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1.
The Baingoin batholith is one of the largest granitic plutons in the North Lhasa terrane. Its petrogenesis and tectonic setting have been studied for decades, but remain controversial. Here we report data on geochronology, geochemistry and isotopes of Early Cretaceous granitoids within the Baingoin batholith, which provide more evidence to uncover its petrogenesis and regional geodynamic processes. The Early Cretaceous magmatism yields ages of 134.4–132.0 Ma and can be divided into I-type, S-type and highly fractionated granites. The I- and S-type granites exhibit medium SiO2, high K2O/Na2O with negative εNd(t) and εHf(t) values, whereas, the albite granites have very high SiO2 (79.04%–80.40%), very low K2O/N2O, negative εNd(t) and a large variation in εHf(t). Our new data indicate that these granitoids are derived from unbalanced melting in a heterogeneous source area. The granodiorites involved had a hybrid origin from partial melting of basalt-derived and Al-rich rocks in the crust, the porphyritic monzogranites being derived from partial melting of pelitic rocks. The albite granites crystallized from residual melt separated from K-rich magma within the ‘mush’ process and underwent fractionation of K-feldspar. We believe that the Early Cretaceous magmatism formed in an extensional setting produced by the initial and continuous rollback of a northward-subducting slab of the NTO.  相似文献   

2.
The magma source, petrogenesis, tectonic setting and geochronology of the late Paleozoic A-type granites widely exposed in the Zhaheba area, East Junggar, have thus far not been well-constrained. A better understanding of these issues will help to reveal the magmatic processes and continental growth of Central Asia. The A-type granites in Zhaheba include the Ashutasi alkaline granites and the Yuyitasi syenogranites, which were emplaced at 321.5 ± 4.8 Ma and 321.7 ± 0.6 Ma, respectively. The major rock-forming minerals are orthoclase, perthite, arfvedsonite and quartz, which exhibit the following principal geochemical characteristics of A2-type granites. (1) Their REE distribution curves each exhibit a ‘V’-shaped pattern and a marked depletion in Eu. They are rich in large-ion lithophile elements Rb, Th and U as well as high-field-strength elements Nb, Ta, Zr and Hf, but significantly depleted in Ba, Sr, P and Ti. (2) Their (87Sr/86Sr)i values (0.7021–0.7041), εNd(t) values (4.57–5.16) and REE distribution patterns are in basic agreement with those of the Kalamaili A-type granite belt in East Junggar. The TDM2 values of the alkaline granites and syenogranites range from 661 to 709 Ma. The A-type granites may be the products of upwelling asthenosphere-triggered partial melting of immature lower crust. The alkaline granites were late-stage products of crystallization and differentiation. Compared to the syenogranites, the alkaline granites are significantly lower in K2O, Na2O, Al2O3, FeO, MgO and CaO, but significantly higher in incompatible elements (e.g., SiO2, Rb, and Sr). The magmatic crystallization temperatures of the syenogranites and alkaline granites are 874°C and 819°C, respectively. As their age gradually decreases (peak ages: 322 Ma and 307 Ma, respectively), there is a gradual decrease in the TDM2 of the A-type granites and a gradual increase in the εNd(t) value from the Ulungur belt to the Kalamaili belt in East Junggar. The study of A-type granites is therefore one of the keys to understanding the laws and mechanisms of crustal accretion during the Phanerozoic period, as well as also being of great significance for understanding the Paleozoic accretion.  相似文献   

3.
夏林圻 《地球化学》1974,(4):272-277
Two conclsions may be drawn on the calculation of Cr2O3 parameters from eight ultrabasic intrusions in northwestern China: (1) To a first approximation, a normal distribution of chromium can he established for chromite-free intrusions, while positive skewness is observed in chromite-bearing masses. (2) The greater the “metallogenetic coefficient” value (ρCr) of the ultrahasic intrusions the greater the potential of chromite deposits.  相似文献   

4.
REE Tetrad Effects in Rare—metal Granites   总被引：1，自引：1，他引：1  
Described in this paper are the characteristics of tetrad effects of REE in rare-metal granites.Based on the analytical data and experimental geochemical data available,it is pointed out that the tetrad effects of REE in the granites are produced in the metal-fluid system.Intense fractional crystallization of granitic melt(containing REE accessary minerals)and its interaction with volatile-rich(F,Cl)fluid are the major factors leading to the tetrad effects of REE.From this,this paper presents a composite genetic model for high-degree fractional crystallization-volatile-rich fluid metasomatism of rare-metal granites.With the model,quantitative calculations have been made.Meanwhile,it is pointed out that the tetrad effects of REE can be used as an important indicator to distinguish mineralized granites from barren ones.  相似文献   

5.
Rubidium (Rb) deposits mostly occur in the South China and Central Asia orogenic belts and are often closely associated with highly differentiated granites. This study investigates a newly-discovered giant Rb deposit at Gariatong in the Central Lhasa terrane in Tibet. Detailed field studies and logging data revealed that the Rb mineralization mainly occurs in monzogranite and is related to greisenization. LA-ICP-MS U-Pb dating of zircon yielded ages of 19.1 ± 0.2 Ma and 19.0 ± 0.2 Ma for greisenized monzogranite and fresh monzogranite, respectively. The monzogranites are characterized as strongly peraluminous, with high contents of SiO2, Al2O3, K2O and Na2O as well as a high differentiation index. They are enriched in light rare earth and large ion lithophile elements with signi?cant negative Eu anomalies and depleted high field-strength elements. Petrological and geochemical features of these ore-related monzogranites suggest that they are highly fractionated S-type granites, derived from remelting of crustal materials in a post-collisional setting. The geochemistry of zircon and apatite points to a low oxygen fugacity of the ore-related monzogranite during the magma’s evolution. The discovery of the Gariatong Rb deposit suggests that the Central Lhasa terrane may be an important region for rare metal mineralization.  相似文献   

6.
Age division of Nanling granites are discussed in relation to geological,stratigraphical,age and other data,The author believes that in Nanling region there exist granites of Xuefeng,Caledonian,Hercynian,Indosinian and Yenshanian ages.Five intrusive stages can be reeognized within the Yenshanian period.The granite belts of Qitianling-Jiufeng and Dadongshan-Guidong,whose ages have been in lively debate for a long time,can be considered as composite belts consisting of multistage emplacement.  相似文献   

7.
Physicochemical conditions of formation for wolframite, cassiterite and columbite and the principal factors which contribute to the Nb^-, Ta^- variation in wolframite and cassiterite were experimentally studied under hydrothermal environments. It has been shown that wolframite, cassiterite, columbite, mierolite, tapiolite can be synthesized under wide ranges of temperature and pressure (300-600℃, 500---2,000 bars). Wolframite and cassiterite can be crystallized under either alkaline or acid conditions. Columbite may be formed in solution with a pH of 2--4, while columbite and microlite crystallize within a pH range of 3-8. In the presence of Ta and Nb, the variation of Ta and Nb in wolframite and cassiterite is found to be controlled largely by solution pH, oxidation-reduction potentials and reaction dynamics.Wolframite crystallizing from acid solution is rich in Ta, while eassiterite in Ta and Nb. On the other hand, Nb, is strongly concentrated in wolframite formed from weakly alkaline selutions, while cassiterite formed under the same condition carries higher content of Ta. Oxidation favors the entry of Ta and Nb into wolframite. Ta and Mb occur as isomorphous impurity or inclusions in wolframite and cassiterite. The maximum content of Ta2O5 in wolframite as isomorphous constituents can be as high as 6.10 percent under the experimental conditions.  相似文献   

8.
Based upon the present research stratus on Nan Ling granites and in the view of the defferenees in the opinions on the ages and periodic division of Nan Ling granites existing among some research units concerned, a proposal has been snbmitted in the paper, pointing out that it is quite necessary to launch a discussion in the deeper-going way on the problem involving the ages of Nan Ling granites and their periodic division in the journal “GEOCHIMICA”. The main topics expected to be discussed are as follows : (1) The existanec of Hereynian granites and the possibility of the formation of non-orogenic granites; (2) The divisional boundary between Yeushanian and Indonsinian granites and their distributional characteristics; (3) The periodic sub-division of Yenshanian granites and their relatiouship with mineralization ; (4) The division of the ,ages of granites older than the Caledonian period.  相似文献   

9.
The Nanyili (南一里), Laohegou (老河沟), and Shaiziyan (筛子岩) granitic intrusions are located in the southern margin of the Bikou (碧口) block in Pingwu (平武) area, Northwest Sichuan (四川). The petrography and geochemical characteristics of the granitic intrusions as well as their source and tectonic settings are reported and discussed in this article. The Laohegou and Shaiziyan granites are with high SiO2 (69.89 wt.%-73.05 wt.%) and Al2O3 contents, and A/CNK=1.04-1.12. They are typi-cal strongly peraluminous granites, with supersaturation in Al and Si. The abundance of ∑REE varies in the range of (33.13-89.12)×106. The rocks show an LREE enrichment pattern and obvious Eu nega-tive anomaly. The trace element geochemistry is characterized evidently by a negative anomaly of Ta, Nb, Ti, etc. and a positive anomaly of Rb, Ba, Sr, etc.. Zircons of the Nanyili granite have higher Th/U ratios, and their CL images have internal oscillatory zoning, suggesting that the zircons of the samples are igneous in origin. The LA ICP-MS zircon U-Pb isotopic concordia diagram yields an age of 223.1±2.6 Ma (MSWD=1.4), which indicates that the granodiorite intrusions formed in the early Late Triassic. The Nanyili, Laohegou, and Shaiziyan granites have the characteristics of post-eollisional granites and are regarded as post-orogenic granites. Thus, the granite intrusions are interpreted as syn-collisional granites that resulted from the crustal thickening caused by the collisions between the North China plate and the Yangtze plate during the Indosinian. The granitic intrusions formed in a transitional environment from syn- (compres-slonal environment) to post-collision (extensionalenvironment).  相似文献   

10.
In the process of combustion of coal organic and inorganic materials in it will undergo a complex variation.Part of thew will become volatiles and,together with coal smoke,enter into atmosphere,some will remain in micro-particulates such as ash and dust and find their way into atmosphere in the form of solid particles,and the rest will be retained in ash and slag.Coal ashes are the residues of organic and inorganic substances in coal left after coal combustion and the compostition of coal ashes in dependent on that of minerals and organic matter in coal.This paper deals with the chemical composition of coal ashes,the distribution of trace elements in them and their petrological characteristics,and also studies the relationship between the yield of coal ashes and the distribution of trace elements.In addition,a preliminary study in also undertaken on the factors that affect the chemical composition of coal ashes.As viewed from the analyses of coal ash samples collected from the Yanzhou mining district,it can be seen clearly that coal ashes from the region studied are composed chiefly of crystalline materials,glassy materials and uncombusted organic matter and the major chemical compositions are SiO2,Al2O3,Fe2O3,and CaO,as well as minor amounts of SO3,PWO5,Na2O,K2O and TiO2.During the combustion of coal,its trace elements will be redistributed and most of them are enriched in coal ashes.At the same time,the concentrations of the trace elements in flying ash are much higher than those of bottom ash,i.e.,with decreasing particle-size of coal ashes their concentrations will become higher and higher.So the contents of trace elements are negatively proportional to the particle-size of coal ashes.There has been found a positive correlation between the trace elements Th.V.Zn,Cu and Pb and the yield of coal ashes while a negative correlation between Cl and the yield of coal ashes.  相似文献   

11.
The studied granitic bodies belong to the south Eastern Desert of Egypt. They extend in a NNW–SSE trend along the same strike of the Nugrus weakness zone by which they are structurally controlled. These rocks are composed of biotite and biotite-muscovite monzogranites to syenogranites. Geochemically, a higher abundance of Ba and Rb in biotite granites with a relatively low abundance in biotite-muscovite granites as well as the diversity of Th, U, Nb, Ta, Zr, and REE reflects their origin from different sources and geodynamic settings. The biotite granites are predominantly metaluminous to low peraluminous whereas the biotite-muscovite granites have a peraluminous nature. Potassium enrichment at the expense of calcium in these rocks reflects a derivation from crustal sources by partial melting in the presence of a volatile system. Radiometric investigation showed high abundances of U(up to 38 ppm) and Th(up to 26 ppm) in biotite-muscovite granites relative to biotite granites(up to 5 ppm U and 18 ppm Th). Radioactive anomalies furthermore have been recorded in parts of biotite-muscovite granites that were affected by the faults(up to 116 ppm eU and 97 ppm eTh). Consequently, biotite-muscovite granites form a potentially fertile source for uranium mineralization.  相似文献   

12.
The Longwangzhuang granite pluton occurs on the southern margin of the North China Craton and consists mainly of biotite syenogranite with aegirine granite being locally distributed.The granites are characterized by high silicon and alkaline contents(SiO2=72.17%-76.82%,K2O+Na2O=8.28%-10.22%,K2O/Na2O>>1),AI(agpaitic index) =0.84-0.95,DI=95-97,ASI(aluminum saturation index)=0.96-1.13,and very high Fe* number(FeO*/(FeO*+Mg)=0.90-0.99),thus the granites are assigned to the metaluminous to weakly peraluminous,alkalic to calc-alkalic ferroan A-type granites.The granites are rich in large ion lithophile elements(LILE),especially high in REE concentrations(REE+Y=854×10-6-1572×10-6);whereas the enrichment of high strength field elements(Nb,Ta,Zr,Hf) is obviously less than that of LILEs,exhibiting mild depletions on trace element spider plots;and the rocks are significantly depleted in Ba,Sr,Ti,and Pb.The low εNd(t) values(-4.5--7.2) and high model ages(2.3-2.5 Ga) of the granites as well as the low εHf(t) values(-1.11--5.26) and high Hf model ages(THf1= 2.1-2.3 Ga,THf2=2.4-2.6 Ga) of zircons from the biotite syenogranite suggest that the granites were probably derived from an enriched mantle source.The zircons from the biotite syenogranite are mainly colorless transparent crystals exhibiting well-developed oscillatory zoning on the cathodoluminescence images with a LA-ICPMS zircon U-Pb age of 1602.1±6.6 Ma(MSWD=0.48).Petrochemical,trace elements,as well as Nd and Hf isotopic compositions of the rocks demonstrate that the granites were formed in a within-plate extensional tectonic regime possibly related to the breakup of the Columbia supercontinent.The granites were most likely formed through extreme fractional crystallization of alkali basaltic magma resulted from partial melting of the mantle,which was fertilized by recycling crustal rocks triggered by the delamination of lithospheric mantle and lower crust following the ～1.8 Ga collision and amalgamation of the North China Craton which is part of the Columbia supercontinent.However,contamination of neo-Archean to Paleoproterozoic crustal rocks during the ascent and emplacement of the magma could not be excluded.Being the youngest known anorogenic magmatism on the southern margin of the North China Craton related to Columbia breakup,it might represent the break off of the North China Craton from Columbia supercontinent at the end of Paleoproterozoic.  相似文献   

13.
In the strdy of the source material of granites ,it is found that cosmic dust can be used as one of the indicators for identifying the genetic types of granites.It is suggested that granites can be grouped into two genetic types, dust-barren granite and dust-containing granite, corresponding to I-type and S-type respectively as defined by Chappell et al.  相似文献   

14.
http://www.sciencedirect.com/science/article/pii/S1674987112000655   总被引：1，自引：1，他引：0  
Four different varieties of charnockitic rocks,with different modes of formation,from the Mesoproterozoic Natal belt are described and new C isotope data presented.Excellent coastal exposures in a number of quarries and river sections make this part of the Natal belt a good location for observing charnockitic field relationships.Whereas there has been much debate on genesis of charnockites and the use of the term charnockite.it is generally recognized that the stabilization of orthopyroxene relative to biotite in granitoid rocks is a function of low aH2O（±high CO2）,high temperature,and composition （especially Fe/（Fe +Mg））.From the Natal belt exposures,it is evident that syn-emplacement.magmatic crystallization of chamockite can arise from mantle-derived differentiated melts that are inherently hot and dry（as in the Oribi Gorge granites and Munster enderbite）,as well as from wet granitic melts that have been affected through interaction with dry country rock to produce localized charnockitic marginal facies in plutons（as in the Portobello Granite）.Two varieties of post-emplacement sub-solidus chamockites are also evident.These include charnockitic aureoles developed in leucocratic,biotite.garnet granite adjacent to cross-cutting enderbitic veins that are attributed to metamorphic-metasomatic processes（as in the Nicholson’s Point granite,a part of the Margate Granite Suite）,as well as nebulous,patchy charnockitic veins in the Margate Granite that are attributed to anatectic metamorphic processes under low-aHO fluid conditions during a metamorphic event.These varieties of chamockite show that the required physical conditions of their genesis can be achieved through a number of geological processes,providing some important implications for the classification of charnockites,and for the interpretation of charnockite genesis in areas where poor exposure obscures field relationships.  相似文献   

15.
Formation conditions of ammoniojarosite in system Fe2（SO4）3-（NH4）2SO4-H2O are investigated in this paper. The results show that ammoniojarosite can be formed rapidly under normal temperature and pressure by controlling suitable pH value and Fe2（SO4）3 and （NH4）2SO4 concentrations. The pH value, temperature and concentration of Fe2（SO4）3 medium are key factors influencing the formation of ammoniojarosite. Under normal temperature, precipitation of ammoniojarosite can be seen within 24 hours at pH values between 2.6-3.1, and a great quantity of ammoniojarosite is formed within 48 hours. At about 90℃, the pH value range forming ammoniojarosite extends to 1.2-3.1, and within this range the rise of pH value is advantageous to the formation of ammoniojarosite and high Fe2（SO4）3 concentration is also advantageous. Relative pure ammoniojarosite is synthesized under high Fe2（SO4）3 concentration （≥0.05 M） and ammoniojarosite containing melanterite and colloid amorphous hydroxide vitriol iron is formed at low Fe2（SO4）3 concentration. The deposition process of ammoniojarosite can be used to harness wastewater from mines and other industries and remove S, Fe and other toxic and harmful elements, such as As, Cr, Hg, Pb in water. Rapid formation of ammoniojarosite and other jarosite analogs under normal temperature and pressure has a good potential prospect for harnessing acid wastewater by means of precipitation of jarosite and its analogs.  相似文献   

16.
The accessory minerals apatite and sphene are the main carriers of REE in alkaline rocks.Their chondrite-normalized REE patterns decline sharply to the right as those of the host rocks,In the patterns an obvious negative Eu anomaly and a positive Ce anomaly can be seen in apatite and sphene,respectively.Zircon from alkaline rocks is different in REE pattern,I,e,. a nearly symmetric“V“-shaped pattern with a maximum negative Eu anomaly.Compared with the equivalents from granites,apatite,sphene and zircon from alkaline rocks are all characterized by higher (La/Yb)N ratio and less Eu depletion,As to the relative contents of REE in minerals,apatite,sphene and zircon are enriched in LREE,MREE and HREE respectively,depending on their crystallochemical properties.  相似文献   

17.
In this paper a technique for determining ^235U abundance is described. After chemical separation, uranium-rich ore (a compound of uranium with chemical and radioactive pure)is made into U3O8 by burning at 850℃, and then the U3O8 is prepared as the radioactive measuring source with a definite weight and shape. The measurement is carried out of the net area of 185.7 keV γ -ray peak of ^235U by Ge (Li) γ -ray spectrometer, with the mixture of a number of primary uranium ores as normal abundance standard. Parallel analysis and counting are performed on the standard and samples with the same method. The abundance of ^235U will be known by comparing their net areas of 185.7 keV γ ray peaks of ^235U both in the samples and the standard. Two samples of uranium ore from China which are suspected to be anomalous in U abundance and one sample from Oklo natural reactor have been determined. The precision of the method is better than 1%.  相似文献   

18.
The main types of intrusive rocks in the Kelameili-Harlik Hercynian erogenic belt include calc-alkaline granites, diabase dykes, kaligranites and alkaline granites. Investigation in field geology, petrology, mineralogy and geochemistry shows that the calc-alkaline granites belong to the syntexis-type (or I-type) and were formed in a pre-collisional magmatic arc environment. In consideration of the fact that kaligranites have many features of alkaline granites with higher consolidation temperatures than the calc-alkaline granites and show a discontinuity of minor element and REE evolution in respect to the calc-alkaline granites, they could not have been derived by differentiation of magmas for the calc-alkaline granites, but are likely to have been generated in an environment analogous to that for alkaline granites. The triplet of basic dyke swarms, kaligranites and alkaline granites could be regarded as a prominent indication of the initial stage of post-collisional delamination and extension. These ro  相似文献   

19.
Types and degree of muturity of organic matters in sedimentary rocks as index for oil generation and evolution can be determined by infrared spectrometry. In normal cases,oil-generating rocks can be preliminarily identified by infrared spectra of solubable bitumen components. However, the spectra of condensed nuclei of aromatic hydrocarbon should be resorted to whenever the composition and structure of organic matters arc comparative complex and their degree ofmuturity are not all the same. Systematic researches of known samples show that a configuration of condensed aromatic hydrccarbon can be proposed on the basis of the index of aromatic hydrocarbon structure and the ratio of methyl and methylene to aromatic nucleus. It is evidenced by preliminary experience that oil- and coal-generating organisms can be distinguished from each other with the help of this configuration.  相似文献   

20.
<正>Thus far,our understanding of the emplacement of Xuebaoding granite and the occurrence and evolution of the Songpan-Garze Orogenic Belt has been complicated by differing age spectra results.Therefore,in this study,the ~(40)Ar/~(39)Ar and sensitive high resolution ion micro-probe(SHRIMP) U-Pb dating methods were both used and the results compared,particularly with respect to dating data for Pankou and Pukouling granites from Xuebaoding,to establish ages that are close to the real emplacements.The results of SHRIMP U-Pb dating for zircon showed a high amount of U,but a very low value for Th/U.The high U amount,coupled with characteristics of inclusions in zircons,indicates that Xuebaoding granites are not suitable for U-Pb dating.Therefore,muscovite in the same granite samples was selected for ~(40)Ar/~(39)Ar dating.The ~(40)Ar/~(39)Ar age spectrum obtained on bulk muscovite from Pukouling granite in the Xuebaoding,gave a plateau age of 200.1±1.2 Ma and an inverse isochron age of 200.6±1.2 Ma.The ~(40)Ar/~(39)Ar age spectrum obtained on bulk muscovite from Pankou granite in the Xuebaoding gave another plateau age of 193.4±1.1 Ma and an inverse isochron age of 193.7±1.1 Ma. The ~(40)Ar/~(36)Ar intercept of 277.0±23.4(2σ) was very close to the air ratio,indicating that no apparent excess argon contamination was present.These age dating spectra indicate that both granites were emplaced at 200.6±1.3 Ma and 193.7±1.1 Ma,respectively.Through comparison of both dating methods and their results,we can conclude that it is feasible that the muscovite in the granite bearing high U could be used for ~(40)Ar/~(39)Ar dating without extra Ar.Based on this evidence,as well as the geological characteristics of the Xuebaoding W-Sn-Be deposit and petrology of granites,it can be concluded that the material origin of the Xuebaoding W-Sn-Be deposit might partially originate from the Xuebaoding granite group emplacement at about 200 Ma.Moreover,compared with other granites and deposits distributed in various positions in the Songpan-Garze Orogenic Belt,the Xuebaoding emplacement ages further show that the main rare metal deposits and granites in peripheral regions occurred earlier than those in the inner Songpan-Garze.Therefore,~(40)Ar/~(39)Ar dating of Xuebaoding granite will lay a solid foundation for studying the occurrence and evolution of granite and rare earth element deposits in the Songpan-Garze Orogenic Belt.  相似文献   

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