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1.
For efficient and targeted management, this study demonstrates a recently developed non-point source (NPS) pollution model for a year-long estimation in the Pingqiao River Basin (22.3 km2) in China. This simple but physically reasonable model estimates NPS export in terms of land use by reflecting spatial hydrological features and source runoff measurements under different land-use types. The NPS export was separately analysed by a distributed hydrological model, a spatial hydrograph-separation technique, and an empirical water quality sub-model. Simulation results suggest that 57 890 kg of total nitrogen (TN) and 1148 kg of total phosphorus (TP) were delivered. The results, validated with observed stream concentrations, show relative errors of 23.3% for TN and 47.4% for TP. Countermeasures for urban areas (5.3% of total area) were prioritized because of the high contribution rate to TN (14.1%) and TP (26.2%) which is caused by the high degree of runoff (8.5%) and pollution source.  相似文献   
2.
The speciation and solubility of kimberlite pathfinder metals (Ni, Nd, Ba and K) in shallow peat groundwaters is investigated over the Yankee, Zulu and Golf kimberlites in the Attawapiskat region, James Bay Lowlands, Canada. The purpose of this study is to examine the relationship between dissolved organic matter (DOM) complexation with kimberlite pathfinder metals and determine the spatial distribution of those metals in shallow peat groundwaters along sampling transects over subcropping kimberlites. Nickel, Nd, Ba and K complexation with DOM and the adsorption of these metals onto ferrihydrite were calculated using Visual MINTEQ 3.0 and the NICA-Donnan database. Calculations predict almost 100% of soluble Nd, Ni and Ba form complexes with DOM at sampling sites with little to no contribution from upwelling groundwater (i.e., dissolved organic C (DOC) concentrations = 40–132 mg/L, pH = 3.9–5.5, and log ionic strength ??3). In only the most ombrotrophic peat groundwater conditions does a majority fraction of K bind to DOM. By contrast, under conditions with large contributions from upwelling groundwaters (i.e., DOC concentrations ?40 mg/L, pH = 5.5–6.5, and log ionic strength = ?3 to ?2), as little as 10% of Nd and Ni, and 0% K and Ba are predicted to complex with DOM. The modeling calculations suggest the dominant control on metal–DOM complexation, particularly with respect to Ni and Nd, is competitive effects for DOM binding sites due to elevated ionic strength where there is evidence of strong groundwater upwelling. Visual MINTEQ modeling of metal adsorption on ferrihydrite surfaces predicts that under strong upwelling conditions, Ni and Nd are scavenged from solution due to increased ferrihydrite precipitation and decreased fractions of metals complexed with DOM. Analytical geochemical data are consistent with model predictions of metal adsorption on ferrihydrite. Total dissolved Ni and Nd concentrations at sites of strong upwelling are up to five times lower than waters with little to no upwelling and log ferrihydrite saturation indices (logSIferr) indicate precipitation (values up to 5) at sites of strong groundwater upwelling. Where the majority of Ni and Nd complex with DOM and ferrihydrite is highly under saturated (logSIferr = ?18 to ?5), the concentrations of total Ni and Nd are elevated compared to other sites along sampling transects. Metal complexation with DOM effectively inhibits metal scavenging from solution via adsorption and/or from forming secondary mineral precipitates. Also, because alkaline earth metals do not compete strongly with Ni and Nd for adsorption sites on ferrihydrite surfaces, but do compete strongly for insoluble organic sites, Ni and Nd are more likely to adsorb onto ferrihydrite.  相似文献   
3.
Major pathways of biogenic carbon (C) flow are resolved for the planktonic food web of the flaw lead polynya system of the Amundsen Gulf (southeast Beaufort Sea, Arctic Ocean) in spring-summer 2008. This period was relevant to study the effect of climate change on Arctic marine ecosystems as it was characterized by unusually low ice cover and warm sea surface temperature. Our synthesis relied on a mass balance estimate of gross primary production (GPP) of 52.5 ± 12.5 g C m−2 calculated using the drawdown of nitrate and dissolved inorganic C, and a seasonal f-ratio of 0.64. Based on chlorophyll a biomass, we estimated that GPP was dominated by phytoplankton (93.6%) over ice algae (6.4%) and by large cells (>5 μm, 67.6%) over small cells (<5 μm, 32.4%). Ancillary in situ data on bacterial production, zooplankton biomass and respiration, herbivory, bacterivory, vertical particle fluxes, pools of particulate and dissolved organic carbon (POC, DOC), net community production (NCP), as well as selected variables from the literature were used to evaluate the fate of size-fractionated GPP in the ecosystem. The structure and functioning of the planktonic food web was elucidated through inverse analysis using the mean GPP and the 95% confidence limits of every other field measurement as lower and upper constraints. The model computed a net primary production of 49.2 g C m−2, which was directly channeled toward dominant calanoid copepods (i.e. Calanus hyperboreus 20%, Calanus glacialis 10%, and Metridia longa 10%), other mesozooplankton (12%), microzooplankton (14%), detrital POC (18%), and DOC (16%). Bacteria required 29.9 g C m−2, a demand met entirely by the DOC derived from local biological activities. The ultimate C outflow comprised respiration fluxes (82% of the initial GPP), a small sedimentation (3%), and a modest residual C flow (15%) resulting from NCP, dilution and accumulation. The sinking C flux at the model limit depth (395 m) supplied 60% of the estimated benthic C demand (2.8 g C m−2), suggesting that the benthos relied partly on other C sources within the bottom boundary layer to fuel its activity. In summary, our results illustrate that the ongoing decline in Arctic sea ice promotes the growth of pelagic communities in the Amundsen Gulf, which benefited from a ∼80% increase in GPP in spring-summer 2008 when compared to 2004 – a year of average ice conditions and relatively low GPP. However, 53% of the secondary production was generated within the microbial food web, the net ecological efficiency of zooplankton populations was not particularly high (13.4%), and the quantity of biogenic C available for trophic export remained low (6.6 g C m−2). Hence it is unlikely that the increase in lower food web productivity, such as the one observed in our study, could support new harvestable fishery resources in the offshore Beaufort Sea domain.  相似文献   
4.
Extreme stream-flow events of Citarum River are derived from the daily stream-flows at the Nanjung gauge station. Those events are identified based on their persistently extreme flows for 6 or more days during boreal fall when the seasonal mean stream-flow starts peaking-up from the lowest seasonal flows of June–August. Most of the extreme events of high-streamflows were related to La Ni?a conditions of tropical Pacific. A few of them were also associated with the negative phases of IOD and the newly identified El Ni?o Modoki. Unlike the cases of extreme high streamflows, extreme low streamflow events are seen to be associated with the positive IODs. Nevertheless, it was also found that the low-stream-flow events related to positive IOD events were also associated with El Ni?o events except for one independent event of 1977. Because the occurrence season coincides the peak season of IOD, not only the picked extreme events are seen to fall under the IOD seasons but also there exists a statistically significant correlation of 0.51 between the seasonal IOD index and the seasonal streamflows. There also exists a significant lag correlation when IOD of June–August season leads the streamflows of September–November. A significant but lower correlation coefficient (0.39) is also found between the seasonal streamflow and El Ni?o for September–November season only.  相似文献   
5.
Inter‐decadal and geographic variations in the diets of Steller sea lion, Eumetopias jubatus, were examined based on the contents of 408 stomachs collected from coastal areas around Hokkaido Island during the periods 1994–1998 and 2005–2012. The most important prey species in the 1990s were gadid fishes (walleye pollock [Gadus chalcogrammus], Pacific cod [Gadus microcephalus] and saffron cod [Eleginus gracilis]). The frequency of occurrence and gravimetric contribution of gadids decreased in the 2000s latter period at three study sites (Rausu, Shakotan and Rebun) and were replaced by Okhotsk Atka mackerel (Pleurogrammus azonus) and smooth lumpsucker (Aptocyclus ventricosus). However, analysis based on gravimetric composition indicated that the dietary diversity of prey showed only a slight inter‐decadal difference, reflecting the wide diversity of prey ingested during both study periods. These results indicate that Steller sea lions along the Hokkaido coast are opportunistic feeders that utilize a wide variety of prey, and appear to feed mainly upon prey that is easily obtained.  相似文献   
6.
This paper deals with the periodic fluctuation of precipitation at three meteorological stations (Atar, Chenguitti, and Akjoujt) in the Adrar and Inchiri provinces in northern Mauritania and its links with sea surface temperature (SST). Trends for these three meteorological stations were evaluated using the Mann–Kendall (MK) nonparametric test, regression analysis, and autocorrelation for persistence analysis. The MK test showed a significant decreasing trend for Akjoujt and an insignificant trend for the other rainfall time series. However, the decreasing linear regression trends were highly significant for the different time series. On the other hand, persistence analysis indicated the presence of a linear Markov type. The cycles found by power spectrum analysis ranged from 0.5 years to about 11 years. The possibility of a connection between precipitation in this region and sunspot numbers was suggested. SST of the Atlantic Ocean, Indian Ocean, and Mediterranean Sea have significant cross-correlations with precipitation in the study area. The El Niño-Southern Oscillation effect was found to be marginal.  相似文献   
7.
Knowledge of the mechanisms of rain‐induced shallow landslides can improve the prediction of their occurrence and mitigate subsequent sediment disasters. Here, we examine an artificial slope's subsurface hydrology and propose a new slope stability analysis that includes seepage force and the down‐slope transfer of excess shear forces. We measured pore water pressure and volumetric water content immediately prior to a shallow landslide on an artificial sandy slope of 32°: The direction of the subsurface flow shifted from downward to parallel to the slope in the deepest part of the landslide mass, and this shift coincided with the start of soil displacement. A slope stability analysis that was restricted to individual segments of the landslide mass could not explain the initiation of the landslide; however, inclusion of the transfer of excess shear forces from up‐slope to down‐slope segments improved drastically the predictability. The improved stability analysis revealed that an unstable zone expanded down‐slope with an increase in soil water content, showing that the down‐slope soil initially supported the unstable up‐slope soil; destabilization of this down‐slope soil was the eventual trigger of total slope collapse. Initially, the effect of apparent soil cohesion was the most important factor promoting slope stability, but seepage force became the most important factor promoting slope instability closer to the landslide occurrence. These findings indicate that seepage forces, controlled by changes in direction and magnitude of saturated and unsaturated subsurface flows, may be the main cause of shallow landslides in sandy slopes. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
8.
W.B. Hubbard  M.F. Hattori  I. Hubeny 《Icarus》2007,187(2):358-364
We present calculations for the evolution and surviving mass of highly-irradiated extrasolar giant planets (EGPs) at orbital semimajor axes ranging from 0.023 to 0.057 AU using a generalized scaled theory for mass loss, together with new surface-condition grids for hot EGPs and a consistent treatment of tidal truncation. Theoretical estimates for the rate of energy-limited hydrogen escape from giant-planet atmospheres differ by two orders of magnitude, when one holds planetary mass, composition, and irradiation constant. Baraffe et al. [Baraffe, I., Selsis, F., Chabrier, G., Barman, T.S., Allard, F., Hauschildt, P.H., Lammer, H., 2004. Astron. Astrophys. 419, L13-L16] predict the highest rate, based on the theory of Lammer et al. [Lammer, H., Selsis, F., Ribas, I., Guinan, E.F., Bauer, S.J., Weiss, W.W., 2003. Astrophys. J. 598, L121-L124]. Scaling the theory of Watson et al. [Watson, A.J., Donahue, T.M., Walker, J.C.G., 1981. Icarus 48, 150-166] to parameters for a highly-irradiated exoplanet, we find an escape rate ∼102 lower than Baraffe's. With the scaled Watson theory we find modest mass loss, occurring early in the history of a hot EGP. In this theory, mass loss including the effect of Roche-lobe overflow becomes significant primarily for masses below a Saturn mass, for semimajor axes ?0.023 AU. This contrasts with the Baraffe model, where hot EGPs are claimed to be remnants of much more massive bodies, originally several times Jupiter and still losing substantial mass fractions at present.  相似文献   
9.
Two inverted echo sounders were maintained on coastal and offshore sides of the Kuroshio south of Japan from October 1993 to July 2004. Applying the gravest empirical mode method, we obtained a time series of geostrophic transport. Estimated transports generally agree well with geostrophic transports estimated from hydrography. Their agreement with the hydrographic transports is better than that of transports estimated from satellite altimetry data. The geostrophic transport is expressed as the surface transport per unit depth multiplied by the equivalent depth. The geostrophic transport varies mostly with the surface transport and fractionally with the equivalent depth. Seasonal variation of the geostrophic transport has a minimum in March and a maximum in September, with a range of about one fifth of the total transport.  相似文献   
10.
A micropaleontologic assemblage zone is defined by occurrence of some characteristic species among many coeval species. When number of assemblage-defining species and total number of species observed are designated as Aand N,respectively, the ratio, A/N,is strongly dependent on duration of the assemblage. Theoretical consideration on the basis of a micropaleontologic cohort model shows that, when origination rate and extinction rate of species are obtained, the most reasonable ratio (A/N) and duration of the assemblage can be determined. The probabilistic model described in this paper provides a theoretical relation between the ratio and the duration. Inaccuracy in correlating micropaleontologic data to certain assemblage zones established can not be avoided because of many natural sorting and artificial biases. Ambiguity arising when data with a small number of characteristic species are correlated with a certain assemblage is numerically estimated.  相似文献   
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