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1.
A simple geochemical technique using the ratio of total sulfur (TS) to total organic carbon (TOC) was successfully used to reconstruct paleoenvironments in the Jurassic–Cretaceous Tetori Group, central Japan. The TS to TOC ratio is often employed as an effective parameter to separate modern marine or brackish sediments from freshwater deposits. To test the TS/TOC method for paleoenvironmental interpretation of the Tetori Group, we first analyzed TS/TOC for samples for which depositional conditions (i.e. marine, brackish or freshwater) had been recognized paleontologically. The results indicate that the method can effectively separate sedimentary rocks deposited under freshwater from marine and brackish settings. Once we had established the effectiveness of this method, we applied it to three sections of the Tetori Group, central Japan. Stratigraphic fluctuations in TS/TOC values revealed episodic incursions of marine or brackish conditions in the dominantly freshwater depositional sequence in the middle of the Jobu Formation of the Itoshiro Subgroup at the Izumi section, Fukui Prefecture. The same paleoenvironment is also suggested to occur at the top of the Tetori Group in the Tateyama section, Toyama Prefecture. This research provides important information to paleogeographers who currently lack evidence from facies fossils to indicate if the uppermost part of the Tetori Group represents marine or brackish settings. A chemostratigraphy of TS/TOC parameters potentially could provide a correlation among Jurassic–Cretaceous sequences along continental margins over East Asia.  相似文献   

2.
Biomarker analyses for evaluating maturity of organic matter and depositional environments such as redox conditions, were performed in sediments across the Cenomanian–Turonian boundary (CTB) in the Saku Formation of the Yezo Group distributed along the Shumarinai‐gawa River and the Omagari‐zawa River, both in the Tomamae area, Hokkaido, Japan. Maturity indicators using steranes and hopanes, show that organic matter in sediments from the Shumarinai‐gawa and Omagari‐zawa sections are of lower maturity than those from the Hakkin‐gawa section (Oyubari area). Moreover, the ββ hopane ratios clearly show that the maturity of the Shumarinai‐gawa samples is lower than that of the Omagari‐zawa samples. These variations in the maturity of organic matter presumably reflect the difference in their burial histories. The results for the pristane/phytane (Pr/Ph) ratios suggest that the Shumarinai‐gawa samples were deposited under dysoxic to anoxic environments across the CTB, while the depositional environments of the Omagari‐zawa samples were relatively oxic. By another paleoredox indicator using C35 homohopanoids including a homohopene index (HHenI), higher values are observed in the Shumarinai‐gawa section, particularly in the horizons of the preceding period and an early stage of the first negative shift phase and the latest oceanic anoxic event 2 (OAE2) interval. These results suggest that the Shumarinai‐gawa samples record dysoxic to anoxic environments across the CTB. In contrast, the signals for the C35 homohopanoid index values show a relatively oxic condition in the Omagari‐zawa section. The trends of stratigraphic variations in redox conditions are different from those in the OAE2 interval in the proto‐Atlantic and Tethys regions as reported previously. Hence, the redox variations in the Tomamae area were basically related to a local environmental setting rather than global anoxia. However, the prominent anoxic emphasis observed in the HHenI profile of the Shumarinai‐gawa section can be a distinctive, and possibly global, event in the North‐West Pacific just before the OAE2.  相似文献   

3.
Abstract The upper Mesozoic Tetori Group contains numerous fossils of plants and marine and non‐marine animals. The group has the potential to provide key information to improve our understanding of the Middle Jurassic to Early Cretaceous biota of East Asia. However, the depositional age of the Tetori Group remains uncertain, and without good age constraints, accurate correlation with other areas is very difficult. As a first step in obtaining reliable ages for the formations within the Tetori Group, we used laser ablation‐inductively coupled plasma–mass spectrometry to measure the U–Pb ages of zircons collected from tuff beds in the Shokawa district, Takayama City, Gifu Prefecture, central Japan. The youngest reliable U–Pb ages from the tuff beds of the Ushimaru, Mitarai and Okurodani Formations are 130.2 ± 1.7, 129.8 ± 1.0 and 117.5 ± 0.7 Ma, respectively (errors represent 2 SE). These results indicate that the entire Tetori Group in the Shokawa district, which was previously believed to be correlated to the Upper Jurassic to Lower Cretaceous, is in fact correlated to the Lower Cretaceous. The maximum ages of the Ushimaru, Mitarai and Okurodani Formations are late Hauterivian to Barremian, late Hauterivian to Barremian and Barremian to Aptian, respectively.  相似文献   

4.
The Izumi Group in southwestern Japan is considered to represent deposits in a forearc basin along an active volcanic arc during the late Late Cretaceous. The group consists mainly of felsic volcanic and plutonic detritus, and overlies a Lower to Upper Cretaceous plutono‐metamorphic complex (the Ryoke complex). In order to reconstruct the depositional environments and constrain the age of deposition, sedimentary facies and U–Pb dating of zircon grains in tuff were studied for a drilled core obtained from the basal part of the Izumi Group. On the basis of the lithofacies associations, the core was subdivided into six units from base to top, as follows: mudstone‐dominated unit nonconformably deposited on the Ryoke granodiorite; tuffaceous mudstone‐dominated unit; tuff unit; tuffaceous sandstone–mudstone unit; sandstone–mudstone unit; and sandstone‐dominated unit. This succession suggests that the depositional system changed from non‐volcanic muddy slope or basin floor, to volcaniclastic sandy submarine fan. Based on a review of published radiometric age data of the surrounding region of the Ryoke complex and the Sanyo Belt which was an active volcanic front during deposition of the Izumi Group, the U–Pb age (82.7 ±0.5 Ma) of zircon grains in the tuff unit corresponds to those of felsic volcanic and pyroclastic rocks in the Sanyo Belt.  相似文献   

5.
The distribution, the relative composition, and their variation of methylated chromans (MTTC) with maturation of organic matter in the source rocks from Mingjia 1 well, Jianghan hypersaline basin, have been analyzed and studied. There is a close relationship between the distribution of methylatd chromans and paleosalinity of depositional environment. In the Eq 1–Eq 3 source rocks deposited under hypersaline environment with lower Pr/Ph ratio, higher gammacerane index and abundant organic sulfur-containing compounds, methyl MTTC and dimethyl MTTC are main components, but in the Eq 4 source rocks deposited non-hypersaline environment with relatively higher Pr/Ph ratio, lower gammacerane index and organic sulfur-containing compounds, trimethyl MTTC is a major compound in methylate chromans. Obviously, the distributions and the compositions of methylated chromans in the source rocks are in harmony with biomarker indicators indicating the paleaosalinity and redox of depositional environment. The relationship between the ratio of 5,8-dimethyl MTTC to 7,8-dimethyl MTTC (dimethyl MTTC ratio) and the maturity of organic matter in the source rocks from Mingjia 1 well has been discussed. The results show that dimethyl MTTC ratio increased with the burial depth and the maturation of organic matter in the source rocks, especially in immature level. It is noteworthy that this ratio is very susceptible to small variation in the maturity of organic matter in the source rocks when vitrinite reflectance R o is less than 0.65%. It may imply that this ratio is a good and susceptible aromatic maturity indicator for the relative maturity of organic matter in immature source rocks.  相似文献   

6.
The steps and methods for the establishment of the global boundary stratotype section and point (GSSP) are summed up briefly as follows. (i) Select rock sequences of approximately the same age duration in a region, make a thorough study of their properties or attributes in order to establish the high-resolution stratigraphic units reflecting the natural rhythms in Earth's history, and proceed by multidisciplinary comprehensive studies to reveal the relationship, including time-space relation and possible mutual causality, among the various stratigraphic units and the different natural rhythms established. (ii) Seek for the "natural break" that represents the "major natural changes in the historical development of the Earth" in shallow marine facies areas, which is frequently the third-order sequence boundaries. (iii) Trace from shallow marine facies areas toward the continental slope and bathyal areas to seek for a continuous depositional sequence that corresponds in time span to the "natural break" of shallow marine facies areas. (iv) Seek for a horizon within the continuous depositional sequence that approximately coincides with the maximum regressive point in the "natural break". This horizon is commonly within a lowerstand systems tract (LST) or a shelf margin systems tract (SMST) of the relevant third-order sequence. (v) Seek immediately above this horizon of maximum marine regression for an organic radiation or explosion event closely related to the natural boundary, which is generally the first flooding surface (FFS) of the relevant third-order sequence. (vi) Select within the organic event deposits closely related to the FFS the base boundary of a fossil taxon with widest geographical range as the Leading Group biozone for designation of the stratigraphic boundary. (vii) Select from among the sections with continuous depositional sequence formed under similar sedimentary palaeogeographic background (in general continental slope or bathyal environments) the section which possesses the shortest distance between the base boundary of the Leading Group biozone and the immediately underlying FFS of the relevant third-order sequence as the global stratotype section. The first appearance datum (FAD) of the Leading Group biozone species in the section may be regarded as the ideal GSSP. The steps suggested above are a supplement and improvement of the currently used procedures and methods for establishing GSSP. The GSSP established by using the steps and methods suggested here would make the stratigraphic boundaries better reflect the "major natural changes in the historical development of the Earth", more readily distinguishable and easily operable in recognition and correlation, and at the same time also make the designation of boundaries more objective.  相似文献   

7.
The formation mechanisms of biphenyl series and benzonaphthothiophene series are investigated by means of simulation experiment. Biphenyl series are likely formed in two ways: one is the aromatization of the chain compounds containing conjugated C== C double bonds or the compounds with such a kind of sidechains, and the other is the reaction of sulfur with ordinary chain compounds, in which sulphur acts on ordinary sidechain compounds by seizing some hydrogens and forming (H2S and) the intermediates with conjugated C== C double bonds first, and then the intermediates are aromatized. One of the basic precursors of benzonaphthothiophenes is likely the phenylnaphthalenes which may originate from the chain compounds containing conjugated C== C double bonds, the compounds with such sidechains and saturate or unsaturate chain compounds. Thermal stability of biphenyls is high, but they can become dibenzothiophenes and polycyclic aromatic hydrocarbons or dibenzofurans and polycyclic aromatic hydrocarbons respectively in the presence of sulphur or oxygen. The ratio of biphenyl and m-biphenyl to biphenyls may be employed to indicate the depositional environment in the mild to medium maturation, of which the higher value indicates a fresh water depositional environment and the lower indicates a saline depositional environment. The relative high content of benzonaphthothiophenes in the crude oil indicates that the crude oil has undergone an intense sulfurization in the source rock or reservoir.  相似文献   

8.
Aromatic hydrocarbons are generally main distillation of crude oil and organic extract of source rocks. Bicyclic and tricyclic aromatic hydrocarbons can be purified by two-step method of chromatography on alumina. Carbon isotopic composition of individual aromatic hydrocarbons is affected not only by thermal maturity, but also by organic matter input, depositional environment, and hydrocarbon generation process based on the GC-IRMS analysis of Upper Ordovician, Lower Ordovician, and Cambrian source rocks in different areas in the Tarim Basin, western China. The subgroups of aromatic hydrocarbons as well as individual aromatic compound, such as 1-MP, 9-MP, and 2,6-DMP from Cambrian-Lower Ordovician section show more depleted 13 C distribution. The 13 C value difference between Cambrian-Lower Ordovician section and Upper Ordovician source rocks is up to 16.1‰ for subgroups and 14‰ for individual compounds. It can provide strong evidence for oil source correlation by combing the 13 C value and biomarker distribution of different oil and source rocks from different strata in the Tarim Basin. Most oils from Tazhong area have geochemical characteristics such as more negative 13C9-MP value, poor gammacerane, and abundant homohopanes, which indicate that Upper Ordovician source rock is the main source rock. In contrast, oils from Tadong area and some oils from Tazhong area have geochemical characteristics such as high 13C9-MP value, abundant gammacerane, and poor homohopanes, which suggest that the major contributor is Cambrian-Lower Ordovician source rock.  相似文献   

9.
By the aid of GC-MS technique, a series of sequentially biodegraded oils from Liaohe Basin have been analyzed. The results show that the concentrations and relative compositions of various aromatic compounds in the biodegraded crude oils will change with increasing biodegradation degree. The concentrations of alkyl naphthalenes, alkyl phenanthrenes, alkyl dibenzothiophene are decreased, and the concentration of triaromatic steroids will increase with increasing biodegradation degree in biodegraded oils. Those phenomena indicate that various aromatic compounds are more easily biodegraded by bacteria like other kinds of hydrocarbons such as alkanes, but different series of aromatic compounds have a varied ability to resistant to biodegradation. The ratios of dibenzothiophene to phenenthrene (DBTH/P) and methyl dibenzothiophene to methyl phenanthrene (MDBTH/MP) are related to the features of depositional environment for source rocks such as redox and ancient salinity. However, in biodegraded oils, the two ratios increase quickly with the increase of the biodegradation degree, indicating that they have lost their geochemical significance. In this case, they could not be used to evaluate the features of depositional environment. Methyl phenanthrene index, methyl phenanthrene ratio and methyl dibenzoyhiophene ratio are useful aromatic maturity indicators for the crude oils and the source rocks without vitrinite. But for biodegraded oils, those aromatic maturity indicators will be affected by biodegradation and decrease with the increase of the biodegradation degree. Therefore, those aromatic molecular maturity indicators could not be used for biodegraded oils.  相似文献   

10.
The Flin Flon Belt of Canada contains Paleoproterozoic volcanic–sedimentary sequences that are related to the Trans‐Hudson Orogeny. The sequences include island arc volcanic and volcaniclastic rocks (Amisk Group) that are unconformably overlain by subaerial sedimentary rocks (Missi Group), and younger deep facies sediments. In the Flin Flon area, several north–south trending faults divide the sequences into blocks and obscure the depositional environment of the deep facies sediments. Locally, within the Flin Flon area, the Embury Lake Formation is in fault contact with island arc volcanic–sedimentary sequences of the Amisk and Missi Groups. To identify the depositional environment of the Embury Lake Formation, we used lithologic and geochemical approaches. Here, we report carbon isotopic values in organic matter (δ13Corg) and sulfur isotopes (δ34S), as well as total organic carbon and total sulfur measurements for the black shale in the formation. Samples were taken from a drill core that contains alternating bands of sandstone and black shale. Pyrite in the black shale is divided into four textural types: euhedral, vein‐type, elliptical, and microcrystalline. Microcrystalline pyrite is typically generated by microbially mediated sulfate reduction. An extremely low S/C ratio (avg. = 0.04) is consistent with lacustrine deposition. The ranges of δ13Corg (?36 ‰ to ?27 ‰) and δ34S (+3.0 ‰ to +7.7 ‰) values can be explained by bacterial photosynthesis that involved Calvin cycle and acetyl CoA pathways, and sulfate reduction in a low‐sulfate environment. Considering the depositional age reported in a previous study of < 1.84 Ga, the Embury Lake Formation was likely emplaced in a lacustrine setting during the Trans‐Hudson Orogeny.  相似文献   

11.
Kazuhiko  Fujita  Hiroaki  Shimoji  Koichi  Nagai 《Island Arc》2006,15(4):420-436
Abstract A new method for reconstructing depositional environments of larger foraminifera‐bearing limestones is proposed. First, depth and spatial distributions of empty tests of 10 foraminiferal taxa in a 1–2 mm size fraction were examined using 32 surface sediment samples collected from depths shallower than 200 m, located to the west of Miyako Island, Ryukyu Islands, northwest Pacific. Distributional ranges of empty tests in the 1–2 mm size fraction appear to be more limited than those including other size fractions in previous reports, partly because larger empty tests of each taxon are less easily transported than smaller ones. Multivariate analyses (Q‐mode cluster analysis and non‐metric multidimensional scaling ordination) based on binary (presence/absence) data of the 10 taxa delineate four sample groups, each of which corresponds to different depositional environments: nearshore zone/bay inlet; back‐reef to fore‐reef; outer shelf to shelf slope; and shelf slope distant from coral reefs. Next, these modern data were applied to reconstruct the depositional environment of a rock section distributed in the Shiratorizaki area (Irabu Island, Ryukyu Islands), which consists of larger foraminiferal limestone of the Pleistocene Ryukyu Group. Multivariate analyses were performed on the fossil plus the modern foraminiferal data to explore the possible relationship of the fossil associations with variations in modern associations, demonstrating that the fossil foraminiferal associations resemble the modern outer shelf associations. The modern analog technique was also applied to estimate paleobathymetry using fossil foraminiferal data. The results indicate that the section studied was deposited in outer shelf environments at depths between 53.5 and 98.6 m. These paleoenvironmental interpretations are consistent with previous studies based on sedimentary facies and the computer‐based expert system. The modern dataset and methods used in our work would be particularly useful for paleoenvironmental reconstructions of Quaternary reef and shelf carbonates along active margins of the northwest Pacific.  相似文献   

12.
Mamiko  Yoshida  Yuka  Yoshiuchi  Koichi  Hoyanagi 《Island Arc》2009,18(2):320-332
River floods influence sedimentary environments and ecosystems from the terrestrial to the deep-marine. This study documents the occurrence conditions of hyperpycnal flows generated by river floods and related organic-matter sedimentation for Holocene sediments of the Niigata Plain, Central Japan, based on detailed sedimentary facies, total sulfur and total organic carbon content, diatom assemblages and organic-matter composition. Holocene sediments of the Niigata Plain consist of sand, mud and gravel that were deposited in estuarine and fluvial systems during a sea-level rise (15 000–6800 years BP) and stillstand (after 6800 years BP) following the Last Glacial Maximum. Hyperpycnites are present in the upper part of the estuarine lagoon sediments. The depositional age is considered to be about 5000 years BP. The hyperpycnites comprise two successions of a top fining-up unit and a basal coarsening-up unit, and include abundant terrigenous organic matter and freshwater diatoms. A large volume of freshwater is inferred to have flowed into the lagoon during deposition of the upper part of the lagoon sediments. In consequence, hyperpycnal flows may have readily formed in the lagoon, because the halocline was weak. The hyperpycnal flows also produced a layer of concentrated terrigenous organic matter in the uppermost part of the hyperpycnites. The abundant organic matter on the estuarine floor is inferred to have produced anoxic bottom conditions owing to oxidative decomposition by benthic bacteria.  相似文献   

13.
Wang C  Sun H  Chang Y  Song Z  Qin X 《Marine pollution bulletin》2011,62(12):2714-2723
Six sediment samples collected from the Gulf of Mexico were analyzed. Total concentrations of the PAHs ranged from 52 to 403 ng g−1 dry weight. The lowest PAH concentration without 5–6 rings PAHs appeared in S-1 sample associated with gas hydrate or gas venting. Moreover, S-1 sample had the lowest organic carbon content with 0.85% and highest reduced sulfur level with 1.21% relative to other samples. And, analysis of the sources of PAHs in S-1 sample indicated that both pyrogenic and petrogenic sources, converserly, while S-8, S-10 and S-11 sample suggested petrogenic origin. The distribution of dibenzothiophene, fluorine and dibenzofuran and the maturity parameters of triaromatic steranes suggested that organic matters in S-1 sample were different from that in S-8, S-10 and S-11 sample. This study suggested that organic geochemical data could help in distinguish the characteristic of sediment associated with gas hydrate or with oil seepage.  相似文献   

14.
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15.
The Yezo Group has a wide longitudinal distribution across Hokkaido, northern Japan. It represents a Cretaceous (Early Aptian–Late Maastrichtian) and Late Paleocene forearc basin‐fill along the eastern margin of the paleo‐Asian continent. In the Nakagawa area of northern Hokkaido, the uppermost part of the Yezo Group consists of the Hakobuchi Formation. Along the western margin of the Yezo basin, 24 sedimentary facies (F) represent 6 facies associations (FA), suggesting prevailing storm‐dominated inner shelf to shoreface environments, subordinately associated with shoreface sand ridges, outer shelf, estuary and fluvial environments. The stacking patterns, thickness and facies trends of these associations allow the discrimination of six depositional sequences (DS). Inoceramids Sphenoceramus schmidti and Inoceramus balticus, and the ammonite Metaplacenticeras subtilistriatum, provide late Early to Late Campanian age constraints to this approximately 370‐m thick final stage of deposition and uplift of the Yezo forearc basin. Six shallow‐marine to subordinately non‐marine sandstone‐dominated depositional sequences include four 10 to 110‐m thick upward‐coarsening regressive successions (FS1), occasionally associated with thin, less than 10‐m thick, upward‐fining transgressive successions (FS2). The lower DS1–3, middle DS4–5 and upper DS6 represent three depositional sequential sets (DSS1–3). These eastward prograding and westward retrograding recurring shallow‐marine depositional systems may reflect third‐ and fourth‐order relative sealevel changes, in terms of sequence stratigraphy.  相似文献   

16.
The partitioning and bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) in water, suspended particulate matter (SPM), and fish samples from the Dongjiang River (DR), Pearl River (PR), and the Pearl River Estuary (PRE) were examined. Although PAHs are much lower in PRE than in DR or PR, PAHs in some fish species are significantly higher in PRE than in DR or PR. Aqueous or particulate PAHs respectively show significant correlations with dissolved organic carbon, particulate organic matter, and chlorophyll a, suggesting that biological pumping effect regulates their distribution. The in situ partitioning coefficients (log Koc) for PAHs are one order magnitude higher than the empirical log Koc–log Kow correlation. The bioconcentration factor (BCF) is slightly higher for the marine fish than for the freshwater fish. The above phenomena indicate that BCF may vary due to the diversity of fish species, feeding habits, and metabolism of PAHs in fish.  相似文献   

17.
本文用索氏抽取法提取了东太湖的沉积物和水生植物中的可溶性有机质,用不同极性溶剂在硅胶／氧化铝柱上分离了饱和烃、芳烃、酮馏分,利用GC-MS至芳烃组分进行了鉴定分析,并对其中重要多环芳烃－菲系列化合物的来源进行了探讨。  相似文献   

18.
Sediment cores were taken at three locations in Narragansett Bay, Rhode Island, USA in 1997 and analyzed for a variety of organic contaminants including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), chlordanes, linear alkyl benzenes (LABs), benzotriazoles (BZTs) and dichlorodiphenyltrichloroethanes (DDTs) and metabolites. The distributions of these chemicals at Apponaug Cove and in the Seekonk River indicate that there was a disturbance in the depositional environment relative to cores collected at these locations in 1986 demonstrating the potential for buried contaminants to be remobilized in the environment even after a period of burial. Sharp breaks in the concentration of several organic markers with known dates of introduction were successfully used to determine the sedimentation rate at Quonset Point. Both the Quonset Point and Seekonk River cores had subsurface maximums for DDTs, PCBs, PAHs and BZTs, which are consistent with expected inputs to the environment. The Apponaug Cove core showed an increase of most contaminants at the surface indicating a recent event in which more contaminated sediments were deposited at that location.  相似文献   

19.
In-Chang Ryu 《Island Arc》2003,12(4):398-410
Abstract Sandstone petrography considered within a sequence stratigraphic framework provides a better understanding of the characteristics of the Eocene Tyee Basin, an accretionary and forearc sequence, southern Oregon Coast Range. Detailed comparison of the relative abundance of major framework grains documents a marked difference in the sandstone composition of each depositional sequence. Such a difference is mainly due to an abrupt change in provenance, from a local Klamath Mountains metasedimentary source to a more distant extrabasinal Idaho Batholith‐Clarno volcanic arc source. Furthermore, the composition of framework grains varies systematically from the lowstand systems tract to the highstand systems tract within a depositional sequence. This suggests that relative sea level change in the depositional basin, and tectonics in the source area, can affect the patterns of sedimentation and sandstone composition. In addition, the Eocene Tyee Basin sandstones have a down‐section distribution of authigenic minerals, consisting of early formed zeolites and late‐stage quartz, as well as a change in the abundance of smectite to mixed‐layer chlorite/smectite with increasing burial depth. The down‐section distribution of authigenic minerals is also causally linked to the compositional variation of framework grains in each depositional sequence with increasing burial temperature. Much primary porosity has been filled with these authigenic minerals, which diminishes the permeability of potential reservoir rocks. Reservoir‐quality porosities and permeabilities, however, are present locally in the basin. The development of these reservoir‐quality sandstones within the Eocene Tyee Basin sequence is due to a complex burial diagenesis, which is directly related to temporal and spatial variations in original detrital mineralogy, in sedimentation pattern, and in burial temperature in the basin.  相似文献   

20.
The fate and transport of highly hydrophobic chemicals are affected by the partitioning between water and dissolved organic carbon. Large variation in the partition coefficient (KDOCw) is often found, due to the selection of model organic matter or potential experimental artifacts. To investigate the roles of the type of organic matter on the partitioning of highly hydrophobic compounds, the partition coefficients of eight selected polycyclic aromatic hydrocarbons (PAHs), with 3–6 aromatic rings, were determined using a passive dosing/extraction method between water and model dissolved organic matter (humic acid, fulvic acid, sodium dodecyl sulfate micelle (SDS), and 2‐hydroxypropyl‐β‐cyclodextrin). Although the KDOCw values for 3–4 ring PAHs in this study were close to those reported in the literature, experimental KDOCw values between Aldrich humic acid (AHA) and water were higher than values reported in the literature for 5–6 ring PAHs. The KDOCw values were highest for AHA, followed by SDS and Suwannee river fulvic acid (SFA). The slopes of the linear regression between log KDOCw and log Kow were 1.23 (± 0.13), 0.82 (± 0.09), and 0.59 (± 0.13) for AHA, SDS, and SFA, respectively. The differences in the KDOCw values between AHA and the other organic matter (SDS, SFA, and CD) increased with increasing hydrophobicity of the PAHs, showing that the sorption of highly hydrophobic chemicals to the humic acid fraction may be important in the presence of mixed organic matter.  相似文献   

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