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1.
云南金平铜厂斑岩Cu(Mo-Au)矿床含矿石英正长斑岩地球化学特征及成因机制探讨 总被引：4，自引：4，他引：0
铜厂斑岩型Cu(Mo-Au)矿床位于金沙江-红河富碱侵入岩带的南段,其含矿的石英正长斑岩侵入体属金沙江-红河富碱侵入岩带的重要组成部分.对铜厂石英正长斑岩开展详细的地球化学研究结果表明,其具有高碱、富钾及准铝质-弱过铝质等特征,属钾玄岩系列岩石;微量和稀土元素分析表明,铜厂石英正长斑岩明显富集Rb、Ba、Th、U、K、La和Sr等大离子亲石元素,相对亏损Nb、Ta和Ti等高场强元素,具有明显的“TNT”负异常,稀土总量高,明显富集轻稀土而亏损重稀土,轻重稀土分馏显著;(87Sr/86Sr)i为0.707097～0.707138,εNd(t)为-7.1 ～ -6.8,在Sr-Nd同位素相关图上,与EMII来源岩石相似.对比金沙江-红河富碱侵入岩带北段的玉龙含矿的二长花岗斑岩和中段的马厂箐含矿的花岗斑岩的地球化学特征,铜厂含矿斑岩具有高的全碱、微量元素和稀土元素含量、高的(87Sr/86Sr)i值和低的εNd(t)值、不具埃达克质岩属性等特征.综合研究表明,铜厂含矿的石英正长斑岩在成因类型上属于A型花岗岩类,形成于～35 Ma的晚碰撞走滑环境且直接起源于EMII地幔的部分熔融铜厂与玉龙及马厂箐斑岩型Cu( Mo-Au)矿床含矿斑岩地球化学特征和成矿规模存在差异,与源区物质的部分熔融程度和地壳物质的混染程度密切相关. 相似文献
2.
西藏甲玛埃达克质斑岩的地球化学特征及意义 总被引：4，自引：0，他引：4
分析了西藏甲玛石英闪长玢岩-二长花岗斑岩-花岗闪长斑岩岩相学、年代学及地球化学特征,研究其形成演化及构造环境,并建立岩浆成因模式。甲玛石英闪长玢岩-二长花岗斑岩-花岗闪长斑岩是具弧岩浆地球化学特征的准铝质高钾钙碱性岩岩石系列,同时具有O型(向C型过渡)埃达克质岩和I型(或磁铁矿型)花岗岩的特征。其成因与新特提斯洋板片脱水熔融形成的流体与地幔楔发生地幔交代作用形成的EMⅡ型富集地幔有关。中新世兰格期(15 Ma左右),由于拉萨地体东西向的"崩塌",导致拉萨地体开始伸展减薄,从而使交代地幔(EMⅡ型富集地幔)减压熔融,形成了富含Cu、Au等成矿物质的具I型(或磁铁矿型)弧岩浆地球化学特征的准铝质富钾O型埃达克质铁镁质岩浆,并在沿该时期的正断层及裂谷系统侵位过程中,不断与下地壳高钾及中—高Fe/Mg的花岗质岩浆发生不同程度的岩浆混合作用,伴随着相对较弱的岩浆结晶分异过程不断侵位浅地表,进而形成了独特的石英闪长玢岩-二长花岗斑岩-花岗闪长斑岩岩石组合。 相似文献
3.
九顶山复式岩体沿北西向金沙江–红河断裂与南北向程海断裂交汇处发育,处于南北地洼区与滇西地洼区接触带,是滇西地洼期斑岩成矿带中段的代表性富碱斑岩体之一。该岩体由呈岩株、岩脉、岩墙或岩床等产出的斑状花岗岩、正长斑岩、(二长)花岗斑岩、碱长花岗斑岩和煌斑岩等组成。本文着重对正长斑岩的形成年代、岩石地球化学和成因特征开展研究,结果表明:正长斑岩的LA-ICP-MS锆石U-Pb年龄为34.6±0.7 Ma,即岩浆侵位于始新世(E2),属滇西地洼激烈期及新生代富碱岩浆活动高峰期(45~30 Ma)的产物;岩石具高硅(Si O256%)、高钾(K2O=3.38%~8.92%,K2O/Na2O1)、富碱(ALK=8.15%~11.15%)和低Mg O(3%)的特征,属钾玄岩系列–高钾钙碱性系列过铝质(A/CNK=0.71~1.22)花岗岩;在微量元素组成上,岩石高Sr(400×10-6)、低Y(18×10-6)和Yb(1.9×10-6),与陆内造山环境形成的"C型"钾质埃达克岩地球化学特征类似;全岩的Sr-Nd-Hf同位素组成特征显示岩浆源区是壳幔物质混合的"EMII型"富集地幔源。正长斑岩的形成应与印度–欧亚板块碰撞俯冲背景下,金沙江–红河断裂大规模左行走滑引起的热扰动和局部引张作用有关,在这种区域热–动力学条件下,地幔部分熔融与地壳物质发生混合作用,形成活化型壳幔混合源高钾富碱岩浆。 相似文献
4.
云南永胜分水岭矿区富碱斑岩地球化学、锆石U-Pb年龄及其地质意义 总被引：1，自引：0，他引：1
云南永胜分水岭矿区富碱斑岩体位于扬子地块西缘宾川-程海断裂与箐河断裂交汇部位,属于金沙江–哀牢山富碱斑岩带组成部分,主要由黑云母花岗闪长斑岩(BGDP)和花岗闪长斑岩(GDP)组成。两类岩石均具有富碱(BGDP的K_2O+Na_2O均值为8.22%、GDP的K_2O+Na_2O均值为8.13%)、富钾(BGDP的K_2O/Na_2O均值为1.08,GDP的K_2O/Na_2O均值为1.2)和准铝质(BGDP的A/CNK均值为0.95、GDP的A/CNK均值为0.94)特征,表明二者均属准铝质高钾钙碱性系列的富碱斑岩。两类岩石均富集大离子亲石元素(Rb、Ba、Pb、Sr)、Th、U和LREE,亏损高场强元素(Ta、Nb和Ti),二者稀土元素配分模式均为右倾平滑型,且Eu异常不显著(δEu=0.85~1.12)。地球化学特征表明它们属同源岩浆演化的产物,具有相似的源区特征和成岩动力学背景。花岗闪长斑岩LA-ICP-MS锆石U-Pb年龄为34.5±0.3 Ma(MSWD=1.5,n=19),落在金沙江–哀牢山富碱斑岩带岩浆活动的高峰期内(45~30 Ma)。综合岩石学、地球化学和成岩年代学资料,认为分水岭矿区富碱斑岩形成的动力学条件和源区特征与金沙江–哀牢山富碱斑岩带一致,即形成于印度–欧亚板块碰撞期后动力学性质转换背景下,是加厚下地壳和上地幔部分熔融的产物,与金沙江–哀牢山走滑断裂构造活动密切相关。 相似文献
5.
本文对躬穷左波Fe-Cu矿区出露的三套酸性侵入岩进行了系统的LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。年代学测试结果显示花岗斑岩、二长花岗斑岩和钾长花岗岩~(206)Pb/238U加权平均年龄分别为147.0 Ma、143.6 Ma和142.8 Ma,矿区存在晚侏罗世—早白垩世存在3期岩浆事件。岩石地球化学组成特征显示,花岗斑岩属准铝质-弱过铝质I型花岗岩;二长花岗斑岩为高钾钙碱性系列,属弱过铝质I型花岗岩;钾长花岗岩经历了强烈的结晶分异作用,属高分异I型花岗岩。岩石微量元素富集Rb、Th、U、Pb而亏损Nb、Ta、Ti、P元素,Nb/Ta比值接近大陆地壳组成及锆石负的εHf(t)值特征,指示成岩物质以壳源物质为主。躬穷左波晚侏罗世矽卡岩型Fe-Cu矿化事件的发现对于完善班—怒带西段成矿规律和指导区域找矿工作具有重要意义。 相似文献
6.
《矿物学报》2015,(4)
大理笔架山铜矿区位于金沙江-红河富碱斑岩成矿带中部,与斑岩有关的铜(金)矿找矿取得了新突破。本文在详实的成矿斑岩岩相学观察基础上,开展了系统的岩石地球化学和年代学研究。与成矿相关的石英二长斑岩具有富碱(K2O+Na2O均值为9.97%)、富钾(K2O/Na2O均值为2.34)和准铝质(A/CNK均值为0.89)特征,属准铝质钾玄岩系列;微量元素具LILE(Rb、Ba、U、Th和Sr)富集和HFSE(Ta、Nb和Ti)亏损特征,与大陆地壳特征相似;稀土元素具LREE富集和Eu(均值0.73)弱负异常特征,与壳幔混合型花岗岩相近。岩石地球化学特征表明,石英二长斑岩源区具典型壳-幔混合特征,其中以部分熔融的古老地壳物质为主。LA-ICP-MS锆石U-Pb年龄(35.6±0.19 Ma)与金沙江-红河富碱斑岩带岩浆活动高峰期(45~30 Ma)一致。研究结果进一步佐证了本区富碱斑岩是在印-欧板块后碰撞伸展背景下,由加厚下地壳和上地幔部分熔融形成的,与金沙江-红河断裂的走滑构造事件相关。 相似文献
7.
喇嘛苏铜矿床斑岩体地质地球化学特征及含矿性评价 总被引：5，自引：0，他引：5
矿区内广泛发育以斜长花岗斑岩和花岗闪长斑岩为主的中酸性斑岩体。斑岩的结构特征反映出岩浆浅成侵位成因。研究表明该区斑岩具有相对富硅和富碱高钾的岩石化学特征,属钙碱性系列;具有Ｃｕ、Ａｇ、Ｂｉ等成矿元素高丰度的微量元素地球化学特征和低ΣＲＥＥ与高δＥｕ值的稀土地球化学特征。矿区内铜矿化富集在斑岩体内外接触带,斑岩体深源浅成特点和富碱高钾岩石化学特征于铜矿化富集有利。Ｃｕ、Ａｇ等成矿元素高丰度及其与矿化类型一致性说明成矿与岩浆活动有密切成因关系。 相似文献
8.
长江中下游贵池矿集区燕山期岩浆作用及其地质意义:年代学、地球化学及Sr-Nd-Hf同位素证据 总被引：17，自引：10，他引：7
长江中下游贵池地区燕山期侵入岩发育,与成矿关系密切.本文对该区侵入岩开展了详细的锆石U-Pb年代学、地球化学及Sr-Nd-Hf同位素研究.结果表明,马头花岗闪长斑岩形成于147±2Ma,而花园巩石英二长岩形成于127±1Ma,比花岗闪长斑岩晚约20Ma.早期的花岗闪长斑岩(147 ～ 145Ma)为高钾钙碱性系列,具有高Al2O3、Sr含量和Sr/Y、La/Yb比值,以及低的Y、Yb含量,与埃达克质岩的地球化学特征一致;而晚期石英二长岩(127Ma)和石英正长岩为钾玄岩系列,具有高的(Na2O+ K2O)、Zr、Nb、Y含量和Y/Nb、Yb/Ta比值,与造山带A2型花岗岩地球化学特征相似;碱长花岗岩(125～124Ma)同样具有A型花岗岩的地球化学特征,但与石英二长岩、石英正长岩相比,碱长花岗岩的Y/Nb、Yb/Ta比值相对较低,具板内环境A1型花岗岩的地球化学特征.因此,贵池地区岩浆岩从早期的埃达克质岩变为晚期的A型花岗岩,反应了晚中生代时期长江中下游地区的构造环境由大陆边缘环境向伸展环境的转变. 相似文献
9.
鹿鸣钼矿是伊春-延寿成矿带内近年发现的大型斑岩钼矿,矿区主要出露含矿的二长花岗岩、花岗斑岩,不含矿的花岗闪长岩及似斑状花岗闪长岩四种岩性。二长花岗岩与花岗斑岩具有相似的低Sr高Y等地球化学特征,形成于194.8±0.7Ma~184Ma前后的早侏罗世,是斑岩型矿床的赋矿围岩。花岗闪长岩及似斑状花岗闪长岩含有暗色岩包体,主要为高钾钙碱性系列岩石,但以高Sr、低Y及富Na为特征,部分地球化学指标与中国东部埃达克岩极为相似,形成于176.2±2.1Ma并与辉钼矿Re-Os法获得的成矿年龄一致,被认定为斑岩型矿床的成矿母岩。高Sr和低Sr两类花岗岩形成于不同的构造背景,与中生代时期中国东部及其邻区几次重大地质事件密切相关。鹿鸣斑岩型钼矿床与中侏罗世太平洋板块俯冲在高氧逸度条件下熔融形成的埃达克质岩浆高侵位有关。鹿鸣矿区埃达克岩的发现表明中侏罗世太平洋板块已经发生了萎缩与消减,与之相关的岩浆作用及成矿应该具有广泛的区域性,扎实的岩石学工作可为区域更多斑岩型矿床的发现提供线索。 相似文献
10.
羊拉铜矿是三江地区金沙江—哀牢山铜金成矿带的大型铜矿床,位于中咱微陆块与昌都—思茅地块相夹持的金沙江板块结合带,矿床与印支期侵入岩(花岗闪长岩体)有密切的时空成因联系。通过对江边花岗闪长斑岩体、花岗闪长岩体的地球化学研究,发现岩体富SiO2、Al和大离子亲石元素,贫Fe、Mg、高场强元素,属准铝质-弱过铝质I型花岗岩;各岩石样品点均落入火山弧花岗岩和同碰撞花岗岩过渡区域,反映江边岩体属活动板块边缘产物,岩浆除幔源外,还混入了下地壳熔融物质。江边岩体锆石原位U-Pb定年分析得出2个花岗闪长斑岩(ZKJ1-1-14、ZKJ2-1-7)年龄为215 Ma、208 Ma,3个花岗闪长岩(ZKJ1-1-17、ZKJ2-1-6、ZKJ2-1-8)年龄为221 Ma、220 Ma和214 Ma,结合对路农、里农和贝吾花岗闪长岩体结晶年龄分析,得出羊拉矿区成矿岩体自南向北年龄逐渐变新的侵位序列;矿区内岩浆活动持续25 Ma,印证江边岩体同属俯冲-碰撞作用所致的造山期岛弧型花岗岩类,为碰撞后拉张背景的典型产物。 相似文献
11.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
12.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
13.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献