共查询到20条相似文献，搜索用时 46 毫秒
1.
— Pressure-induced variations in pore geometry were studied on dry- and fluid- saturated samples by means of electrical impedance spectroscopy and permeability measurements. Hydrostatic pressures (up to 120 MPa) and uniaxial pressures (up to failure) were applied. Hydrostatic pressures reduce the aspect ratio of cracks and thus cause a decrease of permeability and electrical bulk conductivity. The opposite was observed in uniaxial pressure experiments where new cracks were formed and consequently permeability and electrical conductivity were increased. More specific informations of these generated observations were derived from the interpretation of the frequency dispersion of the complex electrical conductivity. This least-squares-refinement considers electrochemical interactions between the fluid pore electrolyte and the inner surface of the sample, thus providing informations on the pore geometry and pressure-induced variations. Consequently changes in aspect ratio, size and geometry of the pore system can be detected by means of impedance spectroscopy. 相似文献
2.
The complex resistivity of synthetic samples has been measured over the frequency range 0.01 Hz to 1.0 MHz. The synthetic samples were made of a quartz matrix and sulphide particles. Grain sizes, volume fractions, and sulphide particles of different nature were used. The samples were saturated to different degrees, with different types of electrolyte. The results obtained were used to check the validity of the theoretical electrochemical model developed by Wong (1979). This model fits the experimental data reasonably well in the frequency range where the dispersion and the phase maxima occur. Against the model expectations, the experiment did not duplicate the Debye-form of spectra because most of the common metals are oxidized to the ionic form and an electrochemical charge transfer reaction occurs at the interface. The model prediction regarding the effect of the distribution of the grain radii on the complex resistivity could not be duplicated experimentally. 相似文献
3.
Shukra Raj Paudel Sushant Prasad Banjara Amrita Wagle Friedemann T. Freund 《Journal of Seismology》2018,22(5):1293-1314
We review changes in groundwater chemistry as precursory signs for earthquakes. In particular, we discuss pH, total dissolved solids (TDS), electrical conductivity, and dissolved gases in relation to their significance for earthquake prediction or forecasting. These parameters are widely believed to vary in response to seismic and pre-seismic activity. However, the same parameters also vary in response to non-seismic processes. The inability to reliably distinguish between changes caused by seismic or pre-seismic activities from changes caused by non-seismic activities has impeded progress in earthquake science. Short-term earthquake prediction is unlikely to be achieved, however, by pH, TDS, electrical conductivity, and dissolved gas measurements alone. On the other hand, the production of free hydroxyl radicals (?OH), subsequent reactions such as formation of H2O2 and oxidation of As(III) to As(V) in groundwater, have distinctive precursory characteristics. This study deviates from the prevailing mechanical mantra. It addresses earthquake-related non-seismic mechanisms, but focused on the stress-induced electrification of rocks, the generation of positive hole charge carriers and their long-distance propagation through the rock column, plus on electrochemical processes at the rock-water interface. 相似文献
4.
Some numerical results for the apparent resistivity of a homogeneous half space containing a vertical steel well casing as measured by a dipole-dipole array are presented. The basic model includes the electromagnetic and induced polarization effects by allowing for frequency dependent eddy currents and an electrochemical boundary of the well casing. It is shown that the well casing produces an apparent complex resistivity response that could be mistaken for an induced polarization anomaly existing above a hydrocarbon deposit. This response of the well casing is strongly dependent on frequency. 相似文献
5.
Transport properties (permeability and electrical conductivity) have been measured at different hydrostatic pressure runs on 7 crystalline rocks (gneisses and amphibolites) sampled from the KTB drilling project. The decrease of permeability by pressure are compared with the pressure-dependent data of the electrical conductivity (formation factor) resulting from complex impedance measurements. According to the equivalent-channel model (ECM), there exists a linear relationship between these parameters by representing both properties on logarithmic scales. The results show that it is possible to extrapolate high-pressure permeability from low-pressure (< 60 MPa) permeability data by using the pressure-dependent electrical conductivity (up to 300 MPa). 相似文献
6.
The basic formulation for the mutual coupling between grounded circuits in the presence of a vertical conductor is used to examine the full electromagnetic and induced polarization response for a homogeneous half-space model. Both interfacial polarization at the steel/electrolyte boundary and induced eddy currents in the casing are accounted for in the analysis. It is shown that for mild steel casings the eddy currents, hitherto neglected, play an important role because of their strong frequency dependence. Calculated curves of the appar- ent complex resistivity as a function of frequency show that the overall response can be influenced by the state of corrosion at the surface of the casing. 相似文献
7.
Abstract Time-domain reflectometry (TDR) is an electromagnetic technique for measurements of water and solute transport in soils. The relationship between the TDR-measured dielectric constant (Ka ) and bulk soil electrical conductivity ([sgrave]a) to water content (θW) and solute concentration is difficult to describe physically due to the complex dielectric response of wet soil. This has led to the development of mostly empirical calibration models. In the present study, artificial neural networks (ANNs) are utilized for calculations of θw and soil solution electrical conductivity ([sgrave]w) from TDR-measured Ka and [sgrave]a in sand. The ANN model performance is compared to other existing models. The results show that the ANN performs consistently better than all other models, suggesting the suitability of ANNs for accurate TDR calibrations. 相似文献
8.
Manukonda Suresh Kumar Ashitha Gopinath Nenthramkunnath Ranjith Safar Ummar Puthiya Veetil Nidheesh 《洁净——土壤、空气、水》2023,51(3):2100169
The integrated steel industry is considered as one of the important industrial sectors, and its outputs are inputs for other sectors including construction, engineering, medical and scientific equipment, and defence. Massive production, consumption, and export of steel signify a country's economic index. This review outlines the World's steel production quantities, the processes involved, and wastewater generation from the industry and its treatment. Wastewater generated from steel plants is highly complex and requires intensive treatment before discharge into natural water bodies. Technologies adopted for treating wastewater generated from steel industries are deliberated, focusing on coking wastewater treatment. Microbial mediated processes provide an effective means of degrading the contaminants, but the toxicity of certain compounds during higher pollutant load inhibits its further treatment. However, these processes can be integrated with either electrochemical technologies or advanced oxidation processes (AOPs), which can reduce the toxicity level. Hence, when a highly concentrated and complex mixture of contaminants is considered, an integrated approach is a resourceful option in terms of cost-effectiveness and treatment efficiency. 相似文献
9.
The dynamic response characterizing the induced-polarization (IP) phenomenon is modelled by a non-linear diffusion equation (Burger's equation) supplemented by relevant initial and boundary values. The analysis of the model yields a voltage step response and an impedance curve in the frequency domain which agree qualitatively with experimental measurements. Curve fits based on the model have been made in the case of electrochemical cell measurements. The diffusion coefficients estimated by means of these curves are of the same order of magnitude as those calculated using experimental measurements. The normalized transient with these diffusion coefficients agrees with observations, but probably has a shorter discharge time. We have also carried out a comparison with predictions obtained from a linear, finite diffusion layer model, thus showing that for most practical situations the nonlinear term modelling the migration effect can be neglected. 相似文献
10.
基于非结构网格有限元方法开展了三维复杂地电模型的线源井地电法的高效正演模拟研究,探讨了通过求取电场响应导数来刻画目标体边界范围、采用差异场地形校正技术来消除地形影响等措施对井地电法成像的效果和精度的影响。并通过对比与解析解,验证了本文数值解算法的有效性。模型计算结果表明：积水巷道的空间位置和走向均会引起视电阻率的显著变化,视电阻率变化率的极值准确且清晰地指示了巷道边界的位置;电位的归一化总水平导数极大地提高了井地电法对目标体复杂边界位置的识别能力;地形对井地电场分布的影响也很大,其视电阻率响应与地形形状近似呈对称关系,利用差异场技术能有效地削弱地形对井地电法高精度成像的影响。 相似文献
11.
P. W. J. Glover J. B. Gomez P. G. Meredith S. A. Boon P. R. Sammonds S. A. F. Murrell 《Surveys in Geophysics》1996,17(3):307-330
Measurement of complex electrical conductivity as a function of frequency is an extremely sensitive probe for changes in pore and crack volume, crack connectivity, and crack surface topography. Such measurements have been made as a function of pore fluid chemistry, hydrostatic confining pressure, as well as uniaxial and triaxial deformation. This paper will; (1) describe the effects of triaxial deformation on the complex electrical conductivity of saturated porous rocks, (2) use the electrical data to model the mechanical stress-strain behaviour, and (3) compare the modelled behaviour with the stress-strain behaviour measured during the deformation. Experimental conductivity data tracks how the rock undergoes compaction with progressive loss of crack volume, followed by dilatation due to new crack formation, growth of existing cracks, crack interlinkage, and finally failure, as axial strain is increased. We have used the complex electrical data to produce a direction-sensitive (anisotropic) crack damage parameter, and used it to calculate the effective Young's modulus by employing the models of Walsh and Bruner. Comparison of the synthetic stress-strain curves so produced, with the experimentally derived stress-strain curves shows good agreement, particularly for undrained tests. This modelling is an improvement on similar curves produced using isotropic crack damage parameters derived from acoustic emission data. The improvement is likely to be due to the directional sensitivity of the electrical conductivity measurement, and its ability to discriminate between the formation of isolated cracks, and those cracks that contribute to the inter-connected crack space i.e. those cracks upon which transport properties of the rock such as electrical conductivity, and mechanical properties depend most critically during triaxial deformation. 相似文献
12.
The combination of magnetotelluric survey and laboratory measurements of electrical conductivity is a powerful approach for exploring the conditions of Earth’s deep interior. Electrical conductivity of hydrous silicate melts and aqueous fluids is sensitive to composition, temperature, and pressure, making it useful for understanding partial melting and fluid activity at great depths. This study presents a review on the experimental studies of electrical conductivity of silicate melts and aqueous fluids, and introduces some important applications of experimental results. For silicate melts, electrical conductivity increases with increasing temperature but decreases with pressure. With a similar Na+ concentration, along the calc-alkaline series electrical conductivity generally increases from basaltic to rhyolitic melt, accompanied by a decreasing activation enthalpy. Electrical conductivity of silicate melts is strongly enhanced with the incorporation of water due to promoted cation mobility. For aqueous fluids, research is focused on dilute electrolyte solutions. Electrical conductivity typically first increases and then decreases with increasing temperature, and increases with pressure before approaching a plateau value. The dissociation constant of electrolyte can be derived from conductivity data. To develop generally applicable quantitative models of electrical conductivity of melt/fluid addressing the dependences on temperature, pressure, and composition, it requires more electrical conductivity measurements of representative systems to be implemented in an extensive P-T range using up-to-date methods. 相似文献
13.
Mohamed Mahmoud Gomaa 《Geophysical Prospecting》2009,57(6):1091-1100
This paper is devoted to study the effect of saturation, with distilled water, on AC electrical conductivity and dielectric constant of a fully and partially saturated hematitic sandstone sample (Aswan area, Egypt). The saturation of the sample was changed from full saturation to partial saturation by air drying. Complex resistivity measurements at room temperature (∼16° C) were performed in the frequency range from 10 Hz to 100 kHz. We used non-polarizing Cu/CuSO4 gel electrodes. Experimental electrical spectra indicate, generally, that the electrical conductivity and dielectric constant vary strongly with water saturation and frequency. The low-frequency electrical conductivity and dielectric constant are supposed to be mainly controlled by surface conduction and polarization of the electrical double layer. Power law behaviours with frequency were noticed. The change in electrical conductivity and dielectric constant with increasing water content is fast at low saturations and slow at high saturations. The behaviour of the electrical conductivity and dielectric constant, with increasing water content, was argued to be the orientational polarization of bound water for very low saturations, displacement of the excess surface charges for relatively low saturations and free exchange of excess ions in double layer with the bulk electrolyte and generation of transient diffusional potentials, which lag behind the applied field for high saturations in addition to membrane polarization on clay and at inter-grain and grain surface water throats having selective charge transport properties. Also, from the data a semi-percolation behaviour was found that has a peak of dielectric constant at a certain concentration and an abrupt change in conductivity at another saturation. 相似文献
14.
Burke J. Minsley Jonathan Ajo‐Franklin Amitabha Mukhopadhyay Frank Dale Morgan 《Ground water》2011,49(2):250-269
Hydrogeophysical methods are presented that support the siting and monitoring of aquifer storage and recovery (ASR) systems. These methods are presented as numerical simulations in the context of a proposed ASR experiment in Kuwait, although the techniques are applicable to numerous ASR projects. Bulk geophysical properties are calculated directly from ASR flow and solute transport simulations using standard petrophysical relationships and are used to simulate the dynamic geophysical response to ASR. This strategy provides a quantitative framework for determining site‐specific geophysical methods and data acquisition geometries that can provide the most useful information about the ASR implementation. An axisymmetric, coupled fluid flow and solute transport model simulates injection, storage, and withdrawal of fresh water (salinity ～500 ppm) into the Dammam aquifer, a tertiary carbonate formation with native salinity approximately 6000 ppm. Sensitivity of the flow simulations to the correlation length of aquifer heterogeneity, aquifer dispersivity, and hydraulic permeability of the confining layer are investigated. The geophysical response using electrical resistivity, time‐domain electromagnetic (TEM), and seismic methods is computed at regular intervals during the ASR simulation to investigate the sensitivity of these different techniques to changes in subsurface properties. For the electrical and electromagnetic methods, fluid electric conductivity is derived from the modeled salinity and is combined with an assumed porosity model to compute a bulk electrical resistivity structure. The seismic response is computed from the porosity model and changes in effective stress due to fluid pressure variations during injection/recovery, while changes in fluid properties are introduced through Gassmann fluid substitution. 相似文献
15.
D. A. Lockner J. D. Byerlee V. S. Kuksenko A. V. Ponomarev 《Pure and Applied Geophysics》1986,124(3):601-608
Measurements of charge separation in rock during stable and unstable deformation give unexpectedly large decay times of 50 sec. Time-domain induced polarization experiments on wet and dry rocks give similar decay times and suggest that the same decay mechanisms operate in the induced polarization response as in the relaxation of charge generated by mechanical deformation. These large decay times are attributed to electrochemical processes in the rocks, and they require low-frequency relative permittivity to be very large, in excess of 105. One consequence of large permittivity, and therefore long decay times, is that a significant portion of any electrical charge generated during an earthquake can persist for tens or hundreds of seconds. As a result, electrical disturbances associated with earthquakes should be observable for these lengths of time rather than for the milliseconds previously suggested. 相似文献
16.
17.
Spectral induced polarization as well as complex electrical measurements are used to estimate, on a non-invasive basis, hydraulic permeability in aquifers. Basic laboratory measurements on a variety of shaly sands, silts and clays showed that the main feature of their conductivity spectra in the frequency range from 10-3 to 103 Hertz is a nearly constant phase angle. Thus, a constant-phase-angle model of electrical conductivity is applied to interpret quantitatively surface and borehole spectral induced polarization measurements. The model allows for the calculation of two independent electrical parameters from only one frequency scan and a simple separation of electrical volume and interface effects. The proposed interpretation algorithm yields the true formation factor, the cation exchange capacity and the surface-area-to-porosity ratio, which corresponds to the inverse hydraulic radius. Using a Kozeny–Carman-like equation, the estimation of hydraulic permeability is possible. 相似文献
18.
Results from a laboratory investigation into the electrical properties of fully and partially saturated Wildmoor Triassic Sandstone have been modelled using the Archie, Waxman–Smits and Hanai–Bruggeman equations. The results demonstrate the limitation of using simple relationships to describe samples when the matrix resistivity ρr is not significantly greater than the saturating electrolyte resistivity ρw. In these situations Archie's parameters m and n are not accurately determined. Conversely, the more sophisticated Waxman–Smits and Hanai–Bruggeman models provide parameters that better describe the electrical properties of the rock and are able to identify heterogeneity between samples that would otherwise be missed. The ranges of values for matrix resistivity (49 < ρr < 161 Ωm) and cementation factor (1.6 < m < 2.1) obtained from the Hanai–Bruggeman model indicate significant variation between samples. Comparison of laboratory‐determined values for cation exchange capacity (0.06 < Qv < 0.51 meq/mL) and those obtained from the Waxman–Smits model (0.09 < Qv < 0.55 meq/mL) indicates a very strong correlation, suggesting this model is appropriate for describing the rock. There is good agreement between parameters modelled using fully and partially saturated versions of both the Hanai–Bruggeman and Waxman–Smits equations, indicating that the data are consistent with these models and that the assumptions made are appropriate. 相似文献
19.
The frequency dependence of complex electrical conductivity in the IP frequency range (10–3 to 103 Hertz) has been investigated for a variety of microcracked rocks from the German continental deep drilling project (KTB), Northern Bavaria. The laboratory measurements were made with a computer controlled four-electrode system on plugs saturated with brine of different salinity. It has been found that the complex nature of the conductivity is caused solely by the capacitive behaviour of the interlayer region between the solid matrix and the electrolytic pore solution. The resulting main feature of the conductivity spectra is a constant phase angle over the investigated frequency range combined with a nearly identical power law frequency dependence of the real as well as the imaginary parts. The low-frequency exponent is in the order of about 0 to 0.05. It is related to common IP-parameters. The relationships between the frequency exponent and microcrack properties are of special interest. The results of the study show that the frequency exponent is (1) proportional to the surface area to porosity ratio, (2) inversely proportional to water salinity, and (3) dependent on water composition. Complex conductivity measurements allow an uncomplicated separation of electrical volume and interface effects. Moreover, the results suggest that determination of specific surface area of microcracked rocks directly from complex electrical measurements can be made. 相似文献
20.
Poddar 《Geophysical Prospecting》1999,47(6):945-958
Long-offset transient electromagnetics (LOTEM) is now regarded as a suitable electrical method for deep exploration along with magnetotellurics (MT). In this method, the vertical magnetic-field impulse response and, occasionally, the horizontal electric-field step response of a grounded-wire source on the surface of the earth are measured. Here, these two responses are computed for 3D models of three deep resistivity structures of interest in hydrocarbon exploration: (i) a faulted graben in a resistive basement rock at a depth of 4 km beneath a conductive overburden; (ii) a facies change in a resistive layer buried at a depth of 2 km in the conductive overburden above a resistive basement; and (iii) an anticlinal uplift of a resistive layer at a depth of 1 km in the conductive overburden above a resistive basement. The results show that the sensitivity of the electric-field response to model perturbation is generally greater than that of the magnetic-voltage response. Further, the electric-field sensitivity is confined to early and intermediate times while that of the magnetic-voltage response is confined to intermediate and late times. Hence it is recommended that both electric and magnetic recordings are made in a LOTEM survey so that the final results can be presented as apparent-resistivity curves derived from the two responses jointly as well as separately. 相似文献