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1.
The separation and simultaneous determination of the traces of U and Th in seawater by IDMS is described. The detection limits of this method are 2.4×10-9 g for Th and 1.1×10-8 g for U. The concentrations of U and Th in seawater nearby Xiamen were measured, which are 3.20 ppb and 7.73 ppt respectively. The precisions fo the method are ±1.7% for U and ±3.6% for Th respectively. 相似文献
2.
A three-dimensional （3-D） finite volume coastal ocean model （FVCOM） was used for the study of water cir culation and seawater exchange in the Benoa Bay, Bali Island. The M2 tidal component was forced in open boundary and discharge from six rivers was included in the numerical calculation. The M2 tidal elevation produced by the FVCOM has a good agreement with the observation data. The M2 tidal current is also suc cessfully calculated under the ebb tide and flood tide conditions. The non-linear M2 tidal residual current was produced by the coastline geometry, especially surrounding the narrow strait between the Serangan Is- land and the Benoa Peninsula. The tidal residual current also generated two small eddies within the bay and one small eddy in the bay mouth. The salinity distribution influenced by river discharge could be success- fully calculated, where the numerical calculation and the observation results have a good correlation （r2） of 0.75. Finally in order to examine the seawater exchange in the Benoa Bay, the Lagrangian particle tracking method and calculation of residence time are applied. The mechanism of particle transport to the flushing of seawater is depicted clearly by both methods. 相似文献
3.
An analytical method is proposed for the direct determination of Cd in seawater by differential pulse anodic stripping voltammetry and the derivative technique with a hanging mercury drop electrode. The process of determination is quick, simple and convenient. The concentration of Cd in seawater is only determined by adjusting the acidity of seawater to pH 2 and by taking three minutes' plating time. Sensitivity of the method is about 1×10-10M, and accuracy of that satisfactory. Relative standard deviation is about 12% when the concentration of Cd in seawater is approximately 0.04 ppb. A good agreement was obtained by a standard curve and a standard addition technique respectively from determining Cd in the same seawater. Actual measurement time per sample is about 10 min. 相似文献
4.
The transfer of 137C3, 60Co along Platymonas sp., Brachionus plieatilis Muller and Tilapia mos-sambica Peters was studied by using the tracer methods of both 137C3 and 60Co with Ge (Li) Gamma ray detector and S-80 type multichannel-analyser for measuring the radioactivity of the sample. The experiment was carried out in four groups and the period of the experiment was fifteen days. It was found that 60Co could be transferred along seawater→Platymonas→Brackionus→Tilapia, and that 137C3 could only be transferred from seawater to Platymonas. 137C3 was not accumulated by Brachionus in any group of the experiment. Brachionus ingested 60Co mainly from Platymonas, when 60Co was ingested by Tilapia; Brachionus played an important role in the transfer and the Tilapia ingested 137C3 mainly from seawater. 相似文献
5.
O-phthaldialdehyde is used for the determination of free amino acid in seawater by measuring the fluorescence produced by its reaction with the a-amino group of amino acids. This method is so sensitive that as little as 1-10 nM of amino acids and less than 1 ml of seawater may be sufficient for one test.This method is simple, rapid and accurate and a-amino acids contained in seawater can directly be determined without concentration and extraction. It is free from the interference of large content of inorganic salts and other nitrogenous compounds in seawater.A hundred and fifty-two samples collected at 24 stations in offshore of Zhejiang have been analyzed. The results obtained show that the range of concentration of the total free amino acid is 0.37-4.70 μM. The values are high near shore and low offshore. 相似文献
6.
Hydraulic transport in pipelines is the most promising conveying method for large ore particles in deepsea mining.The dynamic performances of particles during transportation in vertical,inclined and horizontal pipelines are significant for the design of hydraulic transport systems.In the present study,we focus on the statistical characteristics and flow regimes of the mixture composed of ore particles and seawater in the pipelines.Numerical simulations are conducted by using Computational Fluid ... 相似文献
7.
The adsorption behaviour for uranium of four kinds of amidoxime resinst RNH, RCH, RAH and RPH in seawater has been investigated. It has been found that all these resins are capable of adsorbing rapidly uranium from U-cnriched seawater with a high uranium uptake.RNH was able to adsorb uranium satisfactorily from natural seawater, and the uranium uptake of RNH with a degree of cross-linking of 3-5 mol % was above 200 μg/g-R (adsorption for 15 days). The uranium uptakes of RCH, RAH and RPH from natural seawater were much lower than the uranium uptake of RNH. The factors which caused the difference between resins RCH, RAH, RPH and resin RNH are discussed. 相似文献
8.
AN ECOSYSTEM MODEL ANALYSIS OF THE EFFECT OF MINE TAILINGS ON THE EUPHOTIC ZONE OF A PELAGIC ECOSYSTEM 总被引：1，自引：0，他引：1
A computer analysis was performed on experimental results obtained when mine tailings were added to seawater. The Mixed Upper-Layer Ecotrophie Simulation (MULES) model was tested by changing the extinction coefficient and the abundance of heterotrophic zooflagellates. Increasing the extinction coefficient resulted in a delay of phytoplankton growth, an increase in zooplankton standing stock and better growth of autotrophic flagellates compared with diatoms. Zooflagellates in the ecosystem influence the growth of zooplankton; secondary production by zooplankton was markedly depressed at low levels of zooflagellates. These results are believed to be of general significance for the diagnosis of suspended sediment effects on planktonic ecosystems. 相似文献
9.
DIRECT AND SIMULTANEOUS DETERMINATION OF Zn, Cd, Pb, Cu and Bi IN SEAWATER BY DERIVATIVE-VOLTAMMETRY
吕荣辉 《海洋学报(英文版)》1985,4(4):557-563
This paper suggests direct and simultaneous determinations of the reducible species of Zn, Cd, Pb, Cu and Bi in seawater made by the derivative-differential pulse anodic stripping voltammetry with a hung mercury drop electrode. The influence of Cu on the determination of Zn in this experiment condition has been studied, of which both the accuracy and precision are satisfactory. The procedure of determination is so quick, simple and convenient that the background concentration of these five elements in coastal seawaters can be determined only by adjusting the acidity of seawater to pH 2.5 and by taking 10-minutes plating time. Actual measurement time of these five elements for every sample is approximately 25 min. 相似文献
10.
Transfer rule of 137C3 and 60Co in seawater and an arrificial food web which made up of Platy-monas, Arca, tenaeus and Tilapia were studied.The results showed that the transfer of nuclide could be realized in a longer food chain in which seawater contained radioactivity, the transfer along food chain alone was slight, the pathway of nuclide uptaken by organism was mainly from seawater,but the pressnce of the food was helpful to the transfer of the nuclide, the transfer efficiency of 60Co by every member in the marine food chain was greater than that of 137C3. 相似文献
11.
宁修仁 《海洋学报(英文版)》1983,2(1):165-165
A comparative study using fluorometry on 6 types of filters for the determination ofChl a in seawater was carried out. The results show that whatman GF/C glass fiber filterwith a layer of MgCO_3 is the best among them. The values of Chl a obtained by thisway were not only higher, but transparency of extracts was also better than that by otherfilters. The sensitivity of fluorometry was much higher than that of spectrophotometry, sothat only small amount of seawater was enough. Furthermore, the grinding and centrifuga-tion can be eliminated, so the procedure is much simplified and is suitable to be used onboard ship. 相似文献
12.
As a conservative tracer, oxygen isotopes in seawater are widely used for water mass analysis, along with temperature and salinity. In this study, seawater oxygen-18 datasets in the Canada Basin during 1967–2010 were obtained from the four cruises of the Chinese National Arctic Research Expedition(1999, 2003, 2008, and 2010) and the NASA database. Fractions of sea ice meltwater and river runoff were determined from the salinity-18O system. Our results showed that the river runoff decreased from the south to the north in the Canada Basin. The enhanced amount of river runoff observed in the southern Canada Basin may originate from the Mackenzie River, transported by the Beaufort Gyre. The river runoff component showed maximum fractions during 1967–1969, 1978–1979, 1984–1985, 1993–1994, and 2008–2010, indicating the refresh time of the river runoff was 5.0–16.0 a in the Canada Basin. The temporal variation of the river runoff was related to the change of the Arctic Oscillation(AO) index, suggesting the freshwater stored in the Canada Basin was affected by surface sea ice drift and water mass movement driven by atmospheric circulation. 相似文献
13.
Ferromanganese(Fe-Mn) crusts are potential archives of the Cu and Zn isotope compositions of seawater through time. In this study, the Cu and Zn isotopes of the top surface of 28 Fe-Mn crusts and 2 Fe-Mn nodules were analysed by MC-ICP-MS using combined sample-standard bracketing for mass bias correction. The Zn isotope compositions of the top surface of Fe-Mn crusts are in the range of 0.71‰ to 1.08‰, with a mean δ~(66) Zn value of 0.94‰±0.21‰(2 SD, n=28). The δ~(65) Cu values of the top surface of Fe-Mn crusts range from 0.33‰ to0.73‰, with a mean value of 0.58‰±0.20‰(2 SD, n=28). The Cu isotope compositions of Fe-Mn crusts are isotopically lighter than that of dissolved Cu in deep seawater(0.58‰ vs. 0.9‰). In contrast, the δ~(66) Zn values of Fe-Mn crusts appear to be isotopically heavy compared to deep seawater(0.94‰±0.21‰ vs. 0.51‰±0.14‰). The isotope fractionation between Fe-Mn crusts and seawater is attributed to equilibrium partitioning between the sorption to crusts and the organic-ligand-bound Cu and Zn in seawater. The Cu and Zn isotopes in the top surface of Fe-Mn crusts are not a direct reflection of the Cu and Zn isotopes, but a function of Cu and Zn isotopes in modern seawater. This study proposes that Fe-Mn crusts have the potential to be archives for paleoceanography through Cu and Zn isotope analysis. 相似文献
14.
廖先贵 《海洋学报(英文版)》1986,5(2):215-219
This paper deals with the geochemical characteristics of arsenic in sediments from Bohai Gulf. The arsenic in seawater, surface sediments and cores is determined. Also measured are other physical and chemical parameters, such as Ni, Fe, C, pH and Eh in sediments. The values of As range from 0.6 to 4.5 ppb in seawater, from 10.0 to 20.9 ppm in surface sediments and from 6.8 to 22.8 ppm in cores.The contents of As from south are higher than those from north. However the As in sediments is the element not affected by pollution.The adsorption and codeposition of Ferric oxide colloid are the major form of transference of As from seawater to sediments in Bohai Gulf.The valence state of As in sediments is HAsO42- 相似文献
15.
The methods of ion exchange-elcctrodcposition, ion exchange-precipitation for source-making, and for determining 65Zn in marine environment have been studied in detail. The chemical and radiochemical yields are 90% for organism and sediment, and 85% for seawater. They have good repeatability with a precision of 3%. The decontamination factors for radioactive nuclides are larger than 103. The preconcentration of seawater and the electrode position for source-making are significantly improved and can be used on thin and even source-measucing, applicable to low background β counting. 相似文献
16.
Dimethylsulfide(DMS) is generally thought to be lost from the surface oceans by evasion into the atmosphere as well as consumption by microbe.However,photochemical process might be important in the removal of DMS in the oceanic photic zone.A kinetic investigation into the photochemical oxidation of DMS in seawater was performed.The photo-oxidation rates of DMS were influenced by various factors including the medium,dissolved oxygen,photosensitizers,and heavy metal ions.The photo-oxidation rates of DMS were higher in seawater than in distilled water,presumably due to the effect of salinity existing in seawater.Three usual photosensitizers(humic acid,fulvic acid and anthroquinone),especially in the presence of oxygen,were able to enhance the photo-oxidation rate of DMS,with the fastest rate observed with anthroquinone.Photo-oxidation of DMS followed first order reaction kinetics with the rate constant ranging from 2.5×10-5 to 34.3×10-5 s-1.Quantitative analysis showed that approximately 32% of the photochemically removed DMS was converted to dimethylsulfoxide.One of the important findings was that the presence of Hg2 could markedly accelerate the photo-oxidation rate of DMS in seawater.The mechanism of mercuric catalysis for DMS photolysis was suggested according to the way of CTTM(charge transfer to metal) of DMS-Hg2 complex. 相似文献
17.
Hydrothermal chimney is a product of hydrothermal activity on the seabed. Chimney samples dredged from Jade hydrothermal area in Izena depression of the Okinawa Trough, are characterized by relatively enriched light rare earth elements (LREE) and strongly positive Eu anomalies. ^87Sr/^86Sr and ^143Nd/^144Nd of these samples are exactly between those of seawater and of acidic pumice, averaged at 0.708928 and 0.512292, respectively. These characteristics imply that the main source of hydrothermal sulfide at Jade area is possibly the undersurface acidic rocks. The mineralizing mechanism can be summarized as follows: Large amount of mineralized material would be leached out and LREE-enriched hydrothermal solution would be subsequently produced as a result of thermo-chemical exchange reaction between acidic volcanic rocks and heated seawater that penetrated in advance from upper water mass. The spurting out from the seabed and quickly crystallizing in the seawater of hydrothermal solution are responsible for the formation of Cu-Zn sulfide and barite-amorphous SiO2 minerals that are characterized by enriched LREE and positively strong Eu anomalies. 相似文献
18.
This paper explores the accumulations ana distributions of Cd, Pb and Cu in clam Area granosa through determining their contents in Dlood and soft parts. The results show an order of concentration factors for these metals therein as: Cd>Cu>Pb; the values of concentration factors and the patterns of distribution are similar for Cu and Pb but different from Cd. Concentration factors in blood can reflect the enrichement abilities of soft parts. Exposure experiments have indicated that the Pb level in blood is controlled by Pb concentrations in surrouding seawater, changing with time, that the Pb cocentration causing poisoning in the seawater is 1-100 μg/1, and that the Pb content in blood and soft parts of Area granosa increases with that of Pb increasing in seawater. There exist relationships of double logatithmic concentrations for Pb among the three mediums. 相似文献
19.
The pathway by which "Co and 137C3 got into Area, and the type of uptake in animal were studied. The results showed that 60Co was taken up by gill and was transferred quickly to other organs through blood. There are more uptake pathways for 137Cs. The uptake of 60Co by Arca was mainly active transfer and the energy comes mainly from the process of biotic oxidation. On the contrary, the uptake of 137C3 by Arca was mainly a passive transfer, and for most organs the exchange through body-wall was a significant factor. 相似文献
20.
To find out the decay character of residual chlorine (RC) in the sea water, the concentration of RC was analyzed by N, N-diethyl-p-phenylenediamine (DPD) method under different simulation experimental conditions, in which salinity, temperature, and Chemical Oxygen Demand (COD) were selected. The water used in the experiment was the mixture of aging ocean water, coastal water and extracting solution of coastal sediment at appropriate level. Results are shown as follows:(1) Piecewise function can well reflect the decay dynamics of RC in the cooling seawater. Concretely, the decay dynamics of first 1 min is too rapid to ascertain using a specific kinetic function, and that of the time from 1 to 30 min is fit for the first-order kinetic model. (2) The results could be the foundation of the chemical behavior of RC in seawater, and be used as not only the guidance of the coastal power plants production and sea water desalting companies, but also the establishment of the correlative trade standard. 相似文献