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1.
采用土柱淋滤试验研究了不同填埋年限的垃圾渗滤液DOM在土壤中垂直迁移及其对土壤重金属Pb淋滤溶出的影响。结果表明,不同填埋年限(0.4~5.12 a)的垃圾渗滤液DOM在土壤中垂直向下的迁移速率存在差异,填埋时间短的垃圾渗滤液DOM在土壤中迁移性较强。与对照相比(不加渗滤液DOM),垃圾渗滤液处理对红壤中土壤重金属Pb的累积解吸率高74.25%;在潮土上高-38.79%,且垃圾填埋年限中期的渗滤液DOM对土壤重金属的溶出影响更显著,说明垃圾渗滤液DOM进入土壤环境对重金属的迁移有促进作用。  相似文献   

2.
垃圾填埋场对周边地质环境影响与防治对策   总被引:5,自引:0,他引:5  
垃圾填埋场对周边地质环境的污染越来越受到研究人员的重视,其影响因素复杂,不仅与MSW的性质有关,还与垃圾填埋场的类型及其所处地质环境有密切关系。为分析垃圾填埋场中的渗滤液、重金属以及其他有害物质对周边地质环境(地下水环境、土壤环境)的影响规律,对大量相关文献和实验资料进行研究分析。研究结果表明:渗滤液是垃圾填埋场影响周围地质环境最为重要的因素,对渗滤液污染地表水及地下水情况和防治方法进行了探讨;同样渗滤液也是重金属污染土壤的载体,重金属在土壤剖面中的滞留量一般随深度的增加而逐渐减少;重金属对土壤的污染具有积累性和滞后性特点,随着填埋时间的延长污染加重。最后,根据其污染途径和污染规律,提出了相应具体防治对策。  相似文献   

3.
《Applied Geochemistry》2001,16(7-8):659-718
The literature has been critically reviewed in order to assess the attenuation processes governing contaminants in leachate affected aquifers. Attenuation here refers to dilution, sorption, ion exchange, precipitation, redox reactions and degradation processes. With respect to contaminants, focus is on dissolved organic matter, xenobiotic organic compounds, inorganic macrocomponents as anions and cations, and heavy metals. Laboratory as well as field investigations are included. This review is an up-date of an earlier comprehensive review. The review shows that most leachate contamination plumes are relatively narrow and do not in terms of width exceed the width of the landfill. The concept of redox zones being present in the plume has been confirmed by the reported composition of the leachate contaminated groundwater at several landfills and constitutes an important framework for understanding the behavior of the contaminants in the plume as the leachate migrates away from the landfill. Diverse microbial communities have been identified in leachate plumes and are believed to be responsible for the redox processes. Dissolved organic C in the leachate, although it appears to be only slowly degradable when the volatile organic acids are gone, apparently acts as substrate for the microbial redox processes. Several xenobiotic organic compounds have been found to be degradable in leachate contaminated groundwater, but degradation rates under anaerobic redox conditions have only been determined in a few cases. Apparently, observations in actual plumes indicate more extensive degradation than has been documented in the laboratory. The behavior of cations in leachate plumes is strongly influenced by exchange with the sediment, although the sediment often is very coarse and sandy. Ammonium seems to be subject to anaerobic oxidation, but the mechanisms are not yet understood. Heavy metals do not seem to constitute a significant pollution problem at landfills, partly because the heavy metal concentrations in the leachate often are low, and partly because of strong attenuation by sorption and precipitation. Although complexation of heavy metals with dissolved organic matter is significant, the heavy metals are in most cases still strongly attenuated in leachate-polluted aquifers. The information available on attenuation processes has increased dramatically during the last 15 a, but the number of well-documented full scale leachate plumes are still few and primarily from sandy aquifers. Thus, the diversity of attenuation processes in leachate plumes is probably not yet fully understood. Apparently, the attenuation processes in leachate plumes may for many contaminants provide significant natural remediation, limiting the effects of the leachate on the groundwater to an area usually not exceeding 1000 m from the landfill.  相似文献   

4.
通过对渗透前后垃圾填埋场渗滤液进行化学成分的测定和分析,研究了GCL的吸附能力及其变化规律,并采用X射线荧光光谱分析对试验结果进行了验证。研究结果表明在渗透过程中GCL对渗滤液中的有机物和阳离子存在吸附作用,水化液对GCL的吸附能力有一定影响;在渗透开始阶段,GCL对垃圾渗滤液中阳离子和有机物的吸附能力比较强,而后逐渐达到吸附饱和状态而丧失吸附能力,因此用GCL作为防渗屏障,主要是依靠其低渗透特性,而非其对溶液中有机质和有害离子的吸附作用。通过对膨润土进行X射线荧光光谱分析也发现:经过渗透后的膨润土中除常见氧化物外,还有来自渗透液中被吸附的物质,但含量不大。  相似文献   

5.
Experiments using distilled water, spiked with heavy metal cations and passed through a filtration system composed of greensand containing 80% glauconite at a rate of 2–4 ml/min, showed: (1) starting fluids containing Cd, Co, Cu, Pb, Mn, Ni, Ag, or Zn had an average of 90% of the contaminating cation removed from acidic solutions and an average of 84% removed from the basic solutions; and, (2) filtration through greensand tended to neutralize both acidic and basic solutions. The removal of the contaminant cation from starting fluids containing K, Na, Ca, Mg, Fe, Si, or Al (the principal constituents of glauconite plus Ca from shell material) is not as consistently effective as for the first named metals.  相似文献   

6.
Bacterially mediated methanogenesis in municipal solid waste landfills has been shown to cause an enrichment of carbon stable isotope ratios of dissolved inorganic carbon and hydrogen stable isotope ratios of water in landfill leachate. In the present study, we investigate the universality of this enrichment in leachate obtained from four diverse landfill sites in New Zealand. At each site, surface water samples upstream and downstream of landfills were analysed to examine the applicability of stable isotope ratios as a tool for monitoring leachate contamination in landfill-associated streams. The design of leachate collection systems, operational history, and landfill location appeared to strongly influence leachate isotopic values and the effectiveness of isotope ratios as an environmental monitoring tool for surface water.  相似文献   

7.
垃圾的堆存和填埋会产生大量的渗滤液。渗滤液对垃圾填埋场周围环境能够造成严重污染,尤其使地下水质污染而丧失利用价值。通过阜新市垃圾填埋场现场采集新鲜渗滤液水样、垃圾堆体附近土样的实验研究,获得了新鲜渗滤液的各组分浓度和垃圾堆体附近土壤的性质。结合当地地理气候等情况揭示了垃圾渗滤液中污染溶质在地下水系统中的迁移转化的动态过程,定量化预测了污染范围及时空分布,为研究该地区地下水污染控制、管理和评价提供了可靠依据。  相似文献   

8.
 The Nanjido Landfill is the largest uncontrolled landfill in Korea and it causes various kinds of environmental problems. Landfill gases and leachate are recognized as the most serious environmental problems associated with the landfill. This study employs a series of numerical models and uses test data to interpret the distribution and flow of landfill gases and leachate. Leachate seepage appears about 40–60 m higher than the estimated basal groundwater table. Thus, seepage data indicate that perched or floating leachate layers are formed in the unsaturated zone of the landfill. The leachate production rate is estimated using infiltration test data and a model for unsaturated groundwater flow. Geochemical data indicate that the landfill leachate degrades the basal groundwater quality along the downgradient zone. The environmental impact of the leachate on river water is estimated. Received: 17 June 1996 · Accepted: 2 October 1996  相似文献   

9.
顾华 《地质与资源》2017,26(1):62-66
垃圾填埋是目前处理城市生活垃圾普遍使用的方式,由此产生的垃圾渗滤液成为主要的地下水污染源.本文以上海市某生活垃圾填埋场作为研究对象,研究垃圾填埋对地下水的影响.通过监测该场地垃圾填埋前后2年内场区及周边地下水水质的变化情况,以垃圾填埋前调查区的地下水样品分析结果为本底值,采用本底法对地下水水质进行评价来判定地下水是否受到垃圾渗滤液的影响.评价结果显示,对于本研究的水质动态监测阶段,调查区内的浅层地下水水质暂未受到垃圾渗滤液的影响,个别监测井水质发生较大变化是由于填埋场施工建设过程中,破坏了监测井井盖及挖穿了井边含水层顶层.随着整个垃圾填埋场运行时间的延长,防渗漏措施的有效性以及垃圾渗滤液对周边地下水的影响还需要进一步研究.  相似文献   

10.
11.
The influence of local hydrogeology on natural attenuation of contaminants from landfill leachates in shallow aquifer underlying the active Olusosun landfill base in Lagos was investigated. In addition, the level of groundwater contamination in the vicinity of the landfill and of leachate migration pattern in groundwater down gradient of the landfill base was equally assessed. Landfill leachate and groundwater samples were collected and analyzed and characterized. Physico-chemical analyses of sampled water followed standard analytical methods. Analytical results showed a measurable impact of leachate outflows on groundwater quality. Elevated levels of anions: nitrate, chloride and sulphate in the groundwater body and heavy metals: Cr3. Cd and Cu, were detected at measurable levels in groundwater down gradient of the landfill location without any particular attenuation pattern. The migration pattern and dispersion of leachates down gradient, 750 m away from the landfill location are irregular and difficult to predict as depicted by levels of contaminants present in groundwater. The study highlighted the importance of soil stratigraphy beneath the landfill base as an important factor in the natural attenuation of leachate constituents in the groundwater body.  相似文献   

12.
非开挖HDD技术具有对环境干扰小、施工效率高等优点,被广泛应用于给排水、电力、通信、油气等领域的新管道敷设和既有管线修复中。本文结合英国某垃圾填埋场的渗滤液导流治理工程,分别从技术原理、工程背景、工艺过程、应用效果和改进措施等方面展开了论述。工程实践表明,HDD技术可应用于垃圾填埋场渗滤液水平排放孔的施工中,并应根据现场地层条件和工艺参数对施工过程加以优化。由于填埋堆体含有大量金属废弃物,采用有线导向系统替换了无线电磁导向,可极大提高导向钻孔轨迹的定位精度。采用正向扩孔和管道敷设技术有助于降低阻力,提高敷设效果。对比运行结果显示,相对于传统的渗滤液竖井抽排模式,水平钻孔排放效率更高,成本投入也相对较低,但在设计施工中应充分考虑堆体非均质对施工过程的影响,降低施工风险。  相似文献   

13.
以北京市阿苏卫垃圾填埋场中晚期渗滤液为研究对象,通过正交实验的方法分析了改性土、原土、明矾、改性土加明矾等的用量及搅拌速度、搅拌时间、静置时间等因素对垃圾渗滤液CODcr去除率的影响。通过对改性土、原土、明矾处理垃圾渗滤液的机理进行分析后,将改性土、原土分别用来处理垃圾渗滤液中可溶性物质中的疏水性物质和亲水性物质,并结合明矾的絮凝作用组合处理垃圾渗滤液。处理后垃圾渗滤液CODcr值从4700mg/L明显下降到839mg/L,CODcr去除率为82.15%,BOD5从700mg/L下降到263mg/L,BOD5去除率为62.43%。有机改性膨润土、明矾、原土组合处理是一种有效的处理垃圾渗滤液方法。  相似文献   

14.
宋启龙  王会敏 《地下水》2014,(4):118-120
针对非卫生垃圾填埋场环境污染问题,以某垃圾填埋场为例,通过 WHI UnSat Suite软件 HELP模块计算不同填埋条件下渗滤液渗漏量。利用GMS模拟了该垃圾场中心抽水条件下污染物迁移变化规律。结果表明,简单地表防渗条件下,渗滤液渗漏量为现状条件下的50%,增铺 HDPE土工膜后,渗漏量可减少99%。卫生填埋渗滤液仅为现状条件下的3.6×10-3倍。当抽水量为2000 m3/d时,Cl-浓度呈明显下降趋势,由84 mg/L降至80.1 mg/L。  相似文献   

15.
Magnetic properties and heavy metal content of landfill leachate sludge samples from two municipal solid waste disposal sites near Bandung, West Java, Indonesia, and their correlation with heavy metals are studied in the present work. Leachate was found to be sufficiently magnetic with mass-specific magnetic susceptibility that varies from 64.8 to 349.0 × 10−8 m3 kg−1. It is, however, less magnetic than the soils around the landfill sites. The magnetic minerals are predominantly pseudo-single domain and multidomain magnetite. Leachate samples from the older but inactive disposal site, Jelekong, are found to be more magnetic than that from Sarimukti, the younger and active site. The enhancement of leachate due to the soil-derived ferrimagnetic particles is possibly the same for both Sarimukti and Jelekong. The fact that strong correlation between magnetic parameters and heavy metals is observed in Jelekong but is absent in Sarimukti suggests that the use of magnetic measurement as a proxy measurement for heavy metal content in leachate is plausible provided that the magnetic susceptibility exceeds certain threshold value. Moreover, the accumulation of magnetic minerals and heavy metals in leachate might depend on the activity and the age of landfill site.  相似文献   

16.
邱战洪  何春木  朱兵见  陈合龙 《岩土力学》2012,33(10):3151-3155
近10年的运营经验表明,国内南方地区第1批建造的山谷型垃圾填埋场中的渗滤液水位一般较高。同时,现有研究表明,降雨入渗引起渗滤液水位过高是垃圾填埋场失稳的主要诱因之一。因此,研究强降雨条件下山谷型垃圾填埋场的水分运移规律及其稳定性,具有重要的现实意义。基于七子山填埋场浅层、中层和深层垃圾土的土-水特征曲线和Brooks-Corey公式,利用非线性拟合技术得到垃圾土的渗透性函数;运用饱和-非饱和渗流理论,对递减型、中心型、增强型和平均型4种降雨模式下七子山填埋场的水分运移进行了数值计算;利用极限平衡理论,对不同降雨模式下七子山填埋场的稳定性进行了分析。结果表明,降雨模式对山谷型垃圾填埋场内的水分运移规律和填埋场的稳定性有显著的影响,递减型降雨模式下填埋场内孔隙水压的变化最大,同时填埋场稳定系数也下降最为明显,为最不利降雨模式;经历7 d 746 mm的极端强降雨后,七子山填埋场具有极大的失稳隐患。  相似文献   

17.
The degree of metal contamination (Zn, Pb, Cu, Ni, Cd) has been investigated in the vicinity of an old unmonitored municipal landfill in Prague, Czech Republic, where the leachate is directly drained into a surface stream. The water chemistry was coupled with investigation of the stream sediment (aqua regia extract, sequential extraction, voltammetry of microparticles) and newly formed products (SEM/EDS, XRD). The MINTEQA2 speciation-solubility calculation showed that the metals (Zn, Pb, Cu, Ni) are mainly present as carbonate complexes in leachate-polluted surface waters. These waters were oversaturated with respect to Fe(III) oxyhydroxides, calcite (CaCO3) and other carbonate phases. Three metal attenuation mechanisms were identified in leachate-polluted surface waters: (i) spontaneous precipitation of metal-bearing calcite exhibiting significant concentrations of trace elements (Fe, Mn, Mg, Sr, Ba, Pb, Zn, Ni); (ii) binding to Fe(III) oxyhydroxides (mainly goethite, FeOOH) (Pb, Zn, Cu, Ni); and (iii) preferential bonding to sediment organic matter (Cu). These processes act as the key scavenging mechanisms and significantly decrease the metal concentrations in leachate-polluted water within 200 m from the direct leachate outflow into the stream. Under the near-neutral conditions governing the sediment/water interface in the landfill environment, metals are strongly bound in the stream sediment and remain relatively immobile.  相似文献   

18.
针对南昌市麦园垃圾卫生填埋场渗滤液防渗的实际情况,分析了重金属污染物在黏土固化注浆帷幕中的迁移转化特征,建立了地下水渗流模型和重金属污染物运移的耦合动力学模型。利用该模型对黏土固化注浆帷幕控制重金属污染物的迁移行为进行了模拟研究。数值模拟结果表明,在填埋场设计使用年限内黏土固化注浆帷幕对重金属污染物的阻滞率可以达到94.5 %以上,重金属污染物在防渗系统中的浓度范围沿地下水水流方向逐渐扩展,同一位置的浓度值随时间的延续呈逐渐增大的趋势,但距离污染源越远,污染物的浓度越低。结合现场检测情况,证明了黏土固化注浆帷幕对重金属污染物具有较强的污染控制能力。  相似文献   

19.
《Applied Geochemistry》2000,15(4):493-500
A study was undertaken to explore whether the isotopic compositions of Pb and Sr are useful to distinguish mixtures of uncontaminated groundwater, seawater, and landfill leachate at the Fresh Kills landfill, Staten Island, New York. Ratios of 87Sr/86Sr ranged from 0.7088 to 0.7137 and could be used to distinguish Sr that was derived from seawater from that in uncontaminated groundwater. Lead isotopic abundances did not vary systematically among the different water sources. Plots of 87Sr/86Sr versus dissolved organic C, B, and NH4+ defined perpendicular trends, documenting where leachate or sea water mixed with uncontaminated groundwater, and demonstrating that leachate has not contaminated groundwater in aquifers beneath the landfill.  相似文献   

20.
徐超  李志斌  黄亮 《岩土力学》2006,27(Z2):607-610
近年来土工织物膨润土垫(GCL)被越来越多地应用到各种防渗工程之中,而水化后GCL中膨润土的微观结构会对GCL的长期防渗性能和力学性能产生影响。采用压汞试验,对水化后GCL中膨润土的微观结构进行定量分析,研究了液体对微观结构的影响,并通过化学分析来揭示液体产生影响的机制。结果表明,(1) 采用垃圾渗滤液水化后的膨润土孔隙体积密度最大,大孔径孔隙所占比例最高;(2) 出现上述规律的原因可以归结为两个方面,一是由于渗滤液中阳离子浓度最高而使得蒙脱石表面双电层厚度最小,二是更加频繁的离子交换作用使得蒙脱石表面大直径离子比例最高。  相似文献   

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