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1.
Mercury concentrations are clearly elevated in the surface and sub-surface layers of peat cores collected from a minerotrophic (“groundwater-fed”) fen in southern Greenland (GL) and an ombrotrophic (“rainwater-fed”) bog in Denmark (DK). Using 14C to precisely date samples since ca. AD 1950 using the “atmospheric bomb pulse,” the chronology of Hg accumulation in GL is remarkably similar to the bog in DK where Hg was supplied only by atmospheric deposition: this suggests not only that Hg has been supplied to the surface layers of the minerotrophic core (GL) primarily by atmospheric inputs, but also that the peat cores have preserved a consistent record of the changing rates of atmospheric Hg accumulation. The lowest Hg fluxes in the GL core (0.3 to 0.5 μg/m2/yr) were found in peats dating from AD 550 to AD 975, compared to the maximum of 164 μg/m2/yr in AD 1953. Atmospheric Hg accumulation rates have since declined, with the value for 1995 (14 μg/m2/yr) comparable to the value for 1995 obtained by published studies of atmospheric transport modelling (12 μg/m2/yr).The greatest rates of atmospheric Hg accumulation in the DK core are also found in the sample dating from AD 1953 and are comparable in magnitude (184 μg/m2/yr) to the GL core; again, the fluxes have since gone into strong decline. The accumulation rates recorded by the peat core for AD 1994 (14 μg/m2/yr) are also comparable to the value for 1995 obtained by atmospheric transport modelling (18 μg/m2/yr). Comparing the Pb/Ti and As/Ti ratios of the DK samples with the corresponding crustal ratios (or “natural background values” for preanthropogenic peat) shows that the samples dating from 1953 also contain the maximum concentration of “excess” Pb and As. The synchroneity of the enrichments of all three elements (Hg, Pb, and As) suggests a common source, with coal-burning the most likely candidate. Independent support for this interpretation was obtained from the Pb isotope data (206Pb/207Pb = 1.1481 ± 0.0002 in the leached fraction and 1.1505 ± 0.0002 in the residual fraction) which is too radiogenic to be explained in terms of gasoline lead alone, but compares well with values for U.K. coals. In contrast, the lowest values for 206Pb/207Pb in the DK profile (1.1370 ± 0.0003 in the leached fraction and 1.1408 ± 0.0003 in the residual fraction) are found in the sample dating from AD 1979: this shows that the maximum contribution of leaded gasoline occurred approximately 25 yr after the zenith in total anthropogenic Pb deposition.  相似文献   

2.
Recent Lake Tanganyika Hg deposition records were derived using 14C and excess 210Pb geochronometers in sediment cores collected from two contrasting depositional environments: the Kalya Platform, located mid-lake and more removed from watershed impacts, and the Nyasanga/Kahama River delta region, located close to the lake’s shoreline north of Kigoma. At the Kalya Platform area, pre-industrial Hg concentrations are 23 ± 0.2 ng/g, increasing to 74 ng/g in modern surface sediment, and the Hg accumulation rate has increased from 1.0 to 7.2 μg/m2/a from pre-industrial to present, which overall represents a 6-fold increase in Hg concentration and accumulation. At the Nyasanga/Kahama delta region, pre-industrial Hg concentrations are 20 ± 3 ng/g, increasing to 46 ng/g in surface sediment. Mercury accumulation rate has increased from 30 to 70 μg/m2/a at this site, representing a 2–3-fold increase in Hg concentration and accumulation. There is a lack of correlation between charcoal abundance and Hg accumulation rate in the sediment cores, demonstrating that local biomass burning has little relationship with the observed Hg concentration or Hg accumulation rates. Examined using a sediment focusing-corrected mass accumulation rate approach, the cores have similar anthropogenic atmospheric Hg deposition profiles, suggesting that after accounting for background sediment concentrations the source of accumulating Hg is predominantly atmospheric in origin. In summary, the data document an increase of Hg flux to the Lake Tanganyika ecosystem that is consistent with increasing watershed sediment delivery with background-level Hg contamination, and regional as well as global increases in atmospheric Hg deposition.  相似文献   

3.
《Applied Geochemistry》2005,20(3):569-585
Constructed and natural wetlands can accumulate elevated levels of Se; however, few data are available on cost-effective methods for remobilization and removal of Se from these areas. A field experiment was conducted to assess the effectiveness of flooding on the removal of Se from dry surface sediments. The 83-m2 flood-experiment plot contained 10 monitoring wells, a water-quality minimonitor (continuous measurement of pH, specific conductance, water temperature, and dissolved O2), a down-hole Br electrode, and 2 pressure transducers. Flooding was initiated on August 27, 2002, and a Br tracer was added to water delivered through a pipeline to the flood plot during the first 1.2 h. Standing water depth in the flood plot was maintained at 0.3 m through September 1, 2002. The Br tracer data indicate a dual porosity system that includes fracture (mud cracks) and matrix flow components. Mean vertical water velocities for the matrix flow component were estimated to range from 0.002 to 0.012 m/h. Dissolved (less than 0.45 μm) Se increased from pre-flood concentrations of less than 10 μg/L to greater than 800 μg/L during flooding in samples from deep (2.0 m below land surface) ground water. Selenium concentrations exceeded 5500 μg/L in samples from shallow (0.8 m below land surface) ground water. Ratios of Se to Br in water samples indicate that Se moved conservatively during the experiment and was derived from leaching of near-surface sediments. Cumulative Se flux to the deep ground water during the experiment ranged from 9.0 to 170 mg/m2. Pre- and post-flood surface soil sampling indicated a mean Se flux of 720 mg/m2 through the top 15 cm of soil. Ground-water samples collected 8 months after termination of the flood experiment contained Se concentrations of less than 20 μg/L. The minimonitor data indicate a rapid return to chemically reducing conditions in the deep ground water, limiting the mobility of the Se dissolved in the water pulse introduced during the flood experiment. Ratios of Se to Br in deep ground-water samples collected 8 months after the experiment confirmed the removal of Se from the aqueous phase. Based on the median Se flux rate estimated during the experiment of 0.65 mg/h/m2 (n = 52), 7 flooding cycles would be required to meet the 4 μg/g remediation goal in surface soils from the SLWMA wetland.  相似文献   

4.
Elemental and Sr, Nd, Hf and high precision Pb isotopic data are presented from 59 low-Ti and high-Ti lavas from the syn-break up part of the Faroe Flood Basalt Province. The depleted MORB-like low-Ti lavas erupted in the rift zone between the Faroe Islands and central East Greenland around the time of break up of the North Atlantic have isotopic end-member compositions different from the depleted Iceland lavas. We suggest that the main low-Ti mantle component is NAEM (North Atlantic End-Member (Ellam and Stuart, 2000, J. Petrol. 41, 919) and that the 207Pb/204Pb value of the component should be 15.35 and εHf = + 16.5. NAEM is the main depleted component in the early Iceland plume. This is supported by high mantle potential temperatures (up to 1550 °C) calculated for the source of the low-Ti basalts. The unique mantle isotopic composition of NAEM with low 206Pb/204Pb (17.5) and Δ7/4Pb (? 3.8) precludes a derivation from recycled MORB lithosphere. Instead we suggest that NAEM represents a plume component of recycled depleted Archean lithospheric mantle that was further depleted ~ 500 Ma ago, possibly in connection with the recycling process. Two other isotopic end-members are required to explain the variation of the Faroe low-Ti basalts: (1) The Faroe depleted component (FDC), with 87Sr/86Sr = 0.7025, εNd = + 11, εHf = + 19.5, 206Pb/204Pb = 18.2, 207Pb/204Pb = 15.454 and 208Pb/204Pb = 37.75, which is similar in composition to some Atlantic MORB and is regarded as a local upper mantle source. (2) An enriched EM-type component similar in geochemistry to the Icelandic Öræfajökull lavas. This component is believed to be recycled pelagic sediments in the plume but it can alternatively be a local crustal or lithospheric mantle component. The enriched Faroe high-Ti lavas erupted inland from the rift have isotopic compositions very similar to the enriched Icelandic neo-volcanics and these lava suites apparently share the two enriched plume end-members IE1 and IE2 (Geochim. Cosmochim. Acta 68, 2, 2004). The lack of mixing between high and low-Ti melts at the time of break up, is explained by a zoned plume where only low-Ti sources were present beneath the rift zone surrounded by high-Ti sources on both sides of the rift. The enriched plume components in the high-Ti lava sequences on the Faroe Islands and central East Greenland changed rapidly on a ka-scale which implies, from geophysical modelling, that this area was positioned above the center of the plume, and that the Iceland plume was centered under the Atlantic ridge already from the Paleocene.  相似文献   

5.
Multiple proxies from a 319-cm peat core collected from the Hudson Bay Lowlands, northern Ontario, Canada were analyzed to determine how carbon accumulation has varied as a function of paleohydrology and paleoclimate. Testate amoeba assemblages, analysis of peat composition and humification, and a pollen record from a nearby lake suggest that isostatic rebound and climate may have influenced peatland growth and carbon dynamics over the past 6700 cal yr BP. Long-term apparent rates of carbon accumulation ranged between 8.1 and 36.7 g C m? 2 yr? 1 (average = 18.9 g C m? 2 yr? 1). The highest carbon accumulation estimates were recorded prior to 5400 cal yr BP when a fen existed at this site, however following the fen-to-bog transition carbon accumulation stabilized. Carbon accumulation remained relatively constant through the Neoglacial period after 2400 cal yr BP when pollen-based paleoclimate reconstructions from a nearby lake (McAndrews et al., 1982) and reconstructions of the depth to the water table derived from testate amoeba data suggest a wetter climate. More carbon accumulated per unit time between 1000 and 600 cal yr BP, coinciding in part with the Medieval Climate Anomaly.  相似文献   

6.
The rate of extraterrestrial accretion for particles in the size range 0.45 μm to ∼20 μm was determined from dust concentrates extracted from Greenland Ice Sheet Project 2 (GISP2) ice core samples. Using instrumental neutron activation analysis (INAA), we determined the iridium (Ir) content of the dust. Following a core-specific correction for terrestrial Ir and assuming a chondritic Ir abundance of 500 ppb, we measure an average accretion rate for 0.45 μm to ∼20 μm particles over the entire Earth of 0.22 (± 0.11) × 109 g/yr (kton/yr) for 317 years of ice through the interval 6 to 20 ka. This is consistent with the interplanetary dust accretion rate of 0.17 (± 0.08) x 109 g/yr that we derive from published 3He data for the GISP2 core. Accounting for particles that are larger and smaller than those detected by or experiment, our best estimate of the total accretion rate (including particle sizes up to about 4 cm in diameter) is 2.5 × 109 g/yr. The uncertainty in this estimate is dominated by statistical fluctuations in the number of particles expected to end up in the ice core and not by measurement error. Based on Monte Carlo simulations, we estimate the upper limit for total extraterrestrial accretion to Earth of 6.25 × 109 g/yr (95% confidence level). This accretion rate is consistent with some estimates from micrometeorite concentrations in polar ice, estimates from ground-based radar studies, and with accretion estimates of 3He-bearing interplanetary dust particles, assuming that 3He is correlated with particle surface area. It is, however, lower than estimates based on platinum group element studies of marine sediments. The conflict may indicate systematic errors with either the marine or the non-marine samples, departures from the assumed particle spectrum of Grün and coauthors, or time-variable accretion rates, with the early Holocene period being characterized by low levels of accretion.  相似文献   

7.
In total 27 short and one long sediment core, and 278 surface sediment samples from the Baltic Sea were analyzed for mercury (Hg), and organic carbon contents. Thirteen short cores and the long core were dated by radionuclide methods (210Pb, 137Cs, AMS14C). The dataset allows discriminating between natural and human induced changes on the Hg levels in Baltic Sea sediments. Preindustrial Holocene background concentrations vary between 20 and 50 μg Hg per kg dry sediment and are positively correlated with organic carbon changes. Strong human induced pollution is recorded for the second half of the past century and caused high Hg concentrations of up to several hundred μg Hg per kg dry sediment even in Baltic Sea basins. Maximum concentrations are found at industrial and war waste dumping sites (local hot spots). An Hg concentration decreasing trend toward the present day is observed at most coring sites, a result of environmental measures undertaken during the last two decades. At sites where it is possible to calculate Hg fluxes, the natural accumulation rates vary between 2.1 and 5.4 μg Hg per m2 per year. Anthropogenically sourced Hg accumulation rates vary in a wide range of 30 and 300 μg Hg per m2 per year for the time span of maximum pollution. In areas characterized by discontinuous sedimentation only “inventories” of human sourced Hg expressed as the total amount of deposited Hg (above the natural background) per m2 can be calculated. The inventories of the investigated cores vary in the range of 1 and 8 mg Hg per m2. Additionally, influences of sediment dynamics on spatial distribution pattern of Hg concentrations in surface and subsurface sediments are discussed.  相似文献   

8.
Although recent studies have recognized peatlands as a sink for atmospheric CO2, little is known about the role of Siberian peatlands in the global carbon cycle. We have estimated the Holocene peat and carbon accumulation rate in the peatlands of the southern taiga and subtaiga zones of western Siberia. We explain the accumulation rates by calculating the average peat accumulation rate and the long-term apparent rate of carbon accumulation (LORCA) and by using the model of Clymo (1984, Philosophical Transactions of the Royal Society of London Series B 303, 605-654). At three key areas in the southern taiga and subtaiga zones we studied eight sites, at which the dry bulk density, ash content, and carbon content were measured every 10 cm. Age was established by radiocarbon dating. The average peat accumulation rate at the eight sites varied from 0.35 ± 0.03 to 1.13 ± 0.02 mm yr−1 and the LORCA values of bogs and fens varied from 19.0 ± 1.1 to 69.0 ± 4.4 g C m−2 yr−1. The accumulation rates had different trends especially during the early Holocene, caused by variations in vegetation succession resulting in differences in peat and carbon accumulation rates. The indirect effects of climate change through local hydrology appeared to be more important than direct influences of changes in precipitation and temperature. River valley fens were more drained during wetter periods as a result of deeper river incision, while bogs became wetter. From our dry bulk density results and our age-depth profiles we conclude that compaction is negligible and decay was not a relevant factor for undrained peatlands. These results contribute to our understanding of the influence of peatlands on the global carbon cycle and their potential impact on global change.  相似文献   

9.
Biogeochemical processes in a forested tropical peat deposit and its record of past atmospheric dust deposition were assessed using the vertical distribution of lithophilic and plant essential elements in a dated core profile from Borneo, SE Asia. Peat formation started ∼22,120 14C yr before present (BP), and Ca/Mg mass ratios of the solid peat and very low ash contents indicate a strongly ombrotrophic character throughout the deposit, implying that most of the inorganic fraction has been supplied exclusively by atmospheric inputs. Concentration profiles of Mn, Sr, and Ca suggest a very minor influence of chemical diagenesis in the underlying sediments. Silicon, Ca, Mg, P, S, and K show a strong and extended zone of enrichment in the top 200 cm of the profile, indicating that biological accumulation mechanisms are much more extensive than in temperate peat bogs.In the lower core sections, where the element distribution is dominated solely by past atmospheric deposition, average Al/Ti ratios are similar to the upper continental crust (UCC), whereas Fe is slightly enriched and Si is strongly depleted: this condition favors highly weathered tropical soil dust as the main inorganic mineral source. Significant correlation of Al, Fe, Si, S, Ca, and Ti with the lithophilic elements Y and Zr suggests that the distribution of these elements is controlled by sources of atmospheric mineral dust. The Ca/Mg, Ca/K, and Mg/K ratios of the collected rainwater samples are similar to the global average of continental rainwater and suggest a continental character for the site. This is supported by the similarity of the average concentration of Br, Mg, Ca, and S to that in temperate continental and maritime bogs in Switzerland and Scotland.The concentration profiles of Si, Fe, Al, and Ti show distinct peaks within the profile, implying enhanced dust deposition, reduced rates of peat accumulation, or possibly both owing to climatic changes during the Holocene. Enhanced dust deposition between ∼10,830 and 9060 14C yr BP is tentatively interpreted as a Younger Dryas-like event with dust fluxes of ∼10.8 mg/m2/yr. The variations in Al/Ti and Fe/Ti profiles suggest that mineral dust sources have been changing constantly during the Holocene, with local sources being dominant between ∼7820 and 9500 14C yr BP and long-range transport (derived most likely from China) being important during the late Pleistocene and early Holocene and from ∼7820 14C yr BP to the present.  相似文献   

10.
Sediments of the Lagoa Vermelha (Red Lake), situated in the Ribeira Valley, southeastern Brazil, are made of a homogeneous, organic-rich, black clay with no visible sedimentary structures. The inorganic geochemical record (Al, As, Ba, Br, Co,Cs, Cr, Fe, Mn, Ni, Rb, Sc, Sb, V, Zn, Hg and Pb) of the lake sediments was analyzed in a core spanning 2430 years. The largest temporal changes in trace metal contents occurred approximately within the last 180 years. Recent sediments were found to be enriched in Pb, Zn, Hg, Ni, Mn, Br and Sb (more than 2-fold increase with respect to the “natural background level”). The enhanced accumulation of Br, Sb, and Mn was attributed to biogeochemical processes and diagenesis. On the other hand, the anomalous concentrations of Pb, Zn, Hg and Ni were attributed to pollution. As Lagoa Vermelha is located in a relatively pristine area, far removed from direct contamination sources, the increased metal contents of surface sediments most likely resulted from atmospheric fallout. Stable Pb isotopes provided additional evidence for anthropogenic contamination. The shift of 206Pb/207Pb ratios toward decreasing values in the increasingly younger sediments is consistent with an increasing contribution of airborne anthropogenic lead. In the uppermost sediments (0-10 cm), the lowest values of the 206Pb/207Pb ratios may reflect the influence of the less radiogenic Pb from the Ribeira Valley District ores (206Pb/207Pb between 1.04 and 1.10), emitted during the last 50 years.  相似文献   

11.
Two 14C accelerator mass spectrometry (AMS) wiggle‐match dated peat sequences from Denmark and northern England record changes in mire surface wetness reconstructed using plant macrofossil and testate amoebae analyses. A number of significant mid–late Holocene climatic deteriorations (wet shifts) associated with declines in solar activity were recorded (at ca. 2150 cal. yr BC, 740 cal. yr BC, cal. yr AD 930, cal. yr AD 1020, cal. yr AD 1280–1300, cal. yr AD 1640 and cal. yr AD 1790–1830). The wet shifts identified from ca. cal. yr AD 930 are concurrent with or lag decreases in solar activity by 10–50 years. These changes are replicated by previous records from these and other sites in the region and the new records provide improved precision for the ages of these changes. The rapidly accumulating (up to 2–3 yr cm?1, ～1310 yr old, 34 14C dates) Danish profile offers an unprecedented high‐resolution record of climate change from a peat bog, and has effectively recorded a number of significant but short‐lived climate change events since ca. cal. yr AD 690. The longer time intervals between samples and the greater length of time resolved by each sample in the British site due to slower peat accumulation rates (up to 11 yr cm?1, ～5250 yr old, 42 14C dates) acted as a natural smoothing filter preventing the clear registration of some of the rapid climate change events. Not all the significant rises in water table registered in the peat bog archives of the British and Danish sites have been caused by solar forcing, and may be the result of other processes such as changes in other external forcing factors, the internal variability of the climate system or raised bog ecosystem. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

12.
A Bison antiquus cranium and partial skeleton from Ayer Pond wetland on Orcas Island, San Juan Islands, Washington, date to 11,760 ± 70 14C yr BP. They lay in lacustrine sediments below peat, unconformably above emergent Everson Glaciomarine Drift (> 12,000 14C yr BP). Several bison finds in similar contexts on Orcas and Vancouver Islands dating between 11,750 and 10,800 14C yr BP indicate an early postglacial land mammal dispersal corridor with reduced water barriers between mainland and islands. New bison dates and published shell dates allow estimation of early postglacial relative sea-level trends for the San Juans, with a drop below modern datum ∼ 12,000 14C yr BP, and assist in evaluation of marine reservoir corrections. Emergence by ∼ 60 m is suggested by data from nearby areas. A tundra-like or meadow community and succeeding open pine parkland before 11,000 14C yr BP supported bison but horn-core reduction suggests suboptimal forage or restricted habitat. Expanding mixed-conifer forests after 11,000 14C yr BP contributed to bison extirpation. Dispersing ungulates such as bison must have influenced island vegetation establishment and early succession. Possible evidence for butchering by early coastal people adds significance to the Ayer Pond discovery, given its pre-Clovis age.  相似文献   

13.
Atmospheric mercury (Hg) is delivered to ecosystems via rain, snow, cloud/fog, and dry deposition. The importance of snow, especially snow that has passed through the forest canopy (throughfall), in delivering Hg to terrestrial ecosystems has received little attention in the literature. The snowpack is a dynamic system that links atmospheric deposition and ecosystem cycling through deposition and emission of deposited Hg. To examine the magnitude of Hg delivery via snowfall, and to illuminate processes affecting Hg flux to catchments during winter (cold season), Hg in snow in no-canopy areas and under forest canopies measured with four collection methods were compared: (1) Hg in wet precipitation as measured by the Mercury Deposition Network (MDN) for the site in Acadia National Park, Maine, USA, (2) event throughfall (collected after snowfall cessation for accumulations of >8 cm), (3) season-long throughfall collected using the same apparatus for event sampling but deployed for the entire cold season, and (4) snowpack sampling. Estimates (mean ± SE) of Hg deposition using these methods during the 91-day cold season in 2004–2005 at conifer sites showed that season-long throughfall Hg flux (1.80 μg/m2) < snowpack Hg (2.38 ± 0.68 μg/m2) < event throughfall flux (5.63 ± 0.38 μg/m2). Mercury deposition at the MDN site (0.91 μg/m2) was similar to that measured at other no-canopy sites in the area using the other methods, but was 3.4 times less than was measured under conifer canopies using the event sampling regime. This indicates that snow accumulated under the forest canopy received Hg from the overstory or exhibited less re-emission of Hg deposited in snow relative to open areas. The soil surface of field-scale plots were sprayed with a natural rain water sample that contained an Hg tracer (202Hg) just prior to the first snowfall to explore whether some snowpack Hg might be explained from soil emissions. The appearance of the 202Hg tracer in the snowpack (0–64% of the total Hg mass in the snowpack) suggests that movement of Hg from the soil into the snowpack is possible. However, as with any tracer study the 202Hg tracer may not precisely represent the reactivity and mobility of natural Hg in soils.  相似文献   

14.
The magnitude and sources of lead (Pb) pollution in the Gulf of California Ecoregion (GCE) in northwest Mexico were evaluated using various samples collected from urban and rural areas around two typical subtropical coastal ecosystems. Lead concentrations and isotopic compositions (206Pb/207Pb, 208Pb/207Pb, 206Pb/204Pb and 208Pb/204Pb) were measured using high resolution inductively-coupled plasma mass spectrometry (HR-ICP-MS) and thermal ionization mass spectrometry (TIMS). Urban street dust (157 ± 10.1 μg g− 1) was heavily enriched with Pb, compared to the Pb enrichment of agricultural soils (29.0 ± 16.0 μg g− 1) and surface estuary sediments (35.6 ± 15.4 μg g− 1), all of which contained higher Pb concentrations than found in the natural bedrock (16.0 ± 5.0 μg g− 1). Pb concentrations in SPM (> 95% of total Pb) were significantly higher in sewage effluent (132 ± 49.9 μg g− 1) than in agricultural effluents (29.3 ± 5.9 μg g− 1), and river runoff (7.3 ± 4.2 μg g− 1). SPM in estuary water column averaged 68.3 ± 48.0 μg g−1. The isotopic composition of Pb (206Pb/207Pb, 208Pb/207Pb) in rural samples of aerosols (1.181 ± 0.001, 2.444 ± 0.003) and soil runoff (1.181 ± 0.003, 2.441 ± 0.004) was comparable to that of natural Pb-bearing bedrock (1.188 ± 0.005, 2.455 ± 0.008); while urban samples of aerosols, street dust, and sewage (1.190–1.207, 2.452–2.467) showed a significant contribution from automotive emissions from past leaded gasoline combustion (1.201 ± 0.006, 2.475 ± 0.005). The absence of lead from fertilizer (1.387 ± 0.008, 2.892 ± 0.005) suggests that this mixture is not representative of the GCE. A mixing model revealed that the Pb content in the environmental samples is predominantly derived from natural weathering and the past leaded gasoline combustion with the later influence of inputs from a more radiogenic source related with anthropogenic lead of North American origin (1.21 ± 0.02; 2.455 ± 0.02).  相似文献   

15.
A peat core from an ombrotrophic bog documents the isotopic evolution of atmospheric Pb in central Ontario since AD 1804 ± 53 (210Pb dating). Despite the introduction of unleaded gasoline in the mid-1970’s, the ratio 206Pb/207Pb in atmospheric deposition has not increased as expected, but rather continues to decline. In fact, snowpack sampling (2005 and 2009) and rainwater samples (2008) show that the isotopic composition of atmospheric Pb today is often far less radiogenic than the gasoline lead that had been used in Canada in the past. The peat, snow, and rainwater data presented here are consistent with the Pb isotope data for aerosols collected in Dorset in 1984 and 1986 which were traced by Sturges and Barrie (1989) to emissions from the Noranda smelter in northern Quèbec, Canada’s largest single source of atmospheric Pb. Understanding atmospheric Pb deposition in central Ontario, therefore, requires not only consideration of natural sources and past contributions from leaded gasoline, but also emissions from metal smelting and refining.Lead in the streams which enter Kawagama Lake today (206Pb/207Pb = 1.16 − 1.19) represents a mixture between the natural values (1.191 − 1.201 estimated using pre-industrial lake sediments) and the values found in the humus layer of the surrounding forest soils (206Pb/207Pb = 1.15 − 1.19). In the lake itself, however, Pb is much less radiogenic (206Pb/207Pb as low as 1.09) than in the streams, with the dissolved fraction less radiogenic than particulate material. The evolution of Pb isotope ratios within the watershed apparently reflects preferential removal by sedimentation of comparatively dense, radiogenic, terrestrial particles (derived from the mineral fraction of soils) from the humus particles with lower ratios of 206Pb/207Pb (because of atmospheric Pb contamination). Despite the contemporary enrichments of Pb in rain and snow, concentrations of dissolved Pb in the lake are extremely low (sometimes below 10 ng/l), with Pb concentrations and Pb/Sc ratios approaching “natural” values because of efficient binding to particles, and their subsequent removal in the watershed.  相似文献   

16.
As a consequence of deposition of atmospheric pollution, the lead concentration in the mor layer (the organic horizon) of remote boreal forest soils in Sweden is raised far above natural levels. How the mor will respond to decreased atmospheric pollution is not well known and is dependent on future deposition rates, downward migration losses and upward fluxes in the soil profile. Plants may contribute to the upward flux of lead by ‘pumping’ lead back to the mor surface through root uptake and subsequent litter fall. We use lead concentration and stable isotope (206Pb, 207Pb and 208Pb) measurements of forest vegetation to quantify plant uptake rates from the soil and direct from the atmosphere at two sites in northern Sweden; an undisturbed mature forest and a disturbed site with Scots pine (Pinus sylvestris) growing on a recently exposed mineral soil (C-horizon) containing a minimum of atmospherically derived pollution lead. Analyses of forest mosses from a herbarium collection (spanning the last ∼100 yr) and soil matrix samples suggest that the atmospheric lead deposited on plants and soil has an average 206Pb/207Pb ratio of 1.15, while lead derived from local soil minerals has an average ratio of ∼1.47. Since the biomass of trees and field layer shrubs has an average 206Pb/207Pb ratio of ∼1.25, this indicates that 70% ± 10% of the inventory of 1 ± 0.8 mg Pb m−2 stored in plants in the mature forest originates from pollution. Needles, bark and apical stemwood of the pine growing on the disturbed soil, show lower 206Pb/207Pb ratios (as low as 1.21) than the roots and basal stemwood (having ratios > 1.36), which indicate that plants are able to incorporate lead directly from the atmosphere (∼50% of the total tree uptake). By partitioning the total uptake of lead into uptake from the atmosphere and different soil layers using an isotopic mixing model, we estimate that ∼0.03 ± 0.01, 0.02 ± 0.01 and 0.05 ± 0.01 mg Pb m−2 yr−1 (mean ± SD), is taken up from the mor layer, the mineral soil and the atmosphere, respectively, by plants in the undisturbed mature forest. These small fluxes, which are at least a magnitude lower than reported downward migration losses, suggest that plant uptake will not strongly prolong the self-cleaning rate of the mor layer.  相似文献   

17.
Lead (Pb) isotopic compositions and concentrations, and barium (Ba) and indium (In) concentrations have been determined at monthly resolution in five Law Dome (coastal Eastern Antarctica) ice core sections dated from ∼1757 AD to ∼1898 AD. ‘Natural’ background Pb concentrations in ∼1757 AD average ∼0.2 pg g−1 and can be attributed to mineral dust and volcanic emissions, with 206Pb/207Pb ratios reaching up to 1.266 ± 0.002. From ∼1887 AD to ∼1898 AD, Pb concentrations reached ∼5 pg g−1 and 206Pb/207Pb ratios decreased to 1.058 ± 0.001 as a result of additional inputs of Pb from anthropogenic sources. Seasonal variability in the late 1880s has been investigated by decoupling volcanic Pb from the total measured Pb concentrations, revealing spring and autumn maxima, and consistent winter minima, in anthropogenic Pb and mineral dust (Ba) concentrations. We link this variability to the annual cycle in the position and strength of the Antarctic Circumpolar Trough and, the Southern Ocean westerly winds to the north of the trough region. During the autumn and spring seasons, these systems increase in strength, transporting more impurity laden air from the Southern Hemisphere continental regions to Eastern Antarctica and Law Dome. As this Pb is isotopically identical to that emitted from south-eastern Australia (Broken Hill, Port Pirie) this implies a relatively direct air trajectory pathway from southern Australia to Law Dome (Eastern Antarctica).  相似文献   

18.
High‐resolution pollen, plant macrofossil and sedimentary analyses from early Holocene lacustrine sediments on the Faroe Islands have detected a significant vegetation perturbation suggesting a rapid change in climate between ca. 10 380 cal. yr BP and the Saksunarvatn ash (10 240±60 cal. yr BP). This episode may be synchronous with the decline in δ18O values in the Greenland ice‐cores. It also correlates with a short, cold event detected in marine cores from the North Atlantic that has been ascribed to a weakening of thermohaline circulation associated with the sudden drainage of Lake Agassiz into the northwest Atlantic, or, alternatively, a period with distinctly decreased solar forcing. The vegetation sequence begins at ca. 10 500 cal. yr BP with a succession from tundra to shrub‐tundra and increasing lake productivity. Rapid population increases of aquatic plants suggest high summer temperatures between 10 450 and 10 380 cal. yr BP. High pollen percentages, concentrations and influx of Betula, Juniperus and Salix together with macrofossil leaves indicate shrub growth around the site during the initial phases of vegetation colonisation. Unstable conditions followed ca. 10 380 cal. yr BP that changed both the upland vegetation and the aquatic plant communities. A decrease in percentage values of shrub pollen is recorded, with replacement of both aquatics and herbaceous plants by pioneer plant communities. An increase in total pollen accumulation rates not seen in the concentration data suggests increased sediment delivery. The catchment changes are consistent with less seasonal, moister conditions. Subsequent climatic amelioration reinitiated a warmth‐driven succession and catchment stabilisation, but retained high precipitation levels influencing the composition of the post‐event communities. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

19.
Lago Verde is a fresh-water maar found on the lower slopes of San Martin volcano, at the Sierra de Los Tuxtlas, Mexico, currently the northernmost remnant of the tropical rain forest in America. 210Pb and 137Cs analyzed in a sediment core were used to reconstruct the historical fluxes of Ag, Cd, Cu, Pb, Hg and Zn to the site during the last ∼ 150 yr. The 210Pbxs-derived sediment accumulation rates, the magnetic susceptibility, C/N ratios and δ13C data evidenced background conditions at the lake until 1960s, when enhanced erosion related to the clearing of large forested areas at Los Tuxtlas promoted higher accumulation rates of a heavier and more magnetic sedimentary material. Recent sediments from Lago Verde were found enriched by Pb (26-fold natural concentration level [NCLs]) and moderately enriched by Cd > Cu > Zn and Hg (6-, 5-, 4- and 4-fold corresponding NCLs, respectively). The fluxes of Cu, Hg, Pb and Zn have significantly increased since 1940s, with peak ratios of total modern to pre-industrial fluxes of 11, 11, 19 and 49, respectively. The lake occupies a relatively pristine, non-industrialized basin, and therefore the increased metal fluxes might be related to long-distance aeolian transport of trace metals.  相似文献   

20.
《Applied Geochemistry》2001,16(5):541-558
The Isonzo river mouth has been the source of Hg in the Gulf of Trieste (northern Adriatic sea) since the sixteenth century, making this shallow basin one of the most contaminated marine areas in the length of time and amount of metal accumulated. The occurrence and behaviour of total Hg (range 0.064–30.38 μg g−1; average 5.04 μg g−1; median 3.10 μg g−1, n=80) and related size fractions in sediments of this coastal area were investigated in detail. The relationship between total Hg and the fine silt-clay (< 16 μm) fraction has provided information on the hydrological and mineralogical fractionation process affecting this element, when compared to other heavy metals associated with fluvial inputs. Mercury contents are very high along the littoral zone of the northern (Italian) sector where this metal is present in detrital form (cinnabar) in sandy-silty sediments near the river mouth and the surrounding beaches. Within the sediments belonging to the Gulf area, Hg is bound either to fine particles or adsorbed onto the surface of clay minerals and/or partially complexed by colloids and organic matter. Recent accumulation of Hg in a 70 cm long 210Pb dated core, collected in the central part of the Gulf, was also compared to other heavy metals (Fe, Cr, Cu, Mn, Ni and Zn). A preliminary estimate of Hg enrichment shows that the first 50 cm of sediment in the central sector of the Gulf of Trieste are noticeably contaminated, reaching a maximum of up to 25-fold above the proposed natural regional background of 0.17 μg g−1. The vertical trend is well correlated to historical data of Hg extraction activity at the Idrija mine.  相似文献   

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