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1.
Snow samples collected from a 50 m firn core and two snow pits along the route of the 1996/1997 Chinese First Antarctic Inland Traverse Expedition in Princess Elizabeth Land, East Antarctica, have been analyzed for chemical composition and oxygen isotope ratio. Analyzing the relationship between the concentration and flux of major ions and accumulation rate can draw the following conclusions. 1 ) The concentrations of major ions in the atmosphere in the study region is big enough so that the concentrations of the ions do not vary with snow accumulation rate, that is to say, the concentrations of major chemical species are independent of snow accumulation rate. 2) The results of analyzing the depositional styles of major chemical species suggest that wet deposition dominates the major ions flux. In addition, there is no apparent correlation between nssSO2-4 fluctuations and isotope profile. This would indicate the short-term climatic effect of volcanism is not evident in the region.  相似文献   

2.
Mt. Yulong is the southernmost currently glacier-covered area in Eurasia, including China. There are 19 sub-tropical temperate glaciers on the mountain, controlled by the south-western monsoon climate. In the summer of 1999, a firn core, 10. 10 m long, extending down to glacier ice, was recovered in the accumulation area of the largest glacier, Baishui No. 1. Periodic variations of climatic signals above 7. 8 m depth were apparent, and net accumulation of four years was identified by the annual oscillations of isotopic and ionic composition. The boundaries of annual accumulation were confirmed by higher values of electrical conductivity and pH, and by dirty refreezing ice layers at the levels of summer surfaces. Calculated mean annual net accumulation from 1994/1995 to 1997/1998 was about 900 mm water equivalent. The amplitude of isotopic variations in the profile decreased with increasing depth, and isotopic homogenization occurred below 7. 8 m as a result of meltwater percolation. Variations of δ18O above 7. 8 m showed an approximate correlation with the winter climatic trend at Li Jiang Station, 25 km away. Concentrations of Ca2+ and Mg2+ were much higher than those of Na+ and K+ , indicating that the air masses for precipitation were mainly from a continental source, and that the core material accumulated during the winter period. The close correspondence of C1- and Na+ indicated their common origin. Very low concentrations of SO2-4 and NO3- suggest that pollution caused by human activities is quite low in the area. The mean annual net accumulation in the core and the estimated ablation indicate that the average annual precipitation above the glacier's equilibrium line is 2400 - 3150 mm, but this needs to be confirmed by long term observation of mass balance.  相似文献   

3.
Aerosol samples are collected on the route of the Second Chinese NationalArctic Research Expedition from July 15 to September 28,2003.The concentration ofwater soluble ions(Na~+,NH_4~+,Ca~(2+),Cl~-,MSA,SO_4~(2-)and so on)are ana-lyzed.By correlation analysis,the ions can be divided into three groups:(1)Na~+,Mg~(2+),K~+,Ca~(2+),Cl~-,SO_4~(2-),mainly from sea salt;(2)NH_4~+,NO_3~-,markedlyfrom coastal regions of the continents;(3)Acetate,MSA,C_2O_4~(2-),from othersources.Marine aerosols are the dominant origin,Cl~- and Na~+ are the most domi-nant anion and cation,respectively and these two ions(Na~++Cl~-)account for 55.6% of the total aerosol loading.The mean equivalence ratio of NH_4~+/SO_4~(2-)is 0.45,we suggest that ammonium and sulfate exist mainly as NH_4HSO_4.The concentrationof NO_3~- shows three different patterns on the route of expedition:Japan Sea with me-dian value of 15.2 neq·m~(-3);Sea of Okhostk and Bering Sea of 1.8 neq·m~(-3)andArctic Ocean of 0.4 neq·m~(-3).Bering Sea is a high MSA area.Through the com-parison of the concentration of main water soluble ions between the First and SecondChinese National Arctic Research Expedition,the variation matches each other.  相似文献   

4.
We performed a comparison analysis of the variations .in Mercury ( Hg) concentrations and the precipitation proxies ( e. g. , 18 O values and 10 Be concentrations) in the Dome C ice core. The results showed that there were significant correlations between Hg and δ 10O values, 10Be concentrations, indicating that the accumulation rate in Dome C is one of the key factors controlling the variations of Hg concentrations in the past 34 ,000 years, and implying that Hg concentrations in ice core can be used as another reliable proxy of precipitation rate in Antarctica. Based upon the high-resolution δ 18O values, we estimated the variations in mercury deposition flux to Antarctica over the past 34,000 years. The highest mercury deposition flux is about 3. 80 pg cm-2 yr-1 during the Last Glacial Maxium (LGM) as high as 3. 5 times of the mercury deposition flux ( about 1. 08 pg cm -2 yr -1) in Holocene due to the fluctuations in natural mercury emissions such as the oceanic biological emissions.  相似文献   

5.
IINTRODUCTION been used to Interpret waterqualltycharacteristlcs(SHEN,1994).In fact,the temporal changes of waterSince the 1930s,river water quality has been one quality parameters have ceFtaln re剖larfluctuatlons withof the main topics of water environmental sciences.their own spectrum characteristic and causes.However,Since the 1980s,global change has become the hot spot waterquallty average will lose this statisticall讪matlonOearth science a…  相似文献   

6.
The work presents microparticle concentrations in snowpits from the East Rongbuk Glacier on Mt. Qomolangma (Everest) (ER) (28.02°N, 86.96°E, 6536 m a.s.l.), the Zhadang Glacier on Mt. Nyainqentanglha (NQ) (30.47°N, 90.65°E, 5800m a.s.l.), and the Guoqu Glacier on Mt. Geladaindong (GL) (33.95°N, 91.28°E, 5823m a.s.l.) over the Tibetan Plateau (TP). Variations of microparticle and major ions (e.g. Mg2+, Ca2+) concentrations in snowpits show that the values of the microparticles and ions in the non-monsoon seasons are much higher than those in the monsoon seasons. Annual flux of microparticle deposition at ER is lower than those at NQ and GL, which could be attributed to the long distance away from the possible dust source regions as well as the elevation for ER higher than the others. Compared with other remote areas, microparticle concentrations in the southern TP are much lower than those in the northern TP, but still much higher than those in Greenland and Antarctica. The seasonal and spatial microparticle variations are clearly related to the variations of atmospheric circulation according to the air mass 5-day backward trajectory analyses of HYSPLIT Model. Resultingly, the high microparticle values in snow are mainly attributed to the westerlies and the strong dust storm outbreaks on the TP, while the monsoon circulation brings great amount of precipitation from the Indian Ocean, thus reducing in the aerosol concentrations.  相似文献   

7.
1 Introduction Nowadaysglobalclimatechangehasbeenanimportantissueintheworld.Antarctic areaisjustthekeyandsensitiveregion,fromwhichscientistsaretryingtheirbesttofind theomenofglobalclimatechange.Andfortherevolvingglobalatmosphere,PolarRegions arecoldsource.TheoceanicandatmosphericconditionofPolarRegionsisimportantto globalatmosphericcirculationandclimatechange.Antarcticareaisoneofthecoldsources ofglobalearth atmospheresystem,whileequatorialareaisitsmainheatsource(seeZhou andLuetal.1996).…  相似文献   

8.
1 IntroductionAntarcticicesheetisaburialgroundforatmosphericdeposition .Sincethereiscon tinuousinteractionbetweentheicesheetandtheatmosphere,variousatmosphericsub stancesareinjectedtotheicesheetsequentiallyintimeandspace.Therefore,verticalanalysesoftheicesheetprovideuswithinformationaboutpastclimaticchange (Delmas1 992 ;LegrandandMayewski 1 997)andhorizontalanalysesoftheicesheetprovideuswithknowledgeregardinglong rangetransportofairbornematerials (Kamiyamaetal.1 989;KreutzandMayewski 1 999)…  相似文献   

9.
The changes of plasmalemma permeability and some primary inorganic ions of Antarctic ice microalgae ( Chlamydomonas sp. ICE-L) in the low-temperature stress were examined. The plasmalemma of 1CE-L could maintain the stability at the freezing condition of -6 ℃. That signifies that it could maintain the proper function of plasmalemma and stability of the intracellular environment during sea ice formation. The function of inorganic ions on low-temperature adaptation of ICE-L was investigated by using the X-ray microanalysis method. Low temperature (0 - -6 ℃ ) induces Ca^2 + concentration increment of cytoplasm, but after 24 h the content decrease quickly to normal value. As a matter of fact, Ca^2 + plays an important role as the second messenger in the low temperature adaptation of ICE-L. In addition, low temperature also influences on the other primary inorganic ions transfer and the cell maintains activity by keeping ratio balance among different ions. Above all, it is necessary for Antarctic ice microalgae to survive and breed by maintaining the stability of K^ + content and the balance of Na^ +/Cl^ -.  相似文献   

10.
During CHINARE-22 in austral summer of 2005-2006, a lake sediment core named DG4, which is impacted by penguin droppings, was retrieved from a lake catchment in Gardner Island of Vestfold Hills, East Antarctica. In this study, the concentrations of characteristic elements in the core, local bedrocks and fresh penguin guanos were determined. P, Se, F, S, As, Sr and Cu in DG4 were identified as the bio-element assemblage by R-clustering analysis and compared with those in the local bedrocks and fresh guanos, the results are similar to Y2 in Ardley Island, Antarctic Peninsula. On this basis, P and Se were identified as the optimum bio-elements in DG4 and F, P and S were identified in Y2, respectively. This work will provides the foundation for reconstructing the past penguin populations in Gardner Island of Vest- fold Hills, East Antarctica and comparing the penguin population dynamics between East Antarctica and Antarctic Peninsula.  相似文献   

11.
The concentrations of major elements and some trace elements were determined at 8 core locations in Taihu Lake. The chemical composition of the cores was related to the sediment particle size-chronology and location of sampling site.Concentrations of Al, Mg, K, Ca and Na, the major mineral species in the sediments, were generally uniform, with only slight fluctuation influenced by water waves and current. Surface enrichment of Cu, Zn, and Ni at some locations was observed to be greater than that of the sediments accumulated 100 years ago. The enrichment of these elements is attributed to anthropogenic input in recent years. Concentration profiles for Mn and Fe are related to the migration of these elements in the pore water.  相似文献   

12.
正交试验法在大骨节病区饮水水质研究中的应用   总被引:1,自引:0,他引:1  
本文运用正交试验法对陕西永寿等大骨节病区饮水水质及其与病情间的关系进行了研究和试验,取得了如下初步认识:1)饮用缺乏Mg~(2+)、C1~-、SO_4~(2-)、HCO_3~-、Se、Sr等组分的低矿化度水,是导致大骨节病发生的重要原因。2)水中的Na~++K~+、Mg~(2+)、Ca~(2+);C1~-、SO_4~(2-)、HCO_3~-;可溶性SiO_2、有机耗氧量、矿化度;Sr、Se、Zn等含量(或阴、阳离子毫克当量百分数)的任何一组最优组合,均可用来作为优质水的划分标准。在此基础上,确定出了非致病水的水质标准。文章还对所确定出的非致病水水质标准进行了实际验证。  相似文献   

13.
Hydrochemical characteristics and solute dynamics of bulk meltwater draining from Urumqi Glacier No.1 were investigated in years 2006 and 2007.The glacial meltwater was slightly alkaline with the mean pH of 7.64 and 7.61 in 2006 and 2007,respectively.In the meltwater,the dominant anions were the bicarbonate and sulphate,and the dominant cation was calcium.The concentration of major cations were varied as c(Ca2+) > c(Mg2+) > c(K+) > c(Na+),while the order for the cations was c(HCO3) > c(SO42) > c(NO3) > c(Cl).The total dissolved solids(TDS) in meltwater had inverse relationships with the diurnal discharge.The major ion composition of meltwater was mainly controlled by rock weathering as inferred from the Gibbs model.Furthermore,the ion ratios and Piper diagram indicated that the main processes controlling the meltwater chemistry were carbonate weathering,pyrite weathering and feldspar weathering in rocks,and Ca2+ and HCO3 were the dominant ions during the carbonate weathering process.Solute flux calculation at Glacier No.1 station suggested that chemical denudation rates were 11.46 and 13.90 ton.km 2.yr 1 in 2006 and 2007,respectively.  相似文献   

14.
15.
济南是山东省省会城市,以泉水而闻名,济南泉域位于济南市中部,为掌握济南泉水水质变化情况,根据多年监测的泉水水质资料,采用年度及年内对比方法,分析研究了泉水主要离子多年动态特征及年内变化,研究结果表明,从1984—2013年近30年间,济南泉水主要水质指标呈恶化趋势,主要驱动因素是CO2,SO2-4,Cl-离子含量的增长,其与当地燃煤量持续增长联系密切;而年内主要离子含量动态变化,属短期波动,与泉区排泄点周边的环境影响有关。  相似文献   

16.
In this paper, we use the optimum interpolation sea surface temperature (OISST) provided by the National Center for Environmental Prediction (NCEP) to replace the temperature in the top three layers in the ISHII data, and make use of the modified ISHII temperature data to calculate the thermosteric sea level (called modified steric sea level (SSL) hereafter). We subtract the modified SSL and the steric sea level (called ordinary SSL hereafter) derived from the ISHII temperature and salinity from the steric sea level (SSL) provided by the Gravity Recovery and Climate Experiment (GRACE), respectively, and find that the rms error of the difference of the former is obviously smaller than that of the latter. Therefore we reach the conclusion that under the assumption that the GRACE SSL is accurate, the modified SSL can reflect the true steric sea level more accurately. Making use of the modified SSL, we can find that the modified SSL in sea areas of different spatial scales shows an obvious rising trend in the upper 0-700 m layer for the period 1982-2006. The global mean SSL rises with a rate of 0.6 mm year-1 .The modified SSLs in sea areas of different spatial scales all show obvious oscillations with period of one year. There are oscillations with periods of 4-8 years in global oceans and with periods of 2-7 years in the Pacific. The Empirical Orthogonal Function method is applied to the sea areas of different spatial scales and we find that the first modes all have obvious 1-year period oscillations, the first mode of the global ocean has 4-8 year period oscillations, and that of the Pacific has 2-6 year period oscillations. The spatial distribution of the linear rising trend of the global modified SSL in the upper 0-700 m layer is inhomogeneous with intense regional characteristics. The modified SSL linear trend indicates a zonal dipole in the tropical Pacific, rising in the west and descending in the east. In the North Atlantic, the modified SSL indicates a meridional dipole, rising in the latitude band of 20°N-40°N and 45°N-65.5°N and descending obviously in the latitude band of 40°N-45°N.  相似文献   

17.
Fabric and crystal characteristics of Bohai and Arctic sea ice   总被引:1,自引:0,他引:1  
1 IntroductionBohaione yeariceandAntarcticonehavethesimilarsurface featuresandcorre spondingfabricandcrystalcharacteristics (Allison 1 997;Lietal.1 997;Qin 1 991 ) .DuringtheChinaFirstArcticExpedition ,theresultsinthestudyofone yearicefromBohaiandAntarcticwereusedfo…  相似文献   

18.
Changes in sea surface temperature(SST), seawater oxygen isotope(δ 18 O sw), and local salinity proxy(δ 18 O sw-ss) in the past 155 ka were studied using a sediment core(MD06-3052) from the northern edge of the western Pacifi c Warm Pool(WPWP), within the fl ow path of the bifurcation of the North Equatorial Current. Our records reveal a lead-lag relationship between paired Mg/Ca-SST and δ 18 O during Termination II and the last interglacial period. Similarity in SST between our site and the Antarctic temperature proxy and in CO 2 profi le showed a close connection between the WPWP and the Antarctic. Values of δ 18 O sw exhibited very similar variations to those of mean ocean δ 18 O sw, owing to the past sea-level changes on glacial-interglacial timescale. Calculated values of δ 18 O sw-ss refl ect a more saline condition during high local summer insolation(SI) periods. Such correspondence between δ 18 O sw-ss and local SI in the WPWP may refl ect complex interaction between ENSO and monsoon, which was stimulated by changes in solar irradiance and their infl uence on the local hydrologic cycle. This then caused a striking reorganization of atmospheric circulation over the WPWP.  相似文献   

19.
在内陆干旱区,作为重要饮用水源的地下水常面临氟含量超标问题。查明内陆干旱区高氟地下水的分布规律,了解氟在地下水中的富集过程及其影响因素,既可丰富高氟地下水的研究体系,也是保证内陆干旱区饮水安全的重要基础。以新疆阿克苏地区典型山前洪积扇——依格齐艾肯河-喀拉玉尔滚河河间地带为研究区,基于水文地球化学调查结果,刻画了高氟地下水的分布区;结合氟离子含量与特征性水化学指标间的关系,揭示了高氟地下水的成因机制。结果表明:①地下水中氟含量的变化范围为0.8~6.1 mg/L,83%的水样氟含量超过《生活饮用水卫生标准》(GB 5749-2006)规定的上限(1.0 mg/L);②总体上,氟含量沿地下水流动路径逐渐增大,低氟地下水(ρ(F-)≤1.0 mg/L)分布在国道314以北的补给区,高氟地下水(ρ(F-)>1.0 mg/L)分布在国道314以南的径流区和排泄区;③高氟地下水的水化学类型以Cl·HCO3-Na型为主,而低氟地下水则以Cl·SO4-Na型为主,高氟地下水相比于低氟地下水优势阴离子偏向于HCO3-;④地下水的pH值范围为7.9~8.9(均值为8.4),表明其处于弱碱环境中。地下水中ρ(F-)与pH值呈正相关,此外构成浅层含水层的上更新统沉积物中含有黑云母、氟磷灰石等矿物,其表面存在一定数量的可交换F-,这表明水中OH-与矿物表面F-间的阴离子交换可能对氟的富集有一定贡献;⑤地下水的F-含量与Ca2+含量呈负相关,即高氟地下水中ρ(Ca2+)小于低氟地下水。考虑到氟化钙(CaF2)是自然界中的主要含氟矿物,也是地下水中氟的主要来源,ρ(F-)与ρ(Ca2+)间的这种负相关指示着高氟地下水中可能存在去Ca2+、Mg2+作用,如阳离子交替吸附或碳酸盐岩沉淀等。研究区地下水样中ρ(F-)与ρ(Mg2+)间也呈负相关关系,且和ρ(F-)与ρ(Ca2+)间的关系高度相似,也佐证了高氟地下水中去Ca2+、Mg2+作用的存在;⑥绝大部分地下水样品都位于氯碱性指数图的负值区域,且ρ(F-)与CAI-1和CAI-2均呈较好负相关,CAI-1和CAI-2都随ρ(F-)的增大而减小,这表明高氟地下水中存在Ca2+、Mg2+与Na+间更强的交换作用,对氟富集起着重要作用。地下水中ρ(F-)与SAR间呈较好正相关关系,且高氟地下水样的SAR均值(5.71)远大于低氟地下水SAR均值(1.67),这也进一步证明高氟地下水中的Ca2+、Mg2+与含水介质的Na+间存在强烈的交替作用,对氟的富集起着重要作用;⑦所有地下水样中的萤石均处于未饱和状态,且萤石的饱和指数(SI)与F-含量间呈现较好的正相关,这表明地下水对含氟矿物(主要是萤石)的持续溶解应是导致研究区地下水中氟富集的主要原因。与之相反,研究区所有地下水样中的方解石均处于过饱和状态(SI>0)。这表明CaCO3的沉淀可能促进了CaF2的溶解,导致地下水中氟离子质量浓度增高;⑧研究区低氟地下水的δ18O值介于-11.20‰~-10.67‰间,平均值为-10.94‰,而高氟地下水的δ18O值介于-11.65‰~-11.21‰间,平均值为-11.49‰,即低氟地下水较高氟地下水富集δ18O。此外,F-质量浓度较低(ρ(F-)≤3.0 mg/L)的地下水样中δ18O值与F-质量浓度呈负相关,即低氟地下水具有更正的δ18O值;F-质量浓度较高(ρ(F-)≥4.8 mg/L)的地下水样中δ18O值与F-质量浓度的相关性不显著,随F-质量浓度的增高,δ18O值基本维持不变。以上表明蒸发浓缩作用对地下水中氟的富集贡献较小;⑨研究区地下水中ρ(F-)/ρ(Cl-)比值与ρ(F-)间呈现正相关,即ρ(F-)/ρ(Cl-)比值随ρ(F-)增高呈增大趋势,这也说明地下水中氟富集的主要原因是含氟矿物的溶解,而不是蒸发浓缩作用。此外,Gibbs图也提供了证据:研究区地下水样基本处于水岩作用主导区域,表明地下水化学特征(包括氟的富集)主要受水岩作用控制,蒸发浓缩影响很小。总之,地下水中氟的富集主要由溶解作用引起,OH-与矿物表面F-间的交换也有贡献,但蒸发浓缩作用影响微弱。含氟矿物持续溶解的驱动机制是阳离子交替吸附(地下水中Ca2+与岩土颗粒表面Na+之间)及方解石沉淀所引起的地下水中Ca2+的衰减。   相似文献   

20.
Relevant geological, geographical, archaeological data were collected to study the characteristics of middle Holocene warm period and sea level high on North China coast. Middle Holocene climate and sea level change on North China coast were correlated to warm marine environment events in about 8-3 ka B.E The sea level in about 8 ka B.E was higher than present mean sea level, then fluctuated for 5 000 years and after that it became even in 3 ka B.E The highest sea level occurred in about 6-5 ka B.E; the maximum was about 2-3 m and minimum was about 1-2 m.  相似文献   

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