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1.
C. Hatté  J. Guiot 《Climate Dynamics》2005,25(2-3):315-327
A modified version of the Biome4 vegetation model for simulation of the mean δ13C of plant communities is presented, and used to reconstruct palaeoprecipitation. We treat all fractionations by C3 and C4 plants in all coexistent Plant Functional Types, weighted by their respective net primary production. We constrain the range of variation in the intracellular versus atmospheric CO2 concentration by fixing a lower limit. Finally, we replace some constant parameters by functions of external forcing to account for their responses to environmental variation. The new version of Biome4 was applied as an inverse model and tested on three modern data sets. The fit between observations and simulations is very close to the 1:1 relationship, with respective slopes of 0.90±0.02 (r 2=0.98, n=29) for δ13C and 0.97±0.06 (r 2=0.90, n=29) for precipitation. Inverse modelling was applied using the Metropolis-Hastings algorithm to the Nußloch loess sequence. Over the last glaciation, simulated palaeoprecipitation varies between 240 mm year?1 and 400 mm year?1. This study clearly demonstrates atmospheric teleconnections with the Greenland ice-sheet extension, by matching Dansgaard-Oeschger events with precipitation increase of ca. 100–200 mm year?1.  相似文献   

2.
A coupled climate–carbon cycle model composed of a process-based terrestrial carbon cycle model, Sim-CYCLE, and the CCSR/NIES/FRCGC atmospheric general circulation model was developed. We examined the multiple temporal scale functions of terrestrial ecosystem carbon dynamics induced by human activities and natural processes and evaluated their contribution to fluctuations in the global carbon budget during the twentieth century. Global annual net primary production (NPP) and heterotrophic respiration (HR) increased gradually by 6.7 and 4.7%, respectively, from the 1900s to the 1990s. The difference between NPP and HR was the net carbon uptake by natural ecosystems, which was 0.6 Pg C year?1 in the 1980s, whereas the carbon emission induced by human land-use changes was 0.5 Pg C year?1, largely offsetting the natural terrestrial carbon sequestration. Our results indicate that monthly to interannual variation in atmospheric CO2 growth rate anomalies show 2- and 6-month time lags behind anomalies in temperature and the NiNO3 index, respectively. The simulated anomaly amplitude in monthly net carbon flux from terrestrial ecosystems to the atmosphere was much larger than in the prescribed air-to-sea carbon flux. Fluctuations in the global atmospheric CO2 time series were dominated by the activity of terrestrial vegetation. These results suggest that terrestrial ecosystems have acted as a net neutral reservoir for atmospheric CO2 concentrations during the twentieth century on an interdecadal timescale, but as the dominant driver for atmospheric CO2 fluctuations on a monthly to interannual timescale.  相似文献   

3.
Numerous studies have shown that increased atmospheric CO2 concentration is one of the most important factors altering land water balance. In this study, we investigated the effects of increased CO2 on global land water balance using the dataset released by the Coupled Model Intercomparison Project Phase 5 derived from the Canadian Centre for Climate Modelling and Analysis second-generation Earth System Model. The results suggested that the radiative effect of CO2 was much greater than the physiological effect on the water balance. At the model experiment only integrating CO2 radiative effect, the precipitation, evapotranspiration (ET) and runoff had significantly increased by 0.37, 0.12 and 0.31 mm year?2, respectively. Increases of ET and runoff caused a significant decrease of soil water storage by 0.05 mm year?2. However, the results showed increases of runoff and decreases of precipitation and ET in response to the CO2 fertilisation effect, which resulted into a small, non-significant decrease in the land water budget. In the Northern Hemisphere, especially on the coasts of Greenland, Northern Asia and Alaska, there were obvious decreases of soil water responding to the CO2 radiative effect. This trend could result from increased ice–snow melting as a consequence of warmer surface temperature. Although the evidence suggested that variations in soil moisture and snow cover and vegetation feedback made an important contribution to the variations in the land water budget, the effect of other factors, such as aerosols, should not be ignored, implying that more efforts are needed to investigate the effects of these factors on the hydrological cycle and land water balance.  相似文献   

4.
The study reports estimates of above ground phytomass carbon pools in Indian forests for 1992 and 2002 using two different methodologies. The first estimate was derived from remote sensing based forest area and crown density estimates, and growing stock data for 1992 and 2002 and the estimated pool size was in the range 2,626–3,071 Tg C (41 to 48 Mg C ha???1) and 2,660–3,180 Tg C (39 to 47 Mg C ha???1) for 1992 and 2002, respectively. The second methodology followed IPCC 2006 guidelines and using an initial 1992 pool of carbon, the carbon pool for 2002 was estimated to be in the range of 2,668–3,112 Tg C (39 to 46 Mg C ha???1), accounting for biomass increment and removals for the period concerned. The estimated total biomass increment was about 458 Tg over the period 1992–2002. Removals from forests include mainly timber and fuel wood, whereby the latter includes large uncertainty as reported extraction is lower than actual consumption. For the purpose of this study, the annual extraction values of 23 million m3 for timber and 126 million m3 for fuel wood were used. Out of the total area, 10 million ha are plantation forests with an average productivity (3.2 Mg ha???1 year???1) that is higher than natural forests, a correction of 408 Tg C for the 10 year period was incorporated in total estimated phytomass carbon pool of Indian forests. This results in an estimate for the net sink of 4 Tg C year???1. Both approaches indicate Indian forests to be sequestering carbon and both the estimates are in agreement with recent studies. A major uncertainty in Indian phytomass carbon pool dynamics is associated with trees outside forests and with soil organic carbon dynamics. Using recent remote-sensing based estimates of tree cover and growing stock outside forests, the estimated phytomass carbon pool for trees outside forests for the year 2002, is 934 Tg C with a national average tree carbon density of 4 Mg C ha???1 in non-forest area, in contrast to an average density of 43 Mg C ha???1 in forests. Future studies will have to consider dynamics in both trees outside forests and soil for total terrestrial carbon dynamics.  相似文献   

5.
The potential effects of climate change on net primary productivity (NPP) of U.S. rangelands were evaluated using estimated climate regimes from the A1B, A2 and B2 global change scenarios imposed on the biogeochemical cycling model, Biome-BGC from 2001 to 2100. Temperature, precipitation, vapor pressure deficit, day length, solar radiation, CO2 enrichment and nitrogen deposition were evaluated as drivers of NPP. Across all three scenarios, rangeland NPP increased by 0.26 % year?1 (7 kg C ha?1 year?1) but increases were not apparent until after 2030 and significant regional variation in NPP was revealed. The Desert Southwest and Southwest assessment regions exhibited declines in NPP of about 7 % by 2100, while the Northern and Southern Great Plains, Interior West and Eastern Prairies all experienced increases over 25 %. Grasslands dominated by warm season (C4 photosynthetic pathway) species showed the greatest response to temperature while cool season (C3 photosynthetic pathway) dominated regions responded most strongly to CO2 enrichment. Modeled NPP responses compared favorably with experimental results from CO2 manipulation experiments and to NPP estimates from the Moderate Resolution Imaging Spectroradiometer (MODIS). Collectively, these results indicate significant and asymmetric changes in NPP for U.S. rangelands may be expected.  相似文献   

6.
Organic matter (OM) is involved in the enhancement of soil quality since it acts on soil structure, nutrient storage and biological activity. Organic carbon (OC), the dominant element constituent of OM, and related soil properties are probably the most widely acknowledged indicator of soil quality. The typically Mediterranean climate of the South of Spain promotes low yields on crops and low organic carbon in soil. The present work was carried out to evaluate the effect of the application of alperujo, olive oil waste difficult to eliminate, on the fixation or emission of carbon on soil in an olive grove situated in Montoro (Córdoba, Spain). In the study three treatments were considered: 15 kg (A), 7.5 kg (B), 0 kg (C) of alperujo per tree and the implementation of the amendment has been made for three consecutive years. The results confirm the benefits of the amendment on the carbon content organic soil with a fixation with respect to control of 4.8 and 6.1 t ha???1 for the first year and 8.7 and 6.8 t ha???1 for the second in treatments A and B, respectively. Of the different climatic agents considered in the study, it was the temperature which had a major influence on the emissions of CO2 into the atmosphere and the flow of gas presented the highest values in soils treated with the highest dose.  相似文献   

7.
In this study, variations in carbon dioxide (CO2) fluxes resulting from gross primary production (GPP), net ecosystem exchange (NEE), and respiration (R e) of soybean (Glycine max L.) were investigated by the Eddy Covariance method during the growing period from June to November 2005 on an irrigated sand field at the Arid Land Research Center, Tottori University in Tottori, Japan. Although climatic conditions were humid and temperate, the soybeans required frequent irrigation because of the low water holding capacity of the sandy soil at the field site. Finally, it has been found that the accumulated NEE, GPP, and R e fluxes of soybean over 126 days amount to ?93, 319, and 226 gC m?2, respectively. Furthermore, the average ratio of GPP to R e was 1.4 and the average ratio of NEE to GPP was about ?0.29 for the growth period of soybean. Daily maximum NEE of ?3.8 gC m?2 occurred when LAI was 1.1.  相似文献   

8.
Using a coated-insert flow tube reactor coupled to a low-energy electron-impact mass spectrometer with molecular beam sampling, we studied uptake of NO3 by sea salt at room temperature and [NO3]?=?8?1011???4?1013 molecule cm?3. The radical uptake coefficient γ(t) is time dependent: its initial value (γ ini) decreases exponentially with the characteristic time (τ) to its steady-state value (γ ss) at given [NO3]. The parameters γ ini, γ ss and τ depend on [NO3], whereas γ ss is water vapor independent at [H2O]?=?8?1012???1.6?1015 molecule cm?3 and RH ≤ 0.5 %. HCl and NO2 are uptake products detected in the gas phase. We used these findings to estimate γ values under tropospheric conditions for urban coastal and remote marine environments: at high NO3 (~90 ppt), the time dependence becomes important, and the γ value averaged over the aerosol lifetime is 4?10?3; at low NO3 (~1 ppt), the radical uptake is time independent and proceeds faster with γ ini?=?8?10?3  相似文献   

9.
The available energy (AE), driving the turbulent fluxes of sensible heat and latent heat at the earth surface, was estimated at four partly complex coniferous forest sites across Europe (Tharandt, Germany; Ritten/Renon, Italy; Wetzstein, Germany; Norunda, Sweden). Existing data of net radiation were used as well as storage change rates calculated from temperature and humidity measurements to finally calculate the AE of all forest sites with uncertainty bounds. Data of the advection experiments MORE II (Tharandt) and ADVEX (Renon, Wetzstein, Norunda) served as the main basis. On-site data for referencing and cross-checking of the available energy were limited. Applied cross checks for net radiation (modelling, referencing to nearby stations and ratio of net radiation to global radiation) did not reveal relevant uncertainties. Heat storage of sensible heat J H, latent heat J E, heat storage of biomass J veg and heat storage due to photosynthesis J C were of minor importance during day but of some importance during night, where J veg turned out to be the most important one. Comparisons of calculated storage terms (J E, J H) at different towers of one site showed good agreement indicating that storage change calculated at a single point is representative for the whole canopy at sites with moderate heterogeneity. The uncertainty in AE was assessed on the basis of literature values and the results of the applied cross checks for net radiation. The absolute mean uncertainty of AE was estimated to be between 41 and 52 W m?2 (10–11 W m?2 for the sum of the storage terms J and soil heat flux G) during mid-day (approximately 12% of AE). At night, the absolute mean uncertainty of AE varied from 20 to about 30 W m?2 (approximately 6 W m?2 for J plus G) resulting in large relative uncertainties as AE itself is small. An inspection of the energy balance showed an improvement of closure when storage terms were included and that the imbalance cannot be attributed to the uncertainties in AE alone.  相似文献   

10.
Temperature and CO2 are two of the main environmental factors associated with climate change. It is generally expected that elevated [CO2] will increase crop production. However, other environmental factors such as temperature along with management practices could further modify a crop’s response to CO2. The goal of this study was to determine the interactive effects of elevated [CO2] and above-optimum temperature on growth, development and yield of two peanut (Arachis hypogaea L.) cultivars, e.g., Pronto and Georgia Green. One of the objectives was to determine if there was any variation in response between these two cultivars with respect to possible adaptation to climate change. Peanut plants were grown in controlled environment chambers in the University of Georgia Envirotron under conditions of non-limiting water and nutrient supply. Plants were exposed to day/night air temperatures of 33/21°C (T A), 35.5/23.5°C (T A + 2.5°C), and 38/26°C (T A + 5°C) along with CO2 treatments of 400 and 700 μmol CO2 mol???1 air. The selected range of temperatures was based on the temperatures that are common for southwest Georgia during the summer months. The results showed that LAI of both cultivars responded positively, e.g., 28.3% for Pronto and 49.3% for Georgia Green to elevated [CO2]. Overall, elevated [CO2] alone resulted in a significant increase in total biomass at final harvest across all temperatures (P?< 0.0001), but decreased final seed yield (P?< 0.0005), except for Georgia Green at (T A + 5°C). The higher temperatures compared to T A reduced the relative response of total biomass to CO2 for both cultivars. It can be concluded that final seed yield response to CO2 depends on the sensitivity of individual cultivars to temperature, especially during the reproductive development stage.  相似文献   

11.
Modelling studies predicted that climate change will have strong impacts on the coffee crop, although no information on the effective impact of elevated CO2 on this plant exists. Here, we aim at providing a first glimpse on the effect of the combined impact of enhanced [CO2] and high temperature on the leaf mineral content and balance on this important tropical crop. Potted plants from two genotypes of Coffea arabica (cv. Icatu and IPR 108) and one from C. canephora (cv. Conilon Clone 153) were grown under 380 or 700 μL CO2 L?1 air, for 1 year, after which were exposed to an stepwise increase in temperature from 25/20 °C (day/night) up to 42/34 °C, over 8 weeks. Leaf macro???(N, P, K, Ca, Mg, S) and micronutrients (B, Cu, Fe, Mn, Zn) concentrations were analyzed at 25/20 °C (control), 31/25 °C, 37/30 °C and 42/34 °C. At the control temperature, the 700 μL L?1 grown plants showed a moderate dilution effect (between 7 % and 25 %) in CL 153 (for N, Mg, Ca, Fe) and Icatu (for N, K and Fe), but not in IPR 108 (except for Fe) when compared to the 380 μL L?1 plants. For temperatures higher than control most nutrients tended to increase, frequently presenting maximal contents at 42/34 °C (or 37/30 °C), although the relation between [CO2] treatments did not appreciably change. Such increases offset the few dilution effects observed under high growth [CO2] at 25/20 °C. No clear species responses were found considering [CO2] and temperature impacts, although IPR 108 seemed less sensitive to [CO2]. Despite the changes promoted by [CO2] and heat, the large majority of mineral ratios were kept within a range considered adequate, suggesting that this plant can maintain mineral balances in a context of climate changes and global warming.  相似文献   

12.
We measured the methane flux of a forest canopy throughout a year using a relaxed eddy accumulation (REA) method. This sampling system was carefully validated against heat and CO2 fluxes measured by the eddy covariance method. Although the sampling system was robust, there were large uncertainties in the measured methane fluxes because of the limited precision of the methane gas analyzer. Based on the spectral characteristics of signals from the methane analyzer and the diurnal variations in the standard deviation of the vertical wind velocity, we found the daytime and nighttime precision of half-hourly methane flux measurements to be approximately 1.2 and 0.7?μg?CH4?m?2?s?1, respectively. Additional uncertainties caused by the dilution effect were estimated to affect the accuracy by as much as 0.21?μg?CH4?m?2?s?1 on a half-hourly basis. Diurnal and seasonal variations were observed in the measured fluxes. The biological emission from plant leaves was not observed in our studies, and thus could be negligible at the canopy-scale exchange. The annual methane sink was 835?±?175?mg?CH4?m?2?year?1 (8.35?kg?CH4?ha?1?year?1), which was comparable to the flux range of 379–2,478?mg?CH4?m?2?year?1 previously measured in other Japanese forest soils. This study indicated that the REA method could be a promising technique to measure canopy scale methane fluxes over forests, but further improvement of precision of the analyzer will be required.  相似文献   

13.
The most direct method for flux estimation uses eddy covariance, which is also the most commonly used method for land-based measurements of surface fluxes. Moving platforms are frequently used to make measurements over the sea, in which case motion can disturb the measurements. An alternative method for flux estimation should be considered if the effects of platform motion cannot be properly corrected for. Three methods for estimating CO2 fluxes are studied here: the eddy-covariance, the inertial-dissipation, and the cospectral-peak methods. High-frequency measurements made at the land-based Östergarnsholm marine station in the Baltic Sea and measurements made from a ship during the Galathea 3 expedition are used. The Kolmogorov constant for CO2, used in the inertial-dissipation method, is estimated to be 0.68 and is determined using direct flux measurements made at the Östergarnsholm site. The cospectral-peak method, originally developed for neutral stratification, is modified to be applicable in all stratifications. With these modifications, the CO2 fluxes estimated using the three methods agree well. Using data from the Östergarnsholm site, the mean absolute error between the eddy-covariance and inertial-dissipation methods is 0.25 μmol  m?2 s?1. The corresponding mean absolute error between the eddy-covariance and cospectral-peak methods is 0.26 μmol m?2 s?1, while between the inertial-dissipation and cospectral-peak methods it is 0.14 μmol m?2 s?1.  相似文献   

14.
A systematic comparison of wind profiles and momentum exchange at a trade wind site outside Oahu, Hawaii and corresponding data from the Baltic Sea is presented. The trade wind data are to a very high degree swell dominated, whereas the Baltic Sea data include a more varied assortment of wave conditions, ranging from a pure growing sea to swell. In the trade wind region swell waves travel predominantly in the wind direction, while in the Baltic, significant cross-wind swells are also present. Showing the drag coefficient as a function of the 10-m wind speed demonstrates striking differences for unstable conditions with swell for the wind-speed range 2 m s?1 < U 10 < 7 m s?1, where the trade-wind site drag values are significantly larger than the corresponding Baltic Sea values. In striking contrast to this disagreement, other features studied are surprisingly similar between the two sites. Thus, exactly as found previously in Baltic Sea studies during unstable conditions and swell, the wind profile in light winds (3 m s?1) shows a wind maximum at around 7–8 m above the water, with close to constant wind speed above. Also, for slightly higher wind speeds (4 m s?1 < U 10 < 7 m s?1), the similarity between wind profiles is striking, with a strong wind-speed increase below a height of about 7–8 m followed by a layer of virtually constant wind speed above. A consequence of these wind-profile features is that Monin–Obukhov similarity is no longer valid. At the trade-wind site this was observed to be the case even for wind speeds as high as 10 m s?1. The turbulence kinetic energy budget was evaluated for four cases of 8–16 30- min periods at the trade-wind site, giving results that agree very well with corresponding figures from the Baltic Sea.  相似文献   

15.
Many savannas in West Africa have been converted to croplands and are among the world’s regions most vulnerable to climate change due to deteriorating soil quality. We focused on the savanna-derived cropland in northern Ghana to simulate its sensitivity to projected climate change and nitrogen fertilization scenarios. Here we show that progressive warming–drying stress over the twenty-first century will enhance soil carbon emissions from all kinds of lands of which the natural ecosystems will be more vulnerable to variation in climate variables, particularly in annual precipitation. The carbon emissions from all croplands, however, could be mitigated by applying nitrogen fertilizer at 30–60 kg N ha???1 year???1. The uncertainties of soil organic carbon budgets and crop yields depend mainly on the nitrogen fertilization rate during the first 40 years and then are dominated by climate drying stress. The replenishment of soil nutrients, especially of nitrogen through fertilization, could be one of the priority options for policy makers and farm managers as they evaluate mitigation and adaptation strategies of cropping systems and management practices to sustain agriculture and ensure food security under a changing climate.  相似文献   

16.
Increased precipitation during the vegetation periods was observed in and further predicted for Inner Mongolia. The changes in the associated soil moisture may affect the biosphere-atmosphere exchange of greenhouse gases. Therefore, we set up an irrigation experiment with one watered （W） and one unwatered plot （UW） at a winter-grazed Leymus chinensis-steppe site in the Xilin River catchment, Inner Mongolia. UW only received the natural precipitation of 2005 （129 mm）, whereas W was additionally watered after the precipitation data of 1998 （in total 427 mm）. In the 3-hour resolution, we determined nitrous oxide （N20）, methane （CH4） and carbon dioxide （CO2） fluxes at both plots between May and September 2005, using a fully automated, chamber-based measuring system. N20 fluxes in the steppe were very low, with mean emissions （±s.e.） of 0.9-4-0.5 and 0.7-4-0.5 μg N m^-2 h^-1 at W and UW, respectively. The steppe soil always served as a CH4 sink, with mean fluxes of -24.1-4-3.9 and -31.1-4- 5.3 μg C m^-2 h^-1 at W and UW. Nighttime mean CO2 emissions were 82.6±8.7 and 26.3±1.7 mg C m^-2 h^-1 at W and UW, respectively, coinciding with an almost doubled aboveground plant biomass at W. Our results indicate that the ecosystem CO2 respiration responded sensitively to increased water input during the vegetation period, whereas the effects on CH4 and N2O fluxes were weak, most likely due to the high evapotranspiration and the lack of substrate for N2O producing processes. Based on our results, we hypothesize that with the gradual increase of summertime precipitation in Inner Mongolia, ecosystem CO2 respiration will be enhanced and CH4 uptake by the steppe soils will be lightly inhibited.  相似文献   

17.
The radiative forcings and feedbacks that determine Earth’s climate sensitivity are typically defined at the top-of-atmosphere (TOA) or tropopause, yet climate sensitivity itself refers to a change in temperature at the surface. In this paper, we describe how TOA radiative perturbations translate into surface temperature changes. It is shown using first principles that radiation changes at the TOA can be equated with the change in energy stored by the oceans and land surface. This ocean and land heat uptake in turn involves an adjustment of the surface radiative and non-radiative energy fluxes, with the latter being comprised of the turbulent exchange of latent and sensible heat between the surface and atmosphere. We employ the radiative kernel technique to decompose TOA radiative feedbacks in the IPCC Fourth Assessment Report climate models into components associated with changes in radiative heating of the atmosphere and of the surface. (We consider the equilibrium response of atmosphere-mixed layer ocean models subjected to an instantaneous doubling of atmospheric CO2). It is shown that most feedbacks, i.e., the temperature, water vapor and cloud feedbacks, (as well as CO2 forcing) affect primarily the turbulent energy exchange at the surface rather than the radiative energy exchange. Specifically, the temperature feedback increases the surface turbulent (radiative) energy loss by 2.87 W m?2 K?1 (0.60 W m?2 K?1) in the multimodel mean; the water vapor feedback decreases the surface turbulent energy loss by 1.07 W m?2 K?1 and increases the surface radiative heating by 0.89 W m?2 K?1; and the cloud feedback decreases both the turbulent energy loss and the radiative heating at the surface by 0.43 and 0.24 W m?2 K?1, respectively. Since changes to the surface turbulent energy exchange are dominated in the global mean sense by changes in surface evaporation, these results serve to highlight the fundamental importance of the global water cycle to Earth’s climate sensitivity.  相似文献   

18.
This study provides an analysis of a five-year time series chemical composition of the bulk deposition (2009–2013), collected within a farm surrounded by industrial and urban settlements in a semi-rural area of the Po Valley, with the aim of characterizing potential emission sources affecting precipitation composition at the site. Most monitoring efforts in this region, recognized as one of the most polluted in the world both due to the intense industrialisation and urbanisation as well as to frequent air stagnation conditions, are presently devoted more to gaseous and particulate pollutants than to precipitation chemistry. The bulk deposition samples were very concentrated in chemical species, both acidic and alkaline, high compared to other polluted sites in the world and to locations in the same district. The mean ions concentrations (in μeq l?1) are: NO3 ? (243) > SO4 2? (220) > PO4 3? (176) > Cl? (153) > NO2 ? (29) > F? (2.6); NH4 + (504) > Ca2+ (489) > K+ (151) > Na+ (127) > Mg2+ (127). pH data shows a trend toward slightly alkaline conditions attributed to the large presence of ammonium and crustal elements, in spite of high concentrations of nitrates and sulphates. The relevant concentrations of Ca2+ and Mg2+ further suggests that these alkaline conditions might be due to the correspondingly significant concentrations of carbonates/bicarbonates in our dataset. While back-trajectories analysis suggests the stronger importance of local resuspension over long-range transport, statistical analyses on ion composition highlight the key role exerted by agricultural activity, especially in the case of NH4 +, K+, Ca2+ and PO4 3? (especially linked to fertilisation practices and soil resuspension due to mechanical operations). Apart from Na+ and Cl? ions which correlate well as expected, indicating their likely common origin from marine salt, the identification of the origin of the other ions is very complex due to the contribution of diverse local sources, such as industrial and residential settlements.  相似文献   

19.
The main goal of this work is to describe the anthropogenic energy flux (Q F) in the city of S?o Paulo, Brazil. The hourly, monthly, and annual values of the anthropogenic energy flux are estimated using the inventory method, and the contributions of vehicular, stationary, and human metabolism sources from 2004 to 2007 are considered. The vehicular and stationary sources are evaluated using the primary consumption of energy based on fossil fuel, bio fuel, and electricity usage by the population. The diurnal evolution of the anthropogenic energy flux shows three relative maxima, with the largest maxima occurring early in the morning (??19.9 Wm?2) and in the late afternoon (??20.3 Wm?2). The relative maximum that occurs around noontime (??19.6 Wm?2) reflects the diurnal pattern of vehicle traffic that seems to be specific to S?o Paulo. With respect to diurnal evolution, the energy flux released by vehicular sources (Q FV) contributes approximately 50% of the total anthropogenic energy flux. Stationary sources (Q FS) and human metabolism (Q FM) represent about 41% and 9% of the anthropogenic energy flux, respectively. For 2007, the monthly values of Q FV, Q FS, Q FM, and Q F are, respectively, 16.8?±?0.25, 14.3?±?0.16, 3.5?±?0.03, and 34.6?±?0.41?MJ?m?2?month?1. The seasonal evolution monthly values of Q FV, Q FS, Q FM, and Q F show a relative minimum during the summer and winter vacations and a systematic and progressive increase associated with the seasonal evolution of the economic activity in S?o Paulo. The annual evolution of Q F indicates that the city of S?o Paulo released 355.2?MJ?m?2?year?1 in 2004 and 415.5?MJ?m?2?year?1 in 2007 in association with an annual rate of increase of 19.6?MJ?m?2?year?1 (from 2004 to 2006) and 30.5?MJ?m?2?year?1 (from 2006 to 2007). The anthropogenic energy flux corresponds to about 9% of the net radiation at the surface in the summer and 15% in the winter. The amplitude of seasonal variation of the maximum hourly value of the diurnal variation increases exponentially with latitude.  相似文献   

20.
Ocean emissions of inorganic and organic iodine compounds drive the biogeochemical cycle of iodine and produce reactive ozone-destroying iodine radicals that influence the oxidizing capacity of the atmosphere. Di-iodomethane (CH2I2) and chloro-iodomethane (CH2ICl) are the two most important organic iodine precursors in the marine boundary layer. Ship-borne measurements made during the TORERO (Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated VOC) field campaign in the east tropical Pacific Ocean in January/February 2012 revealed strong diurnal cycles of CH2I2 and CH2ICl in air and of CH2I2 in seawater. Both compounds are known to undergo rapid photolysis during the day, but models assume no night-time atmospheric losses. Surprisingly, the diurnal cycle of CH2I2 was lower in amplitude than that of CH2ICl, despite its faster photolysis rate. We speculate that night-time loss of CH2I2 occurs due to reaction with NO3 radicals. Indirect results from a laboratory study under ambient atmospheric boundary layer conditions indicate a k CH2I2+NO3 of ≤4 × 10?13 cm3 molecule?1 s?1; a previous kinetic study carried out at ≤100 Torr found k CH2I2+NO3 of 4 × 10?13 cm3 molecule?1 s?1. Using the 1-dimensional atmospheric THAMO model driven by sea-air fluxes calculated from the seawater and air measurements (averaging 1.8 +/? 0.8 nmol m?2 d?1 for CH2I2 and 3.7 +/? 0.8 nmol m?2 d?1 for CH2ICl), we show that the model overestimates night-time CH2I2 by >60 % but reaches good agreement with the measurements when the CH2I2 + NO3 reaction is included at 2–4 × 10?13 cm3 molecule?1 s?1. We conclude that the reaction has a significant effect on CH2I2 and helps reconcile observed and modeled concentrations. We recommend further direct measurements of this reaction under atmospheric conditions, including of product branching ratios.  相似文献   

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