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红、蓝宝石是一种主要与中新生代深大断裂构造、原始岩浆性质、火山作用、热液交替变质作用、地壳风化夷平作用等地质作用密切相关的重要经济矿产,在现实生活中具有重要经济作用。本文拟据实际资料对红、蓝宝石矿床成因－－产太进行分类,并对我省主要红、蓝宝石矿产地进行初步地质评价和探讨。 相似文献
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四川铜梁玉峡锶矿床“地下热卤水富集成矿”质疑 总被引：1，自引：0，他引：1
玉峡锶矿中天青石矿层的成因认识,现有两种观点,即开放成矿体系中的同生沉积和封闭成矿体系里的地下热卤水交代富集成矿。本文就后一种矿床成因认识提出了疑问。 相似文献
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滇东北地区峨眉山玄武岩在铅锌成矿中的作用 总被引：1，自引：0，他引：1
川滇黔铅锌成矿域分布有大面积峨眉山玄武岩,绝大多数铅锌矿床位于峨眉山玄武岩之下。对于峨眉山玄武岩与铅锌成矿之间是否有成因上的关系,一直存在着两种观点：一种认为峨眉山玄武岩与铅锌成矿存在成因联系;另一种则认为峨眉山玄武岩与铅锌成矿无成因上的关系,两者仅仅是空间上的叠合。峨眉山玄武岩在滇东北地区铅锌矿床的形成过程中扮演着怎样的角色？本文在总结前人研究观点的基础上,结合地质事实,认为峨眉山玄武岩与铅锌成矿并无直接的成因联系;推测峨眉山玄武岩在铅锌成矿中分别起到了提供热动力活化、萃取成矿物质以及充当＂遮挡层＂和＂保护层＂的作用。 相似文献
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山东迄今发现的蓝宝石砂矿和原生矿位于昌乐地区。根据成因蓝宝石砂矿层分为冲积砂矿层、洪积砂矿层和残坡积砂矿层；洪积砂矿层中蓝宝石最富。蓝宝石原生矿赋存于新生代新近纪临朐群牛山组和尧山组的玄武岩中，与高钾碱性玄武岩关系密切。 相似文献
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《吉林大学学报(地球科学版)》1977,(1)
自七四年起,我院与河北省某地质队相结合,共同组成教育革命实践队,进行一比两万五及一比一万比例尺的填图找矿工作。工作中接触到本地区铁矿成因争论问题,突出表现为火山作用成矿及接触交代作用成矿两种成矿两种成因观点互相争论,对于一些野外地质现象有两种对立的解释,每一种解释均立足于一种成矿作用观点,而去否定另 相似文献
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海南省蓬莱蓝宝石及其形成条件研究 总被引：2，自引：5，他引：2
海南省蓬莱是我国著名的蓝宝石产地之一。本文研究了该地蓝宝石的矿物学及化学组成特征，并首次详细研究了蓝宝石的包裹体特征，测定了蓝宝石的形成温度。最后，综合其它证据，对蓝宝石的成因进行了讨论。 相似文献
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辽东—吉南地区下元古界硼矿床成因的商榷——兼论容矿大理岩及硼矿矿床的成因 总被引：1，自引：0，他引：1
辽东—吉南地区下元古界产有丰富的硼矿资源,半个多世纪以来几乎所有硼矿地质勘查报告及有关论文、专著等无不涉及矿床成因。关于硼矿床成因主要有沉积变质成矿、沉积变质再造成矿、超变质热液成矿等3种观点(称传统观点,下同),传统观点认为硼的成矿物质来源于下元古界地层,经混合岩化或超变质热液将地层中分散的硼活化、迁移至镁质大理岩富集成矿。在编纂《中国矿产地质志·硼矿卷》过程中,对辽吉硼矿进行了新一轮研究,认为传统观点硼矿床成因值得商榷,并提出碳酸岩岩浆期后含硼热液交代早期喷溢的碳酸岩成矿的论说。 相似文献
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山东昌乐蓝宝石的EPR谱研究 总被引：1，自引：0，他引：1
本文较详细地分析论述了山东昌乐蓝宝石EPR谱各共振吸收带的位置、强度及其随EAC轴角度变化规律等特征，对各吸收带的归属也进行了深入讨论。通过EPR谱分析，笔者认为山东昌乐蓝宝石中Fe3 是大量存在的，并有可能是Fe的主要存在形式，由此指出，在昌乐蓝宝石改色工艺中过于看重将Fe2 转变为Fe3 将导致蓝宝石灰色成分增加。 相似文献
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福建明溪蓝宝石的谱学特征及颜色成因 总被引：6，自引：2，他引：4
采用颜色测量、紫外-可见光谱、红外光谱等方法对福建明溪蓝宝石进行的研究表明,明溪蓝宝石颜色蓝中带黄,二色性强。紫外-可见吸收光谱中377,388和451nm吸收带较强。这些吸收带是Fe3 的d－d和Fe3 —Fe3 ,交换相合离子间的电子跃迁引起的。810nm带存在于各色蓝宝石中,强度变化较大,有时伴随有510nm吸收带。它是由Fe2 —Fe3 电荷转移形成的。570nm吸收带只出现在蓝色或绿色的蓝宝石中。结合蓝宝石红外33loom－‘吸收带与宝石颜色之间的关系,笔者将570nm吸收带归属于H、Fe、Ti构成的致色缺陷团。这一研究结果对蓝宝石呈色机理的进一步研究和宝石的合成等具有重要意义。 相似文献
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山东蓝宝石颜色深暗,与其主要致色元素有着直接关系.对其化学成分进行分析认为:Cr2O3是红色、橙黄色、黄色的主要致色因素.而w(TiO2)低,w(TFeO)高,尤其是Fe3 大于全铁的90%,TFeO/TiO2比值大是山东蓝宝石颜色深暗的主要原因.对其紫外-可见光-近红外吸收光谱进行分析,进一步得出Cr3 离子的d-d电子跃迁、成对Fe3 离子、单Fe3 离子的d-d电子跃迁、Fe2 -Ti4 之间的电荷转移、Fe2 Fe3 之间的电荷转移等是山东蓝宝石致色的本质.代表绝大多数山东蓝宝石颜色的深蓝色蓝宝石,缺失紫外-可见光-近红外吸收光谱的575～711nm吸收带,即缺少Fe2 -Ti4 之间的电荷转移.因此,针对性地选择w(TiO2)高的蓝宝石进行改善,或是设法加入TiO2、减少Fe3 含量、在还原条件下改变其TFeO/TiO2的比值,应是目前山东蓝宝石改色的关键. 相似文献
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F. L. Sutherland P. C. Piilonen Khin Zaw S. Meffre J. Thompson 《Australian Journal of Earth Sciences》2013,60(6):761-773
Subordinate sapphire accompanies prevalent zircon megacrysts in the Bo Loei basaltic gem field, Ratanakiri Province, Cambodia. These deposits are important for heat-treated gem zircon. Dark blue sapphire, with rare blue-green, orange-brown and yellow stones, up to a few cm in size, include hexagonal-shaped and growth-zoned crystals. Analyses of the sapphires (electron microprobe and laser ablation-inductively coupled plasma-mass spectrometry) showed Fe as the main chromophore (0.6–2.7 wt%), with minor Ti (<0.7 wt%). Sapphire cores show enrichment in Fe relative to rims and some include exotic heavy elements (Nb up to 56, Ta up to 144, Sn up to 5 ppm). The sapphires show high Ga values (271–724 ppm) and Ga/Mg ratios (4.8–77.0) suggesting magmatic associations. Two sapphires with syngenetic inclusions (zircon, Nb-rich rutile) gave U–Pb (Th-disequilibrium corrected) ages at ca 0.93 ± 0.1 Ma. The Bo Loei sapphires show higher Fe and Ga than other magmatic sapphire suites elsewhere in Cambodia (Pailin), Laos (Ban Huai Sai, Ban Sam Sai), South Vietnam (Dak Nong, Dak Lac) and SE Thailand (Chanthaburi-Trat). This suggests potential for geographic typing of sapphire suites between these different fields. 相似文献
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Rubies and sapphires are of both scientific and commercial interest. These gemstones are corundum colored by transition elements within the alumina crystal lattice: Cr3+ yields red in ruby and Fe2+, Fe3+, and Ti4+ ionic interactions color sapphires. A minor ion, V3+ induces slate to purple colors and color change in some sapphires, but its role in coloring rubies remains enigmatic. Trace element and oxygen isotope composition provide genetic signatures for natural corundum and assist geographic typing. Here, we show that V can dominate chromophore contents in Mogok ruby suites. This raises implications for their color quality, enhancement treatments, geographic origin, exploration and exploitation and their comparison with rubies elsewhere. Precise LA-ICP-MS analysis of ruby and sapphire from Mogok placer and in situ deposits reveal that V can exceed 5,000 ppm, giving V/Cr, V/Fe and V/Ti ratios up to 26, 78, and 97 respectively. Such values significantly exceed those found elsewhere suggesting a localized geological control on V-rich ruby distribution. Our results demonstrate that detailed geochemical studies of ruby suites reveal that V is a potential ruby tracer, encourage comparisons of V/Cr-variation between ruby suites and widen the scope for geographic typing and genesis of ruby. This will allow more precise comparison of Asian and other ruby fields and assist confirmation of Mogok sources for rubies in historical and contemporary gems and jewelry. 相似文献
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J.J. Peucat P. Ruffault E. Fritsch M. Bouhnik-Le Coz C. Simonet B. Lasnier 《Lithos》2007,98(1-4):261-274
Using ICP-MS–LA analyses, we demonstrate that the use of the Ga/Mg ratio, in conjunction with the Fe concentration, is an efficient tool in discriminating between “metamorphic” and “magmatic” blue sapphires. Magmatic blue sapphires found in alkali basalts (e.g. southeastern Asia, China, Africa) are commonly medium-rich to rich in Fe (with average contents between 2000 and 11000 ppm), high in Ga (> 140 ppm), and low in Mg (generally < 20 ppm) with high Ga/Mg ratios (> 10). Conversely, metamorphic blue sapphires found in basalts (e.g. Pailin pastel) and in metamorphic terrains (e.g. Mogok, Sri Lanka, Ilakaka) are characterized by low average iron contents (< 3000 ppm), low Ga contents (< 75 ppm), and high Mg values (> 60 ppm) with low average Ga/Mg ratios (< 10). Basaltic magmatic sapphires have Fe, Ga and Mg contents similar to those obtained for primary magmatic sapphires found in the Garba Tula syenite. This suggests that these both sets of sapphires have a possible common “syenitic” origin, as previously proposed from other criteria. In addition, plumasite-related sapphires and metamorphic sapphires also exhibit similar composition in trace elements. Based on results from the present study, we suggest that fluid circulations during a metamorphic stage produced metasomatic exchanges between mafic and acidic rocks (plumasite model), thus explaining the high Mg contents and converging Ga/Mg ratios observed in metamorphic sapphires. 相似文献
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山东蓝色蓝宝石的着色是由Ｔｉ４＋离子与Ｆｅ２＋离子合理配比而成，一般控制在Ｔｉ４＋／Ｆｅ２＋＝１的配比范围内。多余的Ｆｅ２＋和其它Ｆｅ３＋离子存在都不利于蓝色蓝宝石正常呈色。通过穆斯堡尔谱和电子顺磁共振谱分析，测定了山东蓝宝石中铁离子的不同价态和浓度。对Ｆｅ２＋和Ｆｅ３＋离子所引起的吸收光谱特征作了研究，查明只有Ｆｅ３＋浓度很高时才产生４７７ｎｍ吸收峰，是致使山东蓝宝石表观上呈深蓝带黑色调的的重要原因。 相似文献
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Nelsonite and Fe–Ti oxides ore are common in Proterozoic massif-type anorthosites and layered intrusions. Their geneses have long been controversial, with existing hypotheses including liquid immiscibility between Si-rich and Fe–Ti–P-rich melts and gravitational fractionation among apatite, magnetite, ilmenite and silicates. In this paper, we report detailed field geology and mineral geochemical studies of the nelsonite and Fe–Ti oxides ore from the Damiao anorthosite complex, NE China. Geological observations indicate that the nelsonite and Fe–Ti oxides ore occur as irregularly inclined stratiform-like or lensoid or veins, and are in sharp contact with the anorthosite and gabbronorite. The widespread veins and lenses structure of the Damiao nelsonite and Fe–Ti oxides ore in the anorthosite indicates their immiscibility-derived origin. The apatite in the nelsonite and gabbronorite shows evolution trends different from that in the gabbronorite in the diagrams of Sr versus REEs and Eu/Eu*, suggesting that petrogenesis of the nelsonite and gabbronorite is different from the gabbronorite. Compared with the gabbronorite, the nelsonite and Fe–Ti oxides ore have magnetite high in Cr, plagioclase high in Sr and low in An, and apatite high in Sr, low in REEs with negative Eu anomaly. The evidence permits us to propose that the Damiao Fe–Ti oxides ore/nelsonite and gabbronorite were derived from different parental magmas. The gabbronorite was formed by solidification of the interstitial ferrodioritic magma in the anorthosite, which was the residual magma after extensive plagioclase and pyroxene crystallization and was carried upward by the plagioclase crystal mesh. In contrast, the Fe–Ti oxides ore and nelsonites and mangerite were produced by crystallization of the Fe–Ti–P-rich and SiO2-rich magmas, respectively, due to the liquid immiscibility that occurred when the highly evolved ferrodioritic magma mixed with newly replenished magmas. The variation from Fe–Ti oxides ore to nelsonite and gabbro-nelsonite upwards (as apatite content increases with height) in the steeply inclined Fe–Ti oxides orebodies suggest that gravity fractionation may have played important roles during the crystallization of the Fe–Ti–P-rich magma. 相似文献