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1.
研究了新显色剂２－「２－（５－甲基苯并噻唑）偶氮」－５－二乙氨基苯甲酸（５－Ｍｅ－ＢＴＡＥＢ）的离解平衡及与Ｆｅ＾２＋形成配合物的条件。在十二烷基硫酸钠的存在下,５－Ｍｅ－ＢＴＡＥＢ与Ｆｅ＾２＋形成稳定的蓝紫色２：１配合物,其最大吸收波长为６４０ｎｍ,表观摩尔吸光系数为１．０３＊１０＾５Ｌ．ｍｏｌ＾－１．ｃｍ＾－１。Ｆｅ＾２＋的质量浓度在０－４８０μｇ／Ｌ时服比尔定律。方法用于部级铝合金标样中微量 相似文献
2.
催化动力学光度法测定痕量铁的研究 总被引：2，自引：0，他引：2
研究了在ｐＨ８．５的Ｎａ２Ｂ４Ｏ７－ＨＣｌ介质中,Ｆｅ＾３＋催化Ｈ２Ｏ２氧化茜素红褪色,建立了动力学光度法测定痕量Ｆｅ＾３＋的方法。方法检出限０．０４３μｇ／ｍｌ,线性范围０￣０．１７μｇ／ｍｌ,除Ｍｎ＾２＋、Ｃｏ＾２＋等离子外,其余共存离子基本无干扰,实测了天然水和化学试剂中痕量Ｆｅ＾３＋,结果满意。 相似文献
3.
提出了在同一份样品溶液中采用电位滴定法和库仑滴定法分别直接测定Ｆｅ＾３＋和Ｆｅ＾２＋的方法。在实验确定的最佳条件下测定０．２０－５．００ｍｇ Ｆｅ＾３＋的ＲＳＤ％小于０．９０（ｎ＝５）；测定０．０３２－１０．０ｍｇ Ｆｅ＾２＋的ＲＳＤ％小于０．８６（ｎ＝５）。用岩石一级标准物质和单矿物标准物质检验并参加标准物质ＧＳＲ７－１２的协作定值，结果良好。 相似文献
4.
双波长分光光度法同时测定岩石及合金中低含量铁和铝 总被引：2，自引：0，他引：2
研究了Ｆｅ＾２＋－亚硝基Ｒ盐及Ａｌ＾３＋－铝试剂显色体系。在ｐＨ５．５条件下,在波长８００￣７４０ｎｍ处用亚硝基Ｒ盐测定铁;在波长５６５￣５３０ｎｍ处用铝试剂测量铝,可消除相互间的干扰,故可在一份溶液中同时进行铁、铝的测定。 相似文献
5.
除硅铁钡矿之处，性石是迄今仅知的另一种含有平面四配位Ｆｅ＾２＋的矿物，异性石晶体样品为玫瑰色，透明，有油脂光泽，取自一花岗岩标本，异性石中平面四配位Ｆｅ＾２＋的穆斯堡尔参数：化学位移＝０．７８５（ｍｍ／ｓ）（相对天然铁），四极矩分裂＝０．４１９（ｍｍ／ｓ），明显地低于大多数硅酸矿物中的Ｆｅ＾２＋，但和硅铁钡矿的Ｆｅ＾２＋十分相近，本文对硅酸盐矿物Ｆｅ＾２＋的穆斯堡尔参数与配位数之间的关系做了讨论。 相似文献
6.
对用Fe^3＋／Fe^2＋探讨庐山地区第四纪古温度的讨论 总被引：10，自引：0，他引：10
本文认为用Ｆｅ＾３＋／Ｆｅ＾２＋值推算庐山地区第四纪古温度是可行的，但认为在推算方法上必须严谨合理，文中论证了用Ｆｅ２Ｏ３／ＦｅＯ值代替Ｆｅ＾３＋／Ｆｅ＾２＋值推算古温度，且用少量样品的实验分析结果来划分庐山地区第四纪冰期和间冰期地层是欠妥的，其计算结果误差达０．４１－４．３５。据笔者采用容量法对庐山大校场部面１０个样品Ｆｅ＾３＋和Ｆｅ＾２＋含量的测试，发现这些样品反映的第四纪古温度值未有低达０℃ 相似文献
7.
8.
对江汉盆地Ｔ油田主要的工业储层－下第三系新光沟嘴组沉积岩石的成岩流体进行了热力学研究。实测的成岩矿物流体包裹体的均一温度为１１０－１３９℃，属于该区中成岩阶段的温度范围（６７－１５５℃）。成岩流体的压力为１０．２－５６ＭＰａ。成岩流体中阳离子的活度出现Ｃａ＾２＋＞Ｍｇ＾２＋＞Ｎａ＾＋＞Ｋ＾＋＞Ｆｅ＾３＋＞Ｆｅ＾２＋；阴离子的活离出现ＨＣＯ３＾－＞ＳＯ４＾２－＞Ｆ＾－＞Ｃｌ＾－＞ＣＯ３＾２－；气相成 相似文献
9.
Ｆｅ－对硝基苯基荧光酮－ＣＴＭＡＢ在ｐＨ１０．０－１１．２的硼砂－ＮａＯＨ缓冲溶液中形成蓝色多元配合物，其组成为Ｆｅ：ｐ－ＮＰＦ：ＣＴＭＡＢ＝１：２：４。在吐温－６０下，λｍａｘ为１６０ｎｍ，ε６１０＝１．１２×１０＾５Ｌ．ｍｏｌ＾－１．ｃｍ＾－１，Ｆｅ含量在０－０．２μｇ／ｍｌ范围内符合比耳定律。 相似文献
10.
本文使用穆斯堡尔效应研究了在高温高压下合成的铁橄榄石和铁尖晶橄榄石。２９８Ｋ温度下铁橄榄石的穆斯堡尔谱由一组双峰组成，它被指派给Ｆｅ＾２＋（Ｍ１，Ｍ２）离子。２９８Ｋ温度下铁尖晶橄榄石的穆斯堡尔谱由三组双峰组成，其中两组双峰指派给八面体位置Ｂ上的Ｆｅ＾２＋，另一组双峰归为四面体位置Ａ上的Ｆｅ＾３＋，两组Ｆｅ＾２＋双峰的同质异能迁移近似相等而四极分裂不同，Ｓｉ原子在八面体位置上的占有率为６％～１０％ 相似文献
11.
以29口钻孔的重矿物百分含量数据来分析样本,通过Q型聚类分析、因子分析方法恢复不同物源体系的发育范围及其母岩类型,并以不同物源体系的边界范围为限定条件,结合ZTR指数及其等值线图,对珠江口盆地惠州凹陷M层物源特征进行了系统的研究。研究结果表明：研究区发育3大物源沉积区,分别为东北-北部物源沉积区、西北物源沉积区和东南物源沉积区,且各区重矿物组合特征明显,主次物源分明,整体表现为母岩类型复杂的特征。东北-北部沉积物主要母岩为酸性岩浆岩,次要母岩为变质岩和沉积岩,西北沉积物主要母岩为中性及基性岩浆岩,次要母岩为酸性岩浆岩和变质岩,东南沉积物主要母岩为中性及基性岩浆岩,次要母岩为变质岩。东北-北部物源区和西北物源区为远源沉积的产物,而东南物源区为近源沉积的产物。东北-北部物源区沉积物来自北方和东北方向,而西北物源区和东南物源区沉积物分别来自西北方向和东南方向。 相似文献
12.
两种煤质分析指标的关联方程组研究 总被引：5，自引：0，他引：5
在综合分析大量文献资料的基础上，采用多元线性回归方法，利用MATLAB对大量煤质分析结果进行了回归分析，推导出了煤质元素分析与工业分析的关联方程组。新方法实现了由工业分析结果求元素分析成分的目的，具有重大的实用意义。 相似文献
13.
An algorithm andFortran-iv computer program,cabfac, forQ-mode factor analysis is described. The program will accept up to 1500 items and 50 variables on a moderate-size computer. 相似文献
14.
A piston core from the southern Blake Basin penetrated nine distinct bioclastic carbonate turbidites separated by pelagic terrigenous clay units. X-ray diffraction analysis of the carbonate mineralogy of the graded, laminated, and homogenous units of the individual turbidite units indicated a general loss of unstable carbonates in the homogenous unit beyond that contained in the lower two units. Univariate and multivariate statistical tests were employed to determine the significance of the changes and to determine if different units of a turbidite sequence could be consistently grouped by statistical methods. Principal components, discriminant function, and cluster analysis were used in the multivariate tests. The graded and laminated units were closely related in mineralogy with little significant differences. The mineralogy of the homogenous units was significantly different than that of the other two units except in one example. Cluster analysis generated five groupings of the samples with the end members consisting of graded and laminated units at one end and homogenous units at the other. 相似文献
15.
Ibsen Chivatá Cárdenas 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2019,13(1):53-65
In this paper, we report on the use of Bayesian networks, BNs, learnt from data generated by physical and numerical models, to overcome to a certain degree a number of complications in traditional slope stability analyses that jointly consider the mechanical and hydraulic properties of soils. Discrete Bayesian networks resulted to be useful and efficient to acquire knowledge from simulated data and to identify significant factors by the combined use of backward inference and global sensitivity analysis. Further, BNs enable decision thresholds to be estimated quickly. Along with this, backward inference and global sensitivity analysis are performed in BNs at low computation costs. Moreover, under conditions in which knowledge is scarce, we show how a practitioner can be better informed using the proposed approach. All these previously under-reported modelling features in the specialised literature encourage the further application of the proposed approach to enhance slope stability analysis. 相似文献
16.
以有限元结构矩阵分析为理论基础，结合应力应变测试和现场实际使用情况，利用计算机结构分析程序，对ＺＴ－Ａ系列三个不同高度钻塔的天梁、塔腿和绷绳做了结构应力分析，弄清了Ａ形塔在承受垂直荷载、水平荷载以及偏载条件下，组成钻塔的各构件的荷载及应力分布；对钻塔设计提出了改进意见；并从整体角度分析了绷绳的作用；对在不同荷载条件下有无绷绳时钻塔的结构应力从量上做了对比；最后提出了应当如何布置提升系统才会使钻塔处 相似文献
17.
Paul F. Czeglédy 《Mathematical Geology》1972,4(4):291-305
On the basis of samples taken from a known topographic surface, the parameters of two types of linear models are estimated. The first category is defined by polynomials or trigonometric functions, whose parameters are simultaneously computed from available data. In the second category a set of local centers is defined, and in the neighborhood of each center a fixed-degree polynomial is developed. An approximative resemblance index is calculated, and contour maps corresponding to various models are compared with the topographic map. It is found that with an increasing number of grid points, maps of local polynomials are converging both in continuity and in resemblance. For a sufficient number of grid points, this resemblance is always higher than those produced by models of the first category. 相似文献
18.
Finite element limit analysis with plane strain condition is employed to determine the upper and lower bound solutions of the undrained limiting pressure behind soil gaps and the lateral force acting on a pile per unit length in a contiguous pile wall. Computed bound solutions confirm serious limitations of existing studies in predicting these two solutions. Predicted failure mechanisms and the arching effect behind soil gaps are discussed. A closed-form equation of the limiting pressure factor is proposed for a convenient and accurate prediction of the lateral force acting on a pile in contiguous pile walls in practice. 相似文献
19.
Ulf Grenander 《Mathematical Geology》1975,7(3):267-278
A deformation mechanism is described and analyzed. It is intended for height patterns exposed to erosion and tectonic activity.
A simulation experiment is carried out for this model. Closedform expressions are derived for the covariance field, the properties
of spectral estimates, and for the optimal retrospective reconstruction of earlier, unknown height patterns. For obvious reasons
the author is in no position to make claims about the verisimilitude of the model. It is offered as an example of a potential
application to geology of the theory of patterns developed by the author and his coworkers in recent years. It is hoped that
those more qualified than the author in the subject matter area can extend and modify the analysis to make it closer to geological
reality.
supported by NSF grant GJ-3100X. 相似文献