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1.
关于《二元混合体系的端元Sm-Nd模式年龄计算方法》几个问题探讨杨晓松(中国地质大学地质系武汉430074)作者在《二元混合体系的端元Sm-Nd模式年龄计算方法》一文(下简称原文)中(杨晓松等,1993),提出了端元Sin-Nd模式年龄的概念及计算方法,其目的是解决模式年龄在解释时常遇到的困境(Arndt et al.,1987)。 相似文献
2.
Nd模式年龄的地质解释有多解性(Arndt et al 1987s Jahn et al., 1990),杨晓松等(1993)在《二元混合体系的端元Sm-Nd模式年龄计算方法》一文(下简称杨文)中提出端元模式年龄的概念和计算方法,试图解决模式年龄的多解性问题.公式推导基本正确,但在公式的内涵、适用性和应用条件等方面尚存在一些值得商榷之处。 相似文献
3.
该文就Sm-Nd同位素地质上的应用进行了讨论,并重点讨论了模式年龄的地质意义,一些重要参数值的计算方法,∑_ND~(T)值的解释以及利用fsm/Nd估计非交代地幔Nd同位素组成等。而且提出,地质人员在进行地质研究工作时,应重视对同位素地质信息的研究。 相似文献
4.
徐步台 《矿物岩石地球化学通报》1987,(1)
Sm和Nd均属稀土元素,放射性同位素~(147)Sm经α衰变的产物是稳定同位素~(143)Nd,其半衰期为1.06×10~(11)年。由于岩石中的稀土元素丰度一般都非常低,而~(147)Sm的半衰期又特别长,对稀土同位素的分离和超微量测定难度就相当大。因此,Sm-Nd法在地质年代学中长期得不到实际应用。直至近十年来,随着Sm-Nd同位素分离测试技术的迅速发展,并对它们的地球化学演化规律取得了新的认识之后,Sm-Nd法的应用才日趋广泛。它也同Rb-Sr法一样不仅可进行等时线年龄测定,而且还可以进行模式年龄测定。 相似文献
5.
前言随着地质工作的不断发展,进一步利用同位素地质年龄资料研究和解决地质问题显得越来越重要。我国同位素地质年代学的研究在迅速的发展过程中积累了大量资料。如何根据数学原理,用电子计算机处理和利用这些资料是当前急待解决的问题。本文企图在这方面做些尝试,探索处理和利用同位素地质年龄资料的新方法。 相似文献
6.
指出了《冀北兰城子-蔡家营子-带红旗营子群的Sm-Nd同位素年龄及其地质意义》一文中有违地质学原理和同位素测年方法及解释方面的不当之处。在列举变质作用中流体导致岩石同位素体系再次均一化实例；讨论测年数据的地质意义与地质关系的相互检验和不同测年方法的合理使用问题；深入分析研究红旗营子群内Sm-Nd测年样品的特征之后，认为宜将红旗红旗营子群的生成年代定为新太古代。 相似文献
7.
本文主要介绍了分离Sm-Nd的3种化学方法,其中有适合分离高含量Sm,Nd的了酮-疏氰酸铵纸色层法;适合分离一般含量Sm,Nd的P_(204)柱色层法;适合低含量Sm,Nd的加压离子交换法。同时介绍应用Sm-Nd法得出的我国第一条Sm-Nd等时线,测出了冀东早太古代岩石Sm-Nd同位素地质年龄。 相似文献
8.
《矿物岩石地球化学通报》2016,(3)
本文综述了近10年来激光原位LA-MC-ICP-MS测定地质样品Sm-Nd同位素测试技术的最新进展,着重介绍了同质异位素干扰校正的关键技术难点及校正方案。LA-MC-ICP-MS技术对轻稀土富集矿物可以获得可靠的~(147)Sm /~(144)Nd and~(143)Nd /~(144)Nd值,是当前进行地质样品激光原位Sm-Nd同位素测定的主要技术,配合矿物微区U-Th-Pb年龄测定和微量元素分析,可以对矿物的成因演化提供重要的制约参数。多元同位素体系(Sr-Nd-Hf同位素、U-Th-Pb年龄和微量元素)的原位微区联合测定,低含量地质样品(小于500μg/g)和高Sm/Nd值矿物(如磷钇矿Sm/Nd远远大于1,有时甚至达到10)的Sm-Nd同位素组成的准确测定是未来LA-MC-ICP-MS激光原位Sm-Nd同位素测定的主要发展方向之一,具有广阔的应用前景。 相似文献
9.
10.
赵振华 《矿物岩石地球化学通报》1984,(4)
一九八三年,我国地球化学一些主要领域的发展可简述下如。1.同位素地质年代学和稳定同位素地球化学在1983年9月北京国际前寒武地壳演化讨论会上,法籍华人江博明报导了冀东曹庄附近九个玄武质样品的 Sm-Nd 等时线年龄为3515±115百万年,Nd~(143)/Nd~(144)为0.5087±0.00013。这是目前我国地壳的最老年龄。国内外学者对这一数据的地质意义还有争论,一些人认为这是包体年龄,不代表周围地质体;一些人认为可能为残留体。 相似文献
11.
深刻理解同位素在超高压变质及退变质过程中的地球化学行为对获得超高压变质岩准确并有明确意义的年龄值是非常重要的。对 Sm-Nd,Rb-Sr 同位素体系,只有变质矿物同位素体系达到平衡才能给出精确有意义的等时线年龄。研究表明,与副变质岩互层的细粒榴辉岩的高压变质矿物之间,或者强退变质岩石的退变质矿物之间,其 Nd,Sr 同位素可以达到平衡;然而高压变质矿物与退变质矿物之间 Nd,Sr 同位素不平衡。由于全岩样品总是含有数量不等的退变质矿物,因此石榴石 全岩 Sm-Nd 法或多硅白云母 全岩 Rh-Sr 法将有可能给出无地质意义的年龄。通常低温榴辉岩的高压变质矿物之间存在Nd 同位素不平衡。超高压变质岩多硅白云母所含过剩 Ar 主要源于榴辉岩原岩中角闪石在变质分解时释放出来的放射成因 Ar。因此,不含榴辉岩的花岗片麻岩多硅白云母基本不含过剩 Ar。对变质锆石成因的准确判断是正确理解锆石 U-Ph 年龄意义的关键。本文对不同成因锆石的判别标志及年龄意义做了总结,并指出将阴极发光图形,锆石痕量元素组成及矿物包裹体鉴定相结合是进行锆石成因鉴定的有效方法。高压变质或退变质增生锆石组成单一,是理想变质定年对象。然而变质重结晶锆石域常是重结晶锆石和继承晶质锆石的混合区,因而给出混合年龄。只有完全变质重结晶锆石才能给出准确变质时代。 相似文献
12.
Pb、Sr、Nd同位素体系研究表明沥青与寒武纪、奥陶纪地层中的干酪根具有明显的同位素组成差异,表明来自异源。沥青Pb同位素组成具有明显的幔源与壳幔混合特征,而干酪根显示出壳源特征。沥青与干酪根的Nd同位素组成也存在着明显的差别,反映出老地壳源与新地壳源的明显差别。来自柯坪隆起大湾沟沥青的Nd-Sr同位素体系给出了晚元古的相关等时线,年龄分别为872Ma与1195Ma,可能代表了沥青的最早形成年龄。但来自塔北隆起的沥青其Sm-Nd体系显示出介于大湾沟沥青与干酪根之间的混合相关,表明具有壳源与幔源的二元混合成因。Rb-Sr和Pb-Pb等时线趋向和Pb模式年龄还给出加里东期(～440Ma)和印支期(～250Ma)的原油运移与沥青沉淀年龄信息。Nd模式年龄还表明柯坪-阿克苏地区存在太古宙基底(3.2-2.5Ga).塔里木油藏受深断裂控制。 相似文献
13.
Pb、Sr、Nd同位素体系研究表明沥青与寒武纪、奥陶纪地层中的干酪根具有明显的同位素组成差异,表明来自异源。沥青Pb同位素组成具有明显的幔源与壳幔混合特征,而干酪根显示出壳源特征。沥青与干酪根的Nd同位素组成也存在着明显的差别,反映出老地壳源与新地壳源的明显差别。来自柯坪隆起大湾沟沥青的Nd-Sr同位素体系给出了晚元古的相关等时线,年龄分别为872Ma与1195Ma,可能代表了沥青的最早形成年龄。但来自塔北隆起的沥青其Sm-Nd体系显示出介于大湾沟沥青与干酪根之间的混合相关,表明具有壳源与幔源的二元混合成因。Rb-Sr和Pb-Pb等时线趋向和Pb模式年龄还给出加里东期(～440Ma)和印支期(～250Ma)的原油运移与沥青沉淀年龄信息。Nd模式年龄还表明柯坪-阿克苏地区存在太古宙基底(3.2-2.5Ga).塔里木油藏受深断裂控制。 相似文献
14.
Sm-Nd isotopic compositions of eight lamprophyre samples, which come from the Gezhen gold-bearing shear zone on western Hainan Island, are measured. The Sm-Nd isochron age is 495.98±13.14 Ma, (143Nd/144Nd) 0=0.512094, εNd(t) ranges from +1.80 to +2.00 and TDM from 982 Ma to 1196 Ma (average: 1060 Ma). The authors point out that the whole-rock Sm-Nd isochron age (495.98 ± 13.14 Ma) really represents the petrogenetic age of lamprophyre and the time of magmatism during subsequent subduction. 相似文献
15.
大别山金河桥榴辉岩矿物O—Nd—Pb同位素体系及其对扩散速率的制约 总被引：3，自引：1，他引：2
对大别山太湖金河桥超高压榴辉岩作了矿物Sm-Nd内部等时线定年研究和激光氧同位素分析。石榴石+绿辉石Sm-Nd等时线给出了较低年龄210±3Ma,石榴石+金红石Sm-Nd等时线给出了较高年龄237±4Ma。岩相学观察发现,绿辉石具有角闪石退变质边。氧同位素分析表明,石榴石与绿辉石之间的氧同位素体系处于不平衡状态。据此,石榴石+绿辉石Sm-Nd同位素体系因退变质作用导致Nd同位素不平衡而给出不合理偏低年龄。较老的石榴石+金红石Sm-Nd年龄有可能指示了榴辉岩相前期阶段的时代,且在温度变质峰期没有使它们之间的Nd同位素再次均一化,它指示Nd在金红石中的扩散速率较慢,可能与石榴石相当。矿物对氧同位素测温得到,石英—石榴石对温度为695±35℃,石英—金红石对为460±15℃,与根据金红石U—Pb内部等时线估计的Pb扩散封闭温度470±50℃一致。对比表明,O在石榴石中的扩散速率与Nd相当或略低,而O和Pb在金红石中的扩散速率相近,且均比Nd快。 相似文献
16.
Northeastern Queensland, a part of the Phanerozoic composite Tasman Fold Belt of eastern Australia, has a Paleozoic to Mesozoic history dominated by subduction zone processes. A suite of 13 peridotite xenoliths from the <3 Ma Atherton Tablelands Volcanic Province, predominantly from Mount Quincan, comprise fertile (1.8-3.4 wt.% Al2O3 and 38.7-41.9 wt.% MgO) spinel lherzolites free from secondary volatile-bearing phases and with only weak metasomatic enrichment of incompatible trace elements (SmN/YbN = 0.23-1.1; LaN/YbN = 0.11-4.9). The suite is isotopically heterogeneous, with measured Sr (87Sr/86Sr = 0.7027-07047), Nd (143Nd/144Nd = 0.51249-0.51362), and to a lesser extent, Os (187Os/188Os = 0.1228-0.1292) compositions broadly overlapping MORB source mantle (DMM) and extending to more depleted compositions, reflecting evolution in a time-integrated depleted reservoir. Major and rare earth element systematics are consistent with mantle that is residual after low to moderate degrees of melt extraction predominantly in the spinel facies, but with a few samples requiring partial melting at greater pressures in the garnet field or near the garnet-spinel transition. In contrast to most previously studied suites of continental lithospheric mantle samples, the incompatible trace element contents and Sr and Nd isotopic systematics of these samples suggest only minimal modification of the sampled lithosphere by metasomatic processes.Five of six Mount Quincan xenoliths preserving depleted middle to heavy REE patterns form a whole rock Sm-Nd isochron with an age of ∼275 Ma (εNdi = +9), coincident with widespread granitoid emplacement in the overlying region. This isochron is interpreted to indicate the timing of partial melting of a DMM-like source. Xenoliths from other Atherton localities scatter about the isochron, suggesting that the sampled mantle represents addition of DMM mantle to the lithosphere in the Permian, when the region may have broadly been within a subduction zone setting. A sixth middle to heavy REE-depleted Mount Quincan xenolith has a distinct Nd and Os isotopic composition consistent either with an earlier, possibly Precambrian melt extraction event, or with Permian derivation from a mantle source with a less depleted (time-averaged lower Sm/Nd) Nd isotopic composition, but a more depleted (low Re/Os) Os isotopic composition.The range in measured whole rock Os isotopic compositions cannot solely be the result of time-integrated effects of variable melt extraction, especially considering the coherent Sm-Nd systematics of the suite. The Os heterogeneity more likely reflects either a heterogeneous ∼275 Ma DMM source that would have a present-day Os composition (187Os/188Os ∼ 0.1265-0.1287) overlapping both abyssal peridotites and chondrites, or significant and variable enrichment within the lithospheric mantle by secondary sulfides carrying radiogenic Os in a cryptic chalcophile enrichment event. Regardless of the origin of the Os isotopic variability, these data highlight the mantle Re-Os isotopic heterogeneity that may be present over small length scales where the lithophile Sm-Nd system may be relatively homogeneous. 相似文献
17.
SHRIMP Ion Microprobe Zircon U—Pb Age and Sm—Nd Isotopic Characteristics oof the NE Jiangxi Ophiolite and Its Tectonic Implications 总被引：1，自引：1，他引：1
The new SHRIMP zircon U-Pb isotopic study suggests that the crystallization age of a highly fractionated magma in the NE Jiangxi
ophiolite suite is 968±23 Ma. Re-calculated Sm-Nd isochron age of 955±44 Ma is within analytical errors. consistent with the
zircon U-Pb age. With the exception of two anomalous Sm-Nd data, the remaining 15 analyses so far obtained for the ophiolite
gaveεNd (T) values falling into a limited range from +4.3 to +6.7, indicating that the ophiolite was derived from a relatively
strongly depleted mantle source. Sm-Nd isotopic systematics in some samples may have been strongly affected by post-magmatic
events, such as alteration, deformation and metamorphism, resulting in anomalousεNd (T) values. Combined with published40Ar39Ar age data, it can be concluded that the collision between the Yangtze and South China Blocks occurred during 0.97-0.80 Ga.
This work was financially supported by the President Grant of the Chinese Academy of Sciences. 相似文献
18.
华中榴辉岩带地球化学和年代学研究 总被引：8，自引：0，他引：8
根据地质产状，华中高压超高压变质带中的榴辉岩可划分为与超基性岩伴生的P类和与片麻岩、斜长角闪岩等伴生的G类。它们具有不同的地球化学特征，但均为大洋基性火成岩经复杂成分演化作用的产物。全岩-矿物Sm－Nd和颗粒锆石207Pb-206Pb年代学研究表明，超高压变质作用很可能发生在加里东期（480Ma）；而印支期（265Ma）则可能是超高压变质岩的后期高压退变质改造阶段。 相似文献
19.
Lars E. Borg Larry E. NyquistHenry Wiesmann Young Reese 《Geochimica et cosmochimica acta》2002,66(11):2037-2053
Detailed Rb-Sr and Sm-Nd isotopic analyses have been completed on the lherzolitic shergottites ALH77005 and LEW88516. ALH77005 yields a Rb-Sr age of 185 ± 11 Ma and a Sm-Nd age of 173 ± 6 Ma, whereas the Rb-Sr and Sm-Nd ages of LEW88516 are 183 ± 10 and 166 ± 16 Ma, respectively. The initial Sr isotopic composition of ALH77005 is 0.71026 ± 4, and the initial εNd value is +11.1 ± 0.2. These values are distinct from those of LEW88516, which has an initial Sr isotopic composition of 0.71052 ± 4 and an initial εNd value of +8.2 ± 0.6. Several of the mineral and whole rock leachates lie off the Rb-Sr and Sm-Nd isochrons, indicating that the isotopic systematics of the meteorites have been disturbed. The Sm-Nd isotopic compositions of the leachates appear to be mixtures of primary igneous phosphates and an alteration component with a low 143Nd/144Nd ratio that was probably added to the meteorites on Mars. Tie lines between leachate-residue pairs from LEW88516 mineral fractions and whole rocks have nearly identical slopes that correspond to Rb-Sr ages of 90 ± 1 Ma. This age may record a major shock event that fractionated Rb/Sr from lattice sites located on mineral grain boundaries. On the other hand, the leachates could contain secondary alteration products, and the parallel slopes of the tie lines could be coincidental.Nearly identical mineral modes, compositions, and ages suggest that these meteorites are very closely related. Nevertheless, their initial Sr and Nd isotopic compositions differ outside analytical uncertainty, requiring derivation from unique sources. Assimilation-fractional-crystallization models indicate that these two lherzolitic meteorites can only be related to a common parental magma, if the assimilant has a Sr/Nd ratio near 1 and a radiogenic Sr isotopic composition. Further constraints placed on the evolved component by the geochemical and isotopic systematics of the shergottite meteorite suite suggest that it (a) formed at ∼4.5 Ga, (b) has a high La/Yb ratio, (c) is an oxidant, and (d) is basaltic in composition or is strongly enriched in incompatible elements. The composition and isotopic systematics of the evolved component are unlike any evolved lunar or terrestrial igneous rocks. Its unusual geochemical and isotopic characteristics could reflect hydrous alteration of an evolved Martian crustal component or hydrous metasomatism within the Martian mantle. 相似文献
20.
《Geochimica et cosmochimica acta》1994,58(5):1471-1481
The behaviour of the Rb-Sr and Sm-Nd isotopic systems with increasing degree of Hercynian metamorphic overprint was studied along a transect in Cambrian shales of northwestern Morocco. Clay fractions of < 0.2 to 2–6 μm size from five samples were investigated, representing a range from nonmetamorphic to epizonal metamorphic conditions. The samples were washed in cold l N HC1 prior to digestion to separate soluble/exchangeable Rb, Sr, Sm, and Nd from amounts of these elements fixed in the crystallographic sites of the minerals and to analyze both components separately.The results reveal that the Rb-Sr isotopic system is dominated by Sr hosted by clay mineral phases (both detrital and authigenic illite and chlorite) and carbonate-hosted soluble Sr. Isotopic homogenization of Sr occurred during Hercynian metamorphism, yielding ages between 309 and 349 Ma.The Sm-Nd isotopic system, on the other hand, is dominated by cogenetic apatite and Fe oxide/ hydroxide, both having high contents of leachable REEs. The leachates yield a Sm-Nd isochron age of 523 ± 72 Ma, indicating diagenetic equilibrium between apatite and Fe-oxide/hydroxide. Fine-grained clay fractions of < 0.2 μm size plot onto this reference line, suggesting isotopic equilibrium with the leachates. Size fractions > 0.2 μm show inheritance of a detrital Nd component. The study demonstrates that the diagenesis of the investigated argillaceous sediments can be dated by the Sm-Nd chronometer in authigenic cement phases. The isotopic system of these minerals (apatite, Fe hydroxide/oxide) was homogenized during authigenic mineral growth in a sediment that was flushed by diagenetic fluids and had abundant primary or secondary interconnected pore space.The Hercynian metamorphic overprint caused partial isotopic rehomogenization of the adsorbed and clay-hosted portion of the Sr as well as of the carbonate-hosted Sr. The Sm-Nd system in the cement phases survived this metamorphism. This results in decoupling of the two isotopic systems and allows the dating of diagenesis on the one hand (Sm-Nd) and metamorphism on the other hand (Rb-Sr). 相似文献