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万觉成 《华东地质学院学报》1988,(1)
631矿床赋存在多期多阶段的花岗质杂岩体中,位于混合花岗岩与中粗粒斑状黑云母花岗岩的接触带上。矿体产在以钠质为主的碱交代岩体中,产状与碱交代岩相一致。631矿床的主要矿化类型是碱交代型,其矿石中的主要工业铀矿物为变生锆石。经电子探针分析,变生锆石中,铀含量为2.1％,锆为28.8％,而锆铀的分布与变生锆石的分布是一致的。 相似文献
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锆石是岩石中常见的副矿物,锆石晶体结构和地球化学特征的变化可以记录热液蚀变过程。东秦岭东段白草垛花岗伟晶岩中识别出三种类型锆石。类型一锆石具有明显的振荡环带,部分锆石边部有少量裂隙,微量元素含量相对较低,重稀土元素(HREE)富集,具明显Ce的正异常和Eu的负异常,指示其为岩浆锆石。类型二锆石具核-幔-边结构,边部裂隙发育,核部与类型一锆石具有相似的CL和微量元素特征,为岩浆锆石;幔部呈深色海绵状,内部结构不均匀,偶见环带锆石残留,微量元素含量较高,具有较高的U和Th含量,Ce异常不明显,具热液锆石特征,为热液沿着裂隙进入锆石内部不完全热液改造的结果。类型三锆石的结构特征和微量元素含量与类型二锆石的幔部相似,具有异常高U和Th含量以及较高的Dα值,为类型二锆石近完全热液改造的结果。花岗伟晶岩作为岩浆演化晚期的产物,经过结晶分异,残留的岩浆热液富集微量元素,岩浆热液沿着锆石的裂隙进入晶体内部对锆石经过不同程度热液改造,形成了花岗伟晶岩中不同类型的锆石。 相似文献
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小灶火软玉矿床位于东昆仑造山带西段,同新疆和田玉处于昆仑山脉同一条成矿带上。该矿床软玉种类主要为青玉,其中透闪石含量达99%以上,为特殊的镁矽卡岩矿床。对该矿区青玉及其相关的黑云二长花岗岩进行了系统的LA-MC-ICP-MS锆石微量元素、U-Pb及Lu-Hf同位素研究。结果显示,黑云二长花岗岩中均为具典型韵律振荡环带的岩浆成因锆石,锆石U-Pb定年得到其成岩年龄为415.8±1.7 Ma;锆石ε_(Hf)(t)值为1.5~6.6,亏损地幔Hf模式年龄(tDM)为779~965 Ma,指示黑云二长花岗岩为东昆仑原特提斯造山带后碰撞阶段新生的新元古代地壳物质熔融的产物。青玉中的锆石可分为两类,其中主要锆石群——I类锆石呈补丁状环带、面状环带或无环带,且具有与黑云二长花岗岩中的岩浆锆石明显不同的稀土元素及Hf同位素特征,显示典型的热液锆石特点,其U-Pb年龄416.4±1.5 Ma代表了青玉的形成时间;II类锆石(416 Ma、471 Ma、818 Ma)呈韵律振荡环带,为热液流体从围岩中捕获的继承锆石。小灶火地区成岩-成矿作用的同时性(~416 Ma)表明岩浆岩侵入是软玉矿床形成的岩浆岩条件,软玉成矿作用方式为热液交代和充填作用。值得注意的是,用热液锆石的Hf同位素来示踪软玉成矿流体性质时应十分谨慎,因为成矿热液中的Hf元素在同时结晶的两种不同矿物(热液锆石和透闪石)间发生了重新分配。 相似文献
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湖北铜绿山铜铁矿床中煌斑岩的矿物学特征及岩石成因初探 总被引：2，自引：1，他引：1
湖北铜绿山矽卡岩型铜铁矿床处于长江中下游铁铜成矿带西部的鄂东南矿集区。最近我们在该矿区工作中采集到两条侵入于含矿石英二长闪长玢岩中的煌斑岩脉。本文对这些煌斑岩脉进行了详细的镜下岩相学观察,并对其中造岩矿物黑云母、辉石和长石进行了电子探针成分分析。根据这些数据本文论述了煌斑岩的物源、形成环境以及岩浆体系的物理化学条件。研究表明,煌斑岩中云母为富镁黑云母,其形成的岩浆体系处于中低氧逸度(近Ni-Ni O);黑云母与全岩都具有高钛特征,表明煌斑岩的物源深度可能来自较深部地幔(如软流圈)。煌斑岩中辉石为单斜辉石,环带较为发育,有韵律环带和正环带,其韵律环带的形成可能是由于岩浆温压环境存在振荡性变化而形成的。铜绿山矿床中煌斑岩属于云煌岩;其岩浆来源具幔源性,受到地壳的混染作用不强。 相似文献
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糜棱岩化-绢云母化对东秦岭方城正长岩中锆石U-Pb体系的影响 总被引：2，自引：0，他引：2
方城碱性正长岩岩体产于秦岭造山带东段北秦岭构造域,侵位于新元古界栾川群黑云母、绢云母石英片岩中,主要由霓辉正长岩、霓霞正长岩、黑云母正长岩和角闪霞石正长岩组成。具有轻微绢云母化的霓辉正长岩中的锆石为无色透明的短柱状晶体,其阴极发光图像显示清晰的振荡韵律环带,锆石的LA-ICPMS分析表明岩体形成于新元古代,^ 206 Pb／^238 U加权平均年龄为（844．3±1．6）Ma（MSWD=0．86）。而靠近断裂带的糜棱岩化和强烈绢云母化霓辉正长岩中的锆石则为淡黄-黄褐色半透明颗粒,其阴极发光和背散射电子图像显示其裂隙非常发育,有时为钾长石穿插呈海绵状,仅个别颗粒的局部区域仍可见残留的岩浆锆石的环带结构。LA-ICPMS分析结果表明,交代蚀变所形成的热液锆石的Pb、U、Th含量显著增高,而且成分极不均一,含量变化范围很大,U、Th含量分别在32-1550μg／g和188—4059μg／g之间。锆石Th／U比值具有很大的变化范围,Th／U=0．7—44．9。热液锆石。^ 206 Pb／^238 U表面年龄与其U、放射成因Pb及普通Pb含量成反比。由于岩浆锆石U、Th含量较低,其α衰变放射性剂量较小（Dα=3．65×10^14-2．04×10^15／mg）,因此扩散作用所引起的放射成因铅的活动性可忽略不计,所以糜棱岩化、绢云母化霓辉正长岩中锆石U—Pb体系的扰动应是糜棱岩化对锆石晶体结构的损伤和强烈热液交代的结果。由于热液锆石的形成经历了溶解-再沉积等复杂的过程,其U-Pb年龄（不一致线下交点年龄）的地质意义并不明确。 相似文献
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R. T. Pidgeon A. A. Nemchin G. J. Hitchen 《Contributions to Mineralogy and Petrology》1998,132(3):288-299
Internal structures in zircons from granitoids from the late Archaean Darling Range Batholith show secondary features revealed
by HF etching, which record reconstitution of the zircons and modification of the distribution of trace elements during post
crystallisation cooling of the granitoid. Zircons from the granites commonly contain unzoned to weakly zoned cores surrounded
by rims showing oscillatory zoning which has been modified by recrystallisation. The most striking feature is the development
of high trace element concentration areas found in zircons from a number of granites. These structures range from enhanced
trace element concentrations in primary zones to a single accumulation of most trace elements in one band, about half way
between the outer edge and the centre of the zircon. In any zircon the extent of the concentration of trace elements towards
the formation of a single trace element band appears to be inversely related to the fading and broadening of primary oscillatory
zones in the outer rim. This suggests that the trace element bands formed by migration of trace elements from the outer primary
zones to new concentration sites on an inner set of primary zones. This explanation is supported by the formation of multiple
curved trace element bands that transgress primary zoning and the determination of younger SHRIMP ages on depleted zircon
outer rims compared to remnant primary oscillatory zoned areas of the zircon and unzoned centres. Also observed in some granite
zircons is a finely convoluted zoning which overprints oscillatory zoning in parts of a zoned zircon and in rare cases occurs
throughout the zircon. This structure is explained in terms of secondary migration and reconcentration of trace elements in
curved bands. All structures can be transgressed by generally rounded lobes and patches of low U, weakly nebulously zoned
zircon. This is interpreted as a late stage interaction between the zircon and fluids formed during cooling and crystallisation
of the granitoid, resulting in recrystallisation of affected parts of the zircon with accompanying loss of trace elements
from the zircon.
Received: 6 January 1998 / Accepted: 8 May 1998 相似文献
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Recrystallisation of oscillatory zoned zircon: some geochronological and petrological implications 总被引：17，自引：0，他引：17
R. T. Pidgeon 《Contributions to Mineralogy and Petrology》1992,110(4):463-472
Oscillatory zoning is a common feature in zircons from acid igneous rocks and is believed to form during crystallisation of zircons from a magma by a mechanism which is not yet understood. Many zircons with oscillatory zoning also show a patchwork replacement of zoned by unzoned zircon. The unzoned zircon occurs as rounded, transgressive patches distributed throughout the zoned zircon and as areas of transitional replacement where zoned zircon is progressively replaced by unzoned zircon such that only faint traces of original zones remain. This structure is interpreted as a progressive recrystallisation of the oscillatory zoned zircon made unstable by the incorporation of high concentrations of contaminant elements during magmatic crystallisation. Recrystallisation overprints oscillatory zones and appears to have occurred after completion of primary crystallisation. It is accompanied by loss of U, Th and Pb and the removal of oscillatory zones. The recrystallised unzoned zircon is extremely stable with respect to later Pb loss and tends to retain a concordant or slightly discordant U–Pb age. Recrystallisation provides a mechanism for resetting zircon U–Pb ages which is independent of the degree of radiation damage of the zircon lattice. This differs from other models of discordance which involve a leaching of radiogenic Pb as a consequence of a progressive breakdown of the zircon structure through time-integraded radiation damage further enhanced by high concentrations of trace-element contaminants. The U–Pb age of the unzoned zircon may date the recrystallisation event, which may be close to the age of primary crystallisation or reflect a later metamorphism.Dedicated to Borwin Grauert on the occasion of his sixtieth birthday 相似文献
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Grain-scale variations in trace element composition of fluid-altered zircon,Acasta Gneiss Complex,northwestern Canada 总被引：10，自引：0，他引：10
SEM back-scattered electron images of zircon separates from a 2.9 Ga granitic dyke from the Acasta Gneiss Complex, Slave Province, reveal primary igneous oscillatory zoning which is transgressively overprinted by irregular alteration domains. Electron microprobe analyses show that altered zircon domains are depleted in Zr and Si relative to unaltered zircon while retaining a constant Zr/Si ratio. SIMS trace element analyses indicate that LREE are preferentially enriched in the altered domains. Altered zircon contains elevated concentrations of Ba (up to 580 ppm), Ca (up to 2% weight of the element) and common Pb (>50 ppb). The presence of LREE, Ca, Ba and common Pb in the zircons is interpreted to be the result of secondary alteration by an aqueous fluid, and not by primary incorporation during crystallization. We propose that the alteration-related elements are located in amorphous zircon domains. 相似文献
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聂荣微陆块花岗片麻岩锆石LA-ICP-MS U-Pb定年——新元古代基底岩石的发现及其意义 总被引：5，自引：3，他引：2
聂荣微陆块呈透镜体状夹持在班公湖-怒江板块缝合带内,其上出露有黑云母花岗片麻岩以及二长花岗片麻岩等不同类型的古老片麻岩,本文报道产出于聂荣微陆块上花岗片麻岩的锆石LA-ICP-MS U-Pb定年结果,样品锆石的岩浆震荡环带十分发育,多数锆石具有典型的岩浆结晶锆石的特征。所有测点中有16个测点的Th/U值较高,介于0.58~1.24之间,平均值为0.79,获得的206Pb/238U年龄基本一致,加权平均值为819.6±5.2Ma,笔者等认为该年龄代表了花岗片麻岩的原岩结晶时代为新元古代。我们在羌塘南部地区的碎屑岩中获得了同样的年龄峰值(809Ma)。此外,我们认为年龄中具有507Ma左右的信息反映了泛非事件之后另外一次强烈构造热事件的影响在该区的存在。 相似文献
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The Xihuashan and Tieshanlong tungsten deposit is an important large quartz vein‐type W‐polymetallic deposit in the southern Jiangxi Province, eastern Nanling Range. Zircon U–Pb analyses of representative ore‐forming granites from the Xihuashan and Tieshanlong tungsten deposit yield ages of 146.3 ± 2.9 Ma and 146.0 ± 3.8 Ma, respectively. According to the zircon Raman spectroscopy, these granitic rocks are disturbed by different degrees of hydrothermal alteration, whereas most zircons exhibit primary oscillatory zoning and Th/U ratios in the range of magmatic zircon, which means the analysis results represent the crystallization age of metallogenetic granitic assemblages. In combination with regional geological data, it is suggested that the Late Jurassic is probably another important episode of granitic magmatism and W‐Sn mineralization in southern Jiangxi Provinces, even South China. 相似文献
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席家坝花岗片麻岩、斜长角闪岩和金盆村花岗片麻岩出露于扬子西北缘汉南岩体的东北部。这些侵入体中的锆石具有较高Th/U比值,且在阴极发光图像中显示清晰的岩浆振荡环带,具有典型的岩浆成因锆石特征。我们对这3个侵入体分别开展了LA-ICP-MS锆石U-Pb定年工作,结果显示其形成于846±3 Ma、800±3 Ma和815±3 Ma,对应的εHf（t）为-25～-13、-1～+12、+6～+10。席家坝花岗片麻岩的二阶段模式年龄TDM2为3.43～2.56 Ga、席家坝斜长角闪岩的一阶段模式年龄TDM1为1.41～0.88 Ga、金盆村花岗片麻岩的二阶段模式年龄TDM2为1.31～1.11 Ga。席家坝斜长角闪岩和金盆村花岗片麻岩亏损的Hf同位素组成显示,汉南地区在新元古代经历了一期重要的地壳生长事件。锆石的Ti温度计算出这些花岗片麻岩侵入体的岩浆锆石结晶温度为610 ℃～790 ℃。结合区域资料,全岩Zr饱和温度计算结果显示扬子西北缘新元古代花岗质岩浆岩的形成温度随时间有规律性变化,可以识别出3期高温岩浆岩事件。第一期为897～887 Ma,以西乡流纹岩和米仓山喜神坝黑云母花岗岩为代表,对应汉南同期柳树店洋岛玄武岩,可能与～900 Ma地幔柱岩浆活动有关。第二期为817～760 Ma,以米仓山红庙镇钾长花岗岩和铁船山流纹岩为代表,对应汉南820～750 Ma基性侵入岩记录,可能与板块俯冲形成的弧后盆地伸展相关。第三期为～707 Ma,以西乡正长花岗岩为代表,对应同时期扬子西北缘基性侵入岩记录,可能与米仓山、汉南地区弧-陆后碰撞伸展有关。 相似文献
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Organization of oscillatory zoning in zircon: analysis, scaling, geochemistry, and model of a zircon from Kipawa, Quebec, Canada 总被引：1，自引：0，他引：1
Anthony Fowler Andreas ProkophRichard Stern Celine Dupuis 《Geochimica et cosmochimica acta》2002,66(2):311-328
The character of oscillatory zoning within a zircon crystal from the syenite Kipawa Complex, Quebec, varies with scale of observation. Analysis of an scanning electron microscopy (SEM) back-scatter gray-scale traverse at a resolution of one pixel = 2.43 μm revealed 145 zones over 5130 μm, whereas a detailed high-resolution (one pixel = 0.195 μm) section near the crystal rim revealed 225 zones over 795 μm. In order to mathematically characterize the zoning pattern, wavelet, Fourier, and nonlinear analysis techniques were used on profiles of the SEM gray-scale data, and a series constructed was from the zone widths. Results demonstrate that the zircon oscillatory zoning preserves nonlinear and periodic components. Secondary ion mass spectrometry, electron microprobe, and SEM analyses of trace elements show the SEM back-scatter bright zones are enriched in U, Th, and rare earth elements (REE) in comparison to the darker zones. REE patterns are sharply heavy REE enriched and have negative Eu anomalies and prominent positive Ce anomalies. We model the oscillatory zoning, including a measure of its chemical variation, by use of a periodically forced nonlinear system. Results of this data-driven model are quantitatively similar to the natural data. We envisage that the small-scale oscillatory zoning was the result of a nonlinear feedback process wherein the crystal growth modified the adjacent melt, which in turn affected the crystal composition. The large-scale harmonic zones likely reflect changes in the bulk geochemistry of the system from which the zircon grew. 相似文献
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Recrystallization of zircons under the influence of fluids was studied using examples from Precambrian rocks (microcline granites, metasedimentary, and mafic rocks) of the Kola Peninsula. All zircon crystals showed complex internal textures visible by cathodoluminescence and backscattered electron (BSE) imaging. Detailed mineralogical and geochemical studies with subsequent secondary ion mass spectrometer U–Pb dating of different zircon domains show that secondary texture formation can be interpreted in terms of metasomatic replacement of zircon crystals on the base of crystallogenetic experimental models. Mechanisms of zircon replacement and interpretation of U–Pb ages for secondary zircon domains are dependent on the degree of damage of the zircon structure and the fluid composition. The recrystallization of metamict zircon without additional supply of new zircon substance (Zr, SiO2) goes with the dissolution of amorphous domains and precipitation of new polycrystalline zircon, which preserves the U–Pb initial age, but loses radiogenic lead, and the lower intercept of Discordia lines with the Concordia curve determines the time of fluid influence. The recrystallization of metamict zircon or crystalline zircon with high contents of impurities with additional supply of Si and Zr forms monocrystalline replacements. Dissolution of primary zircon is accompanied by growth of new zircon domains differing in the composition of isomorphic impurities and zones of transitional composition, whose ages have no geological sense. The study is of particular importance for zircons from Precambrian rocks with long and complex histories. 相似文献
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林山岩群是华北克拉通中部造山带南缘前寒武纪结晶基底的一部分,它对于探讨中部造山带碰撞时代及其在克拉通南缘的分布具有重要意义.选择林山岩群主体的变基性岩(斜长角闪片岩)为主要研究对象,利用锆石U-Pb定年和岩石地球化学方法,获得的结果表明斜长角闪片岩样品锆石多呈长柱状,且外形不规则,具弱分带、斑杂状分带和扇形分带结构,其中少量锆石保留有早期原岩残留的岩浆核.锆石核部具岩浆振荡环带特征,大部分Th/U比值范围为0.10~9.24,且外形不规则,边部具溶蚀结构;绝大部分锆石具弱分带、斑杂状分带和扇形分带结构,以及低Th/U比值范围为0~0.09,个别比值为0.12,显示为典型的变质锆石特征.LA-ICP-MS锆石U-Pb定年结果表明该斜长角闪片岩的核部残留加权平均年龄为2 528±43 Ma(MSWD=1.5,n=10),经历变质作用的加权平均时限为2 474±22 Ma(MSWD=1.3,n=21).全岩地球化学结果显示林山岩群变基性岩贫硅(47.70%~50.77%,平均值为48.90%)和低钾(0.56%~1.78%,平均值为1.13%),轻、重稀土分异较弱,亏损微量元素Nb、Th、Ti、Zr等高场强元素,且具有低的微量元素Zr含量(＜130×10-6)和Zr/Y比值(＜4).这些特征表明林山岩群形成于俯冲作用背景下的岛弧环境.因此,上述证据共同反映了华北克拉通东、西陆块碰撞产物的中部造山带经历了新太古代晚期-古元古代早期的俯冲碰撞造山作用. 相似文献