlorophyll-a concentration or [chl a]) and the non-algal compartment in both periods. A statistically significant difference was found between the two periods with respect to the CDOM spectral shape parameter (Scdom), with means of 0.015 (spring) and 0.012 nm?1 (summer). Nonetheless, the mean Scdm values, which describe the slope of detritus plus CDOM spectra, did not differ between the periods (average of 0.013 nm?1). Phytoplankton absorption values in this work showed deviations from mean parameterizations in previous studies, with respect to [chl a], as well as between the two study periods. In spring, despite the microplankton dominance, high specific absorption values and large dispersion were found (a*ph(440)=0.04±0.03 m2 mg [chl a]?1), which could be attributed to an important influence of photo-protector accessory pigments. In summer, deviations from general trends, with values of a*ph(440) even higher (0.09±0.02 m2 mg [chl a]?1), were due to the dominance of small cell sizes and also to accessory pigments. These results highlight the difficulty in deriving robust relationships between chlorophyll concentration and phytoplankton absorption coefficients regardless of the season period. The validity of a size parameter (Sf) derived from the absorption spectra has been demonstrated and was shown to describe the size structure of phytoplankton populations, independently of pigment concentration, with mean values of 0.41 in spring and 0.72 in summer. Our results emphasize the need for specific parameterization for the study region and seasonal sampling approach in order to model the inherent optical properties from water reflectance signatures.  相似文献   

16.
A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag440). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for TChl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (TChl2i in case-2 waters), TTSM (regionally tuned Tassan??s TSM algorithm), and Tag440 or Cag440 (regionally tuned Tassan??s or Carder??s ag440 algorithm) were able to retrieve Chl-a, TSM, and ag440 with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, TChl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. TChl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified TChl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw555) > 2 mW cm?2 ??m?1 sr?1 (TChl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from TChl2s (for case-2 waters) to MOCChl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag440 using SeaWiFS Rrs, we recommend empirical algorithms for TTSM (pre-SeaWiFS-modified form) and MTag440 or MCag440 (SeaWiFS Rrs-modified forms of Tag440 or Cag440). These could retrieve with uncertainties as high as 82 and 52%, respectively.  相似文献   

17.
Purification of cytochromes P-450 from liver microsomes of β-naphthoflavone (BNF)-fed rainbow trout yielded three apparently homogeneous forms. The major form (LM4b)* appears to be a P-448 type of cytochrome. A minor form (LM4a), having properties very similar to LM4b, was also obtained. In addition, a P-450 form (LM2) was isolated, with properties quite different from LM4a or LM4b, including a high rate of aflatoxin B1 (AFB1) metabolism (Williams & Buhler, 1983c). Antibodies to all three forms were obtained from rabbits. The IgGs prepared against LM4a and LM4b both cross-reacted (forming lines of identity) equally well with both antigens on Ouchterlony plates. Rat P-448 cross-reacted (without lines of identity) with both LM4a- and LM4b-IgG. LM4b-IgG was much more effective than LM4a-IgG for inhibition of LM4a or LM4b reconstituted benzo[a]pyrene (BP) hydroxylase, suggesting that these two antibodies recognize different antigenic sites. The LM2-IgG did not cross-react with any of the other rat or trout cytochromes P-450 examined. Levels of LM2 and LM4b in microsomes from untreated, polychlorinated biphenyl (PCB), phenobarbital (PB) or BNF-treated trout were estimated with an immunological technique involving electrophoresis on SDS-PAGE, followed by transfer to nitrocellulose and staining with either LM 2 - or LM4b -IgG. The ratio of in microsomes from PCB- or BNF-treated rainbow trout was much higher than 1, whereas the reverse was true with microsomes from untreated rainbow trout. These results are consistent with previous observations (Vodicnik et al., 1982) that pretreatment with BNF induced the synthesis of a P-448 type cyytochrome, presumably responsible for the great increase in the metabolism and activation of BP seen in these fish. Conversely, pretreatment with PB did not affect the levels of either LM2 or LM4b. This specific immunological technique should make it possible to assay the levels of these P-450 and P-448 isozymes in various strains of rainbow trout and other species of fish. In addition, the effect of age, sex, diet and exposure to P-450 and P-448 inducers could be examined and, perhaps, utilized to predict the relative risk of certain populations to pollutants activated by these different isozymes.  相似文献   

18.
Measurements of sub-surface light attenuation (Kd), Secchi depth and suspended particulate material (SPM) were made at 382 locations in transitional, coastal and offshore waters around the United Kingdom (hereafter UK) between August 2004 and December 2005. Data were analysed statistically in relation to a marine water typology characterised by differences in tidal range, mixing and salinity. There was a strong statistically significant linear relationship between SPM and Kd for the full data set. We show that slightly better results are obtained by fitting separate models to data from transitional waters and coastal and offshore waters combined. These linear models were used to predict Kd from SPM. Using a statistic (D) to quantify the error of prediction of Kd from SPM, we found an overall prediction error rate of 23.1%. Statistically significant linear relationships were also evident between the log of Secchi depth and the log of Kd in waters around the UK. Again, statistically significant improvements were obtained by fitting separate models to estuarine and combined coastal/offshore data – however, the prediction error was improved only marginally, from 31.6% to 29.7%. Prediction was poor in transitional waters (D = 39.5%) but relatively good in coastal/offshore waters (D = 26.9%).SPM data were extracted from long term monitoring data sites held by the UK Environment Agency. The appropriate linear models (estuarine or combined coastal/offshore) were applied to the SPM data to obtain representative Kd values from estuarine, coastal and offshore sites. Estuarine waters typically had higher concentrations of SPM (8.2–73.8 mg l−1) compared to coastal waters (3.0–24.1 mg l−1) and offshore waters (9.3 mg l−1). The higher SPM values in estuarine waters corresponded to higher values of Kd (0.8–5.6 m−1). Water types that were identified by large tidal ranges and exposure typically had the highest Kd ranges in both estuarine and coastal waters. In terms of susceptibility to eutrophication, large macrotidal, well mixed estuarine waters, such as the Thames embayment and the Humber estuary were identified at least risk from eutrophic conditions due to light-limiting conditions of the water type.  相似文献   

19.
An optical model is developed for the remote sensing of coloured dissolved organic matter (CDOM) in a wide range of waters within coastal and open ocean environments. The absorption of CDOM (denoted as ag) is generally considered as an exponential form model, which has two important parameters – the slope S and absorption of CDOM at a reference wavelength ag(λ0). The empirical relationships for deriving these two parameters are established using in-situ bio-optical datasets. These relationships use the spectral remote sensing reflectance (Rrs) ratio at two wavelengths Rrs(670)/Rrs(490), which avoids the known atmospheric correction problems and is sensitive to CDOM absorption and chlorophyll in coastal/ocean waters. This ratio has tight relationships with ag(412) and ag(443) yielding correlation coefficients between 0.77 and 0.78. The new model, with the above parameterization applied to independent datasets (NOMAD SeaWiFS match-ups and Carder datasets), shows good retrievals of the ag(λ) with regression slopes close to unity, little bias and low mean relative and root mean square errors. These statistical estimates improve significantly over other inversion models (e.g., Linear Matrix-LM and Garver-Siegel-Maritorena-GSM semi-analytical models) when applied to the same datasets. These results demonstrate a good performance of the proposed model in both coastal and open ocean waters, which has the potential to improve our knowledge of the biogeochemical cycles and processes in these domains.  相似文献   

20.
基于两种半分析算法的水体吸收系数反演   总被引：1，自引：0，他引：1  
本文基于42组不同年份不同季节获得的遥感反射率、水体各组分吸收系数的实测数据,对QAA（Quasi-Analytical Algorithm）和GSM（Garver-Siegel-Maritorena）算法在寡营养的南海和富营养的福建沿岸两种不同类型水体的吸收系数反演进行了检验。以水样测量值为参考,两种算法在本研究水体中的反演成效与他人在其它水域的研究结果相当。QAA算法在南海的反演成效高于福建沿岸水体。对于443 nm的总吸收系数（a443 ）,南海的对数均方根误差（RMSE ）为0.046,平均相对误差为7.9%,对数平均偏差为0;福建沿岸水体的对数均方根误差（RMSE ）为0.194,平均相对误差为30.6%,对数平均偏差为-0.167 。GSM算法在两类水体的反演成效类似,A443 之RMSE和平均相对误差,南海分别为0.161和27.7%,福建沿岸分别为0.149和32.1%,但从A443的对数平均偏差值看,其在南海反演值低于实测值（对数平均偏差为-0.142 ）,在福建沿岸则略呈高于实测值（对数平均偏差为0.016）。两种算法中的部分经验参数与实测值之间的差异是产生反演误差的主要原因,为了提高反演精度,对算法中经验参数的更进一步区域化调整可能是必要的。  相似文献   

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