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1.
In this experimental study, rate constants were measured for the reactions of ozone with 13 polycyclic aromatic hydrocarbons (PAHs) adsorbed on different types of particles. Graphite and silica were chosen to model, respectively, carbonaceous and mineral atmospheric particles. The pseudo-first order rate constants were obtained from the fit of the experimental decay of particulate PAH concentrations versus time. Second order rate constants were calculated considering the ozone gaseous concentration. At room temperature, rate constants varied, in the case of graphite particles, between (1.5 ± 0.5) × 10−17 and (1.3 ± 0.7) × 10−16 cm3 molecule−1 s−1 for chrysene and dibenzo[a,l]pyrene, respectively, and, in the case of silica particles, between (1.5 ± 0.3) × 10−17 and (1.4 ± 0.3) × 10−16 cm3 molecule−1 s−1 for fluoranthene and benzo[a]pyrene, respectively. Different granulometric parameters (particle size, pore size) and different PAH concentrations were tested in the case of silica particles. Heterogeneous reactions of ozone with particulate PAHs are shown to be more rapid than those occurring in the gas-phase, and may be competitive with atmospheric photodegradation.  相似文献   

2.
Simulations of polar ozone losses were performed using the three-dimensional high-resolution (1∘ × 1∘) chemical transport model MIMOSA-CHIM. Three Arctic winters 1999–2000, 2001–2002, 2002–2003 and three Antarctic winters 2001, 2002, and 2003 were considered for the study. The cumulative ozone loss in the Arctic winter 2002–2003 reached around 35% at 475 K inside the vortex, as compared to more than 60% in 1999–2000. During 1999–2000, denitrification induces a maximum of about 23% extra ozone loss at 475 K as compared to 17% in 2002–2003. Unlike these two colder Arctic winters, the 2001–2002 Arctic was warmer and did not experience much ozone loss. Sensitivity tests showed that the chosen resolution of 1∘ × 1∘ provides a better evaluation of ozone loss at the edge of the polar vortex in high solar zenith angle conditions. The simulation results for ozone, ClO, HNO3, N2O, and NO y for winters 1999–2000 and 2002–2003 were compared with measurements on board ER-2 and Geophysica aircraft respectively. Sensitivity tests showed that increasing heating rates calculated by the model by 50% and doubling the PSC (Polar Stratospheric Clouds) particle density (from 5 × 10−3 to 10−2 cm−3) refines the agreement with in situ ozone, N2O and NO y levels. In this configuration, simulated ClO levels are increased and are in better agreement with observations in January but are overestimated by about 20% in March. The use of the Burkholder et al. (1990) Cl2O2 absorption cross-sections slightly increases further ClO levels especially in high solar zenith angle conditions. Comparisons of the modelled ozone values with ozonesonde measurement in the Antarctic winter 2003 and with Polar Ozone and Aerosol Measurement III (POAM III) measurements in the Antarctic winters 2001 and 2002, shows that the simulations underestimate the ozone loss rate at the end of the ozone destruction period. A slightly better agreement is obtained with the use of Burkholder et al. (1990) Cl2O2 absorption cross-sections.  相似文献   

3.
Ozone tendencies due to chemistry and transport are calculated by a mesoscale model using a fine horizontal resolution (3 km × 3 km), over South-Eastern France. Over that region where the anthropogenic emissions are very strong, ozone pollution is highlighted during two intensive observations periods of the ESCOMPTE campaign, when the sea breeze penetrates far into the Durance and Rhone valleys and the up-slope breezes are developed. From a fine analysis of time series of ozone concentration at different ground stations along these valleys and from numerical results, it is possible to discriminate the tendency due to chemistry from the tendency due to dynamical processes. We can distinguish both processes, either local chemical production/loss or dynamical increase/decrease (transport, deposition) on maps of ozone budget according to the meteorological conditions. In particular, we show that the variations due to transport can be have the same order of magnitude than those due to chemistry, reaching 20 ppbv h−1, whereas those due to chemistry are around 30 ppbv h−1.  相似文献   

4.
未来甲烷排放增加对平流层水汽和全球臭氧的影响   总被引：3，自引：0，他引：3  
利用一个耦合的大气化学-气候模式(WACCM3)研究了地表甲烷排放增加对平流层水汽和全球臭氧变化的影响.结果表明,如果地表甲烷的排放量在2000年的基础上增加50%(达到政府间气候变化专门委员会A1B排放情景中2050年的值),平流层水汽体积分数将平均增加约0.8×10-6.南半球平流层甲烷转化为水汽的效率比北半球高.在北半球平流层中,1mol甲烷分子可以转化为约1.63mol的水汽分子,而在南半球1mol甲烷分子大概可以转化为约1.82mol的水汽分子.甲烷排放增加50%将使全球中低纬度地区以及北半球高纬度地区的臭氧柱总量增加1%-3%,使南半球高纬度地区臭氧柱总量增加近8%,而秋季(南半球春季)南极地区臭氧柱总量增加幅度可高达20%,南极臭氧的这种显着增加主要是由于甲烷增加造成的化学反馈所致.在北半球中高纬度地区,甲烷增加引起的臭氧变化主要与甲烷氧化导致的水汽增加有关.研究还表明,未来甲烷排放增加对臭氧的恢复作用其实与溴化物排放的减少一样重要.  相似文献   

5.
The uptake of water vapor on MgCl2×6H2O and NaCl salt dry solid films was studied over the temperature range 240 to 340 K and at 1 Torr pressure of helium using a flow reactor coupled to a modulated molecular beam mass spectrometer. The H2O to salt uptake data were obtained from the kinetics of H2O loss on salt coated Pyrex rods. The following Arrhenius expression was obtained for the initial uptake coefficient of H2O on MgCl2×6H2O films: γ 0 (MgCl2) = (6.5 ± 1.0) × 10−6 exp[(470 ± 40)/T] (calculated with specific BET surface area, quoted uncertainties are 1σ statistical). The rate of H2O adsorption on NaCl was found to be much lower than on MgCl2×6H2O, and only an upper limit was determined for the corresponding uptake coefficient: γ (NaCl) ≤ 5.6 × 10−6 at T = 300 K. The results show that the rate of H2O adsorption to salt surfaces is drastically dependent on the salt sample composition.  相似文献   

6.
The water vapor budget and the cloud microphysical processes associated with a heavy rainfall system in the Dabie Mountain area in June 2008 were analyzed using mesoscale reanalysis data(grid resolution 0.03 × 0.03,22 vertical layers,1-h intervals),generated by amalgamating the local analysis and prediction system(LAPS).The contribution of each term in the water vapor budget formula to precipitation was evaluated.The characteristics of water vapor budget and water substances in various phase states were evaluated and their differences in heavy and weak rainfall areas were compared.The precipitation calculated from the total water vapor budget accounted for 77% of actual precipitation;surface evaporation is another important source of water vapor.Water vapor within the domain of interest mainly came from the lower level along the southern boundary and the lower-middle level along the western boundary.This altitude difference for water vapor flux was caused by different weather systems.The decrease of local water vapor in the middle-lower layer in the troposphere during the system development stage also contributed to precipitation.The strength and the layer thickness of water vapor convergence and the content of various water substances in the heavy rainfall areas were obviously larger than in the weak rainfall areas.The peak values of lower-level water vapor convergence,local water vapor income,and the concentration of cloud ice all preceded the heaviest surface rainfall by a few hours.  相似文献   

7.
In this study,the clear sky hourly global and net solar irradiances at the surface determined using SUNFLUX,a simple parameterization scheme,for three stations(Gaize,Naqu,and Lhasa) on the Tibetan Plateau were evaluated against observation data.Our modeled results agree well with observations.The correlation coefficients between modeled and observed values were > 0.99 for all three stations.The relative error of modeled results,in average was < 7%,and the root-mean-square variance was < 27 W m 2.The solar irradiances in the radiation model were slightly overestimated compared with observation data;there were at least two likely causes.First,the radiative effects of aerosols were not included in the radiation model.Second,solar irradiances determined by thermopile pyranometers include a thermal offset error that causes solar radiation to be slightly underestimated.The solar radiation absorbed by the ozone and water vapor was estimated.The results show that monthly mean solar radiation absorbed by the ozone is < 2% of the global solar radiation(< 14 W m 2).Solar radiation absorbed by water vapor is stronger in summer than in winter.The maximum amount of monthly mean solar radiation absorbed by water vapor can be up to 13% of the global solar radiation(95 W m 2).This indicates that water vapor measurements with high precision are very important for precise determination of solar radiation.  相似文献   

8.
Estimates of the Chemical Budget for Ozone at Waliguan Observatory   总被引：6，自引：0，他引：6  
Waliguan Observatory (WO) is an in-land Global Atmosphere Watch (GAW) baseline station on the Tibetan plateau. In addition to the routine GAW measurement program at WO, measurements of trace gases, especially ozone precursors, were made for some periods from 1994 to 1996. The ozone chemical budget at WO was estimated using a box model constrained by these measured trace gas concentrations and meteorological variables. Air masses at WO are usually affected by the boundary layer (BL) in the daytime associated with an upslope flow, while it is affected by the free troposphere (FT) at night associated with a downslope flow. An anti-relationship between ozone and water vapor concentrations at WO is found by investigating the average diurnal cycle pattern of ozone and water vapor under clear sky conditions. This relationship implies that air masses at WO have both the FT and BL characteristics. Model simulations were carried out for clear sky conditions in January and July of 1996, respectively. The chemical characteristics of mixed air masses (MC) and of free tropospheric air masses (FT) at WO were investigated. The effects of the variation in NOx and water vapor concentrations on the chemical budget of ozone at WO were evaluated for the considered periods of time. It was shown that ozone was net produced in January and net destroyed in July for both FT and MC conditions at WO. The estimated net ozone production rate at WO was –0.1 to 0.4 ppbv day–1 in FT air of January, 0.0 to 1.0 ppbv day–1 in MC air of January, –4.9 to –0.2 ppbv day–1 in FT air of July, and –5.1 to 2.1 ppbv day–1 in MC air of July.  相似文献   

9.
The results of one year’s monitoring in Srednja Bijambarska Cave (Bosnia and Herzegovina) are presented and discussed. Temporal variations of the carbon dioxide (CO2) concentration are controlled by the switching between two ventilation regimes driven by outside temperature changes. A regression model with a simple perfectly mixed volume applied to a cave sector (“Music hall”) resulted in an estimate of ventilation rates between 0.02 h−1 and 0.54 h−1. Carbon dioxide input per plan surface unit is estimated by the model at around 50 × 10−6 mh−1 during the winter season and up to more than 1000 × 10−6 mh−1 during the first temperature falls at the end of summer (0.62 μmoles m−2 s−1 and 12.40 μmoles m−2 s−1 for normal conditions respectively). These values have been found to be related to the cave ventilation rate and dependent on the availability of CO2 in the surrounding environment. For airflow close to zero the values of CO2 input per plan surface have a range in the order of magnitude of a few units × 10−6 mh−1. Based on two experiments, the anthropogenic contribution from cave visitors has been calculated, at between 0.35 lCO2 min−1 person−1 and 0.45 lCO2min−1person−1.  相似文献   

10.
A study of the oxidation mechanism of N-methyl pyrrolidinone (C5H9NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of cm3 molecule − 1 s− 1): kNMP = (2.2 ± 0.4) × 10− 11, kNMS = (1.4 ± 0.3) × 10− 12 and kFP = (6 ± 1) × 10− 12. The results are presented and discussed in terms of the atmospheric impact.  相似文献   

11.
The Summer Surface Energy Balance of the High Antarctic Plateau   总被引：1，自引：0，他引：1  
The summertime surface energy balance (SEB) at Kohnen station, situated on the high Antarctic plateau (75°00′ S, 0°04′ E, 2892m above sea level) is presented for the period of 8 January to 9 February 2002. Shortwave and longwave radiation fluxes were measured directly; the former was corrected for problems associated with the cosine response of the instrument. Sensible and latent heat fluxes were calculated using the bulk method, and eddy-correlation measurements and the modified Bowen ratio method were used to verify these calculated fluxes. The calculated sub-surface heat flux was checked by comparing calculated to measured snow temperatures. Uncertainties in the measurements and energy-balance calculations are discussed. The general meteorological conditions were not extraordinary during the period of the experiment, with a mean 2-m air temperature of −27.5°C, specific humidity of 0.52×10−3kg kg−1 and wind speed of 4.1ms−1. The experiment covered the transition period from Antarctic summer (positive net radiation) to winter (negative net radiation), and as a result the period mean net radiation, sensible heat, latent heat and sub-surface heat fluxes were small with values of −1.1, 0.0, −1.0 and 0.7 Wm−2, respectively. Daily mean net radiation peaked on cloudy days (16 Wm−2) and was negative on clear-sky days (minimum of −19 W m−2). Daily mean sensible heat flux ranged from −8 to +10 Wm−2, latent heat flux from −4 to 0 Wm−2 and sub-surface heat flux from −8 to +7 Wm−2.  相似文献   

12.
A time series of microwave radiometric profiles over Arctic Canada’s Cape Bathurst (70°N, 124.5°W) flaw lead polynya region from 1 January to 30 June, 2008 was examined to determine the general characteristics of the atmospheric boundary layer in winter and spring. A surface based or elevated inversion was present on 97% of winter (January–March) days, and on 77% of spring (April–June) days. The inversion was the deepest in the first week of March (≈1100 m), and the shallowest in June (≈250 m). The mean temperature and absolute humidity from the surface to the top of the inversion averaged 250.1 K (−23.1°C), and 0.56 × 10−3 kg m−3 in winter, and in spring averaged 267.5 K (−5.6°C), and 2.77 × 10−3 kg m−3. The median winter atmospheric boundary-layer (ABL) potential temperature profile provided evidence of a shallow, weakly stable internal boundary layer (surface to 350 m) topped by an inversion (350–1,000 m). The median spring profile showed a shallow, near-neutral internal boundary layer (surface to 350 m) under an elevated inversion (600–800 m). The median ABL absolute humidity profiles were weakly positive in winter and negative in spring. Estimates of the convergence of sensible heat and water vapour from the surface that could have produced the turbulent internal boundary layers of the median profiles were 0.67 MJ m−2 and 13.1 × 10−3 kg m−2 for the winter season, and 0.66 MJ m−2 and 33.4 × 10−3 kg m−2 for the spring season. With fetches of 10–100 km, these accumulations may have resulted from a surface sensible heat flux of 15–185 W m−2, plus a surface moisture flux of 0.001–0.013 mm h−1 (or a latent heat flux of 0.7–8.8 W m−2) in winter, and 0.003–0.033 mm h−1 (or a latent heat flux of 2–22 W m−2) in spring.  相似文献   

13.
张楠  陈宏  杨晓君  韩婷婷 《气象科学》2023,43(6):820-828
利用欧洲中期天气预报中心（European Centre for Medium-Range Weather Forecasts， ECMWF）再分析资料，基于大气扰动分解技术，对2012年7月华北东部两次副高边缘大暴雨事件进行扰动分析。结果表明：边界层及对流层低层扰动辐合中心与副高边缘大暴雨中心有较好地对应关系；扰动锋区和扰动比湿大值区（4 g·kg-1）叠加的区域与大暴雨落区相对应，与切变线类暴雨不同，副高边缘暴雨中心并不是出现在冷暖空气対峙扰动（0 ℃线）的位置，而是发生在扰动锋区内的暖区一侧（扰动温度0 ℃以南）；两次过程均存在自南向北的水汽通道，且水汽在输送过程中不断得到抬升，大暴雨落区对应的扰动水汽通量散度中心分别达到-6.8×10-8g·cm-2·hPa-1·s-1和-11.9×10-8g·cm-2·hPa-1·s-1，为大暴雨的形成提供了较好地水汽条件。  相似文献   

14.
Simultaneous observations for the total column densities of NO2, O3 and H2O were carried on using the porta-ble Spectrometer (438-450 nm and 400-450 nm) and the visible Spectrometer (544.4-628 nm) during premonsoon thunderstorms and embedded hail storm activity at Pune (18o32’N & 73o51’E), India. These observations confirm the fact that there is an increase in O3 and NO2 column densities during thunderstorms. The increase in O3 was observed following onset of thunderstorm, while the increase in NO2 was observed only after the thunder flashes occur. This implies that the production mechanisms for O3 and NO2 in thunderstorm are different. The observed column density of NO2 value (1 to 3 × 1017molecules · cm-2) during thunderstorm activity is 10 to 30 times higher than the value (1 × 1016molecules · cm-2) of a normal day total column density. The spectrometric observations and observations of thunder flashes by electric field meter showed that 6.4 × 1025molecules / flash of NO2 are produced. The increased to-tal column density of ozone during thunderstorm period is 1.2 times higher than normal (clear) day ozone concentra-tion. The multiple scattering in the clouds is estimated from H2O and O2 absorption bands in the visible spectral re-gion. Considering this effect the calculated amount of ozone added in the global atmosphere due to thunderstorm ac-tivity is 0.26 to 0.52 DU, and the annual production of ozone due to thunderstorm activity is of the order of 4.02 × 1037 molecules /year. The annual NO2 production may be of the order of 2.02 × 1035molecules / year.  相似文献   

15.
Summary  Measurements of landscape-scale methane emission were made over an aapa mire near Kaamanen in Finnish Lapland (69° 8′ N, 27° 16′ E, 155 m ASL). Emissions were measured during the spring thaw, in summer and in autumn. No effect of water table position on CH4 emission was found as the water table remained at or above the surface of the peat. Methane emission fluxes increased with surface temperature from which an activation energy of −99 kJ mol−1 was obtained. Annual emission from the site, modelled from temperature regression and short-term flux measurements made in three separate years, was calculated to be 5.5 ± 0.4 g CH4 m−2 y−1 of which 0.6 ± 0.1 g CH4 m−2 y−1 (11%) was released during the spring thaw which lasted 20 to 30 days. The effect of global warming on the CH4 budget of the site was estimated using the central scenario of the SILMU (Finnish Research Programme on Climate Change) model which predicts annual mean temperature increases of 1.2, 2.4 and 4.4 °C in 2020, 2050 and 2100, respectively. Maximum enhancements in CH4 emission due to warming were calculated to be 18, 40 and 84% for 2020, 2050 and 2100, respectively. Actual increases may be smaller because prediction of changes in water table are highly uncertain. Received September 17, 1999 Revised October 16, 2000  相似文献   

16.
It is essential to quantify the background reactivity of smog-chambers, since this might be the major limitation of experiments carried out at low pollutant concentrations typical of the polluted atmosphere. Detailed investigation of three chamber experiments at zero-NO x in the European Photoreactor (EUPHORE) were carried out by means of rate-of-production analysis and two uncertainty analysis tools: local uncertainty analysis and Monte Carlo simulations with Latin hypercube sampling. The chemical mechanism employed was that for methane plus the inorganic subset of the Master Chemical Mechanism (MCMv3.1). Newly installed instruments in EUPHORE allowed the measurement of nitrous acid and formaldehyde at sub-ppb concentrations with high sensitivity. The presence of HONO and HCHO during the experiments could be explained only by processes taking place on the FEP Teflon walls. The HONO production rate can be described by the empirical equation W(HONO)EUPHORE dry = a × j NO 2× exp (− T 0/T) in the low relative humidity region (RH < 2%, a = 7.3×1021 cm−3, T 0 = 8945K), and by the equation W(HONO)EUPHORE humid = W(HONO)EUPHORE dry+ j NO 2× b × RH q in the higher relative humidity region (2% < RH < 15%, b = 5.8×108 cm−3 and q = 0.36, and RH is the relative humidity in percentages). For HCHO the expression W(HCHO)EUPHORE = c × j NO 2exp (− T′0/T) is applicable (c = 3.1×1017 cm−3 and T′0 = 5686 K). In the 0–15% relative humidity range OH production from HONO generated at the wall is about a factor of two higher than that from the photolysis of 100 ppb ozone. Effect of added NO2 was found to be consistent with the dark HONO formation rate coefficient of MCMv3.1.  相似文献   

17.
大气透过率的计算是红外辐射传输计算的核心,RTTOV（Radiative Transfer for TOVS）通过建立大气廓线中温度、水汽、臭氧和其他气体浓度等参数与卫星通道透过率的统计关系,可实现卫星通道透过率和大气顶辐射率的快速准确计算。但在一些复杂吸收波段,如水汽波段,RTTOV的计算误差较大。为提高RTTOV在水汽敏感波段的计算精度,利用机器学习中的梯度提升树（Gradient Boosting Tree,GBT）方法,选取从ECMWF（European Centre for Medium-Range Weather Forecasts）的IFS-137（The Integrated Forecast System,137-level-profile）廓线集中挑选的1406条廓线和由此计算的透过率真值作为样本,选取风云三号气象卫星上搭载的红外分光计（InfraRed Atmospheric Sounder,IRAS）通道12（7.33 μm）进行个例研究,分别建立陆地和海洋晴空大气等压面至大气层顶透过率的快速计算模型（GBT模型）。通过和透过率、亮温真值的比较,验证了GBT模型。比较结果显示,GBT模型预测的透过率平均绝对误差（Mean Absolute Error,MAE）为:陆地0.0012,海洋0.0009;均方对数误差（Mean Squared Logarithmic Error,MSLE）为:陆地0.0215,海洋0.0095,均小于RTTOV直接计算的透过率的误差（陆地、海洋的MAE分别比RTTOV小0.0008和0.0010,MSLE分别比RTTOV小0.0135和0.0227）;由GBT模型计算的亮温MAE分别为:陆地0.0949 K,海洋0.0634 K,均方根误差（Root Mean Square Error,RMSE）分别为:陆地0.1352 K,海洋0.0831 K,也都小于RTTOV直接模拟的晴空亮温误差（陆地、海洋的MAE分别比RTTOV小0.1685 K和0.1466 K,RMSE分别比RTTOV小0.1794 K和0.1685 K）。本研究的结果表明,在IRAS红外水汽波段,GBT预测的透过率和亮温误差比RTTOV小。机器学习有提高水汽波段正演精度的潜力,或可为辐射传输的快速计算提供可行的替代方法。   相似文献   

18.
Seven year data of hourly surface ozone concentration is analyzed to study diurnal cycle, trends, excess of ozone levels above threshold value and cumulative ozone exposure indices at a tropical megacity, Delhi. The ozone levels clearly exhibit a diurnal cycle, similar to what has been found in other urban places. A sharp increase in the ozone levels during forenoon and a sharp decrease in the early afternoon can be observed. The average rate of increase in ozone concentration between 09 and 12 h has been observed to be 7.1 ppb h−1. We find that the daily maximum and daytime 8-h (10–17 h) ozone levels are increasing at a rate of about 1.7 (± 0.7) and 1.3 (± 0.56) ppb y−1, respectively. The directives on ozone pollution in ambient air provided by United Nations Economic Commission for Europe and World Health Organization for vegetation (AOT40) and human health protection were used to assess the air quality. The present surface ozone levels in the city are high enough to exceed “Critical Levels” which are considered to be safe for human health, vegetation and forest. The human health threshold was exceeded for up to ~45 days per year. The AOT40 (Accumulated exposure Over a Threshold of 40 ppb) threshold was exceeded significantly during winter (D-J-F) and pre-monsoon (M-A-M) (Rabi crop growing season) season in India. Translating AOT40 exceedances during pre-monsoon into relative yield loss we estimate yield loss of 22.7%, 22.5%, 16.3% and 5.5% for wheat, cotton, soybean and rice, respectively.  相似文献   

19.
夏季亚洲季风区是对流层向平流层物质输送的主要通道,其对平流层水汽的变化有重要贡献。以往的研究表明亚洲季风区向平流层的水汽传输主要在青藏高原及周边地区。本文利用多年平均的逐日ERAi、MERRA再分析数据和微波临边观测仪（Microwave Limb Sounder,MLS）数据,首先对比分析夏季青藏高原周边上空水汽的分布特征,再利用再分析资料分析了对流层—平流层水汽传输的特征。结果表明:青藏高原周边特定的等熵面和对流层顶结构分布有利于水汽向平流层的绝热输送;在南亚高压的东北侧,从青藏高原到中太平洋地区,340~360 K层次存在最为显著的水汽向平流层的纬向等熵绝热输送通道,7~8月平均输送强度可达约7×103 kg s-1。此外,在伊朗高原及南亚高压的西部,350~360 K层次也存在一支水汽向平流层的经向等熵绝热输送通道,但强度相对较弱（约2.5×103 kg s-1）。在青藏高原南侧370~380 K层次存在强的水汽向平流层的非绝热输送,主要由深对流和大尺度上升运动引起,7~8月平均输送强度约0.4×103 kg s-1。落基山以东到大西洋西部,350~360 K层次存在水汽向平流层的纬向等熵绝热输送通道,但强度也弱得多（约2.5×103 kg s-1）。  相似文献   

20.
This paper presents the main experimental results of surface ozone concentrations measured at a rural area in Northern Spain from February 2000 to December 2005. Daily and seasonal variation of ozone has been analysed. The peak concentration levels are obtained in the afternoon, mean value around 88 μg m−3, with extreme average values of 59 μg m−3 in January and 113 μg m−3 in July. Small differences are found in the mean and median of the ozone levels from April to August, when spring and summer maxima are observed. Despite the great inter-annual ozone variability obtained, most air quality indicators showed a positive trend. Further analysis of the monthly mean ozone concentrations of the main percentiles have also been performed using a harmonic model. The upward trend was 6.2 ± 1.7 μg m−3 for the 98th percentile. To interpret the main features of the annual cycle and describe the ozone peaks, the influence of meteorological factors is studied. In summer, ozone production is governed by local processes, air temperature being the major controlling factor. However, the origin of the spring maximum is not so well identified.  相似文献   

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