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1.
Geology of Ore Deposits - Abstract—Yellow volborthite Cu2.95(V1.91P0.09)Σ2O7(OH)1.90·2H2O, and turquoise atacamite, Cu2[Cl0.98(OH)0.02]Σ1.00(OH)3 have been found incrusting...  相似文献   

2.
新疆哈密红山高硫化物型浅成低温Cu-Au矿床的氧化带呈漏斗状产于原生硫化物矿体的上部,延深50～60m,以硫酸盐矿物为主。X射线粉晶衍射、湿法化学和差热分析研究表明,钾铁矾、板铁矾和副基铁矾3种硫酸盐矿物均系在中国首次发现。钾铁矾湿法化学分析为:H2O6.35%,SO349.72%,Na2O0.15%,Fe2O326.00%,K2O12.47%,FeO0.25%,SiO23.25%,不溶物0.85%,CaO0.11%,总计99.15%;XRD特征谱线为:4.40(100),4.26(70),6.58(47)。板铁矾湿法化学分析为H2O26.51%,SO349.91%,Na2O0.03%,Fe2O322.52%,MgO0.01%,CaO0.03%,总计99.01%;XRD特征谱线为:9.16(100),3.29(9),4.06(8)。副基铁矾湿法化学分析为H2O24.82%,SO338.53%,Al2O30.18%,Fe2O336.10%,MgO0.02%,CaO0.04%,总计99.69%;XRD特征谱线为:5.00(100),3.11(41),5.85(39)。热分析实验进一步验证了化学分析的可靠性,并对这些硫酸盐热反应机制作了解释。该类硫酸盐矿物已作为新型资源直接制酸用于湿法炼铜,具有选矿和环保上的巨大优势。对该类硫酸盐矿物的共生组合、形成次序、形成条件的深入研究还可用来反演古环境和古气候。  相似文献   

3.
莫来铁尖晶岩中的莫来石是首次发现的一种火山岩型莫来石。在全岩X射线粉晶衍射图上莫来石的d值(nm)为:0.5378(5),0.3428(9),0.3385(10),0.2693 (4),0.2545(5),0.2295 (2),0.1601 (2),0.1542 (4),0.1443 (2)。电子探针分析结果,莫来石的成分(%)为:SiO_2 28.96,TiO_2 0.53,Al_2O_3 67.13,FeO 3.06,MnO 0.05.MgO 0.02,Na_2O 0.21,K_2O 0.02,Cr_2O_3 0.05, NiO 0.02。这种莫来石是从玄武岩浆演化后期产生的富Al_2O_3、FeO(Fe_2O_3)和贫SiO_2的莫来铁尖晶岩浆中直接结晶而成的。  相似文献   

4.
The primary garnet (pyrope-almandine)-omphacite (Cpx 1, 6.5–7 wt% Na2O)-sulfide (Fe-Ni-Co mss) assemblage of the two diamondiferous eclogite xenoliths studied (U33/1 and UX/1) experienced two mantle metasomatic events. The metasomatic event I is recorded by the formation of platy phlogopite (~ 10 wt% K2O), prior to incorporation of the xenoliths in the kimberlite. The bulk of the metasomatic alteration, consisting of spongy-textured clinopyroxene (Cpx 2A, 1–3 wt% Na2O), coarser-grained clinopyroxene (Cpx 2B, 2–5 wt% Na2O), pargasitic amphibole (~ 0.8 wt% K2O; 3–3.5 wt% Na2O), kelyphite (Cpx 3, mostly <1 wt% Na2O; and zoned Mg-Fe-Al spinel), sodalite, calcite, K-feldspar, djerfisherite (K5.95Na0.02Fe18.72Ni2.36Co0.01Cu4.08S26Cl ) and a small amount of K-Ca-Fe-Mg glass, is ascribed to the metasomatic event II that occurred also in the upper mantle, but after the xenoliths were incorporated in the kimberlite. A pervasive chloritic alteration (mainly clinochlore + magnetite) that overprints earlier assemblages probably took place in the upper crustal environment. The diamonds are invariably associated with secondary clinopyroxene and chlorite, but the diamonds formed before the entrainment of the xenoliths in the Udachnaya kimberlite.Editorial Responsibility: T.L. Grove  相似文献   

5.
Single-phase K-cymrite, K[AlSi3O8]·H2O, has been synthesized in the P-T range 3≤P(GPa)≤4 and 350≤T(°C)≤650, and characterized by a variety of techniques like SEM, FTIR, and 29Si MAS-NMR. Its thermal expansivity and compressibility have been measured up to 375?°C and 6.0?GPa, respectively. Within the uncertainty of the microchemical determination of H2O by Karl-Fischer titration, it invariably contains 1?mol of H2O per mol of KAlSi3O8. Under the SEM, it appears a small idiomorphic prisms. It is optically negative, with n o=1.553(1) and n e=1.521(1). FTIR spectrum identifies the water in its structure as molecular H2O. Its lattice constants are a=5.3348(1)?Å, c=7.7057(1) Å, V= 189.924 Å3, the space group being P6/mmm. The 29Si MAS-NMR suggests a weak short-range order of Al and Si in the symmetrically equivalent tetrahedral sites. A Rietveld structure refinement demonstrates that it is isostructural with cymrite (BaAl2Si2O8·H2O), the structure comprising double tetrahedral sheets with H2O molecules residing in their cavities, K serving as an interlayer cation. Whereas cymrite, with its ordered tetrahedral Al/Si distribution, shows a Pm symmetry, the weak short-range Al/Si order in K-cymrite (abbreviated below as KCym) makes it crystallize in the space group P6/mmm. Three reversal experiments on the reaction K[AlSi3O8]·H2O (KCym)=K[AlSi3O8] (Kfs)+H2O, executed in this study, confirm the earlier results of Thompson (1994) and supplement her data. A simultaneous treatment of those reversals, together with the thermodynamic data for Kfs and H2O available in the literature, helps derive the standard enthalpy of formation (?4233±9.4?kJ/mol) and standard entropy (276.3±10.2 J/K·mol) for K-cymrite. The computed phase relations of KCym in the KAlSi3O8-H2O binary are shown in Figure 4 for three different values of aH 2O. Given a 5?°C/km isotherm in a subducting slab of metasediments in a ultra-high-pressure metamorphic environment, KCym will be expected to grow by hydration of Kfs, unless the aH 2O had been substantially less than 0.5. Nevertheless, how far it can survive exhumation of the subducted terrain will depend critically on the rate of uplifting and on the aH 2O prevailing during that process.  相似文献   

6.
在我国广西发现的钡毒铁石   总被引：3，自引：0，他引：3  
赖来仁  施倪承 《矿物学报》1997,17(2):120-125
1989年我们在广西德保矿区发现了钡毒铁石，其化学成分为（％）：BaO8．45，Fe2O335．10，As2O538．15，K2O0．14，Al2O30．07，H2O 18．48，总量为100．38。其理想矿物分子式为Ba0.5Fe4（AsO4）。（OH）4·7H2O，与德国产出的钡毒铁石的矿物分子式［BaFe4（AsO4）3（OH）5·5H2O］有一定的差异，是毒铁石［KFe4（AsO4）3（OH）4·7H2O］的钡端员矿物。该矿物是黄绿色、浅黄色，立方体晶形，硬度H=3，实测比重D=3．00，N=l．724～l．731，均质性，常见光性异常。粉晶X射线分析主要衍射强线（um）为：O．805（200）（99），0．563（220）（23），0．399（400）（47），O．326（422）（100），0284（44O）（73），0．241（542）（33），0．178（841）（23），等轴晶系，空间群为P43m，晶胞参数a=1．603nm。  相似文献   

7.
沂水杂岩中超镁铁质岩的岩石地球化学特征   总被引：2，自引：0，他引：2  
主要以捕虏体形式存在于沂水岩浆杂岩和变质杂岩中的超镁铁质岩石不发育鬣刺结构,岩石化学组成以高MgO和低SiO2、TiO2、K2O含量为主要特征。按岩石中是否含有橄榄石大致可以分为橄榄辉石岩和尖晶角闪二辉石岩两种,前者以强烈发育蛇纹石化为特征,矿物组合以单斜(透)辉石+橄榄石为主(偶见斜方辉石),蚀变矿物组合为蛇纹石±铬铁矿+磁铁矿±角闪石±尖晶石等;后者以局部发育滑石化为特征,矿物组合以斜方(古铜)辉石+单斜(透)辉石+尖晶石为主,其次是角闪石+磁铁矿±滑石等。岩石总体以稀土元素总量(∑REE)相对较低、LREE/HREE=1.64~4.40为特征,稀土元素的球粒陨石标准化配分图解显示所有样品均具Eu和Ce的负异常,除3个橄榄辉石岩样品外,多数样品无明显的轻稀土元素、轻重稀土元素和重稀土元素分异。岩石的微量元素组成以不相容元素Rb、Ba、U、Nb、Sr、Zr等具有明显不同的异常为特征:Ba、Nb呈现负异常,而Rb、U呈现正异常,Sr部分呈正异常,Zr和Ti负异常出现在橄榄辉石岩中,其他样品无Zr异常。样品YS0631的SHRIMP锆石U-Pb定年结果显示其变质锆石年龄值为2 560~2 605 Ma;另有一颗结晶锆石的年龄值为2 719 Ma,εHf(t)值为8.2,亏损地幔模式年龄为2 680 Ma。综上所述,该超镁铁质岩石源于地幔,形成于新太古代早期,随后遭受深熔及岩浆作用影响,经历了变质作用的改造。  相似文献   

8.
Northwest Africa (NWA) 12379 is a new metal-rich chondrite with unique characteristics distinguishing it from all previously described meteorites. It contains high Fe,Ni-metal content (∼ 70 vol.%) and completely lacks interchondrule matrix; these characteristics are typical only for metal-rich carbonaceous (CH and CB) and G chondrites. However, chondrule sizes (60 to 1200 μm; mean = 370 μm), their predominantly porphyritic textures, nearly equilibrated chemical compositions of chondrule olivines (Fa18.1–28.3, average Fa24.9±3.2, PMD = 12.8; Cr2O3 = 0.03 ± 0.02 wt.%; FeO/MnO = 53.2 ± 6.5 (wt.-ratio); n = 28), less equilibrated compositions of low-Ca pyroxenes (Fs3.2–18.7Wo0.2–4.5; average Fs14.7±3.7Wo1.4±1.3; n = 20), oxygen-isotope compositions of chondrule olivine phenocrysts (Δ17O ∼ 0.2–1.4‰, average ∼ 0.8‰), and the presence of coarse-grained Ti-bearing chromite, Cl-apatite, and merrillite, all indicate affinity of NWA 12379 to unequilibrated (type 3.8) ordinary chondrites (OCs). Like most OCs, NWA 12379 experienced fluid-assisted thermal metamorphism that resulted in formation of secondary ferroan olivine (Fa27) that replaces low-Ca pyroxene grains in chondrules and in inclusions in Fe,Ni-metal grains. Δ17O of the ferroan olivine (∼ 4‰) is similar to those of aqueously-formed fayalite in type 3 OCs, but its δ18O is significantly higher (15–19‰, average = 17‰ vs. 3―12‰, average = 8‰, respectively). We suggest classifying NWA 12379 as the ungrouped metal-rich chondrite with affinities of its non-metal fraction to unequilibrated OCs and speculate that it may have formed by a collision between an OC-like body and a metal-rich body and subsequently experienced fluid-assisted thermal metamorphism. Trace siderophile element abundances and isotopic compositions (e.g., Mo, Ni, Fe) of the NWA 12379 metal could help to constrain its origin.  相似文献   

9.
Hoegbomite occurs sparingly in minute (mostly 0.1 mm) grains with fine-grained hercynite, magnetite, and rutile in two coarse-grained kornerupine-cordierite-sillimanite rocks from Ellammankovilpatti, Tamil Nadu, India. The hoegbomite is Ti-poor (2.5 wt% TiO2), Fe-rich (25–26% Fe as FeO), and contains 6.2–6.8% MgO, 59.8–60.1% Al2O3, 1.0–1.3% ZnO, 0.3–0.7% Cr2O3 and 0.02% Li2O. Minor amounts (estimated not to exceed 0.2 wt% oxide) of V, Co, Ni, Ga, and Sn were detected on the electron microprobe, but Be, Nb, and Zr were not detected with the ion microprobe mass analyser. Assuming the crystal structure refined by Gatehouse and Grey (1982) to be applicable to the Ellammankovilpatti hoegbomite, the analyses were recalculated on a basis of 22 cations, 30 oxygens, and two hydroxyls, resulting in 49 to 53% of the iron being ferric. Identification of hoegbomite was confirmed by X-ray powder diffraction. Associated cordierite (Fe/(Fe+Mg)=0.14) and kornerupine (Fe/(Fe+Mg)= 0.27) contain 0.02 weight % Li2O and 0.05–0.07% BeO, while only the kornerupine contains B2O3 — 1.57% (ion microprobe analyses). Hoegbomite and the other oxides may have crystallized at temperatures between 680 and 720° C (P6.5 kbar) following attainment of peak conditions by the reaction: kornerupine+sillimanite±rutile+ZnO+H2O+O2 =cordierite+chlorite+hercynite+hoegbomite +magnetite+B2O3.The conditions for hoegbomite formation at Ellammankovilpatti appear to be characteristic of many hoegbomite parageneses. Critical for hoegbomite are silica undersaturation and relatively high oxygen and water activities at fairly high temperatures, conditions which are most commonly attained in later phases of a metamorphic cycle in upper amphibolite- and granulite-facies terrains.  相似文献   

10.
Hydrothermal experiments with H2O-CO2 fluids at Pfluid = 6 kbar yielded the following quilibrium conditions for reactions important in metamorphosed siliceous dolomites (T = °C; X = Xco2): (3) dolomite + 2 quartz = diopside + 2 CO2T = 620 ± 8X = 0.73 ± 0.03 (5) 5 dolomite + 8 quartz + H2O = tremolite + 3 calcite + 7 CO2T = 600 ± 5 550 ±5 540±5 500±5X = 0.66 ± 0.03 0.21 ± 0.03 0.21 ± 0.04 0.06 ± 0.02 (7) 3 dolomite + 4 quartz + H2O = talc + 3 calcite + 3 CO2T = 550±5 500±5 450 ±5X = 0.25 ± 0.05 0.07 ± 0.02 0.03 ± 0.02 (8) 2 dolomite + talc + 4 quartz = tremolite + 4 CO2T = 550 ± 5 540 ±5 500 ± 5X = 0.22 ± 0.03 0.21 ± 0.02 0.06 ± 0.02 A thermodynamically self-consistent 6 kbar T-XCO2, topology results by extrapolating equilibria from experimental brackets using a modified Redlich-Kwong equation for activities in H2O-CO2 mixtures. This topology restricts the assemblage talc + calcite to a narrow stability band in T-XCO2 space at XCO2 < 0.55 and T < 590°C. Accordingly, the occurrence of talc + calcite in pure siliceous dolomites metamorphosed at Pfluid = 6 kbar implies correspondingly water-rich fluids.  相似文献   

11.
Measured 18O/16O ratios from the Greenland Ice Sheet Project 2 (GISP2) ice core extending back to 16,500 cal yr B.P. provide a continuous record of climate change since the last glaciation. High-resolution annual 18O/16O results were obtained for most of the current millennium (A.D. 818-1985) and record the Medieval Warm Period, the Little Ice Age, and a distinct 11-yr 18O/16O cycle. Volcanic aerosols depress central Greenland annual temperature (1.5°C maximally) and annual 18O/16O for about 4 yr after each major eruptive event. On a bidecadal to millennial time scale, the contribution of solar variability to Holocene Greenlandic temperature change is 0.4°C. The role of thermohaline circulation change on climate, problematic during the Holocene, is more distinct for the 16,500-10,000 cal yr B.P. interval. (Analogous to 14C age calibration terminology, we express time in calibrated (cal) yr B.P. (A.D. 1950 = 0 cal yr B.P.)). The Oldest Dryas/Bølling/Older Dryas/Allerød/Younger Dryas sequence appears in great detail. Bidecadal variance in 18O/16O, but not necessarily in temperature, is enhanced during the last phase of lateglacial time and the Younger Dryas interval, suggesting switches of air mass transport between jet stream branches. The branched system is nearly instantaneously replaced at the beginning of the Bølling and Holocene (at 14,670 and 11,650 cal yr B.P., respectively) by an atmospheric circulation system in which 18O/16O and annual accumulation initially track each other closely. Thermodynamic considerations of the accumulation rate-temperature relationship can be used to evaluate the 18 O/16O-temperature relationship. The GISP2 ice-layer-count years of major GISP2 climate transitions also support the use of coral 14C ages for age calibration.  相似文献   

12.
One-year-resolved and annually-counted stalagmite multi-proxies(δ~(18)O, δ~(13)C, and layer width) from Daoguan Cave, Guizhou Province revealed detailed variability regarding the Asian Summer Monsoon(ASM) and local humidity across Bond events(BE) in the Preboreal. During BEs 8 and 7, 1.5‰ enrichments in δ~(18)O values were generally consistent with high-to low-latitude climate changes. In detail, the decadal-scale minor δ~(18)O oscillations in BE8 were broadly less than the mean value, in contrast to the significant changes in local soil moisture derived from the δ~(13)C values and layer records. In the mid-BE7, δ~(18)O variability was generally above the average level, and higher-amplitude variations were observed in the three proxy indicators. Wavelet analysis on the total δ~(18)O time series and across the specific time windows of BEs 8 and 7 identified periodicities of about 130, 60, and 20-a, respectively. Exceptionally strong in BE7, the 60-a cycle, pervasively observed in instrumental studies, became prominent starting at 11.4 kaBP. Thus, glacial background conditions are important for suppressing the ASM intensity in BE8, while during BE7, tropical hydrological circulations were potentially actively involved. Consequently, climate internal oscillations, analogous to modern conditions, might have occurred in the distant past once the link between the tropical ocean and atmosphere was established as occurs today.  相似文献   

13.
八宿吉利地区寒武纪变质花岗岩位于曲扎湖-提卡一带,主要由变质二长花岗岩和变质花岗闪长岩组成。这一新发现对于认识和恢复原特提斯构造历史演化具有重要意义。锆石CL图像显示变质花岗岩锆石为岩浆成因。锆石LA-ICP-MS测年得出片理化变质二长花岗岩年龄为503.7±4.7Ma、变质花岗闪长岩年龄为494.7±3.4Ma,表明该岩体形成时代属于寒武纪。通过岩石地球化学分析,变质二长花岗岩SiO2含量介于69.87%~79.89%之间;变质花岗闪长岩SiO2含量介于66.63%~70.15%之间。前者Al2O3含量变化于12.36%~14.82%,Na2O含量为2.54%~7.16%,K2O含量为0.15%~5.95%,K2O/Na2O=0.02~2.34;后者Al2O3含量变化于14.66%~15.41%,Na2O含量为3.60%~5.63%,K2O含量为0.77%~2.78%,K2O/Na2O=0.14~0.77,属于钙碱性-碱性过铝质花岗岩。在侵入岩构造环境Rb-(Y+Nb)判别图解、Rb-(Yb+Ta)判别图解中,样品均落入“火山弧花岗岩”区域中,表明其形成于大陆边缘火山弧环境。结合锆石测年结果及区域地质背景分析,认为吉利地区变质花岗岩形成于冈瓦纳大陆裂离卡穷微陆块阶段,同时表明原特提斯洋形成最早时限可追溯至寒武纪。  相似文献   

14.
白云鄂博的碳锶铈矿   总被引：1，自引：0，他引：1  
毛骞  马玉光  王凯怡 《地质学报》2012,86(5):837-841
在对白云鄂博碳酸岩中稀土矿物的研究中,发现了锶-稀土含水复碳酸盐矿物。根据电子探针分析结果,其化学成分相当于碳锶铈矿(Ancylite-Ce)、钙碳锶铈矿(Calcioancylite),前者Sr>Ca,后者Ca>Sr。计算得到的化学式分别为:(Sr0.62,Ca0.18)0.8(Ce0.5,Nd0.36,La0.17,Pr0.02,Sm0.02)1.2(CO3)2(OH1.04,F0.14)1.2H2O、(Ca0.73,Sr0.28,Ba0.17)1.2(Ce0.46,Nd0.15,La0.15,Pr0.04,Sm0.01)0.8(CO3)2(OH0.75,F0.06)0.8H2O,简化为:(Sr,Ca)2-xCex(CO3)2.(OH,F)2-x.H2O,接近理论化学式(Sr,Ca)Ce(CO3)2(OH)H2O,但附加阴离子除OH—外,还含有少量F-。两者均为几微米至十几微米的微小晶体,呈浸染状产出,且仅见于晚期方解石或方解石—白云石交生体中。  相似文献   

15.
黑铝钙石是一种罕见矿物，在邯邢地区镁铝夕卡岩中，发现一种呈六方片状、黄色半透明的黑铝钙石晶体。本文对该晶体进行了粉晶Ｘ射线、四元衍射、电子探针和红外光谱测量，并认为黑铝钙石是镁铝夕卡岩早期阶段的产物，处在一种富铝、贫硅的地球化学环境和高温条件  相似文献   

16.
Integration of calcareous nannofossil data, δ13C and δ18O values, and carbonate contents of the lower Paleocene–upper Paleocene sequence that crops out at the Misheiti section, East Central Sinai, Egypt, were used to denote the Danian/Selandian (D/S) and Selandian/Thanetian (S/T) stage boundaries. The study interval belongs to the Dakhla and Tarawan formations. Four calcareous nannofossil zones (NP4, NP5, NP6, and NP7/8) were recognized. The base of the Selandian Stage is tentatively placed at the lowest occurrences (LOs) of taxa ascribable to the second radiation of fasciculiths (i.e., Lithoptychius janii). This level is marked by a sudden drop of δ13C and δ18O values and carbonate content. No distinctive lithological changes were observed across the D/S boundary at the study section. A hiatus at the NP5/NP6 zonal boundary is indicated by the condensation of zones NP5 and NP6.The base of the Thanetian is placed at the base of Zone NP7/8 at the lithological change observed in correspondence to the boundary between the Dakhla and Tarawan formations. The δ13C and δ18O values abruptly decrease slightly above the base of Zone NP7/8. No consistent variations in the carbonate contents were recorded within Zone NP6 or across the NP6/NP7/8 zonal boundary.  相似文献   

17.
Rare-element pegmatites in the Voron’i tundras, Kola Peninsula, Russia, contain late abundant Rb mineralization. Individual Rb minerals are Rb-dominant feldspars and micas that form continuous solid solution series with K analoques. The feldspars contain from 17 to 86 mol % RbAlSi3O8 (5.5–25 wt % Rb2O) and 1–5 mol % CsAlSi3O8, and the muscovite contains 2.6–9.4 wt % Rb2O. The Li micas are members of the lepidolite-polylithionite series and their Rb-dominant analogues. They form a continuous series of solid solutions with the Rb concentrations varying from 0.09 to 0.54 apfu., K concentrations varying from 0.82 to 0.33 apfu, and Cs concentrations varying from 0.02 to 0.18 apfu The maximum Rb2O concentration in the newly found mineral voloshinite, an Rb analogue of lepidolite, is 12.2 wt %. The Rb-rich feldspars and micas sometimes crystallized directly or were formed via cation exchange with the young fluid. The Rb minerals are spatially and genetically closely associated with pollucite. It is supposed that initially Rb was contained in a high-temperature pollucite solid solution and was released from it at decreasing temperature as a result of a reaction with the aqueous fluid and notably enriched the latter. It is shown that Rb mineralization is generally typical of pollucite-bearing pegmatites.  相似文献   

18.
孟庆涛 《地质与勘探》2021,57(1):122-135
内蒙古北山地区阿民乌素蛇绿岩是芨芨台子-小黄山蛇绿岩带的重要组成部分,主要由变质辉长岩和极少强蛇纹石化橄榄岩组成。变质辉长岩LA-ICP-MS锆石U-Pb年龄453±12 Ma,形成于晚奥陶世。强蛇纹石化橄榄岩MgO(36.90%~37.44%)、Ni(1980×10^-6~2232×10^-6)、Cr(2312×10^-6~2506×10^-6)含量高,而Al2O3(0.59%~1.41%)、TiO 2(0.01%~0.02%)和∑REE(0.85×10^-6~3.25×10^-6)含量低,具亏损地幔岩特征;变质辉长岩MgO(7.22.20%~11.66%)相对含量高;Al2O3(15.61%~18.79%)、TiO 2(0.20%~0.29%)、P2O5(0.01%)、K2O+Na2O(1.36%~2.43%)含量低,且K2O相似文献   

19.
内蒙古突泉县牤牛海地区发育超镁铁质岩,主要岩石类型为蛇纹石化橄榄岩、辉石橄榄岩、异剥辉石橄榄岩和蛇纹岩,局部蛇纹岩中可见显微鬣刺假象结构,包括蛇纹石呈假像的柱状中空骸晶结构、鱼骨状或羽状结构。岩石化学具有高镁(w(MgO)为33.63%~39.44%)、铬(2 200×10~(-6)~17 200×10~(-6))、镍(1 900×10~(-6)~3 000×10~(-6)),高CaO/Al_2O_3(0.56~39.01,平均为7.05),低钛(w(TiO_2)为0.01%~0.02%)、低铝(w(Al2O3)为0.03%~0.36%)、低碱(w(K_2O+Na_2O)为0.03%~0.65%)特征,类似科马提岩;Mg#值(平均为87)与纯橄榄岩(86)接近;稀土元素(w(∑REE)为0.32×10~(-6)~2.79×10~(-6))明显低于大洋脊含量,轻稀土富集(LREE/HREE为2.80~16.68),Eu正异常明显(δEu为0.59~4.84);微量元素富集大离子亲石元素(LILE)Rb、Ba、Sr,亏损高场强元素(HFSE)Nb、P等。说明超镁铁质岩石岩浆源自亏损软流圈地幔,并受到俯冲流体交代作用,形成于岛弧环境。牤牛海超镁铁质岩与西部包括突泉围场、好老鹿场、超日海乌拉、梅劳特乌拉、苏尼特左旗二道井一带超镁铁质岩共同构成一条近东西向展布的超镁铁质岩(蛇绿岩)带,通过地质建造分析,认为该构造带可能为华北板块与西伯利亚板块最终缝合带。  相似文献   

20.
Five new natural white mica reference materials (RMs) were developed for in situ H2O content analyses by secondary ion mass spectrometry at the SwissSIMS laboratory of Lausanne University, Switzerland. The white mica reference materials cover a large part of the natural muscovite–phengite compositional range and are therefore suitable as reference materials for the analysis of natural rocks as well as individual minerals. The independent H2O content of the reference materials UNIL_WM1 to UNIL_WM5 was obtained by thermal conversion elemental analyser and corresponds to 4.35 ± 0.02, 4.33 ± 0.03, 4.30 ± 0.07, 4.50 ± 0.02 and 4.42 ± 0.11 (% m/m, ± 1s), respectively. SIMS determinations of H2O content revealed a matrix effect correlated to the FeO content of white mica. The compositional range in FeO of the reference materials that were calibrated for H2O determination is from 1.13% to 3.67% m/m. No crystallographic orientation dependency was observed at the level of homogeneity of these reference materials. An analytical precision of 0.02% to 0.08% m/m (1SE) is expected for the final uncertainty on measurements of unknown white micas in natural samples.  相似文献   

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