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1.
于2011年5至6月在东海采集不同深度海水样品,研究了其中溶存氧化亚氮(N2O)的分布并估算其海-气交换通量。结果表明,春季东海表层海水中溶存N2O浓度范围为6.31~11.88 nmol/L,平均值为(9.13±1.45)nmol/L;底层海水中N2O浓度范围为7.53~39.75 nmol/L,平均值为(13.71±7.76)nmol/L。随着深度的增加,N2O浓度逐渐升高。温度是影响春季东海N2O分布的主要因素,N2O浓度与温度呈负相关关系。长江冲淡水和黑潮水是东海N2O的重要来源。东海表层海水中N2O的饱和度范围为92.5%~139.3%,平均值为118.5%±10.3%,绝大多数站位都处于过饱和状态,因此,春季东海是大气N2O的净源。利用LM86公式和W92公式求得东海的海-气交换通量分别为(4.96±6.12)μmol/(m2·d)和(10.25±17.18)μmol/(m2·d),初步估算出东海年释放N2O通量约为0.061~0.127 Tg/a,占全球海洋释放总量的2.0%,远高于其所占的面积比0.2%。  相似文献   

2.
韩玉  张桂玲 《海洋与湖沼》2015,46(2):321-328
于2010年5—6月搭乘日本KH10-1航次,对西北太平洋两个不同深度站位甲烷(CH4)和氧化亚氮(N2O)的垂直分布及海气交换通量进行了研究。结果显示:研究海域表层海水中CH4和N2O浓度分别为(2.55±0.22)nmol/L和(7.50±1.11)nmol/L,饱和度分别为126%和116%,均处于轻度过饱和状态。在垂直方向上,CH4浓度分布呈现次表层极大的特征,次表层以下CH4浓度随深度增加逐渐减小。CH4次表层极大值可能是由于细菌利用甲基化合物进行好氧产生和在悬浮颗粒物、浮游动物或其他海洋生物肠道内厌氧微环境产生的综合作用造成的。N2O浓度随深度的增加而增大,在跃层下部达到最大值,N2O与溶解氧的垂直分布呈镜像关系。水体中N2O主要通过硝化过程产生。利用LM86和W92公式计算得到CH4的海气交换通量分别为(0.76±0.57)μmol/(m2·d)和(1.57±0.67)μmol/(m2·d),N2O的海气交换通量分别为(1.96±0.24)μmol/(m2·d)和(3.08±0.38)μmol/(m2·d),因此西北太平洋是大气CH4和N2O的净源。  相似文献   

3.
分别于2014年10月和2015年6月对南海北部陆坡区进行了调查,研究了其溶存氧化亚氮(N_2O)的分布、产生并估算了其海-气交换通量。结果表明:秋季南海北部表层海水中溶解N_2O浓度为(8.19±0.79)nmol/L,饱和度为132.5%±13.4%;夏季表层海水中溶解N_2O浓度为(7.72±0.56)nmol/L,饱和度为135.5%±9.7%。夏季由于受到珠江冲淡水的影响,表层N_2O浓度随盐度升高呈降低趋势,秋季调查区域东北部受到穿过吕宋海峡的黑潮分支表层水的影响,N_2O浓度较低。结合文献资料,南海北部陆坡区表层N_2O浓度季节变化特征为春末秋季夏季,同一季节,南海陆坡区的N_2O浓度高于其他区域。温度是影响N_2O分布的重要因素,ΔN_2O与表观耗氧量(apparent oxygen utilization,AOU)和NO_3~ˉ的显著相关说明硝化作用是南海水体中N_2O产生的主要机制,由此估算硝化作用的N_2O产率分别为秋季0.033%,夏季0.035%。利用N2000和W2014公式分别估算了该区域秋季和夏季N_2O的海-气交换通量:秋季为1.81—23.81(11.11±6.52,平均值±SD,下同)(N2000)和1.73—24.38(11.30±6.81)(W2014),夏季为1.01—21.57(7.04±6.10)(N2000)和0.75—22.69(6.94±6.49)(W2014),单位均为μmol/(m~2·d)。初步估算出南海北部陆坡N_2O释放量为0.055Tg/a,约占全球海洋总释放量的0.39%,远高于其面积比,说明南海北部陆坡是N_2O释放的活跃海域,是大气N_2O的重要源。  相似文献   

4.
分别于2006年8月,12月和2007年4月,10月采集胶州湾及周边海域大气和海水样品,对氧化亚氮(N2O)和甲烷(CH4)浓度进行了测定,并设置1个连续站进行24 h连续观测.结果表明:大气中N2O春、夏、秋、冬的平均浓度(体积分数)分别为(3.17±0.03)×10-7,(3.24±0.15)×10-7,(3.19±0.02)×10-7和(3.08±0.25)×10-7;大气中CH4春、夏、秋、冬的平均浓度(体积分数)分别为(1.89±0.04)×10-6,(1.79±0.04)×10-6,(2.09±0.21)×10-6和(2.01±0.09)×10-6.胶州湾表、底层海水中N2O和CH4的浓度和饱和度表现出明显的季节变化,其中N2O浓度和饱和度冬季最高,春、秋季次之,夏季最低;CH4浓度和饱和度夏季最高,冬季最低.利用Liss and Merlivat(1986)公式和Wanninkhof(1992)公式估算出胶州湾海域N2O的年平均海-气交换通量分别为(11.16±14.15)和(22.42±27.56)μmol m-2·d-1;CH4分别为(7.75±6.19)和(17.76±14.84)μmol m-2·d-1.胶州湾大部分海域表层海水中N2O和CH4呈过饱和状态,是大气中N2O和CH4的净源.  相似文献   

5.
大亚湾海水中N2O的分布特征与通量的初步研究   总被引:1,自引:1,他引:1  
2004年1月(冬季)和4月(春季)在大亚湾海域设置15个采样站,采集大气和海水样品,运用静态顶空气相色谱法测定了大气和海水中溶存N2O的浓度并对其分布特征和海-气通量进行了初步研究。结果显示,海水中N2O浓度范围在10.90—40.54 nmol.L-1,饱和度为122%—454%,处于过饱和状态;N2O浓度在湾的中部分布较为均匀,大鹏岙、核电站、范和港顶和澳头等受人类活动影响较大的沿岸浓度较高,最大值出现在龙歧河口。海-气通量为0.05—0.78μmol.(m2.d)-1。海水中N2O浓度与NH4 的含量之间有较为显著的正相关性,河口与核电站是N2O的排放源,说明人类活动影响了大亚湾海水中N2O的分布。  相似文献   

6.
于2013年10~11月现场测定了东海中二甲基硫(DMS)及其前体物质二甲巯基丙酸内盐(DMSP,分为溶解态DMSPd和颗粒态DMSPp)的含量,研究其水平分布特征、DMSPp的粒径分布及DMSPd的降解速率,并对DMS的海-气交换通量进行了探讨。研究结果表明,表层海水中DMS、DMSPd和DMSPp的浓度平均值分别为(4.84±0.40)、(5.84±0.93)和(13.01±0.52)nmol·L-1。海水中DMSPd的降解速率在2.59~16.36nmol·L-1·d-1之间,平均值为(6.78±0.84)nmol·L-1·d-1。调查海域范围内,小型浮游植物(20μm)是DMSPp和叶绿素a(Chl a)重要贡献者。此外,秋季东海表层海水DMS的海-气交换通量为0.66~31.73μmol·m-2·d-1,平均值为(11.63±0.71)μmol·m-2·d-1。  相似文献   

7.
分析2013-10,2014-05和2015-05对桑沟湾3个航次的调查中采集的表、底层海水样品,研究该海域海水中溶解CH_4的分布特征及海-气交换通量。结果表明:春、秋季桑沟湾水体中CH_4浓度范围为3.0356.4nmol·L~(-1),底层浓度高于表层。由于水温的季节变化和陆源输入的影响,秋季表、底层平均CH_4浓度是春季的37倍。受养殖活动的影响,贝藻混养区表、底层CH_4均高于其他养殖区和湾外。2013-10,2014-05和2015-05桑沟湾表层海水CH_4的平均饱和度分别为(2 704±2 532)%,(330±276)%和(858±417)%,表现为秋季高于春季。根据W2014公式估算出桑沟湾春、秋季表层海水CH_4海-气交换通量范围为3.919.9μmol·m~(-2)·d~(-1),根据N2000公式估算出春、秋季表层海水CH_4海-气交换通量范围为5.520.6μmol·m~(-2)·d~(-1),表明春、秋季桑沟湾是大气CH_4的源区。  相似文献   

8.
三亚河与三亚湾溶存N_2O分布特征与影响因素研究   总被引:2,自引:0,他引:2  
2008年4月在三亚河设置24h观测连续站,10月在三亚湾设置13个采样站,同时采集大气、表层和底层海水样品,运用静态顶空气相色谱法对海水中溶存N2O的浓度进行了测定。结果表明,三亚湾海水中溶存N2O的浓度范围为7.57—15.04nmol/L,饱和度范围为101.8%—202.2%,均处于过饱和状态,明显受到三亚河水人为污染的影响;三亚河N2O浓度日变化范围在12.7—17.6nmol/L,饱和度范围在170.9%—236.9%,全天也均处于高度过饱和状态,表明三亚河和三亚湾都是大气N2O的源。对三亚河和三亚湾N2O浓度与盐度,营养盐的关系进行相关分析可得,其与盐度之间的关系为负相关,与硝酸盐,亚硝酸盐,氨盐的关系为正相关。此外还利用Liss提出的双层模型计算了三亚河和三亚湾的N2O海-气交换通量,分别为5.71—11.63μmol/(m2·d)、0.33—8.26μmol/(m2·d),表明三亚河与三亚湾水体中N2O的过饱和现象主要来源于城市污水的影响。  相似文献   

9.
于2006年4月至2007年1月对桑沟湾海域进行了4个航次的调查,采集表层海水样品,研究了该海域表层海水中溶解N_2O的分布特征及海气交换通量的季节变化,结果表明:桑沟湾表层海水中溶解N_2O浓度和饱和度存在一定的季节性变化,浓度表现为冬季最高而饱和度为夏季最高.利用Liss和Merlivat公式(LM86)以及Wanninkhof公式(W92)估算了该海湾海水中N_2O的年平均海-气交换通量,分别为0.2 μmol/(m~2·d)±0.1 μmol/(m~2·d)和1.5 μmol/(m~2·d)±1.0 μmol/(m~2·d).  相似文献   

10.
根据2006年7~8月和2007年1月对北黄海进行的大面调查,分析研究了夏冬季表层海水中二甲基硫(DMS)的浓度分布和海-气交换通量.研究表明:表层海水以及大气中DMS浓度季节变化明显,夏季平均值分别是冬季的3.2和3.7倍.相关性分析显示,海水中DMS和Chl a浓度存在明显的相关性,说明浮游植物生物量是影响DMS浓度分布的1个重要因素.利用Liss和Merlivat公式(LM86)估算了北黄海夏冬季DMS的海-气交换通量,其平均值分别为7.31和4.98 μmol·m-2·d-1.另外,根据测定的大气中甲基磺酸盐(MSA)和非海盐硫酸盐(Nss-SO2-4)的浓度及比例,估算出夏冬季北黄海生源硫释放对气溶胶中Nss-SO2-4的贡献比例分别为10.1%和2.8%.此结果表明北黄海大气中Nss-SO2-4主要来源于人为排放.  相似文献   

11.
海上大直径钢管桩打桩过程中,桩周土体受到强烈扰动而发生强度弱化,掌握桩周土体强度弱化规律对于准确预测打桩过程、保证工程安全具有重要意义。为研究土体强度弱化规律,开展了环剪试验模拟打桩对桩周土体的扰动,测试土体强度随剪切速率的变化规律,建立了描述土体强度弱化规律的拟合公式,引入到打桩分析软件中。研究结果表明:土体的强度折减程度不仅与土体本身的性质有关还受到土体的埋深和剪切速率的影响,埋深越深土体强度折减程度越低,剪切速率越高土体强度折减越高,在打桩分析中可采用这里推荐的线性折减方法来模拟不同深度处土体强度的折减规律。  相似文献   

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14.
A set of 27 marine planktonic bacteria isolated from the polar regions was characterized by 16S rDNA sequencing and physiological and biochemical testing. More than half of these bacteria were positive for caseinase, gelatinase and 13-glucosidase, and could utilize glucose, maltose or malic acid as carbon source for cell growth. Twelve isolates expressed nitrate reduction activities. Except for one antarctic isolate BSwlO175 belonging to Actinobacteria phylum, these isolates were classified as γ-Proteobacteria, suggesting that γ-Proteobacteria dominated in cultivable marine bacterioplankton at both poles. Genus Pseudoalteromonas was the predominant group in the Chukchi Sea and the Bering Sea, and genus ShewaneUa dominated in cultivable bacterioplankton in the Prydz Bay. With sequence similarities above 97%, genus Psychrobacter was found at both poles. These 27 isolates were psychrotolerant, and significant 16S rDNA sequence similarities were found not only between arctic and antarctic marine bacteria ( 〉 99% ), but also between polar marine bacteria and bacteria from other aquatic environments ( ≥ 98.8% ), including temperate ocean, deep sea, pond and lake, suggesting that in the polar oceans less temperature-sensitive bacteria may be cosmopolitan and have a bipolar, even global, distribution at the species level.  相似文献   

15.
Sediment properties, such as water content and density, have been used to estimate the dry and wet weights, as well as the volume of sediment recovered and discharged, during benthic impact experiments conducted in the Pacific and Indian Oceans. The estimates show that the weights of dry (355-1332 t) and wet sediment (1651-4888 t) recovered during the experiments, are not only a function of the total duration and distance covered during the experiment, but also depend on water content and density of the sediment. Estimation of dry sediment and its volumetric ratio in the discharge, are key parameters for calculating the discharged volume. The estimated volume of wet sediment recovered (1427-4049 m 3 ) as well as discharged (2693-6951 m 3 ) during the experiments, provide important inputs to evaluate the sediment resettlement and migration. Using these estimates, the average depth of excavation on the seafloor, can also been calculated. However, the stages of sediment recovery and discharge are expressed differently in some of the experiments. In order to standardize these, different stages have been identified, and definitions of certain terms have been suggested, for use in the future. The methods of calculating different properties, as well as weight and volume of discharged sediment are described in the paper for use in other applications concerning deep-sea discharges.  相似文献   

16.
A vertically integrated model has been used to study the tidal circulation and currents in the Gulf of Kachchh along the west coast of India. The model is fully nonlinear and uses a semiexplicit finite difference scheme to solve the basic hydrodynamic equations on a staggered grid. The model is forced by prescribing the tides along the open boundary of the model domain. The flow is simulated both with and without the presence of the proposed tidal barrage across the Hansthal Creek in the Gulf of Kachchh. The results show a considerable change in the behavior of the tidal flow in the presence of the barrage.  相似文献   

17.
<正>The typhoon,as a mature tropical cyclone that develops in the western part of the North Pacific Ocean with high wind speed and heavy rainfall,is one of the most lethal and costly of natural disasters for the densely populated countries of East Asia.It can be easily detected by space-borne sensors operated at microwave,visible or infrared bands(Liu et al.,2014).Synthetic Aperture Radar(SAR)is  相似文献   

18.
本文介绍了用国产D401型螯合树脂分离富集海水中铜、铅、锌、镉、铁、锰等痕量元素,并用原子吸收光谱仪测定其含量的方法。讨论了各元素的分离条件选择及干扰元素的影响,并与溶剂萃取法的结果作了比较。各元素检测的定量下限为:铜0.5μg/L、铅0.1μg/L、锌1.0μg/L、镉0.01μg/L、铁2.0μg/L、锰2.0μg/L。方法精密度在4—8%之间,回收率为90—102%。  相似文献   

19.
Soil core samples fromRhizophora mangleL. andAvicennia schauerianaStapf & Leech forests from south-eastern Brazil were analysed for their total organic matter content and their sugars, amino acid and amino sugars composition. Organic carbon and nitrogen contents were higher inAvicenniathan inRhizophorasoils. The contribution of sugars and amino acids to the total organic carbon pool was constant with depth inRhizophorasoils whereas inAvicenniasoils it increased. Spectral distribution of sugars and amino acids showed a dominance of Ca-affine monomers, particularly acidic amino acids, and the sugar arabinose. Biogeochemical indicators derived from ratios of individual sugar and amino acid monomers confirm previous studies which showed that organic matter in both soils is mainly of mangrove origin. The results further suggest accumulation of organic matter inRhizophorasoils and a continuing degradation of organic matter inAvicenniasoils. The latter may thus release more nutrients to adjacent ecosystems thanRhizophorasoils.  相似文献   

20.
Orange roughy Hoplostethus atlanticus are unusual fish. They form dense aggregations that have fuelled lucrative fisheries at great depths (600–1 400 m), especially off Namibia, New Zealand and Australia. They are thought to be very long-lived (>100 years, maturity at 22 – 40 years), and to have exceptionally low natural mortality (M = 0.045–0.064 year?1) and slow growth rates (K = 0.055–0.070 year?1). In addition, they spawn large eggs and have low fecundity. These factors combine to make orange roughy highly susceptible to overfishing; most stocks are below 30% of pristine levels. Assessments are obtained from indices of catch rate and trawl, acoustic and egg surveys. Acoustic estimates are the most direct, but are confounded by the species' low target strength (?50 to ?53 dB)–attributable to the wax-filled swim bladder. Extracellular wax esters are stored in abundance and comprise mostly mono-unsaturated fatty acids, with low concentrations of the ω-3 fatty acid family. This unusual composition (resultant from the species' diet) ensures neutral buoyancy. Stock separation has been inferred mainly from biological studies, but genetic studies have also found differences among stocks within New Zealand and Australia. Deep-water habitat may be damaged by trawling operations and may take many years to recover, so in some quarters there is a call for a portion of suitable habitat to be set aside for preservation. Although Namibian orange roughy are shallower, smaller and younger than those in other stocks, the Namibian fishery sustained high catches for only a few years before quotas were reduced, from 12 000 to 1 875 tons. Three management lessons are suggested for developing orange roughy fisheries based on the Namibian experience: (1) imposition of catch limits during exploratory fishing; (2) starting the acoustic surveys earlier in the fishery, if possible; (3) greater reliance on trends in catch rate until a survey series has been established.  相似文献   

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