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1.
薄基岩浅埋煤层覆岩破坏移动演化规律研究 总被引：10，自引：0，他引：10
以榆阳煤矿为研究基地,进行了地下水动力学参数、覆岩力学组合结构特征与基岩风化带的阻隔水特性试验。结果表明,风积沙层底部为强含水层;主采煤层上覆覆岩泥岩强度高于砂岩;砂岩孔隙率高,含水率大,抗压、抗拉强度比值高;泥岩和砂岩的黏土矿物含量低、具有典型的脆性易裂、抗扰动能力差和再生隔水能力弱等新的破坏移动特性,并通过多因素拟合,确立了薄基岩浅埋煤层覆岩采动破坏“两带”高度的动态变化特征,提出了长壁工作面开采防止突水溃砂的调控技术,成功应用于榆阳煤矿并实现绿色保水开采,为陕北榆神大煤田薄基岩浅埋煤层进一步推广高效开采技术和保护生态环境实现绿色保水开采奠定了基础。 相似文献
2.
The hydrodynamic and sedimentary setting of nearshore coral reefs, central Great Barrier Reef shelf, Australia: Paluma Shoals, a case study 总被引：4，自引：0，他引：4
The Great Barrier Reef (GBR) shelf contains a range of coral reefs on the highly turbid shallow inner shelf, where interaction occurs with terrigenous sediments. The modern hydrodynamic and sedimentation regimes at Paluma Shoals, a shore‐attached ‘turbid‐zone’ coral reef, and at Phillips Reef, a fringing reef located 20 km offshore, have been studied to document the mechanisms controlling turbidity. At each reef, waves, currents and near‐bed turbidity were measured for a period of ≈1 month. Bed sediments were sampled at 135 sites. On the inner shelf, muddy sands are widespread, with admixed terrigenous and carbonate gravel components close to the reefs and islands, except on their relatively sheltered SW side, where sandy silty clays occur. At Paluma Shoals, the coral assemblage is characteristic of inner‐shelf or sheltered habitats on the GBR shelf (dominated by Galaxea fascicularis, up to >50% coral cover) and is broadly similar to that at Phillips Reef, further offshore and in deeper water. The sediments of the Paluma Shoals reef flats consist of mixed terrigenous and calcareous gravels and sands, with intermixed silts and clays, whereas the reef slope is dominated by gravelly quartz sands. The main turbidity‐generating process is wave‐driven resuspension, and turbidity ranges up to 175 nephelometric turbidity units (NTU). In contrast, at Phillips Reef, turbidity is <15 NTU and varies little. At Paluma Shoals, turbidity of >40 NTU probably occurs for a total of >40 days each year, and relatively little time is spent at intermediate turbidities (15–50 NTU). The extended time spent at either low or high turbidities is consistent with the biological response of some species of corals to adopt two alternative mechanisms of functioning (autotrophy and heterotrophy) in response to different levels of turbidity. Sedimentation rates over periods of hours may reach the equivalent of 10 000 times the mean global background terrigenous flux (BTF) of sediment to the sea floor, i.e. 10 000 BTF, over three orders of magnitude greater than the Holocene average for Halifax Bay of <3 BTF. As elsewhere along the nearshore zone of the central GBR, dry‐season hydrodynamic conditions form a primary control upon turbidity and the distribution of bed sediments. The location of modern nearshore coral reefs is controlled by the presence of suitable substrates, which in Halifax Bay are Pleistocene and early Holocene coarse‐grained (and relatively stable) alluvial deposits. 相似文献
3.
Adem Bayram Hızır Önsoy Murat Kankal Murat İhsan Kömürcü 《Arabian Journal of Geosciences》2014,7(11):4987-4996
Suspended sediment related studies based on direct measurements for Turkish rivers and streams are very few for various reasons such as cost, time, or fewer operational sediment gauging stations, and thus the researchers tend to look for indirect methods. Turkey is a developing country and in need of many investments, which resulted in engineering and management modifications in its river and stream systems. This paper investigates the spatial and temporal variations of suspended sediment concentration (SSC, mg/L) versus turbidity (NTU) in the stream Har?it watershed having a length of the main branch at 143 km and catchment area of 3,280 km2, Eastern Black Sea Basin of Turkey. Subsequently, the effect of the all kinds of anthropogenic activities was evaluated, namely, dam operation, levee construction, municipal wastewater discharge, sand–gravel mining on SSC, and turbidity in the watershed. In situ turbidity monitoring and water sampling studies were semimonthly conducted at ten stations from March 2009 to February 2010. On a semimonthly basis, it was revealed that SSC and turbidity values having significant correlation varied spatially and temporarily. The municipal wastewater discharge from the city of Gümü?hane together with the decreasing flow rate revealed itself with a significant increase in the turbidity and SSC, especially in the summer months. Torul Dam having a reservoir volume of 168 hm3 could trap 78.6 % of the SSC and could remove 66.6 % of the turbidity, thanks to its long hydraulic residence time; however, Kürtün Dam released the suspended sediment as a result of its sluiceway tunnel operation. Sand–gravel mining activities between the last two stations severely affected the water quality by increasing the SSC and turbidity. 相似文献
4.
This paper analyses the causes of the catastrophic failure of an earth dam that took place on 21 January 2001 during the first filling test in the NE of Spain (Altorricón village, Huesca Province). The San Juan reservoir, with a capacity of 850,000 m3, was built in 1999 on gypsiferous mantled pediment deposits overlying Tertiary dispersive clay sediments. The basin of the reservoir was excavated in the alluvial cover and Tertiary bedrock. An earth dam was constructed on the pediment surface along the perimeter of the artificial basin. The dam has a core of compacted clay material derived from the excavation, which is indented 1 m in the Tertiary shales of the bedrock, cutting the highly pervious alluvial mantle. Field observations, analysis of the basin and dam materials and eyewitnesses accounts have helped to infer the processes involved in the failure of the earth dam. These processes include (1) subsidence and ravelling (suffosion) processes induced by the dissolution of the 4-m-thick detrital cover with a gypsum content of around 40%; (2) piping processes affecting the embankments and core of the dam built with dispersive clays that have high exchangeable sodium percentage (ESP) and show active pipes; and (3) water circulation through biogenic burrows in the pediment deposits. This case study demonstrates the frequently hidden limitations that evaporite sediments and dispersive clay materials pose to the construction of dams. It also shows that highly permeable surficial deposits should be stripped before the construction of the dam structure. 相似文献
5.
K. Ilayaraja R. R. Krishnamurthy M. Jayaprakash P. M. Velmurugan S. Muthuraj 《Environmental Earth Sciences》2012,66(8):2459-2476
The large tsunami, which was generated by an earthquake on 26 December 2004, affected most of the countries around the Indian Ocean. A total of 48 tsunamigenic surface sediments and nine core samples have been collected from various coastal geomorphological features such as beaches, estuaries/creeks and mangrove areas in the Andaman Islands. These samples were analysed for textural analysis and geochemical studies to evaluate effects of the tsunami on sediment contamination. The studied sediments, deposited by the 26 December 2004 tsunami in Andaman group of islands, belong to poorly sorted, coarse to medium sands. Generally the concentration of heavy metals in the tsunamigenic surface sediments is mainly in the order of Cu > Mn > Fe > Zn > Pb during the post-tsunami (2005) and Cu > Fe > Mn > Zn > Pb during the post-monsoon (2008). The analysed core samples show that tsunami sediments have been preserved at certain depths from the sampling locations and indicate that they were derived from shallow littoral to neritic depths. The approximate width of deposits deposited by the 26 December 2004 Tsunami in Diglipur and Mayabandar areas (North Andaman) is ~10 cm, in Rangat and Baratang (Middle Andaman) the thickness of the deposits is ~15 cm. In Chidiyatapu, Junglighat, Rutland Islands and Havelock Island (South Andaman) the thickness of the deposits is ~30, ~8, ~25 and ~5 cm, respectively, and in Hut Bay (Little Andaman) the thickness of the deposits is about ~15 cm. 相似文献
6.
普拉姆岛(Plum island)是美国东北部缅因湾最大的障壁海岸,岛内向陆一侧为新英格兰地区最大潟湖和沼泽区,它们是晚第四纪末次冰期冰川作用和冰后期海岸作用的沉积响应。通过普拉姆岛研究区上更新统—全新统160个钻孔描述,识别出8种沉积物: 泥炭、冰川黏土、黏土、粉砂、细砂、中粗砂、砾、坠石。根据沉积物类型及其组合特征,结合沉积环境,共划分出8种沉积微相: 障壁沙丘、滨岸沙、水下临滨沙、河道、潮汐水道、潟湖、潮坪、沼泽。研究区在晚第四纪末次冰盛期(MIS2)被劳伦斯蒂德冰盖(Laurentide Ice Sheet)覆盖,发育冰川地貌,冰川泥覆盖在基岩之上,形成底层沉积; 冰后期(MIS1),冰盖消融,海平面发生变化,在冰川地貌鼓丘附近形成沙坝,最终沉积演化为障壁岛—潟湖环境,潟湖通过潮汐水道与广海相连通。 相似文献
7.
Experiments were carried out in a 10 × 6 m basin to simulate turbidity currents generated by the Horgen Slumping Events of 1875. The conditions for kinematic similarity were satisfied and the experiments gave further insight into the mechanics of transport triggered by the Horgen slumps. The experimental turbidity currents laid down thick deposits on a subaqueous fan, and thin sheets of turbidite on the floor of the elongate basin through longitudinal transport, comparable with the simulated deposits in Lake Zurich. It is concluded that longitudinal transport is a general phenomenon of turbidity currents. 相似文献
8.
9.
Goat Paddock in northern Western Australia is a ～5 km-diameter impact crater of Eocene age excavated in gently dipping Proterozoic sandstones. Roughly radial gorges formed by post-impact erosion provide cross-sectional views of the wall and rim zone. The predominant structural theme is one of synclinal rim folding with broad zones in which bedrock strata were deformed by impact to steep, vertical and overturned attitudes. Impact breccia is found craterward of deformed bedrock, on top of it, and downdropped into fault troughs roughly concentric to the crater. The bedrock?–?breccia contact is sharp in some places and gradational in others. In at least one section, the entire mass of upturned bedrock and breccia was displaced radially over essentially undisturbed bedrock, as indicated by slickensides on the horizontal contact. Talus deposits are similar to breccia, but show rough size sorting and clast orientation that dips steeply craterward, indicating that the talus formed as slides down the oversteepened crater wall immediately after crater formation. Shatter cones in some clasts indicate that allogenic material is incorporated in these deposits. Suevite, characterised by ropy flow textures, and by microclasts of quartz with planar deformation features, planar fractures, and of vesiculated silica glass, was found overlying deformed bedrock at a point where the surface of the bedrock forms a nearly horizontal bench midway up the crater wall. The crater was at least partially filled by later sediments, represented by bedded conglomerate close to the crater wall grading inward to sand, silt and mudstone recovered by drillholes on the crater floor. Some of the talus and conglomerate occupy re-entrants in the crater walls, suggesting an original scalloped outline to the crater. Two drillholes, one central and one halfway to the wall, both reached brecciated sandstone after penetrating 210 m of lake sediments. Goat Paddock has a flat floor with no indication of a central uplift and a depth/diameter ratio of ～0.073. This crater form, coupled with the modification of the crater walls by slumping and the scalloped outline of the crater rim suggests that Goat Paddock bridges the two traditional classes of impact crater: simple and complex. 相似文献
10.
Mohamed Abdallah Gad Darwish 《Environmental Earth Sciences》2017,76(23):804
The Marahiq area represents a portion of the Pan-African belt from the Neoproterozoic age in south Egypt and includes metamorphosed ultramafic rocks, metavolcanic rocks, and granodiorite pluton. The area is characterized by the ancient abandoned Au mine and the recent active talc mines. The present paper provides a preliminary assessment of stream sediments for gold (Au) placer and environmental hazard. Steam sediments from 36 stations were analyzed using ICP-MS for determining the concentration of 53 elements. Various statistical techniques, graphical representations, a set of complementary sediment quality assessment methods, and different mapping methods have been applied. The results showed that Au and the investigated elements were influenced by long history of the ancient mining activities and weathering processes, leading to elevate Au and some heavy metal(loid)s concentrations and exhibit enrichment ratios as follows: Te > As > Au > Cu > Cd > Co > Ni > V. Whereas Cd, Co, and V were attributed to geogenic origin, As, Au, Cu, Ni, and Te were derived from anthropogenic mining activities. It is found that the anomalies of Au and the element of interest are indicative of Au placer and point out a new perspective Au-sulfide mineralization hosted along the favorable tectonic zones that were the main source of Au placer. Both As and Te are good pathfinders to explore Au placer and related mineralization. Environmentally, the excess of As, Cu, Ni, and Te could generate moderate levels of contamination and low level of ecological risk in the sediments. Although As, Cu and Ni posed medium–low potentially adverse effects and low toxicity levels, they cannot cause harmful influences on biological life. Accordingly, streambed sediments are considered as safe and acceptable as inoffensive materials for environmental management. Overall, this study is as reference values for governmental organizations for appraising future environmental pollution in the area. Also, it is fruitful for Au placer and promising with success for Au exploration along the shear zones and strike-slip faults. 相似文献
11.
N. H. A. Al-Saati E. H. Hwaidi S. H. Jassam 《International Journal of Environmental Science and Technology》2016,13(12):2875-2882
A comparative study was performed between cactus (Opuntia spp.) and alum as coagulants. Monthly samples of raw water, delivered from (Al-Mashroo Canal), were studied and analyzed for turbidity removal during the period from August 29, 2014, to July 23, 2015. The analysis was conducted to decide the optimum dose, optimum velocity gradient, and optimum flocculation time for both coagulants. The results of the study indicate the efficiency of alum over cactus and that the optimum dose of alum was larger than that of cactus. The pH level of raw water was in the range of 7.734–8.203, while the temperature of raw water was in the range of 13–35 °C during the period of the study. The reliable velocity gradient for both coagulants was 25 1/s, and the reliable flocculation time for both coagulants was 20 min. The residual turbidity for cactus was in the range of 0.0–296 NTU, while that of alum was in the range of 0.0–5.81 NTU. 相似文献
12.
Gold paleoplacers become progressively more affected by diagenetic processes with age and burial. Mesozoic paleoplacer deposits in southern New Zealand display intermediate stages of diagenetic transformation compared to little-affected Late Cenozoic paleoplacers and strongly-affected Paleozoic and Precambrian paleoplacers. The Mesozoic (Cretaceous) diagenesis resulted in near-pervasive alteration, cementation and lithification of the paleoplacer. Lithic clasts and matrix have been extensively altered to illite, ferrous iron-bearing smectite-vermiculite, and kaolinite, and the cement consists mainly of clays and calcite. Diagenetic pyrite, marcasite, vivianite, and Mn oxide also contributed to cementation. Alteration occurred under near-surface (<500 m depth) conditions with groundwater that had circumneutral pH, high alkalinity, and elevated dissolved K, Mg and Ca. Detrital albite remained unaffected by alteration. Detrital gold has been variably dissolved and redeposited, with widespread formation of gold overgrowths on the 1–10 μm scales, with 1–3 wt% Ag. Gold mobility was driven by reduced sulphur complexes in the low redox, high pH diagenetic environment. The overgrowth gold locally contributed to cementation of fine clastic grains, and has intergrown with diagenetic clays and Mn oxide. Post-diagenetic oxidation of the paleoplacer deposit has transformed much of the pyrite to ferric oxyhydroxide and deposited some ferric oxyhydroxide coatings on gold. These oxidation processes have had only minor effects on gold mobility and textures. Hence, the low redox conditions of diagenetic gold mobility were distinctly different from those typically associated with oxidation-related supergene gold mobility. Diagenesis can affect economics of paleoplacer mining by hindering rock disaggregation during processing, coating gold particles with secondary minerals, and increasing the clay content of the deposit, all of which can lower the efficiency of gold recovery. 相似文献
13.
Lake sediments are integrators of watershed wide environmental information that includes bedrock geology, glacial overburden, vegetation, hydrology and land use. Lake sediments were collected from an area covering approximately 13,600 km2 from the Gowganda and Temagami regions to determine the geochemical background conditions representing different bedrock types. For the entire dataset, the median value for arsenic in lake sediment was 2.6 mg/kg, well within the prescribed limits indicating that the Canadian national objective for arsenic in sediments for the protection of aquatic life (17 mg/kg). Overall, the vast majority of lake sediment samples (97.2%) were below the 17 mg/kg Canadian objective for the protection of aquatic life, however, catchments with Nipissing Diabase had the highest background levels for arsenic (10 mg/kg) with some lakes ranging up to 30 mg/kg. The major geological controls influencing changes in lake sediment geochemistry were determined using random forest classification and principal component analysis (PCA). Random forest classification was able to identify which geological province the samples were derived from and the dominant rock types in the sample catchment with respectable accuracy. PCA revealed strong spatial relationships between lake sediment geochemistry and bedrock geology, particularly a strong relationship between Nipissing Diabase in the watershed of the lake and the cobalt-type mineralization indicator elements in the lake sediment including naturally higher levels of arsenic. Within the samples that exceeded regulatory standards, over half the samples that exceeded the regulatory objectives were located in watersheds that contained Nipissing Diabase in their catchment. This study demonstrates that unique geochemical assemblages can be associated with specific geological areas which is of interest to exploration geologists, for target generation and prospecting, and to environmental policy makers, for site-specific restoration targets. 相似文献
14.
Chemical availability of arsenic and heavy metals in sediments from abandoned cinnabar mine tailings 总被引：1，自引：1，他引：0
Raquel Larios Rodolfo Fernández-Martínez Verónica Silva Isabel Rucandio 《Environmental Earth Sciences》2013,68(2):535-546
The understanding of the solid-phase speciation of arsenic in soils and sediments is important in the evaluations of its potential mobility and availability in the environment. The spoil heaps of abandoned mercury mines contain waste materials with high arsenic and heavy metals concentrations. The weathering of these tailings can cause their mobilization to the surroundings. In this work, the mobility and availability of arsenic and some heavy metals were evaluated in sediments from two heavily polluted mercury mining districts in Asturias (NW Spain). For this purpose, a slightly modified version of the Bureau Community of Reference sequential extraction scheme was applied to sediments. The total contents in the operationally defined fractions were analysed by inductively coupled plasma-atomic emission spectrometry. Extremely high total arsenic concentrations were found in all sediments ranging from 4,000 to 24,800 mg kg?1. High easily mobilizable arsenic contents were found in the first mining area, related to the solubilization of Ca-bearing phases, supported by extracts analyses, X-ray diffraction results and the positive correlation found among the As and Ca fractionations. Ni and Zn were the most mobile among heavy metals, being Cr the least mobile, suggesting an anthropogenic origin due to the metallurgical processes, transport or dispersion generated from neighbour spoil heaps. In the second mining area, the bulk of As was concentrated in the residual phase, as well as Cr, Cu, Fe, Pb, Ti, indicating a mineralogical origin and the low availability of these elements. The strong correlations established between As and Fe and Ti distributions support the hypothesis that As is mainly associated to structural mineral phases in these sediments. 相似文献
15.
Isabel Ribeiro da Costa Rita Fonseca Catarina Pinho Alexandre Araújo Luísa Catarina Martins Nuno Dias Ana Isabel Janeiro Guilherme Freitas 《Environmental Earth Sciences》2018,77(5):202
Draining through industrial areas of the Minas Gerais mining state (Brazil), some tributaries of the São Francisco River constitute a potential environmental hazard for this great river and threaten the quality of the regional soils for agriculture and other activities. Extensive geochemistry and mineralogy of sediments, soils and alluvial plains from six selected areas within the Consciência drainage basin close to an important Zn-extraction plant, have been carried out. In this report, detailed mineralogy of those samples and supporting geochemical data are discussed, taking into account their specific climactic and environmental context. Petrographic and electron microprobe characterization of the sand-grained fraction of these materials was complemented by XRD on their finer fraction: the main contaminant minerals are willemite (one of the Zn ores used in the industrial plant) and jarosite, though their contents are quite variable in the studied areas and also with depth; minor amounts of Zn-, Pb-, Cd-, and Mn-bearing mineral phases are also frequent, usually as inclusions in willemite or in polycrystalline clasts, or adsorbed on the finer materials, such as clay minerals and associated Fe-hydroxides. Mineralogical contamination is responsible for high metal contents in the soils and sediments of the areas closer to the plant (e.g. Zn ? 2000 mg kg?1 and Cd ? 20 mg kg?1, which are the Intervention Values for Industrial Areas) and the greatest contamination risks are related to the more labile phases that circulate throughout the alluvial plains, the shallow sediments and the stream bed. Monitoring the mineral/chemical contamination and its extent also constitutes a useful basis for future proposals to remediate and recover this industrial area in order to decrease medium- and long-term negative impacts of metal contamination on the local and downstream environments. 相似文献
16.
Post-convergence evolution of the Variscan belt is characterized by the development of intramontane coal-bearing basins containing volcano-sedimentary successions. In the French Massif Central, K––Ar ages on clay particles from fine-grained sediments of the Bosmoreau basin (Limousin area), help pinpoint the evolution of the basin. In the lower part of the sedimentary pile, illite in a siltstone underlying a volcanic layer previously dated at 332±4 Ma by the U––Pb method on zircon, yields a consistent K––Ar age of ca. 340 Ma. Upward in the sedimentary succession, illite yields Stephanian K––Ar ages, which can be combined to provide a mean deposition age of 296.5±3.5 Ma. The Bosmoreau basin, albeit mainly filled with Stephanian deposits, was initiated during the late Visean, i.e. ca. 30 Ma earlier than inferred from biostratigraphical constraints. During the Stephanian, the same structure was reactivated and late Visean deposits were eroded and subsequently blanketed by thick clastic sediments. These results emphasise a two-stage evolution for the Bosmoreau basin, which is closely related to extensional tectonics identified on basement country rocks, and they are used to propose a geodynamic evolution of the studied area. 相似文献
17.
V. Ya. Yevzerov 《Lithology and Mineral Resources》2007,42(6):505-514
Rock associations in fluvioglacial deltas reflect climatic cyclicity. Climatic cycles determined the accumulation of sediments in the association of hydrodynamic, debris, and turbidity flows. Hydrodynamic flows formed successively the near-summit part of the delta (pebble and boulder) and its frontal slope in the course of accumulation of the pebble, sand-pebble or sandy and, less common pebble-boulder layers inclined toward the basin. Decrease in energy of flows in the basin resulted in successive reduction of particle grain-size along these layers and toward distal areas of the delta during its formation. The formation of the deltaic frontal slope was followed by the initiation of debris and turbidity flows. They spread along the floor of marine and freshwater basins and deposited successively gravel material, different-size sands, and varved clay. In the study region, sediments of the association under consideration include sand and sand-gravel deposits (up to 40% of total reserves in the Murmansk region) and almost all known brick clay deposits. 相似文献
18.
Sedimentological study of the digitated lobes of gravel and associated sediments in the north of Durgapur results in identification
of five major facies. Facies analysis indicates the sediments were deposited from an alluvial fan that has prograded in to
an inferred shallow body of water. The analysis also suggests debris flow deposits dominate proximal part, modified grain
flow and turbidity current the middle part and current generated channel and non-channel deposits in the distal part of the
alluvial fan — fan-delta sequence. 相似文献
19.
Fine-grained fluvial residual channel infillings are likely to reflect systematic compositional changes in response to climate change, owing to changing weathering and geomorphological conditions in the upstream drainage basin. Our research focuses on the bulk sediment and clay geochemistry, laser granulometry and clay mineralogy of Late-glacial and Early Holocene River Meuse (Maas) unexposed residual channel infillings in northern Limburg (The Netherlands). We demonstrate that residual channel infillings register a systematic bulk and clay compositional change related to climate change on a 1–10 k-yr time-scale. Late-glacial and Holocene climatic amelioration stabilised the landscape and facilitated prolonged and intense chemical weathering of phyllosilicates and clay minerals due to soil formation. Clay translocation and subsequent erosion of topsoils on Palaeozoic bedrock and loess deposits increased the supply of smectite and vermiculite within River Meuse sediments. Smectite plus vermiculite contents rose from 30–40% in the Pleniglacial to 60% in the Late Allerød and to 70–80% in the Holocene. Younger Dryas cooling and landscape instability caused almost immediate return to low smectite and vermiculite contents. Following an Early Holocene rise, within about 5000 yr, a steady state supply is reached before 5 ka (Mid-Holocene). Holocene sediments therefore contain higher amounts of clay that are richer in high-Al, low-K and low-Mg vermiculites and smectites compared with Late (Pleni-)glacial sediments. The importance of clay mineral provenance and loess admixture in the River Meuse fluvial sediments is discussed. © 1998 John Wiley & Sons, Ltd. 相似文献
20.
《Journal of African Earth Sciences》2007,47(1):39-48
Quaternary deposits in the southeastern part of the Olduvai basin, northern Tanzania, consist of lake margin deposits, followed by a series of fluvial sediments. The clay mineral fraction of the lake margin deposits (Bed I and lower part of Bed II) is composed of smectite and subordinate illite. All smectite is largely dioctahedral and shows indications for a limited degree of irregular interstratification by illite. In the overlying fluvial deposits (Beds II–IV), illite is the most abundant clay mineral. Smectite only occurs in lower parts of the fluvial deposits (up to the middle of Bed III), where it generally shows a high degree of irregular interstratification. Differences in clay mineral composition between the lake margin deposits and the fluvial deposits record differences in sediment source area and degree of alteration. Dioctahedral smectite in the lake margin deposits and the oldest fluvial deposits is derived from a region with volcanic material extending to the east and south of the basin, which also supplies a certain amount of illite. Illite in the fluvial deposits of Bed IV originates from an area with a metamorphic bedrock to the west and north. Alteration of detrital clay minerals resulted in Mg-enrichment of dioctahedral smectite in part of the lake margin deposits and partial illitization of smectite in the older fluvial deposits. Formation of clay minerals during diagenesis or soil development is not documented by analysis of the total clay fraction. 相似文献