Associations of organic matter with minerals in Tagish Lake meteorite via high spatial resolution synchrotron‐based FTIR microspectroscopy          下载免费PDF全文

Mehmet Yesiltas  Yoko Kebukawa 《Meteoritics & planetary science》2016,51(3):584-595

We have investigated spatial and spectral associations between mineral species and organic matter in the Tagish Lake meteorite. Synchrotron‐based infrared microspectroscopy allowed us to spatially locate specific organic and inorganic compounds within multiple Tagish Lake grains with high spatial resolution. Generated two‐dimensional infrared maps present strong spatial association between aliphatic C‐H and OH in phyllosilicates in Tagish Lake grains. These observations indicate possible roles of phyllosilicates for the formation, evolution, and preservation of organic matter. Infared spectra of all studied Tagish Lake grains show a strong carbonate band, which also shows a weak but positive correlation with organic matter in some grains. However, intergrain correlation was not observed between carbonates and organics, which is likely due to the difference of carbonate occurrence, e.g., presence of larger grains or intergrowth of carbonates on phyllosilicates. Possible scenarios further explaining the observed associations of organics with phyllosilicates and carbonates are presented.  相似文献   

Empirical ocean-color algorithms to retrieve chlorophyll-a, total suspended matter, and colored dissolved organic matter absorption coefficient in the Yellow and East China Seas   总被引：4，自引：1，他引：3  

Eko Siswanto  Junwu Tang  Hisashi Yamaguchi  Yu-Hwan Ahn  Joji Ishizaka  Sinjae Yoo  Sang-Woo Kim  Yoko Kiyomoto  Keiko Yamada  Connie Chiang  Hiroshi Kawamura 《Journal of Oceanography》2011,67(5):627-650

A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag₄₄₀). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for T_Chl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (T_Chl2i in case-2 waters), T_TSM (regionally tuned Tassan??s TSM algorithm), and T_ag440 or C_ag440 (regionally tuned Tassan??s or Carder??s ag₄₄₀ algorithm) were able to retrieve Chl-a, TSM, and ag₄₄₀ with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, T_Chl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. T_Chl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified T_Chl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw₅₅₅) > 2 mW cm^?2 ??m^?1 sr^?1 (T_Chl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from T_Chl2s (for case-2 waters) to MOC_Chl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag₄₄₀ using SeaWiFS Rrs, we recommend empirical algorithms for T_TSM (pre-SeaWiFS-modified form) and MT_ag440 or MC_ag440 (SeaWiFS Rrs-modified forms of T_ag440 or C_ag440). These could retrieve with uncertainties as high as 82 and 52%, respectively.  相似文献   

Mapping the ideological networks of American climate politics     

Dana R. Fisher  Philip Leifeld  Yoko Iwaki 《Climatic change》2013,116(3-4):523-545

How do we understand national climate change politics in the United States? Using a methodological innovation in network analysis, this paper analyzes discussions about the issue within the US Congress. Through this analysis, the ideological relationships among speakers providing Congressional testimony on the issue of climate change are mapped. For the first time, issue stances of actors are systematically aggregated in order to measure coalitions and consensus among political actors in American climate politics in a relational way. Our findings show how consensus formed around the economic implications of regulating greenhouse gases and the policy instrument that should do the regulating. The paper is separated into three sections. First, we review the ways scholars have looked at climate change policymaking in the United States, paying particular attention to those who have looked at the issue within the US Congress. Next, we present analysis of statements made during Congressional hearings on climate change over a four-year period. Our analysis demonstrates how a polarized ideological actor space in the 109^th Congress transforms into a more consensual actor landscape in the 110^th Congress, which is significantly less guided by partisan differences. This paper concludes by discussing how these findings help us understand shifting positions within American climate politics and the implications of these findings.  相似文献   

Diets of Steller sea lions off the coast of Hokkaido,Japan: An inter‐decadal and geographic comparison          下载免费PDF全文

Yoko Goto  Akihiko Wada  Noboru Hoshino  Takahiro Takashima  Masaki Mitsuhashi  Kaoru Hattori  Orio Yamamura 《Marine Ecology》2017,38(6)

Inter‐decadal and geographic variations in the diets of Steller sea lion, Eumetopias jubatus, were examined based on the contents of 408 stomachs collected from coastal areas around Hokkaido Island during the periods 1994–1998 and 2005–2012. The most important prey species in the 1990s were gadid fishes (walleye pollock [Gadus chalcogrammus], Pacific cod [Gadus microcephalus] and saffron cod [Eleginus gracilis]). The frequency of occurrence and gravimetric contribution of gadids decreased in the 2000s latter period at three study sites (Rausu, Shakotan and Rebun) and were replaced by Okhotsk Atka mackerel (Pleurogrammus azonus) and smooth lumpsucker (Aptocyclus ventricosus). However, analysis based on gravimetric composition indicated that the dietary diversity of prey showed only a slight inter‐decadal difference, reflecting the wide diversity of prey ingested during both study periods. These results indicate that Steller sea lions along the Hokkaido coast are opportunistic feeders that utilize a wide variety of prey, and appear to feed mainly upon prey that is easily obtained.  相似文献   

Ductile deformation and development of andalusite microstructures in the Hongusan area: Constraints on the metamorphism and tectonics of the Ryoke Belt     

Yoko  Adachi  Simon  Wallis 《Island Arc》2008,17(1):41-56

Abstract   The main mesoscopic features of the ductile deformation in the Hongusan region of the Ryoke Belt can be explained in terms of a single deformation phase, Dm . The associated stretching lineation is roughly east–west and has an associated top-to-the-west sense of shear. This information fills an important gap in our knowledge about the deformational history of the Ryoke metamorphic belt. Andalusite porphyroblasts are well-developed in the Hongusan area and their microstructure can be used to link the deformational history with the metamorphism. However, the andalusite porphyroblasts show both intertectonic and post-tectonic microstructures. Some porphyroblasts have an intertectonic core and post-tectonic rim. Analysis of associated metamorphic minerals and bulk-rock chemistry suggests that the distinct types of microstructure can be explained in terms of distinct formation reactions related to regional and contact metamorphism. The intertectonic microstructure shows the presence of a deformation pre-dating Dm , referred to as Dc . These two deformation stages are sufficient to account for all the main deformation features. The distribution of post-tectonic andalusite growth shows a very broad thermal effect around an intrusion in the area. This can help place constraints on the thermal history of the Ryoke metamorphic belt.  相似文献   

Infrared imaging spectroscopy with micron resolution of Sutter's Mill meteorite grains     

Mehmet Yesiltas  Yoko Kebukawa  Robert E. Peale  Eric Mattson  Carol J. Hirschmugl  Peter Jenniskens 《Meteoritics & planetary science》2014,49(11):2027-2037

Synchrotron‐based Fourier transform infrared spectroscopy and Raman spectroscopy are applied with submicrometer spatial resolution to multiple grains of Sutter's Mill meteorite, a regolith breccia with CM1 and CM2 lithologies. The Raman and infrared active functional groups reveal the nature and distribution of organic and mineral components and confirm that SM12 reached higher metamorphism temperatures than SM2. The spatial distributions of carbonates and organic matter are negatively correlated. The spatial distributions of aliphatic organic matter and OH relative to the distributions of silicates in SM2 differ from those in SM12, supporting a hypothesis that the parent body of Sutter's Mill is a combination of multiple bodies with different origins. The high aliphatic CH₂/CH₃ ratios determined from band intensities for SM2 and SM12 grains are similar to those of IDPs and less altered carbonaceous chondrites, and they are significantly higher than those in other CM chondrites and diffuse ISM objects.  相似文献   

Quantitative evaluation of the seasonal variations in climate model cloud regimes   总被引：1，自引：1，他引：0  

Yoko Tsushima  Mark A. Ringer  Mark J. Webb  Keith D. Williams 《Climate Dynamics》2013,41(9-10):2679-2696

An extended cloud-clustering method to assess the seasonal variation of clouds is applied to five CMIP5 models. The seasonal variation of the total cloud radiative effect (CRE) is dominated by variations in the relative frequency of occurrence of the different cloud regimes. Seasonal variations of the CRE within the individual regimes contribute much less. This is the case for both observations, models and model errors. The error in the seasonal variation of cloud regimes, and its breakdown into mean amplitude and time varying components, are quantified with a new metric. The seasonal variation of the CRE of the cloud regimes is relatively well simulated by the models in the tropics, but less well in the extra-tropics. The stratocumulus regime has the largest seasonal variation of shortwave CRE in the tropics, despite having a small magnitude in the climatological mean. Most of the models capture the temporal variation of the CRE reasonably well, with the main differences between models coming from the variation in amplitude. In the extra-tropics, most models fail to correctly represent both the amplitude and time variation of the CRE of congestus, frontal and stratocumulus regimes. The annual mean climatology of the CRE and its amplitude in the seasonal variation are both underestimated for the anvil regime in the tropics, the cirrus regime and the congestus regime in the extra-tropics. The models in this study that best capture the seasonal variation of the cloud regimes tend to have higher climate sensitivities.  相似文献   

Ocean Color Satellite Imagery and Shipboard Measurements of Chlorophyll a and Suspended Particulate Matter Distribution in the East China Sea   总被引：1，自引：0，他引：1  

Yoko Kiyomoto  Kazuo Iseki  Kazumaro Okamura 《Journal of Oceanography》2001,57(1):37-45

Satellite-derived ocean color data of Coastal Zone Color Scanner (CZCS) on board the Nimbus-7 and Ocean Color and Temperature Scanner (OCTS) on board the Advanced Earth Observing Satellite (ADEOS) are jointly used with historical in situ data to examine seasonal and spatial distributions of chlorophyll a (Chl-a) and suspended particulate matter (SPM) concentrations in the East China Sea. Ocean color imagery showed that Chl-a concentrations on the continental shelf were higher than those of the Kuroshio area throughout the year. Satellite-derived Chl-a concentrations are generally in good accordance with historical in situ values during spring through autumn (although no shipboard in situ measurement was conducted at nearshore areas). In contrast, ocean color imagery in winter indicated high Chl-a concentrations (4–10 mg m^–3) on the continental shelf where bottom depth was less than 50 m when surface water was turbid (2–72 g m^–3 of SPM at surface), while historical in situ values were usually less than 1 mg m^–3. This suggests that resuspended bottom sediment due to wind-driven mixing and winter cooling is responsible for the noticeable overestimation of satellite-derived Chl-a concentrations. The algorithm for ocean color needs to be improved urgently for turbid water.  相似文献   

Lower Cd/P ratio in settling particles than in surface seawater in the Okinawa Trough     

Kazuo Abe  Kazuo Iseki  Kazumaro Okamura  Yoko Kiyomoto 《Journal of Oceanography》2006,62(5):745-752

The characteristics of the ratios between cadmium (Cd) and phosphorus (P) in settling particles collected from the Okinawa Trough in the East China Sea were examined using a sediment trap, moored at a depth of 811 m for one year. The Cd/P ratios varied within a narrow range throughout the year, in spite of the large seasonal change in the total dry mass, Cd, and P fluxes. The average Cd/P ratio of settling particles was 0.062 (nmol/μmol), which was obviously lower than that of surface seawater around the study site (0.16). This lower ratio in the Okinawa Trough particles collected using the 811 m-moored trap certainly reflected the mixture of biologically produced organic matter around the study site and other components that were mainly transported as lateral flux from the shelf edge and slope area of the East China Sea.  相似文献   

Concentrations of 137Cs, 90Sr, 108m Ag, 239+240 Pu and atom ratio of 240Pu/239Pu in tanner crabs, Chionoecetes japonicus and Chionoecetes opilio collected around Japan     

Morita T  Ohtsuka Y  Fujimoto K  Minamisako Y  Iida R  Nakamura M  Kayama T 《Marine pollution bulletin》2010,60(12):2311-2322

The anthropogenic radionuclides, ¹³⁷Cs, ⁹⁰Sr, ^108mAg, ^239+240Pu, were measured in two Chionoecetes species, red queen crab (Chionoecetes japonicus) and snow crab (Chionoecetes opilio) collected around Japan during 1996–2007. There was no increase in the concentrations of these radionuclides and no large variation of the atom ratio of ²⁴⁰Pu/²³⁹Pu during this research period. These results indicated that the source of the radionuclides was not the radioactive wastes dumped by the former USSR and Russia and originated from past nuclear weapon tests. The higher atom ratio in the crab species than that from global fallout would be contributed by the Pacific Proving Grounds close-in fallout. The variability of the concentration of radionuclides in the crab species would result from the variability of the composition and quantity in the diet. However, the decrease in the concentration of radionuclides with sampling depth would depend on the concentration in the seawater and diet.  相似文献