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1.
The relative nucleus density (RND) model of dynamically recrystallized grain size [Sakai, T., Jonas, J.J. 1984. Dynamic recrystallization: mechanical and microctructutal consideration. Acta metallurgica, 32, 198–209] was applied to experimentally and to naturally deformed marbles that have undergone dynamic recrystallization. The model shows that a relationship between initial grain size (D0) and stable dynamically recrystallized grain size (DS) for a given value of temperature-corrected strain-rate (Z) controls grain size evolution during dynamic recrystallization. New microstructural mechanism maps (MM-maps) for experimentally and naturally deformed marbles (based on previously published data) were defined in log grain size–log Z space and show two distinct regions of grain reduction and grain coarsening. The boundary between these two regions corresponds to an equation relating dynamically recrystallized grain size and temperature corrected strain rate, as proposed in this work. The new MM-map was used to trace semi-quantitatively microstructural and grain size evolution in naturally deformed marbles that underwent dynamic recrystallization at different thermal conditions. The boundary between grain coarsening and grain reduction does not necessarily coincide with the boundary between rotation and migration recrystallization mechanisms. Assessment of available natural data shows that the boundary condition D0 = 2DS between grain-coarsening and grain-reduction introduced by Sakai and Jonas [Sakai, T., Jonas, J.J. 1984. Dynamic recrystallization: mechanical and microctructutal consideration. Acta metallurgica, 32, 198–209] is not required for naturally deformed marble.  相似文献   

2.
It is often observed that dynamic recrystallization results in a recrystallized grain size distribution with a mean grain size that is inversely related to the flow stress. However, it is still open to discussion if theoretical models that underpin recrystallized grain size–stress relations offer a satisfactorily microphysical basis. The temperature dependence of recrystallized grain size, predicted by most of these models, is rarely observed, possibly because it is usually not systematically investigated. In this study, samples of wet halite containing >10 ppm water (by weight) were deformed in axial compression at 50 MPa confining pressure. The evolution of the recrystallized grain size distribution with strain was investigated using experiments achieving natural strains of 0.07, 0.12 and 0.25 at a strain rate of 5×10−7 s−1 and a temperature of 125 °C. The stress and temperature dependence of recrystallized grain size was systematically investigated using experiments achieving fixed strains of 0.29–0.46 (and one to a strain of 0.68) at constant strain rates of 5×10−7–1×10−4 s−1 and temperatures of 75–240 °C, yielding stresses of 7–22 MPa. The microstructures and full grain size distributions of all samples were analyzed. The results showed that deformation occurred by a combination of dislocation creep and solution-precipitation creep. Dynamic recrystallization occurred in all samples and was dominated by fluid assisted grain boundary migration. During deformation, grain boundary migration results in a competition between grain growth due to the removal of grains with high internal strain energy and grain size reduction due to grain dissection (i.e. moving boundaries that crosscut or consume parts of neighbouring grains). At steady state, grain growth and grain size reduction processes balance, yielding constant flow stress and recrystallized grain size that is inversely related to stress and temperature. Evaluation of the recrystallized grain size data against the different models for the development of mean steady state recrystallized grain size revealed that the data are best described by a model based on the hypothesis that recrystallized grain size organizes itself in the boundary between the (grain size sensitive) solution-precipitation and (grain size insensitive) dislocation creep fields. Application of a piezometer, calibrated using the recrystallized grain size data, to natural halite rock revealed that paleostresses can vary significantly with temperature (up to a factor of 2.5 for T=50–200 °C) and that the existing temperature independent recrystallized grain size–stress piezometer may significantly underestimate flow stresses in natural halite rock.  相似文献   

3.
Near the eastern end of the Tonale fault zone, a segment of the Periadriatic fault system in the Italian Alps, the Adamello intrusion produced a syn-kinematic contact aureole. A temperature gradient from 250 to 700 °C was determined across the Tonale fault zone using critical syn-kinematic mineral assemblages from the metasedimentary host rocks surrounding deformed quartz veins. Deformed quartz veins sampled along this temperature gradient display a transition from cataclasites to mylonites (frictional–viscous transition) at 280±30 °C. Within the mylonites, zones characterized by different dynamic recrystallization mechanisms were defined: Bulging recrystallization (BLG) was dominant between 280 and 400 °C, subgrain rotation recrystallization (SGR) in the 400–500 °C interval, and the transition to dominant grain boundary migration recrystallization (GBM) occurred at 500 °C. The microstructures associated with the three recrystallization mechanisms and the transitions between them can be correlated with experimentally derived dislocation creep regimes. Bulk texture X-ray goniometry and computer-automated analysis of preferred [c]-axis orientations of porphyroclasts and recrystallized grains are used to quantify textural differences that correspond to the observed microstructural changes. Within the BLG- and SGR zones, porphyroclasts show predominantly single [c]-axis maxima. At the transition from the SGR- to the GBM zone, the texture of recrystallized grains indicates a change from [c]-axis girdles, diagnostic of multiple slip systems, to a single maximum in Y. Within the GBM zone, above 630±30 °C, the textures also include submaxima, which are indicative of combined basal a- and prism [c] slip.  相似文献   

4.
Microstructures and quartz c-axis fabrics were analyzed in five quartzite samples collected across the eastern aureole of the Eureka Valley–Joshua Flat–Beer Creek composite pluton. Temperatures of deformation are estimated to be 740±50 °C based on a modified c-axis opening angle thermometer of Kruhl (J. Metamorph. Geol. 16 (1998) 142). In quartzite layers located closest (140 m) to the pluton-wall rock contact, flattened detrital grains are plastically deformed and partially recrystallized. The dominant recrystallization process is subgrain rotation (dislocation creep regime 2 of Hirth and Tullis (J. Struct. Geol. 14 (1992) 145)), although grain boundary migration (dislocation creep regime 3) is also evident. Complete recrystallization occurs in quartzite layers located at a distance of 240 m from the contact, and coincides with recrystallization taking place dominantly through grain boundary migration (regime 3). Within the quartzites, strain is calculated to be lowest in the layers closest to the pluton margin based on the aspect ratios of flattened detrital grains.The c-axis fabrics indicate that a slip operated within the quartzites closest to the pluton-wall rock contact and that with distance from the contact the operative slip systems gradually switch to prism [c] slip. The spatial inversion in microstructures and slip systems (apparent “high temperature” deformation and recrystallization further from the pluton-contact and apparent “low temperature” deformation and recrystallization closer to the pluton-contact) coincides with a change in minor phase mineral content of quartzite samples and also in composition of the surrounding rock units. Marble and calc-silicate assemblages dominate close to the pluton-wall rock contact, whereas mixed quartzite and pelite assemblages are dominant further from the contact.We suggest that a thick marble unit located between the pluton and the quartzite layers acted as a barrier to fluids emanating from the pluton. Decarbonation reactions in marble layers interbedded with the inner aureole quartzites and calc-silicate assemblages in the inner aureole quartzites may have produced high XCO2 (water absent) fluids during deformation. The presence of high XCO2 fluid is inferred from the prograde assemblage of quartz+calcite (and not wollastonite)+diopside±K-feldspar in the inner aureole quartzites. We suggest that it was these “dry” conditions that suppressed prism [c] slip and regime 3 recrystallization in the inner aureole and resulted in a slip and regime 2 recrystallization, which would normally be associated with lower deformation temperatures. In contrast, the prograde assemblage in the pelite-dominated outer part of the aureole is biotite+K-feldspar. These “wet” pelitic assemblages indicate fluids dominated by water in the outer part of the aureole and promoted prism [c] slip and regime 3 recrystallization. Because other variables could also have caused the spatial inversion of c-axis fabrics and recrystallization mechanisms, we briefly review those variables known to cause a transition in slip systems and dislocation creep regimes in quartz. Our conclusions are based on a small number of samples, and therefore, the unusual development of crystal fabrics and microstructures in the aureole to the EJB pluton suggests that further study is needed on the effect of fluid composition on crystal slip system activity and recrystallization mechanisms in naturally deformed rocks.  相似文献   

5.
The electron backscattering diffraction technique (EBSD) was used to analyze bulging recrystallization microstructures from naturally and experimentally deformed quartz aggregates, both of which are characterized by porphyroclasts with finely serrated grain boundaries and grain boundary bulges set in a matrix of very fine recrystallized grains. For the Tonale mylonites we investigated, a temperature range of 300–380 °C, 0.25 GPa confining pressure, a flow stress range of ~ 0.1–0.2 GPa, and a strain rate of ~ 10− 13 s− 1 were estimated. Experimental samples of Black Hills quartzite were analyzed, which had been deformed in axial compression at 700 °C, 1.2–1.5 GPa confining pressure, a flow stress of ~ 0.3–0.4 GPa, a strain rate of ~ 10− 6 s− 1, and to 44% to 73% axial shortening. Using orientation imaging we investigated the dynamic recrystallization microstructures and discuss which processes may contribute to their development. Our results suggest that several deformation processes are important for the dismantling of the porphyroclasts and the formation of recrystallized grains. Grain boundary bulges are not only formed by local grain boundary migration, but they also display a lattice misorientation indicative of subgrain rotation. Dynamic recrystallization affects especially the rims of host porphyroclasts with a hard orientation, i.e. with an orientation unsuitable for easy basal slip. In addition, Dauphiné twins within porphyroclasts are preferred sites for recrystallization. We interpret large misorientation angles in the experimental samples, which increase with increasing strain, as formed by the activity of fluid-assisted grain boundary sliding.  相似文献   

6.
Grain boundary migration between strained, substructured grains and newly appearing, strain free grains has been observed during static in-situ annealing of pre-deformed rocksalt in the SEM. With increasing temperature (T) the migration velocity increases and the character of grain boundary migration changes. As temperature increases there is an increase in the length of individual migrating boundary segments that move at similar rates. In addition, the frequency of migrating boundaries that form traces of a {100} boundary plane of at least one of the crystals involved increases, and moving grain boundaries between new and old grains change from highly irregular to smooth, straight boundaries. At the same time there is a decrease in the influence of the substructure of pre-existing strained grains on the grain boundary movement. Resultant microstructures reflect these changes. At  325–350 °C, the deformed-then-annealed microstructure is characterized by very irregular grain boundaries, a high abundance of 5–50 m scale remnants of old, substructured grains within new grains, giving a poikilitic microstructure. At  350–400 °C, grain boundaries often exhibit elongate embayments into the strained grains and most remnants of old, strained grains are located at former grain boundaries. At > 400 °C, grain boundaries between new and old, strained grains are straight to smoothly curved.The grain boundary velocity observations are explained by the effect of temperature on mobility coupled with local driving force variations. Additionally, at low annealing temperature, impurity (solute) drag and driving-force variations are influential, while at high temperature the anisotropy in grain boundary energy with crystallographic orientation becomes more important. Transferring the knowledge from our experiments to geological samples enables us to recognize and interpret similar microstructures in rocks, thereby making it is possible to relate microstructural characteristics to the pre-annealing and post-deformational annealing history.  相似文献   

7.
Fast diffusion along mobile grain boundaries in calcite   总被引：1，自引：0，他引：1  
Experimental measurements of grain boundary diffusion are usually conducted on static boundaries, despite the fact that grain boundaries deep in the Earth are frequently mobile. In order to explore the possible effect of boundary mobility on grain boundary diffusion rates we have measured the uptake of 44Ca from a layer of 44Ca-enriched calcite powder during the static recrystallization of a single crystal of calcite at 900°C. A region about 500 μm wide adjacent to the powder layer is heterogeneously enriched in 44Ca, and complex zoning patterns, including sharp steps in composition and continuous increases and decreases in 44Ca content, are developed. In metamorphic rocks, these would normally be interpreted in terms of changes in pressure or temperature, Rayleigh fractionation, or episodic fluid infiltration. These explanations cannot apply to our experiments, and instead the zoning patterns are interpreted as being due to variations in grain boundary migration rate. We have applied an analytical model which allows the product of grain boundary diffusion coefficient and grain boundary width (D GB δ) to be calculated from the grain boundary migration rate and the compositional gradient away from the powder layer. The value of D GB δ in the mobile grain boundaries is at least five orders of magnitude greater than the published value for static boundaries under the same conditions. In order to allow the scale of chemical equilibrium (and hence textural evolution) to be predicted under both experimental and geological conditions, we present quantitative diffusion-regime maps for static and mobile boundaries in calcite, using both published values and our new values for grain boundary diffusion in mobile boundaries. Enhanced diffusion in mobile boundaries has wide implications for the high temperature rheology of Earth materials, for geochronology, and for interpretations of the length- and time-scales of chemical mass-transport. Moreover, zones of anomalously high electrical conductivity in the crust and mantle could be regions undergoing recrystallization such as active shear zones, rather than regions of anomalous mineralogy, water- or melt-content as is generally suggested.  相似文献   

8.
A microstructural analysis was carried out on mylonitic rocks of the Azul megashear zone (AMSZ), Tandilia, which were formed in a range of metamorphic conditions from lower greenschist to amphibolite facies. Tailed porphyroclasts are common and mostly symmetric. Scarce asymmetric rotated porphyroclasts show both sinistral and dextral senses of shear. In sections parallel to the mylonitic foliation, porphyroclasts are round. The AMSZ is probably related to the late Transamazonian orogenic cycle and may be due to NNE–SSW-directed convergence. In weakly deformed protolith and protomylonites, quartz deforms by dynamic recrystallization, mainly subgrain rotation in dislocation creep Regime 2. K-feldspar porphyroclasts and plagioclase show scarce fracturation and deform by dynamic recrystallization along grain boundaries. Quartz microstructures in mylonites indicate predominantly Regime 3 grain boundary migration recrystallization. Feldspar structures indicate recrystallization through the nucleation and growth of new grains at grain boundaries. The temperatures of deformation from mineral assemblages in the CNKFMASH system in four bulk compositions are in the range of 400–450 °C, and the pressures are more than 6 kb.  相似文献   

9.
Part I of this contribution (Gardés et al. in Contrib Mineral Petrol, 2010) reported time- and temperature-dependent experimental growth of polycrystalline forsterite-enstatite double layers between single crystals of periclase and quartz, and enstatite single layers between forsterite and quartz. Both double and single layers displayed growth rates decreasing with time and pronounced grain coarsening. Here, a model is presented for the growth of the layers that couples grain boundary diffusion and grain coarsening to interpret the drop of the growth rates. It results that the growth of the layers is such that (Δx)2 ∝ t 1−1/n , where Δx is the layer thickness and n the grain coarsening exponent, as experimentally observed. It is shown that component transport occurs mainly by grain boundary diffusion and that the contribution of volume diffusion is negligible. Assuming a value of 1 nm for the effective grain boundary width, the following Arrhenius laws for MgO grain boundary diffusion are derived: log D gb,0Fo (m2/s) = −2.71 ± 1.03 and E gbFo = 329 ± 30 kJ/mol in forsterite and log D gb,0En (m2/s) = 0.13 ± 1.31 and E gbEn = 417 ± 38 kJ/mol in enstatite. The different activation energies are responsible for the changes in the enstatite/forsterite thickness ratio with varying temperature. We show that significant biases are introduced if grain boundary diffusion-controlled rim growth is modelled assuming constant bulk diffusivities so that differences in activation energies of more than 100 kJ/mol may arise. It is thus important to consider grain coarsening when modelling layered reaction zones because they are usually polycrystalline and controlled by grain boundary transport.  相似文献   

10.
The mylonitization of the Pankenushi gabbro in the Hidaka metamorphic belt of central Hokkaido, Japan, occurred along its western margin at ≈600 MPa and 660–700 °C through dynamic recrystallization of plagioclase and a retrograde reaction from granulite facies to amphibolite facies (orthopyroxene + clinopyroxene + plagioclase + H2O = hornblende + quartz). The reaction produced a fine-grained (≤100 μm) polymineralic aggregate composed of orthopyroxene, clinopyroxene, quartz, hornblende, biotite and ilmenite, into which strain is localized. The dynamic recrystallization of plagioclase occurred by grain boundary migration, and produced a monomineralic aggregate of grains whose crystallographic orientations are mostly unrelated to those of porphyroclasts. The monomineralic plagioclase aggregates and the fine-grained polymineralic aggregates are interlayered and define the mylonitic foliation, while the latter is also mixed into the former by grain boundary sliding to form a rather homogeneous polymineralic matrix in ultramylonites. However in both mylonite and ultramylonite, plagioclase aggregates form a stress-supporting framework, and therefore controlled the rock rheology. Crystal plastic deformation of pyroxenes and plagioclase with dominant (100)[001] and (001)1/2 slip systems, respectively, produced distinct shape- and crystallographic-preferred orientations of pyroxene porphyroclasts and dynamically recrystallized plagioclase grains in both mylonite and ultramylonite. Euhedral to subhedral growth of hornblende in pyroxene porphyroclast tails during the reaction and its subsequent rigid rotation in the fine-grained polymineralic aggregate or matrix produced clear shape- and crystallographic-preferred orientations of hornblende grains in both mylonite and ultramylonite. In contrast, the dominant grain boundary sliding of pyroxene and quartz grains in the fine-grained polymineralic aggregate of the mylonite resulted in their very weak shape- and crystallographic-preferred orientations. In the fine-grained polymineralic matrix of the ultramylonite, however, pyroxene and quartz grains became scattered and isolated in the plagioclase aggregate so that they were crystal-plastically deformed leading to stronger shape- and crystallographic-preferred orientations than those seen in the mylonite.  相似文献   

11.
The combination of cathodoluminescence (CL) analysis, temperature and temperature–time calculations, and microstructural numerical modelling offers the possibility to derive the time-resolved evolution of a metamorphic rock. This combination of techniques is applied to a natural laboratory, namely the Ballachulish contact aureole, Scotland. Analysis of the Appin Quartzite reveals that the aureole was produced by two distinct magmatic events and infiltrated by associated fluids. Developing microstructures allow us to divide the aureole into three distinct regions. Region A (0–400?m, 663°C?<?T max?<?714°C) exhibits a three-stage grain boundary migration (GBM) evolution associated with heating, fluid I and fluid II. GBM in region B (400–700?m, 630°C?<?T max?<?663°C) is associated with fluid II only. Region C (>700?m of contact, T max?<?630°C) is characterised by healed intragranular cracks. The combination of CL signature analysis and numerical modelling enables us to recognise whether grain size increase occurred mainly by surface energy-driven grain growth (GG) or strain-induced grain boundary migration (SIGBM). GG and SIGBM result in either straight bands strongly associated with present-day boundaries or highly curved irregular bands that often fill entire grains, respectively. At a temperature of ~620°C, evidence for GBM is observed in the initially dry, largely undeformed quartzite samples. At this temperature, evidence for GG is sparse, whereas at ~663°C, CL signatures typical for GG are commonplace. The grain boundary network approached energy equilibrium in samples that were at least 5?ka above 620°C.  相似文献   

12.
The polyphase evolution of the Seridó Belt (NE-Brazil) includes D1 crust formation at 2.3–2.1 Ga, D2 thrust tectonics at 1.9 Ga and crustal reworking by D3 strike-slip shear zones at 600 Ma. Microstructural investigations within mylonites associated with D2 and D3 events were used to constrain the tectono-thermal evolution of the belt. D2 shear zones commenced at deeper crustal levels and high amphibolite facies conditions (600–650 °C) through grain boundary migration, subgrain rotation and operation of quartz c-prism slip. Continued shearing and exhumation of the terrain forced the re-equilibration of high-T fabrics and the switching of slip systems from c-prism to positive and negative a-rhombs. During D3, enhancement of ductility by dissipation of heat that came from syn-D3 granites developed wide belts of amphibolite facies mylonites. Continued shearing, uplift and cooling of the region induced D3 shear zones to act in ductile-brittle regimes, marked by fracturing and development of thinner belts of greenschist facies mylonites. During this event, switching from a-prism to a-basal slip indicates a thermal path from 600 to 350 °C. Therefore, microstructures and quartz c-axis fabrics in polydeformed rocks from the Seridó Belt preserve the record of two major events, which includes contrasting deformation mechanisms and thermal paths.  相似文献   

13.
Abstract

The Cadomian Dyje Batholith, in the foot–wall of the Variscan Moravian nappe pile, has been involved in Variscan ductile deformation. The Cadomian Brunovistulian rocks were obliquely underthrusted during Carboniferous dextral transpression.

Strain intensity is inversely proportional to the distance from the contact of the Variscan thrust front. The microstructures of deformed granodiorites and quartz–diorites show a characteristic zonality marked by relatively high temperature flow in the west (550–580 °C) characterized by dynamic recrystallization of feldspars and grain boundary migration recrystallization of quartz. The size of quartz grains decreases with decreasing strain towards the east. At the easternmost part of the autochthonous Dyje massif, fracturing of feldspar and subgrain rotation recrystallization of quartz predominate. Flow stress estimates calculated from recrystallized quartz grain size show a regional increase of stress intensity from the highly strained margin towards the less deformed core of the Dyje massif. This microstructural zonation is oblique with respect to the major thrust boundary and corresponds roughly to metamorphic isogrades. The microstructural zonation reflects underthrusting of the Brunovistulian domain below the Moldanubian nappe.

The main ductile tectonic event D1 is followed by a retrogressive brittle–ductile and brittle deformation D2. D2 results in the development of shear zones and faults superimposed on the D1 mylonite fabric. D2 is related to extension oblique to the D1 fabric, associated with detachment and the westward movement of the Moravian nappes. © Elsevier, Paris  相似文献   

14.
Evolution of grain size in synthetic marbles was traced from compaction of unconsolidated powder, through primary recrystallization and normal grain growth, to a size stabilized by second phases. To form the marbles, reagent grade CaCO3 was mixed with 0, 1 and 5 volume% mica and heat-treated under pressure with added water. Densification with negligible recrystallization occurred within one hour at 500° C and 500 MPa confining pressure. Primary recrystallization occurred at 500–550° C, causing increases of grain size of factors of 2–5. Resulting samples had uniform grain size, gently curved grain boundaries, and near-equilibrium triple junctions; they were used subsequently for normal grain growth studies. Normal grain growth occurred above 550° C; at 800° C, grain size (D) increased from 7 m (D 0) to 65 m in 24 hours. Growth rates fit the equation, D n -D 0 n =Kt, where K is a constant and n2.6. Minor amounts of pores or mica particles inhibit normal grain growth and lead to a stabilized grain size, D max, which depends on the size of the second phases and the inverse of their volume fraction raised to a power between 0.3 and 1. Once D max is reached, normal growth continues only if second phases are mobile or coarsen, or if new driving forces are introduced that cause unpinning of boundaries. Normal grain growth in Solnhofen limestone was significantly slower than in pure synthetic marble, suggesting that migration is also inhibited by second phases in the limestone.  相似文献   

15.
The microstructure of a quartzite experimentally deformed and partially recrystallised at 900 °C, 1.2 GPa confining pressure and strain rate 10−6/s was investigated using orientation contrast and electron backscatter diffraction (EBSD). Boundaries between misoriented domains (grains or subgrains) were determined by image analysis of orientation contrast images. In each domain, EBSD measurements gave the complete quartz lattice orientation and enabled calculation of misorientation angles across every domain boundary. Results are analysed in terms of the boundary density, which for any range of misorientations is the boundary length for that range divided by image area. This allows a more direct comparison of misorientation statistics between different parts of a sample than does a treatment in terms of boundary number.The strain in the quartzite sample is heterogeneous. A 100×150 μm low-strain partially recrystallised subarea C was compared with a high-strain completely recrystallised subarea E. The density of high-angle (>10°) boundaries in E is roughly double that in C, reflecting the greater degree of recrystallisation. Low-angle boundaries in C and E are produced by subgrain rotation. In the low-angle range 0–10° boundary densities in both C and E show an exponential decrease with increasing misorientation. The densities scale with exp(−θ/λ) where λ is approximately 2° in C and 1° in E; in other words, E has a comparative dearth of boundaries in the 8–10° range. We explain this dearth in terms of mobile high-angle boundaries sweeping through and consuming low-angle boundaries as the latter increase misorientation through time. In E, the density of high-angle boundaries is larger than in C, so this sweeping would have been more efficient and could explain the relative paucity of 8–10° boundaries.The boundary density can be generalised to a directional property that gives the degree of anisotropy of the boundary network and its preferred orientation. Despite the imposed strain, the analysed samples show that boundaries are not, on average, strongly aligned. This is a function of the strong sinuosity of high-angle boundaries, caused by grain boundary migration. Low-angle boundaries might be expected, on average, to be aligned in relation to imposed strain but this is not found.Boundary densities and their generalisation in terms of directional properties provide objective measures of microstructure. In this study the patterns they show are interpreted in terms of combined subgrain rotation and migration recrystallisation, but it may be that other microstructural processes give distinctive patterns when analysed in this fashion.  相似文献   

16.
Well ordered tridymites containing atmost 0.016% Na (0.004% Na) were prepared at 1400° C from Na2WO4-(K2WO4-) fluxes using high purity amorphous silica as starting material. No further reduction of these Na-contents was attainable by soxhlet extraction. These tridymites were treated hydrothermally at temperatures between 815 and 950° C and 200 bars H2O. The products obtained were investigated optically as well as by powder X-ray methods and were analyzed for Na-contents: the hydrothermal treatment resulted either in recrystallization of tridymite or transformation into quartz mostly depending on Na-contents. Na-contents below about 0.015% tend to favour recrystallization of tridymite within the quartz field (<870° C), Na-contents above about 0.03% tend to favour formation of quartz within the tridymite field (>870° C). This may be due to influences of Na-traces either on the kinetics or on the equilibrium temperature of tridymite-quartz transformation.  相似文献   

17.
We present geochronologic and paleomagnetic data from a north-trending quartz diorite intrusion that cuts Archean metasedimentary and metaigneous rocks of the South Pass Greenstone Belt of the Wyoming craton. The quartz diorite was previously thought to be either Archean or Early Proterozoic (?) in age and is cut by north and northeast-trending Proterozoic diabase dikes of uncertain age, for which we also report paleomagnetic data. New U–Pb analyses of baddeleyite and zircon from the quartz diorite yield a concordia upper intercept age of 2170±8 Ma (95% confidence). An 40Ar/39Ar amphibole date from the same sample yields a similar apparent age of about 2124±30 Ma (2σ), thus confirming that the intrusion is Early Proterozoic in age and that it has probably not been thermally disturbed since emplacement. A magmatic event at ca. 2.17 Ga has not previously been documented in the Wyoming craton. The quartz diorite and one of the crosscutting diabase dikes yield essentially identical, well-defined characteristic remanent magnetizations. Results from eight sites in the quartz diorite yield an in situ mean direction of north declination and moderate to steep positive inclination (Dec.=355°, Inc.=65°, k=145, α95=5°) with a paleomagnetic pole at 84°N, 215°E (δm=6°, δp=7°). Data from other diabase dike sites are inconsistent with the quartz diorite results, but the importance of these results is uncertain because the age of the dikes is not well known. Interpretation of the quartz diorite remanent magnetization is problematic. The in situ direction is similar to expected directions for magnetizations of Late Cretaceous/early Tertiary age. However, there is no compelling evidence to suggest that these rocks were remagnetized during the late Mesozoic or Cenozoic. Assuming this magnetization to be primary, then the in situ paleomagnetic pole is strongly discordant with poles of 2167, 2214, and 2217 Ma from the Canadian Shield, and is consistent with proposed separation of the Wyoming Craton and Laurentia prior to about 1.8 Ga. Correcting the quartz diorite pole for the possible effects of Laramide-age tilting of the Wind River Range, based on the attitude of nearby overlying Cambrian Flathead Sandstone (dip=20°, N20°E), gives a tilt corrected pole of 75°N, 58°E (δm=4°, δp=6°), which is also discordant with respect to time-equivalent poles from the Superior Province. Reconstruction of the Superior and Wyoming Province using a rotation similar to that proposed by Roscoe and Card [Can. J. Earth Sci. 46(1993)2475] is problematic, but reconstruction of the Superior and Wyoming Provinces based on restoring them to their correct paleolatitude and orientation using a closest approach fit indicates that the two cratons could have been adjacent at about 2.17 Ga prior to rifting at about 2.15 Ga. The paleomagnetic data presented are consistent with the hypothesis that the Huronian and Snowy Pass Supergroups could have evolved as part of a single epicratonic sedimentary basin during the Early Proterozoic.  相似文献   

18.
This investigation presents and interprets fluid inclusion data from different lithological units of the Cu skarn deposits at Mazraeh, north of Ahar, Azarbaijan, NW Iran. The results provide an assessment of the P–T conditions and mineral–fluid evolution and suggest new exploration parameters. Five types of inclusions are recognized from quartz and garnet. The temperature of homogenization of Type I inclusions with daughter minerals halite and sylvite ranges from 312° to 470 °C with total salinity of 52 to 63 wt.% NaCl equiv.; Type II and III inclusions with halite have homogenization temperatures of 230° to 520 °C and salinity of 31 to 50 wt.% NaCl equiv. The salinity of Types IV and V biphase (liquid + vapor) inclusions, based on their final ice melting temperature, varies between 10.2 to 20.8 wt.% NaCl equiv. Th vs. salinity plots of inclusions show that the salinity of the fluids correlates positively with temperature. The inclusions formed at low pressure. Changes in the temperature and salinity of the fluids can be reconstructed from the inclusions. Highly saline, high-temperature fluids were most abundant during the main chalcopyrite ore-forming phase in the skarn and mineralized quartz veins. Low-salinity aqueous fluids were abundant in barren veins, in which there is no evidence for early hot high-salinity brine, and might have resulted from late-stage dilution and mixing of hydrothermal fluids with meteoric water. Based on petrographic features and fluid-inclusion data, early-stage magnetite deposition is related to boiling of fluid at temperatures of about 500 °C. At a later stage, boiling at temperatures of around 320° to 400 °C favored the deposition of sulfides and Fe mobility was decreased at these lower temperatures. The following inclusion characteristics may be used as exploration parameters in the Mazraeh area. (i) Presence of high-temperature, salt-bearing inclusions, with Th between 300 and 500 °C; (ii) High-salinity fluid inclusions; and (iii) Inclusions showing evidence of boiling of the fluid. In addition, the presence of magnetite is an important exploration parameter.  相似文献   

19.
The dominant flow mechanism in tectonic processes depends on the rheological properties of geological materials and the physical conditions prevailing during deformation. We have evaluated the relative importance of intercrystalline diffusion and intracrystalline creep in crustal deformation in terms of temperature and grain size.Oxygen isotope thermometry has been used to elucidate the thermal environment obtaining during deformation and contemporaneous metamorphism of Dalradian rocks from Southwest Scotland. The temperature and grain size data, applied in conjunction with microstructural criteria for evaluating independent mechanisms of steady-state flow, allow recognition of a low-temperature deformation regime dominated by intercrystalline diffusion, and a high-temperature regime dominated by dislocation processes.The transition between the fields of intercrystalline diffusion and dislocation creep for quartz and calcite of 100 Mm grain size occurs at about 450° C and about 300° C, respectively. These empirically derived results are consistent with the temperature intervals over which intercrystalline diffusion and dislocation creep, respectively, are predicted to be dominant at geologically reasonable strain rates, as derived from theoretically formulated deformation mechanism maps for quartz and calcite.Grain growth may play an important role in delimiting the higher-temperature boundary of the intercrystalline diffusion field. Intercrystalline diffusion is the only deformation mechanism that involves mass transfer over distances that are large in relation to the grain size. This result has important consequences for geochemical transport phenomena.  相似文献   

20.
Anisotropy of magnetic susceptibility (AMS) in micaceous quartzites with mean susceptibility (K m) >50 × 10−6 SI units is known to be on account of the orientation distribution of the para/ferromagnetic minerals (e.g. micas, magnetite), which comprise the minor phase in the rocks. However, the strain in such deformed micaceous quartzites is dominantly accommodated by the quartz grains, which are the major phase in them. The objective of this paper is to explore the extent to which AMS data from micaceous quartzites provide information about the shape of the strain ellipsoid. AMS analysis of 3 quartzite blocks is performed, and the shape of the AMS ellipsoid is recorded to be oblate. From AMS data, the three principal planes of the AMS ellipsoid are identified in each block and thin sections are prepared along them. Quartz grain shape (aspect ratio, R q), intensity of quartz and mica shape preferred orientation (κq and κmi, respectively) and 2D strain (E) recorded by quartz are measured in each section. R q, κq, κmi and E are all noted to be minimum in the section parallel to the magnetic foliation plane as compared to the other two sections. This indicates that the quartz grains have oblate shapes in 3D and accommodated flattening strain, which is similar to the shape of the AMS ellipsoid. The role of mica in causing Zener drag and pinning of quartz grain boundaries is discussed. It is concluded that during progressive deformation, migration of pinned grain boundaries is inhibited. This causes enhanced recrystallization at the grain boundaries adjacent to the pinned ones, thus guiding the shape modification of quartz grains. A strong correlation is demonstrated between κq and κmi as well as κmi and E. It is inferred that fabric evolution of quartz was controlled by mica. Hence, the shape of the AMS ellipsoid, which is on account of mica, provides information about shape of the strain ellipsoid.  相似文献   

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