共查询到20条相似文献，搜索用时 78 毫秒
1.
2.
3.
水系沉积物测量在我国是一门比较成熟的技术,但在不同的表生环境条件下开展水系沉积物测量的最佳采样粒度也不尽相同。通过对豫西熊儿山金矿田牛头沟矿区不同粒度土壤和水系沉积物样品风化过程中元素行为的研究,发现土壤和水系沉积物样品随粒度变细其风化程度增强,且这一特征在水系沉积物样品中表现更为明显。当样品粒度为4～100目时,元素含量逐渐升高或降低,变化趋势较为稳定;当粒度小于100目时,样品中元素含量发生显著变化,其主导风化机制可能发生了改变。热液成矿元素在土壤样品中相对富集在60～100目的粒度,在水系沉积物样品中相对富集在80～100目的粒度,参考各粒级样品在全粒级样品中的质量分数,建议选择60～100目作为水系沉积物测量的最佳采样粒度。这一粒级样品既可继承原岩在连续风化过程中的元素行为,又不受后期新的风化机制的明显影响,同时可最大限度地风化而分散以达到降低采样密度的需要。选择60～100目粒级样品在牛头沟金矿区开展了1∶5万化探普查,结果发现元素浓集中心与各矿段空间位置吻合较好,为豫西熊儿山地区开展1∶5万化探普查提供了技术参考。 相似文献
4.
中国南部湿润半湿润丘陵山区不同粒级水系沉积物地球化学特征对比研究 总被引：1，自引：0，他引：1
不同景观条件下选取合适的采样粒级是准确地获取地球化学信息,提升地质找矿效果的关键。为研究中国南部湿润半湿润中低山丘陵景观区水系沉积物测量最佳采样粒级,本文在安徽省南部胡乐司—宁国墩地区开展了区域化探采样粒度方法技术试验,采集-60目和-10目~+80目两种粒级样品,采用波长色散X射线荧光光谱法和电感耦合等离子体质谱法为主体的配套分析方案和测试技术获取了全国区域化探扫面规定的40种元素高精度数据。研究表明:两种粒级水系沉积物中造岩元素背景含量与区域岩石背景值基本接近,其他微量元素多呈富集状态,以-10~+80目粒级中As、Au、Hg、Mo、Pb、Sb等成矿元素富集程度最强;-10~+80目粒级受后期表生改造作用影响较弱,最大限度保留了原生地球化学分布特征,并在准确圈定与矿化有关的异常和清晰反映矿致异常特征等方面明显优于-60目粒级。因此,建议在安徽省南部中低山丘陵景观区,选择-10~+80目粒级为水系沉积物测量的最佳采样粒级,研究结果可以为中国相似景观区地球化学勘查找矿水系沉积物测量采样粒级的选择提供参考。 相似文献
5.
通过开展福建街面—水口地区1:5万水系沉积物测量工作,获得了较丰富的水系沉积物地球化学测量成果。对水系沉积物18种元素总体含量和在不同地质单元中的含量特征进行了统计分析,明确了成矿有利期和主要成矿元素。根据元素异常分布规律结合成矿地质条件、已有矿床(点)划分了找矿远景区,明确了研究区找矿方向。 相似文献
6.
在广东北市地区选择310 km2试验区开展1∶5万水系沉积物测量粒级试验。在同一采样点位分别采集-10~+80目和-60目两种粒级的样品,进行多元素含量测试,从水系沉积物粒级分布特征、元素含量分布特征、富集倾向性和地球化学特征4方面对上述两种粒级试验效果进行综合评价。结果表明:(1)水系沉积物中-10~+80目粒级段样品占全部样品的86.59%,质量上占有绝对优势;(2)除W、Sn、Pb外,试验区多数元素在两种粒级总体上具有相似的含量分布特征,且在高背景区或矿(化)区均不同程度富集于-10~+80目粗粒级,在低背景区或非矿(化)区则正好相反;(3)包括Au、Ag、Zn、Mo、Sb在内,多数元素-10~+80目粗粒级显示的区域地球化学分布与区域地质吻合度更高,地球化学分布界线与地质界线更为接近;(4)多数元素-10~+80目粗粒级显示的地球化学高背景-正异常区的规模和强度整体上大于-60目细粒级,Mo、Sb等尤为明显。因此,广东北市地区1∶5万水系沉积物的最佳采样粒级为-10~+80目。 相似文献
7.
8.
9.
《地质科技情报》2020,(3)
通过在青海省都兰县石灰沟地区开展的1∶50 000水系沉积物测量工作,运用元素的变化系数、元素富集离散特征、叠加系数对石灰沟地区水系沉积物测量的10种微量元素进行地球化学统计分析,论述了10种微量元素的成矿潜力,得出Au、Cu、Pb、Zn这4种微量元素具有较大的成矿潜力,并通过相关分析、因子分析确立了测区内元素组合特征,共划分了3组成矿元素组合(Ag-Cu-Pb-Zn,Au-As-Sb,W-Bi-Hg)。通过衬值异常法圈定组合异常显示:研究区组合异常明显,异常套合较好。最后,根据组合衬值异常套合结果,在研究区优选了3处金铜铅锌多金属找矿靶区(A,B,C)。 相似文献
10.
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
13.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
14.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
15.
16.
S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
17.
18.
19.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
20.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献