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1.
Sulfide minerals in the Boulder batholith occur 1. as disseminated grains, visible in hand specimens; 2. in aplitic-pegmatitic pods and masses; 3. along joint and shear surfaces; 4. in hydrothermal veins; and 5. as minute masses within pyrite and silicate minerals and along intergranular sites. Hydrothermally altered rocks have an average sulfide content of 0.8 weight per cent, compared to an average of 0.01 per cent for unaltered rocks. Unaltered rock of the batholith may contain as much as 0.7 weight per cent sulfide. Sulfide inclusions in pyrite, the most abundant sulfide of the batholith, are common and represent a captured iss-phase which later changed to chalcopyrite plus pyrrhotite or mackinawite. Inclusions are most abundant, and more complex, in pyrites of hydrothermally altered and ore rocks. Electron-probe analyses show that pyrites of the Boulder batholith have very similar compositions to those found for pyrites from other ore deposits around the world.  相似文献   

2.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

3.
Accumulation rates and chemical compositions have been obtained for pelagic sediments for 73 locations in the Pacific and for 11 in the Indian Ocean. The data for the Pacific show that many elements accumulate rapidly close to the continents and slowly in the central part of the ocean. This pattern is interrupted by two major zones of relatively high accumulation rates, one along the Equator and one along the East Pacific Rise. Deposition of opaline silica is almost completely restricted to areas of known high biological productivities at the Equator and at very high latitudes. Cu and Ni show stronger tendencies than Fe and Mn to precipitate with opaline silica. The highest accumulation rates of Fe and Mn in the open Pacific occur along the East Pacific Rise, to some extent also Cu and Ni are enriched there due to volcanic processes. Al and Ti show high accumulation rates only close to the continents; these elements appear to be almost completely terrigenous.Provenance studies of minerogen fractions, using the relations between Fe, Ti, Al and Mn, show that significant quantities of basaltic matter (oceanic crust) are incorporated into the sediments only in areas of very low total sedimentation rates in the vicinity of oceanic island groups such as Polynesia and Hawaii, whereas hydrothermal processes act as a major sediment source only on the East Pacific Rise. Sediments in the north as well as in the southernmost part of the Pacific are nearly entirely terrigenous. A balance estimate of the minerogen fraction of the deep-sea sediments from the open Pacific suggests that between 75 and 95% of all sediments in the Pacific are terrigenous and that submarine weathering (and release of basaltic debris in general) and submarine exhalations each account for only a small fraction of the sediments.  相似文献   

4.
The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements.  相似文献   

5.
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

6.
This purpose of this paper is to propose starting points for a critically informed understanding of the role of risk in contemporary environmental practice, and to flesh out some preliminary implications of the work risk does as a logic though which environment is managed. Taking cues from scholarship interrogating the production of capitalist natures (e.g., Smith, 1984/2008; Braun, 2000, Heynan et al., 2007). I ask what it means in environmental terms to put risk at the intersection of capital and rule--to conceive of it as something that to paraphrase Dillon (2008, p. 319) makes the combination of capital and rule possible, and to interpret risk as something which (as Martin (2007b, p. 67) has suggested) undertakes to create the very conditions that make new wealth possible. I argue that in order to understand the intersection of capital and rule in environmental terms, risk must be understood as an epistemic framework and political ontology consistent with the advent of capitalist political economy--not as an occasion of danger or geographical condition of insecurity. Using difference as a starting point to attempt to think through connections between risk and accumulation I suggest that risk is a knowledge practice instrumental to accumulation and the politics of rule that secure it, which obscures the functioning of difference and processes of differentiation.  相似文献   

7.
The development of the Yugoslavian, Albanian, and Italian segments of the Mediterranean geosyncline is compared, using the province of Montenegro as the standard for correlation of the paleogeographic analysis during the Alpine tectonic cycle. The tectonic zones, characteristic of the Montenegro area are four in number and given as the Maritime zone with rocks ranging from Upper Carboniferous to Oligocene; the old Montenegro zone consisting of Triassic, Jurassic, Cretaceous and upper Oligocene sediments; the Ku?a zone deposits ranging from Upper Permian through Mesozoic; and the Durmitor zone with Devonian, Carboniferous, Permian, Triassic, and Jurassic sedimentary and volcanic-sedimentary bodies and Upper Cretaceous flysch.—IGR Staff.  相似文献   

8.
《International Geology Review》2012,54(12):1795-1797
At 500–600°C and 500–800 atm, in alkaline solutions, two mechanisms of the migrations of Ti, Zr, and Hf are experimentally indicated: a) in the absence of fluorine and other halogens, these metals migrate as titanates, zirconates, and hafnates of K and Na, the forms which are conducive to their dissipation but not deposition-accumulation in the rocks, within a wide range of temperature, as long as the pH of the solution remains alkaline; b) in the presence of fluorine, Ti, Zr, and Hf migrate as fluoride complexes (with Na and K) from which they may be liberated by hydrolysis and deposited at decreasing temperature, as the corresponding oxides.  相似文献   

9.
长沙、株洲、湘潭三市土壤中重金属元素的来源   总被引：13，自引：0，他引：13  
为追踪长沙、株洲、湘潭3个城市表层土壤中Cd、As、Pb等重金属元素的来源,分析了土壤、基岩、大气干湿沉降、水、悬浮物等介质之间重金属元素的质量平衡和土壤自身重金属元素含量随时间变化的特点。结果显示,除As外,区内基岩中的重金属元素含量低于克拉克值;残积物中Cd相对基岩贫化,As、Pb、Cu、Hg等重金属元素相对基岩的富集小于3倍;大气干湿沉降重金属元素相对土壤富集了数倍至数十倍;湘江水体主要向沿江潮土提供As、Cd物源:近50年内土壤重金属元素有较高的增加速率。不同介质间重金属元素的质量变化特点支持长沙、株洲、湘潭三市土壤重金属元素富集的主要物源为大气沉降,地表水及悬浮物是沿江湖土重金属元素的主要物源,基岩对土壤提供的物源有限的结论。  相似文献   

10.
三江源地区美丽中国建设存在的问题、成功案例与启示   总被引：1，自引：0，他引：1  
杨建平  康韵婕  唐凡  秦彧 《冰川冻土》2021,43(5):1551-1559
长江、黄河与澜沧江源区（简称三江源区）是中华与亚洲“水塔”,是我国重要的生态安全屏障与水安全保障,是三大河流域经济带的共有源地,稳藏固疆的战略要地,美丽中国建设的战略高地。掌握该地区美丽中国建设进程,发现存在的问题,及时总结典型成功案例,有助于更好建设美丽高原,服务生态文明建设与社会经济高质量发展的全国战略部署。就建设内容与进程看,目前三江源区整体仍处于物质建设阶段,除畜牧业外,缺乏其他产业,忽视文化建设,美丽缺少内涵、不可持续;就建设成效而言,美丽乡村与美丽城镇工程建设成绩显著,但配套设施严重滞后,以及游牧文化与聚落文化的冲突,美丽仍流于形式;尽管存在这些问题,但亦涌现了若干成功案例,“岗龙模式”和“甘达模式”尤为典型,为三江源其他地区美丽中国建设提供了样板与发展启示：（1）找准优势资源,最大化资源潜力、实现经济“美”是高原美丽中国建设成功的物质基础;（2）领导人/团队/致富带头人是高原美丽中国建设成功的关键核心;（3）产业与因地制宜的运作机制是高原美丽中国建设可持续的强大支撑与必由之路;（4）不断探索永远走在发展路上是美丽中国建设成功的坚实动力。  相似文献   

11.
Apatite fission-track (AFT) thermochronological modeling as a diagnostic tool for periods of stability (peneplanation) and tectonic activity (orogeny) has been broadly used in tectonic studies of Central Asia in recent years. We discuss more than 100 AFT ages of samples from the Kyrgyz Tien Shan and Altai and compare them with AFT data from northern Kazakhstan. Geological, geomorphological, and AFT data indicate intense activity in the Late Cenozoic Eurasian continental interior. The impact from the India-Eurasia collision on the northern Tien Shan, Altai, and northern Kazakhstan regions showed up at 11, 5, and 3 Ma, respectively, as a result of stress propagation into the continent, with the ensuing reactivation and mountain growth. We hypothesize that a distant effect of the Late Cenozoic India-Eurasia collision was to rejuvenate Paleozoic fault zones and to deform the Mesozoic sedimentary cover north of the collision front as far as the West Siberian Plate. The reactivation facilitated formation of tectonic oil and gas traps. The activity in northern Central Asia under the effect of the Indian indentation into Eurasia appears to continue and may evolve to include uplift of southern West Siberian plate with uplift.  相似文献   

12.
结合矿物物理化学特征解释了沉积岩中常见的稳定重砂矿物石榴石、锆石、金红石、磷灰石、电气石和榍石的碎屑形态和稳定性;借助扫描电镜下呈现出来的形貌特征,如溶蚀、裂开、圆化程度等,分析了控制稳定重砂矿物蚀变作用的物理化学因素;认为稳定重砂矿物之间的相对稳定性受沉积环境和成岩条件的控制.在同生和成岩过程中,有机酸参与的流体可以改变部分稳定重砂矿物(如磷灰石、石榴石、电气石)的稳定性,并导致其分解,因此稳定重砂矿物的蚀变特征一方面可以辅助解释重砂矿物组合的空间变化,另一方面还可以揭示沉积过程中的气候条件、植被发育程度,从而指示沉积相,并约束成岩过程中流体的化学性质;此外,导致稳定重砂矿物溶蚀的流体对于其他造岩矿物的影响以及对次生孔隙的贡献程度值得进一步研究.  相似文献   

13.
This paper presents a review of the available information on the significant porphyry, epithermal, and orogenic gold districts in Argentina, including the tectonic, geological, and structural settings of large deposits or deposits that have been exploited in the past. Based on this review of the geology and mineralization, targeting models are developed for epithermal and orogenic gold systems, in order to produce GIS-based prospectivity models. Using publically available digital geoscience data, weights of evidence and fuzzy logic prospectivity maps were generated for epithermal and orogenic gold mineralization in Argentina. The results of the prospectivity mapping highlight existing gold deposits within known mineralized districts throughout Argentina, as well as other highly prospective areas with no known deposits within these districts. Additionally, areas within Argentina that have no known gold mineralization (based on publically available information) were highlighted as being highly prospective based on the models used.  相似文献   

14.
Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO2 diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SIcrit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SIcrit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).  相似文献   

15.
丹霞地貌定义、分类及丹霞作用研究   总被引：3，自引：0，他引：3  
丹霞地貌以广东丹霞山最为典型而得名,是一种发育赤壁丹崖群的特殊地貌类型,近年来随着旅游开发不断升温而成为景观地貌学关注的重要对象,但其中一些基本问题长期争论不休。本文从命名地的地质、地貌特征和我国区域地质发展史角度出发,重新厘定了丹霞地貌的定义与分类,强调丹霞地貌的三大基本要素:赤壁丹崖地貌特征、燕山旋回以来陆相红层基础和以流水侵蚀为主的地质营力。西北地区也广泛发育丹霞地貌,一类是黄土覆盖下的古丹霞,另一类是干旱区片流侵蚀和泥乳贴膜的丹霞。丹霞作用是对中新生代陆相碎屑岩经流水侵蚀、重力崩塌和风化剥落等多种地质作用的统称,其产物就是丹霞地貌。岩性控制和崖壁片流垂蚀是丹霞作用的两种特殊机理。红层盆地的沉积相及其岩性差异控制着丹霞地貌的发育及其景观类型,据此在地貌发育的构造、外力和时间三个因素基础上增加了岩性因素。南方典型的红层盆地中,边缘冲积扇相粗碎屑岩地区可经历青年、中年和老年等发展阶段,盆地中央湖泊相泥岩、粉砂岩却没有经历过绝壁陡崖发展阶段。暴雨水流在丹霞崖壁上发生近垂直向下的侵蚀作用叫片流垂蚀作用。其中冲蚀作用形成竖状沟槽、竖状洞穴,涡蚀作用(借助风力吹动发展成垂直崖壁的涡旋)形成圆锥状洞穴、串珠状洞穴,后者使得洞穴沿软弱岩层分布,进一步扩大成扁平状洞穴。这些洞穴形成年代具有垂向一致性,不具有上老下新变化趋势,而在水平方向上,不同部位洞穴的形成年代可能不同。  相似文献   

16.
Subtropical estuaries have received comparatively little attention in the study of nutrient loading and subsequent nutrient processing relative to temperate estuaries. Australian estuaries are particularly susceptible to increased nutrient loading and eutrophication, as 75% of the population resides within 200 km of the coastline. We assessed the factors potentially limiting both biomass and production in one Australian estuary, Moreton Bay, through stoichiometric comparisons of nitrogen (N), phosphorus (P), silicon (Si), and carbon (C) concentrations, particulate compositions, and rates of uptake. Samples were collected over 3 seasons in 1997–1998 at stations located throughout the bay system, including one riverine endmember site. Concentrations of all dissolved nutrients, as well as particulate nutrients and chlorophyll, declined 10-fold to 100-fold from the impacted western embayments to the eastern, more oceanic-influenced regions of the bay during all seasons. For all seasons and all regions, both the dissolved nutrients and particulate biomass yielded N:P ratios <6 and N:Si ratios <1. Both relationships suggest strong limitation of biomass by N throughout the bay. Limitation of rates of nutrient uptake and productivity were more complex. Low C:N and C:P uptake ratios at the riverine site suggested light limitation at all seasons, low N:P ratios suggested some degree of N limitation and high N:Si uptake ratios in austral winter suggested Si limitation of uptake during that season only. No evidence of P limitation of biomass or productivity was evident.  相似文献   

17.
At the Justice mine, in the Ashanti goldfields of southwestern Ghana, chemical weathering of gold- bearing sulfide-rich lodes has produced a series of characteristic mineralogical and geochemical features that are diagnostic. In this type of gold mineralization, the most abundant sulfides are arsenopyrite, pyrite, pyrrhotite, and chalcopyrite with minor bornite and sphalerite. Gold occurs predominantly as native gold, spatially associated and chemically bound with arsenopyrite. Elsewhere gold-silver tellurides are present in quartz veins. During sulfide oxidation, arsenopyrite is replaced by amorphous and crystalline Fe-Mn arsenates, goethite, hematite, and arsenolite in box- and ladderwork textures. In the extremely weathered gossans exposed at surface or in exploration pits, goethite, hematite, and scorodite are present as pseudomorphs of oxidized arsenopyrite, which can be used as a visual pathfinder for gold-arsenic mineralization. As with arsenopyrite, pyrite and pyrrhotite alteration produces boxwork and ladderwork textures with the sulfide replaced by goethite, hematite, and a complex limonite. Copper sulfides and goethite replace bornite and chalcopyrite in ladder-type textures. With more intensive weathering, this assemblage is replaced by cuprite, goethite, and hematite. Gold mineralogy in the gossan is complex, with evidence of in situ precipitation of supergene gold as well as alteration of hypogene native gold. The concentration of pathfinder elements decreases in the gossan as a result of supergene leaching. Mass- balance calculations confirm that gossan production largely is in situ and, consequently, the hypogene geochemical dispersion patterns are preserved even though the proportion of many elements decreases as intensity of weathering increases.

The problem remains of discriminating between auriferous and non-auriferous gossans, or those produced by pedological concentration of iron. Although mineral textures such as box-and ladderwork replacement and mineral pseudomorphs are useful field criteria, the most reliable guide for evaluation still is trace-element geochemistry. By use of multi-element discriminant analysis, gossans of different origins can be distinguished (along with their surface expression) from ironstones and barren lateritic soils. In regional reconnaissance studies, the evaluation of trace-element geochemistry as a discriminant along with field mapping may indicate gold potential of even extremely altered products of mineralization and, in so doing, provide a basis for the classification of weathered samples.  相似文献   

18.
A solution of dilute hydrochloric acid, ascorbic acid, and potassium iodide has been found to dissolve weakly bound metals in soils, stream sediments, and oxidized rocks. Silver, Bi, Cd, Cu, Mo, Pb, Sb, and Zn are selectively extracted from this solution by a mixture of Aliquat 336 (tricaprylyl methyl ammonium chloride) and MIBK (methyl isobutyl ketone). Because potentially interfering major and minor elements do not extract, the organic separation allows interference-free determinations of Ag and Cd to the 0.05 ppm level, Mo, Cu, and Zn to 0.5 ppm, and Bi, Pb, and Sb to 1 ppm in the sample using flame atomic absorption spectroscopy. The analytical absorbance values of the organic solution used in the proposed method are generally enhanced more than threefold as compared to aqueous solutions, due to more efficient atomization and burning characteristics. The leaching and extraction procedures are extremely rapid; as many as 100 samples may be analyzed per day, yielding 800 determinations, and the technique is adaptable to field use.The proposed method was compared to total digestion methods for geochemical reference samples as well as soils and stream sediments from mineralized and unmineralized areas. The partial leach showed better anomaly contrasts than did total digestions. Because the proposed method is very rapid and is sensitive to pathfinder elements for several types of ore deposits, it should be useful for reconnaissance surveys for concealed deposits.  相似文献   

19.
锂矿主要类型、特征、时空分布及找矿潜力分析   总被引：1，自引：0，他引：1       下载免费PDF全文
锂是重要的能源金属,分布高度集中。目前可开发利用的锂矿床主要有盐湖卤水型、伟晶岩型、黏土型、锂沸石型、其他卤水型（包括油气田卤水亚类和地热卤水亚类）和离子吸附型6种类型。除伟晶岩型锂矿的时代呈幕式分布,其他类型的锂矿主要集中形成于新生代。新生代锂矿占全球已查明资源量的75%,主要分布于显生宙造山带如安第斯锂三角地区、中国川藏地区、北美科迪勒拉等地区,其余锂矿则主要分布在前寒武纪克拉通如西澳克拉通、刚果克拉通、西非克拉通和加拿大地盾等区域。盐湖卤水型和伟晶岩型锂矿找矿潜力大,是目前勘探开发的主要类型。  相似文献   

20.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引：25，自引：2，他引：25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

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