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1.
原子荧光光谱法快速测定锌精矿中汞,砷,锑   总被引:8,自引:1,他引:7  
研究拟定了不经分离富集,直接测定锌精矿中Hg、As、Sb的原子荧光光谱法。适用于锌精矿中0 ̄0.125%的Hg;0 ̄0.5%的As及0 ̄0.1%的Sb的测定,方法简便、快速,结果令人满意。  相似文献   

2.
何秋玲  范必威 《岩矿测试》1996,15(2):114-116123
微晶萘-双十二烷基二硫代乙酰二胺(DDO)吸附显色剂与铂(Ⅱ)、钯(Ⅱ)卤络合物所形成的有色螯合物沉淀,经分离洗涤后分别溶于氯仿-石油醚混合溶剂中,于510nm和445nm处测定铂和钯螯合物的吸光度,在10mL的CHCl3-石油醚中0 ̄10μgPt及Pd均符合比尔定律。采用在铜镍矿基体中标准加入法检验所拟方法,钯的回收率为93.3% ̄106.7%,铂为90% ̄106%。  相似文献   

3.
研究了410哌啶树脂对Cd的吸附行为,在2%~20%HCI介质中[CdCl_3] ̄-被树脂吸附,采用4%~30/HNO_3溶液可以解脱Cd,回收率在96%以上。测定了Cd在该树脂上的分配系数为5490,对含Cd0.067μg/g的标样GSR-3平行测定6次,相对标准偏差为9.5%。方法用于化探样品中0.0X×10 ̄-6级Cd的测定,结果满意。  相似文献   

4.
安徽沙溪斑岩铜矿床成矿流体演化及分布规律   总被引:3,自引:0,他引:3  
对安徽沙溪斑岩铜矿床流体包裹体进行了详细研究,得到气液包裹体的均一化温度为100 ̄500℃,盐度为2.0wt% ̄60wt%NaCl,并且流体包裹体的成分和温度随时间、空间变化而呈现出一定的变化规律。对热液脉石英及其流体包裹体中H2O、CO2的氧、氢、碳同位素组成分别进行了测定,得到热液δ^18OSMOW为+3.51‰ ̄+5.52‰,δDSMOW为-60‰ ̄-82‰,δ^13CPDB为-3.61‰ ̄  相似文献   

5.
疏松多孔、固结程度低的虎亭白土,属火山碎屑沉积岩。湿法选矿膨润土的产率为28% ̄35%,蒙脱石含量80%左右(二次精矿可达90%以上),可生产优质膨润土,用作涂料,陶瓷和冶金球团的原料,铸造用砂的胶结剂,污水处理的吸附剂,牲畜饲料添加剂等。  相似文献   

6.
澜沧铅锌银铜矿床矿物包裹体及成矿物化条件的研究   总被引:4,自引:0,他引:4  
李虎杰  田煦 《矿产与地质》1995,9(2):107-111
矿物流体包裹体的研究表明,澜沧铅锌银铜矿床成矿流体的温度为160 ̄350℃,压力69000kPa,盐度4.6 ̄17.0NaClwt%,密度0.85 ̄1.0g/cm^3,fs210^-9.3 ̄10^-11.0Pa,fo210^-35 ̄10^-37Pa,Ph值5.1 ̄5.7。成矿元素主要以氯化物络合物的形式迁移、温度降低,fs2和pH值的升高是引起矿物质沉淀的主要因素。  相似文献   

7.
湖南临澧县白土坡膨润土特征及开发应用初探   总被引:3,自引:0,他引:3  
白土坡膨润土产于第四系下更新统中,矿层稳定、厚度较大,为钙基膨润土,主要矿物成分为蒙脱石,含量35.7 ̄46.8%,其他矿物有石英、高岭石等。矿石中Fe2O3含量为5.72 ̄6.51%,白度为26.5 ̄34%。原 工艺技术性能达到铸用膨润土工业指标要求。初步提纯后蒙脱一达55.2 ̄69.3%,钠化处理后湿压强度 为0.18kgf/cm^2 ̄0.27kgf/cm^2,热湿拉强 17.8gf/cm^2  相似文献   

8.
塞曼原子吸收法测定大洋多金属结核中的铜钴镍   总被引:1,自引:0,他引:1  
刘昌岭  张红 《岩矿测试》1997,16(2):98-100108
报道以HNO3-HF-HClO4分解多金属结核样品,用日立180-80偏振塞曼原子吸收分光光度计测定Cu、Co和Ni的方法。试验了介质及共存元素对测定的影响,选择了最佳测定条件。用该法测定了大洋锰结核标准物质中的Cu、Co、Ni,结果与标准值符合,且方法已应用于大批量样品分析中。对这些标样6次测定的RSD分别是Cu0.49% ̄1.99%,Co1.86% ̄2.66%,Ni0.46% ̄1.96%。  相似文献   

9.
5‘—硝基水杨基荧光酮与锆显色反应及其应用   总被引:8,自引:0,他引:8  
付佩玉  王正祥 《岩矿测试》1997,16(3):238-240
在0.08 ̄0.10mol/L HCl介质中,溴化十六烷基三甲铵(CTMAB)存在下,Zr(Ⅳ)与5'-硝基水杨基荧光酮(5'-NSF)发生显色反应,形成1:4的桔红色络合物,λmax=540nm,ε为1.46×10^5L·mol^-1·cm^-1,Zr(Ⅳ)含量在0 ̄0.5mg/L符合比尔定律。方法用于氧化铝及陶瓷釉料中锆的测定,结果与ICP-AES法相符,RSD(n=5)在1.3% ̄3.7%。  相似文献   

10.
流动注射-原子荧光法测定岩矿中痕量硒和碲   总被引:4,自引:0,他引:4  
讨论了题示方法中的干扰,指出在一般岩石中多数共存元素不干扰Se和Te的测定;Cu的干扰可在含Fe ̄3+、HClO_4的介质中加入邻菲罗啉沉淀预先消除;Pb的干扰可在H_2SO_4分解试样时形成PbSO_4消除;试液保存在塑料容器中可免除残留F ̄-的影响。所拟方法每次采样1mL,每小时测定90次。对Se和Te的检出限均为0.2μg/L,测定浓度为10μg/L的Se和Te,其RSD(n=12)分别为3.7%和4.3%。经标样分析验证,方法可行。  相似文献   

11.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

12.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

13.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

14.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

15.
16.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

17.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

18.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

19.
GEOCHEMISTRY     
正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861  相似文献   

20.
正20141768 An Shaopeng(Institute of Rock and Soil Mechannics,Chinese Academy of Sciences,Wuhan 430071,China);Wei Lide Experimental Study on Mechanical Behavior of Xigeda Formation Siltstone and Structure Interface(Journal of Engineering Geology,ISSN1004-9665,CN11-3249/P,21(5),2013,p.702-708,9illus.,1 table,16 refs.)  相似文献   

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