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1.
对黑龙江陈家店金矿区内花岗斑岩进行LA-ICP-MS锆石U-Pb定年及元素地球化学研究。测年结果显示,花岗斑岩锆石~(206)Pb/~(238)U加权平均年龄为(227±4)Ma。岩石地球化学特征显示,花岗斑岩具有富Si、富Al、富碱质和低Mg、低Ca的特征;微量元素表现出高场强元素(HFSE)Th、Rb和K明显富集,而大离子亲石元素(LILE)Ba、Sr和Ti明显亏损的特点;稀土元素以明显的轻稀土元素富集重稀土元素相对亏损为特征,轻、重稀土元素分馏程度较强(La/Yb)_N=0.47~4.99,有强烈的Eu负异常(δEu=0.08~0.68)。构造判别图解显示,花岗斑岩具有碰撞后花岗岩特征,形成于碰撞后的构造环境。综合研究认为,矿区花岗斑岩的成因类型为S型花岗岩,其成岩时代为晚三叠世,形成于古亚洲洋闭合后的陆陆碰撞造山环境,地处火山弧形构造带,属于安第斯型大陆边缘。  相似文献   

2.
欧阳学财  狄永军  张达  徐洋  杨秋  王守营  陈杰  杜斌 《地质通报》2016,35(11):1869-1883
通过对东乡铜矿花岗斑岩进行岩石地球化学特征、锆石U-Pb定年研究,探讨其岩石成因、构造环境、形成时代与成矿的关系。东乡花岗斑岩的LA-ICP-MS锆石U-Pb年龄为156.4±1.5~161±1.0Ma。该岩体为高钾钙碱性系列,轻稀土元素富集,重稀土元素较亏损,具有明显的负Eu异常。微量元素富集大离子亲石元素,而亏损高场强元素。地球化学特征表明,东乡岩体形成于碰撞构造环境,岩浆来源于地幔,但形成演化期间经历了地壳物质的同化混染。该区矿石与花岗斑岩的稀土元素配分曲线存在一定的相似性,且成矿时间与岩浆侵入时间相近,表明岩浆侵入对东乡铜矿床的形成具有重要贡献。  相似文献   

3.
利用LA-ICP-MS锆石U-Pb法测得程潮矿区花岗岩成岩年龄为（128.8±0.5） Ma,石英二长斑岩成岩年龄为（128.3±0.5） Ma,闪长岩成岩年龄为（140.0±0.3） Ma,辉绿玢岩成岩年龄为(125.5±0.5) Ma,皆形成于早白垩世。地球化学分析结果显示：花岗质岩为高钾准铝质I型系列;闪长岩和辉绿玢岩为高钾钙碱性系列。各岩体的稀土元素总量较高,轻稀土强烈富集,轻、重稀土元素分异明显,无明显的负铕异常。花岗质岩的微量元素以富集Rb、Th、U、La等元素,贫Ba、Nb、Sr等元素为特点。闪长岩和辉绿玢岩具有相似的微量元素特征,表现为K、La、Nd富集和Ta、Nb、Sr、P、Ti亏损的特点。根据岩体的锆石Hf同位素组成和地球化学特征可知,程潮矿区各岩体可能是岩石圈地幔在部分熔融过程中,混入了不同数量古老下地壳物质的产物。矿区花岗质岩的成岩年龄与程潮Fe矿床的成矿年龄相近,暗示其与矿体有着密切的联系。  相似文献   

4.
通过详细的野外考察及测试分析发现,位于内蒙古阿巴嘎旗北部哈日化地区的花岗岩体,具有高硅、铝、富碱而贫钙、镁的特征;且稀土总量含量偏低,轻稀土相对富集,亏损重稀土元素,具中等负Eu异常,富集Rb、Th、U等大离子亲石元素,高场强元素Nb、P、Ti则表现为强烈亏损,高的Sr及低Rb/Sr值表明岩浆来自强烈富集地幔源区,属火山弧环境,显示TTG岩类特征;LAICP-MS锆石U-Pb测年结果表明,岩体侵位时代为(367.5±1.4)Ma,属于晚泥盆世。  相似文献   

5.
青海乌兰县赛坝沟金矿床位于柴北缘结合带东部,为一中型石英脉型金矿。为进一步确定该矿床形成年龄和成因,对矿区内与成矿关系密切的花岗斑岩脉进行锆石U-Pb年代学和岩石地球化学研究。花岗斑岩LA-ICP-MS锆石U-Pb年龄为(372.4±4.1) Ma,是晚泥盆世岩浆活动的产物。花岗斑岩具高硅、富碱的特征,分异指数(DI)为81.40~84.54,固结指数(SI)为3.56~8.17,表明岩石结晶分异程度较高;微量元素原始地幔标准化图解显示La、Hf、Rb、Th相对富集,而Nb、Ta、P、Ti、Ba、Sr相对亏损;稀土元素球粒陨石标准化配分曲线呈右倾的轻稀土元素富集型,且具轻微Eu元素负异常。综合判别图解分析,认为花岗斑岩属过铝质钙碱性的I型花岗岩。赛坝沟金矿床花岗斑岩形成时间与柴北缘中晚泥盆世陆内伸展时间一致,整体形成于柴北缘中晚泥盆世陆内伸展阶段的后造山构造环境中。脉岩紧邻矿体产出并充填在构造裂隙中,其形成与成矿年龄相接近,因此可将赛坝沟金矿形成时间上限限定在372.4 Ma。后期找矿勘查工作应重点围绕花岗斑岩脉展开。  相似文献   

6.
云南宾川小龙潭矿区斑岩体位于扬子板块西缘程海断裂带东侧,属金沙江-红河富碱侵入岩带组成部分.本文对矿区内与成矿密切相关的花岗斑岩进行了岩石学、年代学及地球化学研究.结果显示:花岗斑岩由二长花岗斑岩(MGP)和钾长花岗斑岩(KGP)组成,二者岩相学特征相似,空间上无明显分带关系,呈过渡渐变关系,具典型斑状结构.二长花岗斑岩和钾长花岗斑岩均具富碱、低钛和准铝质-弱过铝质特征,属准铝质-弱过铝质钾玄岩系列富碱斑岩;二者富集轻稀土元素(LREE)和大离子亲石元素(Rb、Ba、U),亏损重稀土元素(HREE)和高场强元素(Ta、Nb、Ti,Zr,Hf),具有较高Sr含量和Sr/Y值,中等负Eu异常(δEu=0.39～0.78),表现出C型埃达克质岩地球化学特征.二长花岗斑岩和钾长花岗斑岩具相似的地球化学特征,表明它们属同源岩浆演化产物.二长花岗斑岩锆石U-Pb年龄为34.7±0.3 Ma,反映其形成于古近纪始新世,与金沙江-红河富碱侵入岩活动高峰期(45～30 Ma)吻合.综合研究表明,小龙潭矿区花岗斑岩属具C型埃达克质岩地球化学特征的花岗岩,起源于底侵作用带来的幔源岩浆与石榴角闪岩相加厚下地壳部分熔融的混合岩浆,是印度-欧亚板块晚碰撞期力学性质由挤压向伸展转化动力学背景下的产物,具备成矿作用发生的物质基础,有较好的成矿潜力.  相似文献   

7.
江西山南铀矿区位于相山铀矿田的北部,矿区内出露有大量的流纹岩和花岗斑岩,两者也是矿区内最主要的赋矿岩石。地球化学和Sr、Nd同位素研究表明,流纹英安岩和花岗斑岩具有高硅(SiO2质量分数为69.47%~72.19%和72.32%~78.6%)、富钠(K2O/Na2O为0.4~0.52和0.4~0.67之间)的碱性岩特征,具有过铝质特征;流纹英安岩和花岗斑岩富集Th、U、Pb等高场强元素和Rb、K等大离子亲石元素,相对亏损Zr、Ti、Ta、Ce等高场强元素和Ba、Sr等大离子亲石元素,表现出轻稀土元素富集,重稀土元素亏损(LREE/HREE分别为9.32~11.59和2.12~8.27),(La/Yb)N值分别为10.59~14.26和1.41~9.47,两者具有明显的负Eu异常(0.41~0.56和0.09~0.32),地球化学特征显示流纹英安岩和花岗斑岩形成于低压环境,属于板内环境;锆石饱和温度计得出两者具有较高的结晶温度,分别为812.5~904.9℃和772.1~826℃;流纹英安岩和花岗闪长斑均具有较大的I Sr含量,较小的εNd(t)值(-7.81~-8.93)。地球化学和Sr、Nd同位素特征显示山南矿区的流纹英安岩和花岗斑岩具有明显的S型花岗岩特征,形成过程中经历了部分熔融和同化混染作用。流纹英安岩和花岗斑岩及铀矿化具有强烈的壳源特征,区域内分布的元古代变质岩中的砂质岩和泥质岩很可能就是两者的源岩。结合前人年代学研究和本次地球化学、Sr-Nd同位素研究结果,说明相山矿田山南矿区内的流纹英安岩和花岗斑岩及相应的铀矿化形成与中生代华南地区岩石圈发生大规模的伸展减薄有关。  相似文献   

8.
内蒙古塔尔气地区花岗斑岩的形成时代与岩石成因   总被引：2，自引：1，他引：1  
通过对内蒙古塔尔气地区花岗斑岩的野外地质特征、LA-ICP-MS锆石U-Pb年龄及地球化学特征的研究,讨论了该地区花岗斑岩的形成时代和成因机制。锆石U-Pb年龄及地球化学结果表明,塔尔气地区花岗斑岩形成于早白垩世136.5~126.4Ma;花岗斑岩具有高硅、富碱,弱过铝质(A/CNK=1.0~1.29),分异程度高的特点,属于高钾钙碱性系列,相对富集轻稀土元素和部分大离子亲石元素(Rb、Th、U、K),亏损高场强元素(Nb、Ta、Ti、P)。锆石Hf同位素组成表明,花岗斑岩具有较高的εHf(t)值(+7.19~+7.29),二阶段模式年龄为851~569Ma,暗示其可能起源于新元古代—早古生代期间从亏损地幔增生的地壳物质的部分熔融。结合区域地质资料分析,塔尔气花岗斑岩与研究区白音高老组火山岩可能为同期岩浆活动的产物,形成于伸展的构造环境。  相似文献   

9.
内蒙古东部新胜屯地区晚侏罗世A型花岗岩特征与成因   总被引：1，自引：0，他引：1  
代晓光 《江苏地质》2016,40(2):197-204
内蒙古新胜屯地区花岗岩侵入晚侏罗世玛尼吐组及白音高老组火山岩的岩性主要为中粒花岗岩、花岗斑岩及钾长花岗斑岩。在野外地质调查的基础上,通过研究晚侏罗世花岗岩的产出特征、岩石学特征及岩石地球化学特征,发现新胜屯地区花岗岩具有高硅碱富钾和贫镁低钙、TFeO/MgO比值高、碱性及准铝质—过铝质的特征;稀土元素总量高,轻稀土富集,Eu亏损显著,稀土元素配分曲线呈不对称右倾的"海鸥型"展布;微量元素Zr、Y、Ce及高场强元素Rb、Th、K、Sm、Nd含量高,而Sr、Ba、P、Ti亏损。上述岩体地球化学特征表明岩体属铝质A型花岗岩,形成于非造山期板内拉张的构造环境。  相似文献   

10.
黑龙江洋灰洞子斑岩型铜矿床地处兴蒙造山带东段、吉黑褶皱带北部,矿体主要赋存在花岗闪长斑岩和构造角砾岩中。为厘定洋灰洞子铜矿床的成岩成矿时代和构造背景,笔者对洋灰洞子花岗闪长斑岩进行了元素地球化学和LA--ICP--MS锆石U--Pb年代学的相关研究。岩石地球化学特征显示,花岗闪长斑岩富硅贫镁,属于过铝质钙碱性系列,富集轻稀土元素(LREE),(La/Yb)N=10.49~19.79,Eu显示弱负异常或正异常,高Sr低Y和Yb,富集大离子亲石元素(LILE),相对亏损高场强元素(HFSE),具有埃达克岩或埃达克质岩的特征。LA--ICP--MS锆石U--Pb测年结果显示,花岗闪长斑岩锆石206Pb/238U加权平均年龄为204.4±2.8 Ma和201.2±1.7 Ma。综合研究认为,洋灰洞子斑岩型铜矿床的成岩成矿时代可能为晚三叠世—早侏罗世之交,该矿床形成于古亚洲洋闭合后的陆陆碰撞造山环境,是加厚下地壳部分熔融形成的岩浆流体作用的结果。  相似文献   

11.
A pressure-volume-temperature data set has been obtained for lawsonite [CaAl2Si2O7(OH)2.H2O], using synchrotron X-ray diffraction and an externally heated diamond anvil cell. Unit-cell volumes were measured to 9.4 GPa and 767 K by angle dispersive X-ray diffraction using imaging plates. Phase changes were not observed within this pressure-temperature range, and lawsonite compressed almost isotropically at constant temperature. The P-V-T data have been analyzed using a Birch- Murnaghan equation of state and a linear equation of state expressed as β=–1/V0 (∂V/∂P) T . At room temperature, the derived equation of state parameters are: K 0=124.1 (18) GPa K'0 set to 4) and β–1=142.0(24) GPa, respectively. Our results are intermediate between previously reported measurements. The high-temperature data show that the incompressibility of lawsonite decreases with increasing temperature to ∼500 K and then increases above. Hence, the second order temperature derivative of the bulk modulus is taken into account in the equation of state; a fit of the volume data yields K 0=123.9(18) GPa, (∂K/∂T)P=–0.111(3) GPa K–1, (∂2 K/∂T 2)P=0.28(6) 10–3 GPa K–2, α0=3.1(2) 10–5 K–1, assuming K'0=4. Received: 2 June 1998 / Revised, accepted: 12 Ocotber 1998  相似文献   

12.
In order to avoid the pollution of trace metals in marine environment, it is necessary to establish the data and understand the mechanisms influencing the distribution of trace metals in marine environment. The concentration of heavy metals (Fe, Mn, Cr, Cu, Ni, Pb, Zn, Co and Cd) were studied in sediments of Ennore shelf, to understand the metal contamination due to heavily industrialized area of Ennore, south-east coast of India. Concentration of metals shows significant variability and range from 1.7 to 3.7% for Fe, 284–460 μg g−1 for Mn, 148.6–243.2 μg g−1 for Cr, 385–657 μg g−1 for Cu, 19.8–53.4 μg g−1 for Ni, 5.8–11.8 μg g−1 for Co, 24.9–40 μg g−1 for Pb, 71.3–201 μg g−1 for Zn and 4.6–7.5 μg g−1 for Cd. For various metals the contamination factor (CF) and geoaccumulation index (I geo) has been calculated to assess the degree of pollution in sediments. The geoaccumulation index shows that Cd, Cr and Cu moderately to extremely pollute the sediments. This study shows that the major sources of metal contamination in the Ennore shelf are land-based anthropogenic ones, such as discharge of industrial wastewater, municipal sewage and run-off through the Ennore estuary. The intermetallic relationship revealed the identical behavior of metals during its transport in the marine environment.  相似文献   

13.
Geochemistry of Thermal Waters of Continental Margin of Far East of Russia   总被引：2，自引：0，他引：2  
Studied waters belong to warm(T=30-50℃),alkaline(pH=8.9-9.3),low mineralized(TDS235 mg/1)Na-HCO_3 or Na-SO_4-HCO_3 thermal waters with high content of SiO_2(up to 81 mg/l)and F(up to 3.9 mg/1),occur on modern volcano-tectonic rejuvenated areas of Eastern Sikhote-Alin orogenic belt.Low~3He concentration as well as N_2/O_2 and N_2/Ar ratios exclude influence of deep mantle fluid.New rare earth element data constrain our understandmg of water-rock interaction occurring in the water source region.Meteoric origin of waters is proved by stable isotope values varying from-71‰to-136.1‰and from-10.8‰to-18.8‰forδ~2U andδ~(18)O respectively.REE patterns reflect high pH,resultfing from water-rock interaction and oxidative conditions.Calculations of deep aquifer temperature using Na-K and quartz geothermometers show 116.8-131.1°C and 82.2-125.8℃respectively.Presence of deep faults both with abnormal thermal gradient(~45-50 K/km)define unique geochemical shape of thermal waters of Sikhote-Alin,area,where no present volcanic activity is registered.  相似文献   

14.
On the south-eastern edge of Russia, the chemical composition of rainwater is controlled by sea salts, terrestrial material, as well as volcanic (Kuril islands volcanic area) and anthropogenic emissions, mostly in the southern part of the area. The predominant major ions of the Primorye, Sakhalin and the Kuril Islands rainwaters were respectively HCO3−–SO42−, Ca–Na, and of Cl–Na. Concentration of trace elements changes within 1–2 orders of magnitude but some difference in the distribution of the elements between continental and island rainwater is found. The concentration of the chemical elements in the particulate fraction varies from < 10% to 90% of the total concentration (dissolved + particulate) with the following distribution: Tl, Na, Ca, Sr, Zn, Cd (< 10%)–Be, Th, Bi, Rb, U, K, Sc (10–20%)–Cu, Mn, Mg, Mo, Se, Ba, Ni, As, Ag, Cs, Co, Y, Ga, V (20–50%)–Sb, Pb, Ge, Cr, Fe, Al (50–90%).The concentration of elements of the particulate fraction of the rainwater usually is significantly different from concentrations in the crust, including both higher and lower concentrations. The terrestrial contribution to dissolved elements was evaluated and follows the decreasing order: Fe > K, Mg, Ca > Ba, Sr > Na (65–1%). Close order was found for total (dissolved and solid) concentrations. Sea salt contribution to dissolved element concentration in the rainwater decrease in the following order: Cl, Mg > K, SO4 > Ca > HCO3−, Ba, Fe (78–0.1%). Calculation of anthropogenic and volcanic inputs for two ions (Cl− and SO42−) shows that anthropogenic inputs for the Vladivostok and Yuzno-Sakhalinsk cities can be evaluated as 15–20% of Cl− and up to 80–90% of SO42−. Volcanic components in the Kuril Islands, where anthropogenic inputs are absent, can reach up to 76% of SO42− and 36% of Cl−.  相似文献   

15.
Although, the Eastern Desert of Egypt forms about 22% of the surface area of the country, the area is undeveloped due to the limited availability of water. The morphologic units of the Eastern Desert consist of a number of drainage basins covering about 147,820 km2 (66.5% of the total surface area of the Eastern Desert). The basins drain the occasional rainwater, either towards the Nile Valley or to the Red Sea, causing flood hazards. The availability of water from the hydrologic systems of these basins could be improved by constructing runoff controlling systems in these areas (e.g. dykes and partially effective dams), which could save and make use of a considerable amount of water. The groundwater resources in the Eastern Desert can be divided into four main water-bearing units: the fractured crystalline Pre-Cambrian aquifer, the Nubian sandstone aquifer, the fractured limestone and sandstone aquifer and the Quaternary aquifer. The most productive aquifer is the Nubian sandstone while the fractured limestone and sandstone (Miocene) are only productive along the eastern part of the desert. The Quaternary aquifer occurs along the major dry washes (wadis) and is considered of limited potential as it is recharged mainly from the occasional rainfall. Detailed assessment of these aquifers should be carried out locally for further development of the area.
Resumen Aunque el Desierto Oriental de Egipto constituye alrededor del 22% de la superficie del país, esta área no se encuentra desarrollada por causa de la escasez de agua. Las unidades morfológicas del Desierto Oriental consisten de un número de cuencas de drenaje que cubren alrededor de 147,820 km2 (66.5% del área superficial total del Desierto Oriental). Estas cuencas drenan las aguas lluvias ocasionales, bien hacia el Valle del Nilo o hacia el Mar Rojo, causando amenazas de inundación. La disponibilidad de agua a partir de los sistemas hidrológicos de estas cuencas, puede ser mejorada al construir sistemas de control de escorrentía allí (Ej. Diques y presas de efectividad parcial), las cuales podrían almacenar y permitir el uso de una cantidad considerable de agua. Los recursos de agua subterránea en el Desierto Oriental, pueden dividirse en cuatro unidades principales portadoras de agua: El acuífero fracturado cristalino Pre – Cámbrico, el acuífero de la Arenisca de Nubia, el acuífero de arenisca y caliza fracturadas y el acuífero Cuaternario. El acuífero más productivo es la arenisca de Nubia, mientras que la arenisca y caliza fracturadas (Mioceno), son productivas únicamente a lo largo de la parte oriental del desierto. El acuífero Cuaternario se encuentra a lo largo de las corrientes intermitentes mayores (Wadis) y se le considera de potencial limitado por ser recargado principalmente a partir de lluvia ocasional. Una evaluación detallada de estos acuíferos debe llevarse a cabo localmente, para el desarrollo adicional de esta área.
Résumé Bien que le Désert Est occupe 22% de la surface de lEgypte, la région est sousdeveloppée à cause de la ressource en eau limitée. Les unités morphologiques consistent en des bassins drainant qui couvrent une surface de 147,820 km2 ,représentant 66.6% de la surface du Désert Est. Les bassins drainent les plues intermittentes vers la vallée du Nil ou vers la Mer Rouge en provocant des inondations. On peut augmenter la ressource en eau dans cette région en réalisant des systèmes de contrôle de ruissellements (des digues...) qui peuvent sauver et utiliser un volume considérable deau. La ressource en eau souterraine du Désert Est est cantonnée dans quatre grandes structures: l› aquifère fracturé cristallin Précambrien, l› aquifère gréseux Nubien, l› aquifère calcaire et gréseux et l› aquifère quaternaire. Le plus productif est l› aquifère gréseux Nubien tendis que les calcaire et les grèses dage miocène sont productives seulement dans la partie est du désert. L› aquifère quaternaire se trouve au long des oueds sèches et on considéré quil a un potentiel limité, étant rechargé seulement par les plues intermittentes. Pour le futur développement de la région il est nécessaire une évaluation détaillée, à léchelle locale de ces aquifères.
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16.
Isothermal thermogravimetric experiments have been carried out to determine the reaction kinetics of the dehydration processes in fuller's earth, a natural Ca-montmorillonite. Dehydration in swelling clays is a complex reaction, and analysis of the thermogravimetric data using empirical rate equations and time-transformation analysis reveals that the nature of the rate controlling mechanism is dependent upon both the temperature regime of the sample as well as the extent of reaction. For fuller's earth, we find that the dehydration kinetics are dominated by a nucleation and growth mechanism at low temperatures and fractions transformed (stage I), but above 90 °C the last stages of the reaction are diffusion controlled (stage II). The activation energy for dehydration during stage I is around 35 kJ · mol−1, whereas the removal of water during stage II requires an activation energy of around 50 kJ · mol−1. These two stages of dehydration are associated with primary collapse of the interlayer (stage I) and movement of water that is hydrated to cations within the interlayer (stage II). Received: 28 August 1998 / Revised, accepted: 27 January 1999  相似文献   

17.
在南极格罗夫山普通球粒陨石的风化等级划分中出现了和Wlotzka(1993)标准矛盾的现象。部分普通球粒陨石的金属和陨硫铁氧化不足20%,然而硅酸盐却发生了蚀变。如果考虑金属的氧化量,这种风化程度应为W1,如果考虑硅酸盐的蚀变,这种风化程度应为W5。对于存在如此大的差异本文给出了折衷的解决办法——对金属和硅酸盐同时进行风化等级划分。金属的风化等级划分为W_m0-W_m4五个,硅酸盐风化等级划分为W_s0-W_s3四个。依据新方案,GRV 021588、021636、021772和021957等4块无法用Wlotzka(1993)标准来确定风化等级的陨石的风化等级均为W_m1-W_s1。而陨石GRV 023312的风化等级为W_m3-W_s0,其相当于Wlotzka(1993)标准中的W3。  相似文献   

18.
This study presents a numerical investigation of the effect of volatilization and the supercritical state of pore water on maturation of organic matter in host rocks based on the heat flow models assuming the instantaneous and finite-time intrusion mechanisms of magma. A 15 m thick, well-dated basic sill in the DSDP 41-368 hole near Cape Verde Rise, eastern Atlantic is selected as an example due to the sufficient thermophysical parameters of rocks and the definite burial and thermal history of the shale host rocks. Results indicate: (1) The effect of the temperature-dependent thermal properties of pore water at a hydrostatic pressure of 414 bar on the predicted vitrinite reflectance (Rr) is less than 0.1% no matter which intrusion mechanism of magma is assumed and can hence be ignored reasonably; (2) The consideration of volatilization of pore water can reduce the predicted Rr of host rocks significantly. In case of the instantaneous intrusion mechanism, the maximum deviation of the predicted Rr caused by pore-water volatilization reaches 1.3% at the location of half the sill thickness away from the contact (i.e. X/D = 0.5), and the deviation above 0.5% can occur in the region from 0.3 to 1.0 in the form of X/D. In case of the finite-time intrusion mechanism, the maximum deviation of the predicted Rr due to pore-water volatilization attains 1.15% at X/D = 0.25, and the region where the deviation is larger than 0.5% lies between 0.15 and 0.6 in the form of X/D; (3) If hydrothermal convection in the host rocks is allowed for, the predicted Rr of the overlying host rocks is less than that of the underlying host rocks at the same X/D in the inner region of the contact aureole of igneous intrusions, whereas the phenomenon is converse in the outer region. In contrast, the measured Rr profile shows that at the same X/D, Rr of the overlying host rocks is totally higher than that of the underlying host rocks. Thus, it is not the hydrothermal convection in the overlying host rocks that resulted in the asymmetry of the current Rr profiles below and above the sill; (4) The predicted Rr based on the heat conduction model assuming the finite-time intrusion mechanism and pore-water volatilization matches well with the measured one out of the region where the Rr geothermometer is unreliable due to the effect of volatilization of pore water. This demonstrates that the finite-time intrusion mechanism of magma, together with pore-water volatilization, possibly represents natural conditions.  相似文献   

19.
As a pilot study of the role of water in the attenuation ofseismic waves in the Earth's upper mantle, we have performeda series of seismic-frequency torsional forced-oscillation experimentson a natural (Anita Bay) dunite containing accessory hydrousphases, at high temperatures to 1300°C and confining pressure(Pc) of 200 MPa, within a gas-medium high-pressure apparatus.Both oven-dried and pre-fired specimens wrapped in Ni–Fefoil within the (poorly) vented assembly were recovered essentiallydry after 50–100 h of annealing at 1300°C followedby slow staged cooling. The results for those specimens indicatebroadly similar absorption-band viscoelastic behaviour, butwith systematic differences in the frequency dependence of strain-energydissipation Q–1, attributed to differences in the smallvolume fraction of silicate melt and its spatial distribution.In contrast, it has been demonstrated that a new assembly involvinga welded Pt capsule retains aqueous fluid during prolonged exposureto high temperatures—allowing the first high-temperaturetorsional forced-oscillation measurements under high aqueousfluid pore pressure Pf. At temperatures >1000°C, a markedreduction in shear modulus, without concomitant increase inQ–1, is attributed to the widespread wetting of grainboundaries resulting from grain-scale hydrofracturing and themaintenance of conditions of low differential pressure Pd =Pc – Pf . Staged cooling from 1000°C is accompaniedby decreasing Pf and progressive restoration of significantlypositive differential pressure resulting in a microstructuralregime in which the fluid on grain boundaries is increasinglyrestricted to arrays of pores. The more pronounced viscoelasticbehaviour observed within this regime for the Pt-encapsulatedspecimen compared with the essentially dry specimens may reflectboth water-enhanced solid-state relaxation and the direct influenceof the fluid phase. The scenario of overpressurized fluids andhydrofracturing in the Pt-encapsulated dunite specimen may havesome relevance to the high Q–1 and low-velocity zonesobserved in subduction-zone environments. The outcomes of thisexploratory study indicate that the presence of water can havea significant effect on the seismic wave attenuation in theupper mantle and provide the foundation for more detailed studieson the role of water. KEY WORDS: seismic wave attenuation; water; dunite; hydrous mineral; shear modulus; viscoelasticity; olivine; grain-scale hydrofracturing  相似文献   

20.
Distribution of fluoride in groundwater of Maku area, northwest of Iran   总被引：3，自引：0，他引：3  
High fluoride groundwater occurs in Maku area, in the north of West Azarbaijan province, northwest of Iran. Groundwater is the main source of drinking water for the area residents. Groundwater samples were collected from 72 selected points including 40 basaltic and 32 nonbasaltic springs and wells, in two stages, during June and August 2006. The areas with high fluoride concentrations have been identified, and the possible causes for its variation have been investigated. Regional hydrogeochemical investigation indicates that water-rock interaction is probably the main reason for the high concentration of ions in groundwater. The concentration of F− in groundwater is positively correlated with that of HCO3 − and Na+, indicating that groundwater with high HCO3 − and Na+ concentrations help to dissolve some fluoride-rich minerals. All of the water samples, collected from the basaltic areas do not meet the water quality standards for fluoride concentration and some other parameters. Hence, it is not suitable for consumption without any prior treatment. Inhabitants of the area that obtain their drinking water supplies from basaltic springs and wells are suffering from dental fluorosis. The population of the study area is at a high risk due to excessive fluoride intake especially when they are unaware of the amount of fluoride being ingested due to lack of awareness.  相似文献   

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