Laboratory studies on cometary molecules     

Markandey Singh  Jai Prakash Chaturvedi 《Earth, Moon, and Planets》1987,38(3):253-261

We show results for some new bands of C₂, CN, N₂ ⁺, CO⁺, NH, OH, and CH hitherto unidentified, but expected to be present in the spectrum of comets by the analysis of Franck-Condon factors. Vibrational transition probabilities, Franck-Condon factors have been evaluated by an approxximate analytical method for the A-X system of C₂, A-X, and B-X systems of CN, B-X system of N₂ ⁺, A-X, and B-A systems of CO ⁺ , A-X system of NH and A–X system of OH.  相似文献   

Radioastronomical observations of comets IRAS-Araki-Alcock (1983d) and Sugano-Saigusa-Fujikawa (1983e)     

W.M. Irvine  Z. Abraham  M. A&#x;Hearn  W. Altenhoff  Ch. Andersson  J. Bally  W. Batrla  A. Baudry  D. Bockelée-Morvan  G. Chin  J. Crovisier  I. de Pater  D. Despois  L. Ekelund  E. Gerard  T. Hasegawa  C. Heiles  J.M. Hollis  A. Wootten 《Icarus》1984,60(1):215-220

Detections and upper limits to the continuum emission (1 ≤ λ ≤6 cm) and spectral line emission (OH, CO, CS, HCN, HCO⁺, CN, CH₃CN, CH₃C₂H, NH₃, H₂O, HC₃N, CH₃CH₂CN) are reported from radio observations of Comets 1983d and 1983e. Comparison is made with observations of CN at optical wavelengths. These results may be useful in planning future cometary observations.  相似文献   

Optical Spectroscopy and Near-Infrared Observations of Comet C/2000 Wm1 (Linear) in December 2001 from Chile and Brazil     

Picazzio  Enos  De Almeida  Amaury A.  Churyumov  Klim I.  Andrievski  Sergei M.  Luk'yanyk  Igor V. 《Earth, Moon, and Planets》2002,90(1-4):391-400

We report on the preliminary analysis of the high-resolution spectrum of CometC/2000 WM1 (LINEAR), obtained on Dec. 1, 2001 with the Fiber fed ExtendedRange Optical Spectrograph (FEROS) installed on the 1.52-m telescope of ESO(Chile). Many emission lines of the molecules C₂, C₃, CN, CH, CH⁺,NH₂, CO, CO⁺, H₂O⁺ and, presumably, C₂ ^- were identifiedin the spectral range 400–900 nm. Also, near-infrared photometry was performed on Dec. 2 and 3, with the infraredcamera (CamIV) attached to the 0.60-m Boller and Chivens telescope of the Picodos Dias Observatory (LNA/MCT), Brazil. We report the preliminary and comparativeanalysis of the I-J and J-H color indices.  相似文献   

Monte Carlo modeling of neutral gas and dust in the coma of Comet 1P/Halley     

Martin Rubin  Valeriy M. Tenishev  Kenneth C. Hansen  Kathrin Altwegg 《Icarus》2011,213(2):655-677

The neutral gas environment of a comet is largely influenced by dissociation of parent molecules created at the surface of the comet and collisions of all the involved species. We compare the results from a kinetic model of the neutral cometary environment with measurements from the Neutral Mass Spectrometer and the Dust Impact Detection System onboard the Giotto spacecraft taken during the fly-by at Comet 1P/Halley in 1986. We also show that our model is in good agreement with contemporaneous measurements obtained by the International Ultraviolet Explorer, sounding rocket experiments, and various ground based observations.The model solves the Boltzmann equation with a Direct Simulation Monte Carlo technique (Tenishev, V., Combi, M., Davidsson, B. [2008]. Astrophys. J. 685, 659-677) by tracking trajectories of gas molecules and dust grains under the influence of the comet’s weak gravity field with momentum exchange among particles modeled in a probabilistic manner. The cometary nucleus is considered to be the source of dust and the parent species (in our model: H₂O, CO, H₂CO, CO₂, CH₃OH, C₂H₆, C₂H₄, C₂H₂, HCN, NH₃, and CH₄) in the coma. Subsequently our model also tracks the corresponding dissociation products (H, H₂, O, OH, C, CH, CH₂, CH₃, N, NH, NH₂, C₂, C₂H, C₂H₅, CN, and HCO) from the comet’s surface all the way out to 10⁶ km.As a result we are able to further constrain cometary the gas production rates of CO (13%), CO₂ (2.5%), and H₂CO (1.5%) relative to water without invoking unknown extended sources.  相似文献   

Radial distribution of production rates, loss rates and densities corresponding to ion masses ?40 amu in the inner coma of Comet Halley: Composition and chemistry     

S.A. Haider 《Icarus》2005,177(1):196-216

In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH₃OH⁺₂, H₃CO⁺, NH⁺₄, H₃S⁺, H₂CN⁺, H₂O⁺, NH⁺₃, CO⁺, C₃H⁺₃, OH⁺, H₃O⁺, CH₃OH⁺, C₃H⁺₄, C₂H⁺₂, C₂H⁺, HCO⁺, S⁺, CH⁺₃, H₂S⁺, O⁺, C⁺, CH⁺₄, C⁺₂, and O⁺₂) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH⁺₄, H₃O⁺, CH₃OH⁺₂, H₃S⁺, H₂CN⁺, and H₂O⁺, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H₃O⁺, CH₃OH⁺₂, H₂O⁺, H₃CO⁺, C₂H⁺₂, and NH⁺₄; along with ions CO⁺, OH⁺, and HCO⁺, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models.  相似文献   

The Gas Production Rate and Coma Structure of Comet C/1995 O1 (Hale–Bopp)     

Morgenthaler  Jeffrey P.  Harris  Walter M.  Roesler  Frederick L.  Scherb  Frank  Anderson  Christopher M.  Doane  Nathaniel E.  Oliversen  Ronald J. 《Earth, Moon, and Planets》2002,90(1-4):77-87

The University of Wisconsin–Madison and NASA–Goddard conducted acomprehensive multi-wavelength observing campaign of coma emissionsfrom comet Hale–Bopp, including OH 3080 Å, [O I] 6300 Å H₂O⁺ 6158 Å, H Balmer-α 6563 Å, NH₂ 6330 Å, [C I] 9850 ÅCN 3879 Å, C₂ 5141 Å, C₃ 4062 Å,C I 1657 Å, and the UV and optical continua. In thiswork, we concentrate on the results of the H₂O daughter studies.Our wide-field OH 3080 Å measured flux agrees with other, similarobservations and the expected value calculated from published waterproduction rates using standard H₂O and OH photochemistry.However, the total [O I] 6300 Å flux determined spectroscopically overa similar field-of-view was a factor of 3-4 higher than expected.Narrow-band [O I] images show this excess came from beyond theH₂O scale length, suggesting either a previously unknown source of[O I] or an error in the standard OH + ν→ O(¹ D) + H branching ratio. The Hale–Bopp OH and[O I] distributions, both of which were imaged tocometocentric distances >1 × 10⁶ km, were more spatiallyextended than those of comet Halley (after correcting for brightnessdifferences), suggesting a higher bulk outflow velocity. Evidence ofthe driving mechanism for this outflow is found in the Hα lineprofile, which was narrower than in comet Halley (though likelybecause of opacity effects, not as narrow as predicted by Monte-Carlomodels). This is consistent with greater collisional coupling betweenthe suprathermal H photodissociation products and Hale–Bopp's densecoma. Presumably because of mass loading of the solar wind by ionsand ions by the neutrals, the measured acceleration of H₂O⁺ downthe ion tail was much smaller than in comet Halley. Tailwardextensions in the azimuthal distributions of OH 3080 Å,[O I], and [C I] , as well as a Doppler asymmetry in the[O I] line profile, suggest ion-neutral coupling. While thetailward extension in the OH can be explained by increased neutralacceleration, the [O I] 6300 Å and [C I] 9850 Å emissions show 13%and >200% excesses in this direction (respectively), suggesting anon-negligible contribution from dissociative recombination of CO⁺and/or electron collisional excitation. Thus, models including theeffects of photo- and collisional chemistry are necessary for the fullinterpretation of these data.  相似文献   

The spectrum of comet C/2009 R1 (McNaught) in 4140–5240 Å wavelength region     

Pavlo Korsun  Irina Kulyk  Sergey Velichko 《Planetary and Space Science》2012,60(1):255-260

The spectroscopic observations of comet C/2009 R1 (McNaught) were carried out with the 2 m Zeiss-RCC Telescope of Pik Terskol Observatory operated by the International Center for Astronomical and Medico-Ecological Research (Ukraine, Russia). The Multi Mode Cassegrain spectrometer was used to obtain spectra of moderate spectral resolving power with a wavelength coverage from 4140 to 5240 Å. The spectrum is characterized by the extremely low continuum level and strong molecular features. 192 emission lines of C₂, CN, CH, NH₂, CO⁺, and CH⁺ have been identified by the comparison of the observed and theoretical spectra of the molecules. The ratios of the gas production rates of Q(C₂)/Q(CN)=1.32, Q(CH)/Q(CN)=0.49, and Q(NH₂)/Q(CN)=0.81 were derived using a Haser model.  相似文献   

New Molecular Species in Comet C/1995 O1 (Hale-Bopp) Observed with the Caltech Ssubmillimeter Observatory     

Lis  D. C.  Mehringer  D. M.  Benford  D.  Gardner  M.  Phillips  T. G.  Bockelée-Morvan  D.  Biver  N.  Colom  P.  Crovisier  J.  Despois  D.  Rauer  H. 《Earth, Moon, and Planets》1997,78(1-3):13-20

We present millimeter-wave observations of HNCO, HC₃N, SO, NH₂CHO, H¹³CN, and H₃O⁺ in comet C/1995 O1 (Hale-Bopp)obtained in February–April, 1997 with the Caltech Submillimeter Observatory (CSO). HNCO, first detected at the CSO in comet C/1996B2 (Hyakutake), is securely confirmed in comet Hale-Bopp via observations of three rotational transitions. The derived abundance with respect to H₂O is (4-13) × 10^-4. HC₃N, SO, and NH₂CHO are detected for the first time in a comet. The fractional abundance of HC₃N based on observations of three rotational lines is (1.9 ± 0.2) × 10^-4. Four transitions of SO are detected and the derived fractional abundance, (2-8) ×10^-3, is higher than the upper limits derived from UV observations of previous comets. Observations of NH₂CHO imply a fractional abundance of (1-8) × 10^-4. H₃O is detected for the first time from the ground. The H¹³CN (3-2)transition is also detected and the derived HCN/H¹³CN abundance ratio is 90 ± 15, consistent with the terrestrial¹²C/¹³C ratio. In addition, a number of other molecular species are detected, including HNC, OCS, HCO⁺, CO⁺, and CN(the last two are first detections in a comet at radio wavelengths). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Ion composition and chemistry in the coma of Comet 1P/Halley—A comparison between Giotto's Ion Mass Spectrometer and our ion-chemical network     

Martin Rubin  Kenneth C. Hansen  Michael R. Combi  Hans Balsiger 《Icarus》2009,199(2):505-519

In order to understand the cometary plasma environment it is important to track the closely linked chemical reactions that dominate ion evolution. We used a coupled MHD ion-chemistry model to analyze previously unpublished Giotto High Intensity Ion Mass Spectrometer (HIS-IMS) data. In this way we study the major species, but we also try to match some minor species like the CH_x and the NH_x groups. Crucial for this match is the model used for the electrons since they are important for ion-electron recombination. To further improve our results we included an enhanced density of supersonic electrons in the ion pile-up region which increases the local electron impact ionization. In this paper we discuss the results for the following important ions: C⁺, CH⁺, CH⁺₂, CH⁺₃, N⁺, NH⁺, NH⁺₂, NH⁺₃, NH⁺₄, O⁺, OH⁺, H₂O⁺, H₃O⁺, CO⁺, HCO⁺, H₃CO⁺, and CH₃OH⁺₂. We also address the inner shock which is very distinctive in our MHD model as well as in the IMS data. It is located just inside the contact surface at approximately 4550 km. Comparisons of the ion bulk flow directions and velocities from our MHD model with the data measured by the HIS-IMS give indication for a solar wind magnetic field direction different from the standard Parker angle at Halley's position. Our ion-chemical network model results are in a good agreement with the experimental data. In order to achieve the presented results we included an additional short lived inner source for the C⁺, CH⁺, and CH⁺₂ ions. Furthermore we performed our simulations with two different production rates to better match the measurements which is an indication for a change and/or an asymmetric pattern (e.g. jets) in the production rate during Giotto's fly-by at Halley's comet.  相似文献   

Representative abundances of a few positive ions in the innermost coma of comet Halley     

P. P. Saxena  Alka Misra 《Earth, Moon, and Planets》1993,60(1):59-68

The production rate of H₂O molecules at a heliocentric distance of 1 AU for comet Halley and the abundance ratio with respect to water (H₂O) of parent molecules at the cometary nucleus from the paper of Yamamoto (1987) have been used to compute the number densities of positive ions viz. H₃O⁺, H₃S⁺, H₂CN⁺, H₃CO⁺, CH₃OH ₂ ⁺ and NH ₄ ⁺ at various cometocentric distances within 600 kms from the nucleus.The role of proton transfer reactions in producing major ionic species is discussed. A major finding of the present investigation is that NH ₄ ⁺ ion which may be produced through proton transfer reactions is the most abundant ion near the nucleus of a comet unless the abundance of NH₃ as a parent is abnormally low. Using the quoted value of Q(NH₃)/Q(H₂O) for comet Halley and the life times of NH₃ and H₂O molecules, the abundance ratio N(NH₃)/N(H₂O) is found to be one-third of that used in the present paper. The consequent proportionate decrease in the NH ₄ ⁺ ions does not, however, affect its superiority in number density over other ions near the nucleus.The number density of the next most abundant ion viz. H₃O⁺ is found to be 4 × 10⁴ cm^-3 at the nucleus of comet Halley and decreases by a factor of two only upto a distance of 600 K ms from the nucleus. The ionic mass peak recorded by VEGA and GIOTTO spacecrafts atm/q = 18 is most probably composite of the minor ionic species H₂O⁺, as its number density = 10² cm^-3 remains virtually constant in the inner coma and of NH ₄ ⁺ , the number density of which at large cometocentric distances may add to the recorded peak atmlq = 18. The number densities of other major ions produced through proton transfer from H₃O⁺ are also discussed in the region within 600 K ms from the nucleus of comet Halley.  相似文献   

Spectral studies of comet C/2001 Q4 (NEAT)     

A. V. Ivanova  P. P. Korsun  S. A. Borisenko  Yu. N. Ivashchenko 《Solar System Research》2013,47(2):71-79

The paper presents the results of the spectral observations of comet C/2001 Q4 (NEAT) acquired with the Zeiss-600 telescope of the Andrushevka astronomical observatory in May 2004. The spectrum of the comet was obtained in the range of 3600–8200 Å. We identified a number of emission features in the spectrum of comet C/2001 Q4 (NEAT). The emission bands of C₂, C₃, CN, CH, NH₂, H₂O⁺ were detected in the spectrum of the comet, and their intensities were determined. The ratios of gas-production rates Q(C₂)/Q(CN) = 0.23, Q(C₃)/Q(CN) = ?0.79, and Q(NH₂)/Q(CN) = ?0.029 were determined with the Haser model.  相似文献   

The chemical evolution in a model of contracting cloud     

M. Y. Amin  M. S. El-Nawawy 《Earth, Moon, and Planets》1996,75(1):25-39

The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm^–3 diffuse initial cloud model to a dense cloud with central density number of n >- 10⁵ cm^–3 after a time of 1.2 × 10⁷ yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C₂H, CN, SO₂, CO₂, H₂O, C₂, NH₃, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies.  相似文献   

Electronic Sputtering Analysis of Astrophysical Ices     

L. S. Farenzena  P. Iza  R. Martinez  F. A. Fernandez-Lima  E. Seperuelo Duarte  G. S. Faraudo  C. R. Ponciano  M. G. P. Homem  A. Naves de Brito  K. Wien  E. F. da Silveira 《Earth, Moon, and Planets》2005,97(3-4):311-329

Experimental results on fast ion collision with icy surfaces having astrophysical interest are presented. ²⁵²Cf fission fragments projectiles were used to induce ejection of ionized material from H₂O, CO₂, CO, NH₃, N₂, O₂ and Ar ices; the secondary ions were identified by time-of-flight mass spectrometry. It is observed that all the bombarded frozen gas targets emit cluster ions which have the structure X_nR^±, where X is the neutral ice molecule and R^± is either an atomic or a molecular ion. The shape of the positive or negative ion mass spectra is characterized by a decreasing yield as the emitted ion mass increases and is generally described by the sum of two exponential functions. The positive ion water ice spectrum is dominated by the series (H₂O)_nH₃O⁺ and the negative ion spectrum by the series (H₂O)_nOH⁻ and (H₂O)_nO⁻. The positive ion CO₂ ice spectrum is characterized by R⁺ = C⁺, O⁺, CO⁺, O₂⁺ or CO₂⁺ and the negative one by R⁻ = CO₃⁻. The dominant series for ammonia ice correspond to R⁺ = NH₄⁺ and to R⁻ = NH₂⁻. The oxygen series are better described by (O₃)_nO_m⁺ secondary ions where m = 1, 2 or 3. Two positive ion series exist for N₂ ice: (N₂)_nN₂⁺ and (N₂)_nN⁺. For argon positive secondary ions, only the (Ar)_nAr⁺ series was observed. Most of the detected molecular ions were formed by one-step reactions. Ice temperature was varied from ∼20 K to complete sublimation.  相似文献   

A Multi-Wavelength Simultaneous Study of the Composition of the Halley Family Comet 8P/Tuttle     

E. Jehin  D. Bockelée-Morvan  N. Dello Russo  J. Manfroid  D. Hutsemékers  H. Kawakita  H. Kobayashi  R. Schulz  A. Smette  J. Stüwe  M. Weiler  C. Arpigny  N. Biver  A. Cochran  J. Crovisier  P. Magain  H. Rauer  H. Sana  R. J. Vervack  H. Weaver  J.-M. Zucconi 《Earth, Moon, and Planets》2009,105(2-4):343-349

We report on simultaneous optical and infrared observations of the Halley Family comet 8P/Tuttle performed with the ESO Very Large Telescope. Such multi-wavelength and coordinated observations are a good example of what can be done to support space missions. From high resolution optical spectroscopy of the CN (0,0) 388 nm and NH₂ (0,9,0) 610 nm bands using UVES at UT2 we determined ¹²C/¹³C = 90 ± 10 and ¹⁴N/¹⁵N = 150 ± 20 in CN and we derived a nuclear spin temperature of NH₃ of 29 ± 1 K. These values are similar to those found in Oort-Cloud and Jupiter Family comets. From low resolution long slit spectroscopy with FORS1 at UT2 we determined the CN, C₃ and C₂ production rates and the parent and daughter scale lengths up to 5.2 10⁵ km tailward. From high resolution IR spectroscopy with CRIRES at UT1 we measured simultaneously the production rates and mixing ratios of H₂O, HCN, C₂H₂, CH₄, C₂H₆, and CH₃OH.  相似文献   

Spectra Of Split Comet C/1999 S4 (Linear)     

Churyumov  K. I.  Luk'yanyk  I. V.  Vlassyuk  V. V.  Borisov  N. V. 《Earth, Moon, and Planets》2002,90(1-4):141-146

We obtained spectra of comet C/1999 S4 (LINEAR) with the UAGS spectrograph(long slit and CCD) installed on the 1-m Zeiss reflector of the SAO of the RAS(Northern Caucuses, Nizhny Arkhyz) on July 23/24, 26/27 and 27/28, 2000. OnJuly 22/23, before the splitting of the cometary nucleus, several emission lines,such as C₂, C₃, CN, NH, CH, NH₂, CO⁺, H₂O⁺ wereclearly identified in the spectra. The inspections of the CCD spectra obtainedon July 27/28, 2000 reveals only very weak emission lines superimposed on thesolar reflection spectrum. From analyzing the surface brightness profile of C₂ along the slit the velocity of separation of two secondary fragments (V = 10 km/h) and the energy of the fragment separation (E = 8.7 × 10¹⁵ erg) were estimated. A luminescence cometary continuum of 26% of the total continuum level is detected in the spectra of the comet at 5000 Å. Possible mechanisms of nucleus splitting are discussed.  相似文献   

Ion chemistry in the cometary atmosphere     

Mikio Shimizu 《Astrophysics and Space Science》1975,36(2):353-361

Dirty ice of a second kind (major components, H₂O, CO, and N₂; minor components less than several percents, NH₃, CH₄, and other organic substances such as HCN, CH₃CN etc.) is assumed for the composition of volatiles in the cometary nucleus. The consistency with the observations of molecular ions and daughter molecules in the cometary atmosphere is argued by taking into account various ion-molecular reactions and dissociative recombinations. There is a satisfactory agreement for the second kind of dirty-ice model, but the presence of large amounts of CH₄ and NH₃ is found to be rather in contradiction with observational evidence. A velocity of 8 km s^?1 for the hydrogen atoms, derived from analysis of the hydrogen Lyman-alpha corona around comets, is found from the dissociative recombination of H₃O⁺, the dominant constituent of cometary ionosphere, in accordance with H₃O⁺+e ^?→OH+H+H.  相似文献   

Charge coupled device (CCD) spectroscopy of comets: Tuttle,Stephan-Oterma,Brooks 2, and Bowell     

J.R. Johnson  U. Fink  S.M. Larson 《Icarus》1984,60(2):351-372

Spectra of the four comets, Tuttle, Stephan-Oterma, Brooks 2, and Bowell, were taken with a prototype space telescope charge coupled device (CCD) camera using a 500 × 500 Texas Instruments chip. The spectra extended from 5600 to 10,400 Å at a resolution of $\text{～25}\text{A}\text{?}$. The spatial coverage along the slit was 180^?; its resolution was defined by the seeing ($\text{2–3}{}^{\mathrm{?}}$). Both absolute flux scales and spectral albedos were determined with the data reduction procedure which included flat fielding and sky subtraction. Comet Tuttle displayed extensive emissions by NH₂, the red system of CN, and the C₂ Swan bands as well as emissions by the forbidden oxygen lines [OI] ¹D at 6300 and 6364 Å, and the ionic species H₂O⁺. A feature at 6851 Å has been tentatively identified as the 3-0 band of CS⁺. Notable is the absence of the C₂ Phillips bands whose transitions are optimally placed in our spectrum. The much dustier comet, Stephan-Oterma showed emissions by CN, NH₂, and [OI] while only [OI] could be discerned in the noisier Brooks 2 spectrum. The fresh comet Bowell exhibited an unusually extended coma with an albedo times cross section two orders of magnitude larger than the other comets, a very flat albedo spectrum, and no emission features. For Tuttle and Stephan-Oterma, CN and NH₂ column densities using a number of bands were calculated. The CN band intensity ratios show good agreement with theoretical fluorescence models. The spatial profiles for CN and NH₂ were compared to two step Haser model decay calculations. The scale lengths most consistent with the data were compared with values previously reported and with values expected for various photodissociation reactions. Production rates were calculated for CN and NH₂. These should be less model dependent because of the simultaneous collection of spectral and spatial information. The production rate ratios of the parents of CN and NH₂ to the parent of OH are several orders of magnitude smaller than the solar abundance ratios of C/O and N/O.  相似文献   

Molecule searches in Comet Kohoutek (1973f) at microwave frequencies     

S.A. Mango  K.J. Johnston  M.F. Chui  A.C. Cheung  D. Matsakis 《Icarus》1974,23(4):590-594

Nine transitions of the possible parent molecules H₂O, NH₃, CH₃OH and N₂O as well as the OH radical were searched for in Comet Kohoutek (1973f) in the frequency range 22.2–25.2 GHz. These molecules were not detected, but the upper limits for the optical depth, mean column density and the production rate are derived for each of the molecules. These results are discussed and compared with the reported detections of HCN and CH₃CN emission and OH absorption.  相似文献   

Optical Spectroscopy of Comet C/2000 WM1 (LINEAR) at the Guillermo Harro Astrophysical Observatory in Mexico     

Churyumov  Klim I.  Luk'yanyk  Igor V.  Berezhnoi  Alexei A.  Chavushyan  Vahram H.  Sandoval  Lourdes S.  Palma  Alejandro A. 《Earth, Moon, and Planets》2002,90(1-4):361-368

We present a preliminary analysis of medium resolution optical spectra of comet C/2000 WM1 (LINEAR) obtained on 22 November 2001. Theemission lines of the molecules C₂, C₃, CN, NH₂,H₂O⁺ and presumably CO (Asundi and triplet bands) and C₂ ^-were identified in these spectra. By analysing the brightnessdistributions of the C₂, C₃, CN emission lines along theslit of the spectrograph we determined some physical parameters of theseneutrals, such as their lifetimes and expansion velocities inthe coma. The Franck–Condon factors for the CO Asundi bands and C₂ ^- bands were calculated using a Morse potential model.  相似文献   

Chemical diagnostics of magnetized boundary layers     

L. A. M. Nejad  T. W. Hartquist 《Astrophysics and Space Science》1994,220(2):253-260

  相似文献