首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 15 毫秒
1.
To study arsenic(As) content and distribution patterns as well as the genesis of different kinds of water, especially the different sources of drinking water in Guanzhong Basin, Shaanxi province, China, 139 water samples were collected at 62 sampling points from wells of different depths, from hot springs, and rivers. The As content of these samples was measured by the intermittent flowhydride generation atomic fluorescence spectrometry method(HG-AFS). The As concentrations in the drinking water in Guanzhong Basin vary greatly(0.00–68.08 μg/L), and the As concentration of groundwater in southern Guanzhong Basin is different from that in the northern Guanzhong Basin. Even within the same location in southern Guanzhong Basin, the As concentrations at different depths vary greatly. As concentration of groundwater from the shallow wells(50 m deep, 0.56–3.87 μg/L) is much lower than from deep wells(110–360 m deep, 19.34–62.91 μg/L), whereas As concentration in water of any depth in northern Guanzhong Basin is 10 μg/L. Southern Guanzhong Basin is a newly discovered high-As groundwater area in China. The high-As groundwater is mainly distributed in areas between the Qinling Mountains and Weihe River; it has only been found at depths ranging from 110 to 360 m in confined aquifers, which store water in the Lishi and Wucheng Loess(Lower and Middle Pleistocene) in the southern Guanzhong Basin. As concentration of hot spring water is 6.47–11.94 μg/L; that of geothermal water between 1000 and 1500 m deep is 43.68–68.08 μg/L. The high-As well water at depths from 110 to 360 m in southern Guanzhong Basin has a very low fluorine(F) value, which is generally 0.10 mg/L. Otherwise, the hot springs of Lintong and Tangyu and the geothermal water in southern Guanzhong Basin have very high F values(8.07–14.96 mg/L). The results indicate that highAs groundwater in depths from 110 to 360 m is unlikely to have a direct relationship with the geothermal water in the same area. As concentration of all reservoirs and rivers(both contaminated and uncontaminated) in the Guanzhong Basin is 10 μg/L. This shows that pollution in the surface water is not the source of the high-As in the southern Guanzhong Basin. The partition boundaries of the high- and low-As groundwater area corresponds to the partition boundaries of the tectonic units in the Guanzhong Basin. This probably indicates that the high-As groundwater areas can be correlated to their geological underpinning and structural framework. In southern Guanzhong Basin, the main sources of drinking water for villages and small towns today are wells between 110–360 m deep. All of their As contents exceed the limit of the Chinese National Standard and the International Standard(10 μg/L) and so local residents should use other sources of clean water that are 50 m deep, instead of deep groundwater(110 to 360 m) for their drinking water supply.  相似文献   

2.
A monolith representing 5420 14C yr of peat accumulation was collected from a blanket bog at Myrarnar, Faroe Islands. The maximum Hg concentration (498 ng/g at a depth of 4.5 cm) coincides with the maximum concentration of anthropogenic Pb (111 μg/g). Age dating of recent peat accumulation using 210Pb (CRS model) shows that the maxima in Hg and Pb concentrations occur at AD 1954 ± 2. These results, combined with the isotopic composition of Pb in that sample (206Pb/207Pb = 1.1720 ± 0.0017), suggest that coal burning was the dominant source of both elements. From the onset of peat accumulation (ca. 4286 BC) until AD 1385, the ratios Hg/Br and Hg/Se were constant (2.2 ± 0.5 × 10-4 and 8.5 ± 1.8 × 10-3, respectively). Since then, Hg/Br and Hg/Se values have increased, also reaching their maxima in AD 1954. The age date of the maximum concentrations of anthropogenic Hg and Pb in the Faroe Islands is consistent with a previous study of peat cores from Greenland and Denmark (dated using the atmospheric bomb pulse curve of 14C), which showed maximum concentrations in AD 1953.The average rate of atmospheric Hg accumulation from 1520 BC to AD 1385 was 1.27 ± 0.38 μg/m2/yr. The Br and Se concentrations and the background Hg/Br and Hg/Se ratios were used to calculate the average rate of natural Hg accumulation for the same period, 1.32 ± 0.36 μg/m2/yr and 1.34 ± 0.29 μg/m2/yr, respectively. These fluxes are similar to the preanthropogenic rates obtained using peat cores from Switzerland, southern Greenland, southern Ontario, Canada, and the northeastern United States. Episodic volcanic emissions and the continual supply of marine aerosols to the Faroe Islands, therefore, have not contributed significantly to the Hg inventory or the Hg accumulation rates, relative to these other areas. The maximum rate of Hg accumulation was 34 μg/m2/yr. The greatest fluxes of anthropogenic Hg accumulation calculated using Br and Se, respectively, were 26 and 31 μg/m2/yr. The rate of atmospheric Hg accumulation in 1998 (16 μg/m2/yr) is comparable to the values recently obtained by atmospheric transport modeling for Denmark, the Faroe Islands, and Greenland.  相似文献   

3.
《Applied Geochemistry》2003,18(9):1297-1312
The concentrations of As in surface- and up to 90 °C ground waters in a tholeiite flood basalt area in N-Iceland lie in the range <0.03–10 μg/kg. With few exceptions surface waters contain <0.5 μg/kg As whereas ground waters generally contain >0.5 μg/kg As. The As content of ground waters increases on the whole with rising temperature. Arsenic is highly mobile in the basalt-water environment of the study area. An insignificant fraction of the As dissolved from the rock is taken up into secondary minerals. Arsenic is less mobile than B but considerably more mobile than Na which has the highest mobility among the major aqueous components. A significant fraction of the As in the basalt occurs in an easily soluble form. The As hosted in the primary minerals is expected to be concentrated in the titano-magnetite. This mineral is stable in contact with both surface- and ground waters and does not, therefore, supply As to the water, explaining the difference in mobility between As and B. Aqueous As concentrations are a reflection of water/rock ratios, i.e. how much rock a given quantity of water has dissolved. This ratio increases with increasing temperature and increasing residence time of the water in contact with the rock. The distribution of As species has been calculated on the assumption of equilibrium at the redox potential retrieved from measurement of aqueous Fe(II) and Fe(III) concentrations. These calculations indicate that pentavalent As is stable in surface waters and in ground waters with an in situ pH of <10 and would occur mostly as H2AsO4− and HAsO4−2. In higher pH ground waters the concentrations of the arsenite species H2AsO3− is significant at equilibrium, up to 65% of the total dissolved As.  相似文献   

4.
《Applied Geochemistry》2004,19(3):343-358
Ion-exchange batch experiments were run on Cretaceous (Magothy aquifer) clay cores from a nearshore borehole and an inland borehole on Long Island, NY, to determine the origin of high SO42− concentrations in ground water. Desorption batch tests indicate that the amounts of SO42− released from the core samples are much greater (980–4700 μg/g of sediment) than the concentrations in ground-water samples. The locally high SO42− concentrations in pore water extracted from cores are consistent with the overall increase in SO42− concentrations in ground water along Magothy flow paths. Results of the sorption batch tests indicate that SO42− sorption onto clay is small but significant (40–120 μg/g of sediment) in the low-pH (<5) pore water of clays, and a significant part of the SO42− in Magothy pore water may result from the oxidation of FeS2 by dissolved Fe(III). The acidic conditions that result from FeS2 oxidation in acidic pore water should result in greater sorption of SO42− and other anions onto protonated surfaces than in neutral-pH pore water. Comparison of the amounts of Cl− released from a clay core sample in desorption batch tests (4 μg/g of sediment) with the amounts of Cl− sorbed to the same clay in sorption tests (3.7–5 μg/g) indicates that the high concentrations of Cl− in pore water did not originate from connate seawater but were desorbed from sediment that was previously in contact with seawater. Furthermore, a hypothetical seawater transgression in the past is consistent with the observed pattern of sorbed cation complexes in the Magothy cores and could be a significant source of high SO42− concentrations in Magothy ground water.  相似文献   

5.
Mathematical simulations on dam break or failure using BOSS DAMBRK hydrodynamic flood routing dam break model were carried out to determine the extent of flooding downstream, flood travel times, flood water velocities and impacts on downstream affected residences, properties and environmental sensitive areas due to floodwaters released by failure of the dam structure. Computer simulations for one of the worse case scenarios on dam failure using BOSS DAMBRK software accounted for dam failure, storage effects, floodplains, over bank flow and flood wave attenuation. The simulated results reviewed a maximum flow velocity of 2.40 m/s with a discharge of approximately 242 mз /s occurred at 1.00 km downstream. The maximum discharge increased from 244 m3/s (flow velocity = 1.74 m/s occurred at 8th. km) to 263 m3/s (flow velocity = 1.37 m/s occurred at 12th. km); about a 39% drop in flow velocity over a distance of 4.00 km downstream. If the entire dam gives way instantly, some spots stretching from 0.00 km (at dam site) to approximately 3.40 km downstream of the dam may be categorized as “danger zone”, while downstream hazard and economic loss beyond 3.40 km downstream can be classified as “low” or “minimal” zones.  相似文献   

6.
In April 2010, an ice/rockfall into Lake 513 triggered a glacial lake outburst flood (GLOF) along the Chucchun River in the Cordillera Blanca of Peru. This paper reconstructs the hydrological characteristics of this as yet undocumented event using a 1D flood model prepared with HEC-RAS. The principle model inputs were obtained during detailed field surveys of surface characteristics and topography within the river and across the adjacent floodplain; a total of 120 cross-sections were surveyed. These inputs were refined further by eyewitness accounts and additional geomorphological observations. The flood modelling has enabled us to constrain the extent of the water surface and its elevation at each cross-section in addition to defining the peak discharge (580 m3 s?1). These modelling results show good agreement with other information about the flood including: flood marks and minimum flood levels; the lake displacement wave height; the extent of the flooded area; and the travel time from Lake 513 to the confluence with the Santa River. This demonstrates that the model offers a reliable reconstruction of the basic hydrological characteristics of the GLOF. It provides important information about the flood intensity and significantly improves our ability to model future flood scenarios along both the studied river and within neighbouring catchments. The flood hazard, defined by the flood depth during peak discharge, shows that the majority of the damaged infrastructure (houses, bridges, and a drinking water treatment plant) was only subjected to low or medium flood intensities (defined by a maximum water depth of less than 2 m). These low flood intensities help to explain why the flooding caused comparatively minor damage despite the significant public attention it attracted.  相似文献   

7.
The present study describes variations in the vertical fluxes measured concurrently with sediment traps at both a shallow water (4 m) and a deeper water (7.5 m) position in a coastal lagoon in April 1995. A tripod equipped with five sediment traps (trap openings at 0.35 m, 0.75 m, 1.05 m, 1.40 m, and 1.80 m above the seabed) was placed at the shallow water position. This tripod was deployed three times during the study period and deployment periods varied between 2 d and 5 d. The second sediment trap, placed at the deep water position in the central part of the lagoon, measured vertical flux for intervals of 12 h at 1.4 m above the seabed. The horizontal distance between the sediment traps was 8 km. The average maximum vertical flux at the shallow water position reached 27.9 g m−2 d−1 during a period of high, westerly wind speeds, and a maximum vertical flux of 16.9 g m−2 d−1 was reached at the deep water position during a period of high, easterly wind speeds. Both strong resuspension events were closely related to increased wave shear stress derived from surface waves. Maximum wave-induced resuspension rate was 10 times higher at the shallow water position and 3.8 times higher at the deep water position compared with the net sedimentation rate in the lagoon. Small resuspension events occurred at the shallow water position during periods of increased current shear stress, Estimations of conditions for transport of sediment between shallow water and deep water showed that particles must be resuspended to a height between 3 m and 4 m and that current speeds must be higher than about 0.1 m s−1. An average sedimentation rate of 3.8 g m−2 d−1 was obtained at the shallow water position during a period without wave shear stress and low current shear stress. This rate measured by sediment traps is similar to a net sedimentation rate in the lagoon of 4.4 g m−2 d−1, which was determined by radiocarbon dating of a sediment core (Kristensen et al. 1995).  相似文献   

8.
《Applied Geochemistry》1993,8(2):115-126
The major tributaries draining the Kendrick Reclamation Project (KRP) account for an average of 52% of the total Se load measured in the North Platte River downstream from Casper, Wyoming. The Casper Creek drainage basin contributed the largest Se load of the five tributary sites to the North Platte River. The 4-d average Se concentration in water samples from one site in the part of the North Platte River that receives irrigation return flows exceeded the 5 μg/l U.S. Environmental Protection Agency's aquatic life criterion five time during a 50-d monitoring period in 1989. In agreement with the water-quality data, muscle and liver tissue rom rainbow trout collected from the same part of the North Platte River had Se concentrations exceeding levels known to cause reproductive failure and chronic Se poisoning. On the basis of Se: Cl, 18O/16O and D/H ratios in water from Goose and Rasmus Lee Lakes (closed-basin systems), the large Se concentrations in those lakes were derived by natural evaporation of irrigation water without leaching of soluble forms of Se from soil or rocks. Water samples from Thirtythree Mile Reservoir and Illco Pond (flow-through systems) showed considerable enrichment in Se over evaporative concentration, presumably due to leaching and desorption of Se from soil and rock. The Se: Cl ratios of irrigation drain water collected from the KRP indicate that leaching and desorption of soluble forms of Se from soils and rocks are the dominant processes in drain water. Results of a Wilcoxon matched-pairs test for 43 paired drain-water samples collected during June and August 1988, indicated there is a statistically larger concentration of Se (0.01 significance level) during the June sampling period. The larger concentrations of Se and other chemical constitutents during the early part of the irrigation season probably were due to dissolution of seleniferous salts that have accumulated in soils within the KRP since the last irrigation season. The large Se concentrations in water samples from wetland sites in the KRP were reflected in the aquatic-bird food chain. Most waterfowl and shorebirds nesting at the KRP showed Se concentrations in livers and eggs greater than levels suspected of causing adverse reproductive effects.  相似文献   

9.
《Geodinamica Acta》2013,26(1-3):89-100
The study presents natural hazards in Slovenia's karst, focusing on flooding in karst poljes. A specific study was done on the flood dynamics of two typical and connected karst poljes (Cerknica and Planina) of the Classical Karst region. In the case of particularly extreme hydrological conditions in the autumn of 2008, detailed analyses of the recharge-discharge regime and the interrelationship of flooding on the two poljes were done. Daily precipitation, discharge, and water level values from several monitoring sites were analyzed and cross-correlated, and additional hydrological analyses were done using a digital elevation model in order to acquire water level increase and decrease intensity, flood water volumes, and the extent of flooding and to understand the conditions controlling karst flooding. The results reveal that the hydrological functioning of the studied karst poljes is influenced by the hydrogeological and temporary hydrological conditions in the catchment area. The response of the binary karst system (i.e., the influence of autogenic and allogenic recharge) is especially distinct. The study shows that during extremely intense recharge, the reactions of karst aquifer systems to precipitation are as rapid as the response of surface waters (the water level of Cerknica Lake increased with an intensity of 38-63 cm/day or 55 m3/s respectively) while retention capacities are negligible. In contrast to flash floods, floods in karst areas may last from several weeks to several months. For the observed period a three-dimensional simulation of the flooding was made. At the maximum recorded water level, the volume of water on the Cerknica polje was 51 million m3, and 26 million m3 on the Planina polje. The maximum extent of flooding on the Cerknica polje was 23 km2 and on the Planina polje 9.5 km2. On the basis of the study, information was provided regarding future hazard mitigation. However, the study demonstrated that a sufficiently dense monitoring network is necessary to predict the occurrence and duration of floods with greater certainty.  相似文献   

10.
《Applied Geochemistry》2004,19(2):201-214
Detailed hydrochemical measurements, δ34SSO4 and 3H analyses were performed on 37 groundwater samples collected during February 1999, January and March 2000 from 6 locations in eastern and southeastern Bangladesh to examine redox processes that lead to As mobilization in groundwater. The study sites were chosen based on available nation-wide As surveys to span the entire spectrum of As concentrations in Bangladesh groundwater, and to represent 3 of 5 major geological units of the Ganges-Brahmaputra Delta: uplifted Pleistocene terrace, fluvial flood plain and delta plain. Arsenic was found to be mobilized under Fe-reducing conditions in shallow aquifers (<35 m depth), presumably of Holocene age. It remained mobile under SO4-reducing conditions, suggesting that authigenic sulfide precipitation does not constitute a significant sink for As in these groundwaters. The redox state of the water was characterized by a variety of parameters including dissolved O2, NO3−, Mn2+, Fe2+ concentrations, and SO42−/Cl− ratios. High dissolved [As] (> 50 μg/l; or > 0.7 μM ) were always accompanied by high dissolved [HCO3−] (> 4 mM), and were close to saturation with respect to calcite. Groundwater enriched in As (200–800 μg/l; or 2.7–10.7 μM) and phosphate (30–100 μM) but relatively low in dissolved Fe (5–40 μM) probably resulted from re-oxidation of reducing, As and Fe enriched water. This history was deduced from isotopic signatures of δ34SSO4 and 3H2O (3H) to delineate the nature of redox changes for some of the reducing groundwaters. In contrast, As is not mobilized in presumed Pleistocene aquifers, both shallow (30–60 m) and deep (150–270 m), because conditions were not reducing enough due to lack of sufficient O2 demand.  相似文献   

11.
Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l?1 for both F and Cl and 10 ng l?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg?1 for F and Cl and 2 μg kg?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg?1 for F and Cl, 100 μg kg?1 for Br and 25 μg kg?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level.  相似文献   

12.
Intense rainstorms in 2008 resulted in wide-spread flooding across the Midwestern United States. In Wisconsin, floodwater inundated a 17.7-km2 area on an outwash terrace, 7.5 m above the mapped floodplain of the Wisconsin River. Surface-water runoff initiated the flooding, but results of field investigation and modeling indicate that rapid water-table rise and groundwater inundation caused the long-lasting flood far from the riparian floodplain. Local geologic and geomorphic features of the landscape lead to spatial variability in runoff and recharge to the unconfined sand and gravel aquifer, and regional hydrogeologic conditions increased groundwater discharge from the deep bedrock aquifer to the river valley. Although reports of extreme cases of groundwater flooding are uncommon, this occurrence had significant economic and social costs. Local, state and federal officials required hydrologic analysis to support emergency management and long-term flood mitigation strategies. Rapid, sustained water-table rise and the resultant flooding of this high-permeability aquifer illustrate a significant aspect of groundwater system response to an extreme precipitation event. Comprehensive land-use planning should encompass the potential for water-table rise and groundwater flooding in a variety of hydrogeologic settings, as future changes in climate may impact recharge and the water-table elevation.  相似文献   

13.
Two boreholes and ten piezometers in the Ganges flood plain were drilled and installed for collecting As-rich sediments and groundwater. Groundwater samples from the Ganges flood plain were collected for the analysis of cations (Ca2+, Mg2+, K+, Na+), anions (Cl−, NO3 −, SO4 2−), total organic carbon (TOC), and trace elements (As, Mn, Fe, Sr, Se, Ni, Co, Cu, Mo, Sb, Pb). X-ray powder diffraction was performed to characterize the major mineral contents of aquifer sediments and X-ray fluorescence (XRF) to analyze the major chemical composition of alluvial sediments. Results of XRF analysis clearly show that fine-grained sediments contain higher amounts of trace element because of their high surface area for adsorption. Relative fluorescence index (15–38 QSU) of humic substance in groundwater was measured using spectrofluorometer, the results revealed that groundwater in the Ganges flood plain contains less organic matter (OM). Arsenic concentration in water ranges from 2.8 to 170 μg/L (mean 50 μg/L) in the Ganges flood plain. Arsenic content in sediments ranges from 2.1 to 14 mg/kg (mean 4.58 mg/kg) in the flood plains. TOC ranges from 0.49 to 3.53 g/kg (mean 1.64 g/kg) in the Ganges flood plain. Arsenic is positively correlated with TOC (R 2 = 0.55) in sediments of this plain. Humic substances were extracted from the sediments from the Ganges flood plain. Fourier transform infrared analysis of the sediments revealed that the plain contains less humic substances. The source of organic carbon was assigned from δ13C values obtained using elemental analysis-isotope ratio mass spectrometry (EA-IRMS); the values (−10 to −29.44‰) strongly support the hypothesis that the OM of the Ganges flood plain is of terrestrial origin.  相似文献   

14.
《Applied Geochemistry》2004,19(7):1123-1135
About 200 samples from selected public supply, domestic, and observation wells completed in alluvial aquifers underlying the western Mojave Desert were analyzed for total dissolved Cr and Cr(VI). Because Cr(VI) is difficult to preserve, samples were analyzed by 3 methods. Chromium(VI) was determined in the field using both a direct colorimetric method and EPA method 218.6, and samples were speciated in the field for later analysis in the laboratory using a cation-exchange method developed for the study described in this paper. Comparison of the direct colorimetric method and EPA method 218.6 with the new cation-exchange method yielded r2 values of 0.9991 and 0.9992, respectively. Total dissolved Cr concentrations ranged from less than the 0.1 μg/l detection limit to 60 μg/l, and almost all the Cr present was Cr(VI). Near recharge areas along the mountain front pH values were near neutral, dissolved O2 concentrations were near saturation, and Cr(VI) concentrations were less than the 0.1 μg/l detection limit. Chromium(VI) concentrations and pH values increased downgradient as long as dissolved O2 was present. However, low Cr(VI) concentrations were associated with low dissolved O2 concentrations near ground-water discharge areas along dry lakes. Chromium(VI) concentrations as high as 60 μg/l occurred in ground water from the Sheep Creek fan alluvial deposits weathered from mafic rock derived from the San Gabriel Mountains, and Cr(VI) concentrations as high as about 36 μg/l were present in ground water from alluvial deposits weathered from less mafic granitic, metamorphic, and volcanic rocks. Chromium(III) was the predominant form of Cr only in areas where dissolved O2 concentrations were less than 1 mg/l and was detected at a median concentration of 0.1 μg/l, owing to its low solubility in water of near-neutral pH. Depending on local hydrogeologic conditions and the distribution of dissolved O2, Cr(VI) concentrations may vary considerably with depth. Samples collected under pumping conditions from different depths within wells show that Cr(VI) concentrations can range from less than the 0.1 μg/l detection limit to 36 μg/l in a single well and that dissolved O2 concentrations likely control the concentration and redox speciation of Cr in ground water.  相似文献   

15.
Land subsidence in Bangkok, Thailand   总被引：9，自引：0，他引：9  
Land subsidence from deep well pumping has been affecting Bangkok for the past 35 years. Its impact is particularly critical because of the flat low-lying topography and the presence of a thick soft clay layer at the ground surface that augment flood risk and foundation engineering problems, respectively. The subsidence reached its most critical state in the early 1980s when it occurred at a rate as high as 120 mm/year. The rate decreased in the subsequent period but the subsidence-affected area expanded following the growth of the city. Despite various attempts implemented to remedy the crisis, groundwater pumping from the thick aquifer system underneath the city continued to increase from 1.2 million m3/day in the early 1980s to more than 2.0 million m3/day at the turn of the century. Piezometric levels in the main aquifer layers had been drawn down by as much as 65 m. Monitoring data showed a clear correlation between the subsidence and piezometric drawdown. The data suggested that for 1 m3 of groundwater pumped out in Bangkok Plain, approximately 0.10 m3 of ground loss occurred at the surface. Significant development has been made in numerical methods for prediction of differential settlements between building foundations caused by the piezometric drawdown in the aquifers. The strict mitigation measures adopted recently, comprising a pricing policy for groundwater management, an expansion of tap water supply, and strict enforcement of groundwater laws, have resulted in a marked drop in groundwater use. However, the land subsidence will continue for a long while owing to the time-dependent consolidation behavior of the soft clay layer and clay aquitards.  相似文献   

16.
The chemical reactivity of uranium was investigated across estuarine gradients from two of the world’s largest river systems: the Amazon and Mississippi. Concentrations of dissolved (<0.45 μm) uranium (U) were measured in surface waters of the Amazon shelf during rising (March 1990), flood (June 1990) and low (November 1991) discharge regimes. The dissolved U content was also examined in surface waters collected across estuarine gradients of the Mississippi outflow region during April 1992, August 1993, and November (1993). All water samples were analyzed for U by isotope dilution inductively coupled plasma mass spectrometry (ICP-MS). In Amazon shelf surface waters uranium increased nonconservatively from about 0.01 μg I?1 at the river’s mouth to over 3 μg I?1 at the distal site, irrespective of river discharge stage. Observed large-scale U removal at salinities generally less than 15 implies a) that riverine dissolved U was extensively adsorbed by freshly-precipitated hydrous metal oxides (e.g., FeOOH, MnO2) as a result of flocculation and aggregation, and b) that energetic resuspension and reworking of shelf sediments and fluid muds on the Amazon shelf released a chemically reactive particle/colloid to the water column which can further scavenge dissolved U across much of the estuarine gradient. In contrast, the estuarine chemistry of U is inconclusive within surface waters of the Mississippi shelf-break region. U behavior is most likely controlled less by traditional sorption and/or desorption reactions involving metal oxides or colloids than by the river’s variable discharge regime (e.g., water parcel residence time during estuarine mixing, nature of particulates, sediment storage and resuspension in, the confined lower river), and plume dispersal. Mixing of the thin freshwater lens into ambient seawater is largely defined by wind-driven rather than physical processes. As a consequence, in the Mississippi outflow region uranium predominantly displays conservative behavior; removal is evident only during anomalous river discharge regimes. ‘Products-approach’ mixing experiments conducted during the Flood of 1993 suggest the importance of small particles and/or colloids in defining a depleted U versus salinity distribution.  相似文献   

17.
《Applied Geochemistry》2002,17(6):751-779
Uranium concentrations and 234U/238U ratios in saturated-zone and perched ground water were used to investigate hydrologic flow and downgradient dilution and dispersion in the vicinity of Yucca Mountain, a potential high-level radioactive waste disposal site. The U data were obtained by thermal ionization mass spectrometry on more than 280 samples from the Death Valley regional flow system. Large variations in both U concentrations (commonly 0.6–10 μg l−1) and 234U/238U activity ratios (commonly 1.5–6) are present on both local and regional scales; however, ground water with 234U/238U activity ratios from 7 up to 8.06 is restricted largely to samples from Yucca Mountain. Data from ground water in the Tertiary volcanic and Quaternary alluvial aquifers at and adjacent to Yucca Mountain plot in 3 distinct fields of reciprocal U concentration versus 234U/238U activity ratio correlated to different geographic areas. Ground water to the west of Yucca Mountain has large U concentrations and moderate 234U/238U whereas ground water to the east in the Fortymile flow system has similar 234U/238U, but distinctly smaller U concentrations. Ground water beneath the central part of Yucca Mountain has intermediate U concentrations but distinctive 234U/238U activity ratios of about 7–8. Perched water from the lower part of the unsaturated zone at Yucca Mountain has similarly large values of 234U/238U. These U data imply that the Tertiary volcanic aquifer beneath the central part of Yucca Mountain is isolated from north-south regional flow. The similarity of 234U/238U in both saturated- and unsaturated-zone ground water at Yucca Mountain further indicates that saturated-zone ground water beneath Yucca Mountain is dominated by local recharge rather than regional flow. The distinctive 234U/238U signatures also provide a natural tracer of downgradient flow. Elevated 234U/238U in ground water from two water-supply wells east of Yucca Mountain are interpreted as the result of induced flow from 40 a of ground-water withdrawal. Elevated 234U/238U in a borehole south of Yucca Mountain is interpreted as evidence that natural downgradient flow is more likely to follow southerly paths in the structurally anisotropic Tertiary volcanic aquifer where it becomes diluted by regional flow in the Fortymile system.  相似文献   

18.
A strong He-U anomaly, discovered in the Thelon basin of the N.W.T. during a regional U exploration program in 1981, was studied in detail in 1982. The anomaly is confined to a 3-km2 lake situated 160 km northwest of Baker Lake. Lake bottom water and sediment samples taken in June through the ice on a 50 m × 50 m grid, were analyzed for a number of trace and minor elements.In the lake sediments He and U were highly anomalous and parallel the strong anomaly patterns of He observed in the water. Median and maximum values in the sediments were 57 ppm and 396 ppm U, and 296 nL/L and 13870 nL/L He. Regional medians were 4.3 ppm U and 50 nL/L He. Se and V in sediments gave weak but similar anomaly patterns to those observed for U and He.The anomaly is somewhat of an enigma. The unusually high U content indicates an oxidizing, hence, near surface, water regime, and the highly anomalous He flux into the lake and a thick cover of permafrost in the region indicate a very deep source where conditions are normally reducing, rendering U immobile.Coincident anomaly patterns and increasing concentrations with depth of minor and trace elements and gases in the lake water prove that groundwater is the source of the anomalies. Contoured element maps indicate that this groundwater enters the lake in at least four places.The fact that up to 35 ppb U, 6 ppm dissolved O2 and virtually no Fe and Mn, were detected in lake waters above groundwater entry points indicates that the groundwaters were oxidizing with respect to these elements. This is indeed surprising because permafrost is believed to be about 300 m thick in the region; at such depths groundwaters are usually rich in Fe and void of U.The highly anomalous He in this lake indicates deep fractures which serve as conduits for mineralized water entering the lake from depth and creating a frost-free window in the permafrost. The fractures probably penetrate well into the basement for only major deep fractures are known to produce such strong He anomalies. The additional presence of anomalous U suggests U mineralization at depth.  相似文献   

19.
《Applied Geochemistry》1995,10(5):491-503
Gross-beta activity has been used as an indicator of beta-emitting isotopes in water since at least the early 1950s. Originally designed for detection of radioactive releases from nuclear facilities and weapons tests, analysis of gross-beta activity is widely used in studies of naturally occurring radioactivity in ground water. Analyses of about 800 samples from 5 ground-water regions of the United States provide a basis for evaluating the utility of this measurement. The data suggest that measured gross-beta activities are due to (1) long-lived radionuclides in ground water, and (2) ingrowth of beta-emitting radionuclides during holding times between collection of samples and laboratory measurements.Although40K and228Ra appear to be the primary sources of beta activity in ground water, the sum of40K plus228Ra appears to be less than the measured gross-beta activity in most ground-water samples. The difference between the contribution from these radionuclides and gross-beta activity is most pronounced in ground water with gross-beta activities > 10 pCi/L, where these 2 radionuclides account for less than one-half the measured ross-beta activity. One exception is groundwater from the Coastal Plain of New Jersey, where40K plus228Ra generally contribute most of the gross-beta activity. In contrast,40K and228Ra generally contribute most of beta activity in ground water with gross-beta activities < 1 pCi/L.The gross-beta technique does not measure all beta activity in ground water. Although3H contributes beta activity to some ground water, it is driven from the sample before counting and therefore is not detected by gross-beta measurements. Beta-emitting radionuclides with half-lives shorter than a few days can decay to low values between sampling and counting. Although little is known about concentrations of most short-lived beta-emitting radionuclides in environmental ground water (water unaffected by direct releases from nuclear facilities and weapons tests), their activities are expected to be low.Ingrowth of beta-emitting radionuclides during sample holding times can contribute to gross-beta activity, particularly in ground water with gross-beta activities > 10 pCi/L. Ingrowth of beta-emitting progeny of238U, specifically234Pa and234Th, contributes much of the measured gross-beta activity in ground water from 4 of the 5 areas studied. Consequently, gross-beta activity measurements commonly overestimate the abundance of beta-emitting radionuclides actually present in ground water. Differing sample holding times before analysis lead to differing amounts of ingrowth of the two progeny. Therefore, holding times can affect observed gross-beta measurements, particularly in ground water with238U activities that are moderate to high compared with the activity of40K plus228Ra. Uncertainties associated with counting efficiencies for beta particles with different energies further complicate the interpretation of gross-beta measurements.  相似文献   

20.
The rate of extraterrestrial accretion for particles in the size range 0.45 μm to ∼20 μm was determined from dust concentrates extracted from Greenland Ice Sheet Project 2 (GISP2) ice core samples. Using instrumental neutron activation analysis (INAA), we determined the iridium (Ir) content of the dust. Following a core-specific correction for terrestrial Ir and assuming a chondritic Ir abundance of 500 ppb, we measure an average accretion rate for 0.45 μm to ∼20 μm particles over the entire Earth of 0.22 (± 0.11) × 109 g/yr (kton/yr) for 317 years of ice through the interval 6 to 20 ka. This is consistent with the interplanetary dust accretion rate of 0.17 (± 0.08) x 109 g/yr that we derive from published 3He data for the GISP2 core. Accounting for particles that are larger and smaller than those detected by or experiment, our best estimate of the total accretion rate (including particle sizes up to about 4 cm in diameter) is 2.5 × 109 g/yr. The uncertainty in this estimate is dominated by statistical fluctuations in the number of particles expected to end up in the ice core and not by measurement error. Based on Monte Carlo simulations, we estimate the upper limit for total extraterrestrial accretion to Earth of 6.25 × 109 g/yr (95% confidence level). This accretion rate is consistent with some estimates from micrometeorite concentrations in polar ice, estimates from ground-based radar studies, and with accretion estimates of 3He-bearing interplanetary dust particles, assuming that 3He is correlated with particle surface area. It is, however, lower than estimates based on platinum group element studies of marine sediments. The conflict may indicate systematic errors with either the marine or the non-marine samples, departures from the assumed particle spectrum of Grün and coauthors, or time-variable accretion rates, with the early Holocene period being characterized by low levels of accretion.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号