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1.
The veneer cladding of the Oeconomicum (OEC, Göttingen), the State Theatre of Darmstadt (STD, Darmstadt) and of the State and University Library (SUB, Göttingen) is characterised by pronounced bowing after a short time of exposure. Direct comparison of bowing data related to measurements from 2000 to 2003 at the SUB clearly show that the amplitude in bowing had significantly increased. The bowing is different in intensity and orientation (concave, convex). The cladding material (Peccia marble, Rosa Estremoz marble and Carrara marble) are different in lattice preferred orientation, grain size distribution and grain interlocking. Depending on the bowing, panels may show cracks mostly initiated at the dowels. The percentage of visible cracks and breakouts increases with the amplitude of bowing except for the STD. Repetitive heating–cooling under dry conditions leads to considerable inelastic residual strain only after the first or second thermal cycle. The residual strain continuously increases again if water is present, whereby the moisture content after a thermal cycle has a certain impact on the decay rate. The water-enhanced thermal dilatation strongly correlates with the deterioration rate obtained from the laboratory bow test. Detailed petrophysical investigations provide evidence that with increasing bowing a decrease of mechanical properties (flexural strength or breaking load at dowel hole) occur. Marble degradation is also connected with the increase in porosity and a general shift of the maximum pore radii to larger pore sizes. On-site damage analyses were combined with laboratory tests of the bowing potential to constrain factors that may influence the risk failure. The experimental bowing data clearly demonstrate that after 40 heating cycles combined with the effect of moisture a certain impact on the decay rate is observed. In the case of demounted panels the bowing tests show that already strongly deformed panels from the building exhibit a lower bowing potential than those with lower amplitudes of bowing. This is not the general case for all marble types. Finally, the artificial bowing causes a significant reduction of the flexural strength and the breaking load at the dowel hole. The strength loss of the experimentally aged claddings combined with on-site damage analyses led to conclusions concerning risk assessment and the predicted lifetime of the investigated marble claddings. 相似文献
2.
Three calcitic marble types often used as cladding material and different in lattice preferred orientation (texture), grain shape preferred orientation, grain size distribution and grain interlocking are investigated to study the combined effect of thermal cycles (day-night) and moisture on the decay of marble, particularly on the bowing phenomenon. Repetitive heating-cooling under dry conditions leads to considerable inelastic residual strain only in the first thermal cycle. The residual strain continuously increases again if water is present, whereby the moisture content after a thermal cycle has a certain impact on the decay rate. The water-enhanced thermal dilatation strongly correlates with the deterioration rate obtained from the laboratory bow test. All applied approaches reveal that the texture in combination with the grain shape preferred orientation control the intensity and anisotropy of marble deterioration, thus, the cutting direction of facade panels has to be considered in terms of durability. On-site analysis from building facades confirm the laboratory results such as the bowing tendency of different marbles, directional dependence, relevance of moisture content during cyclical heating and the loss of strength due to environmental impact.Special Issue: Stone decay hazards 相似文献
3.
In order to describe and explain the effect of bowing of marble facade panels, neutron time-of-flight diffraction was applied to determine residual macro- and microstrain on the calcite mineral phase. The measurements were combined with investigations of the crystallographic preferred orientation (texture) measurements by neutron diffraction, macroscopic measuring of the bowing on marble building stones, as well as microfabric analyses. Three samples were investigated to explain the bowing effect: a fresh broken sample, a good conditioned facade panel and a strongly deformed facade panel. Residual intracrystalline strain was detected in all investigated samples, which differed in the degree of bowing. For the first time, the preferred orientation and the residual strain were found to be related. The results show that different strain magnitudes are reflected by residual strains, which differ significantly in magnitude and direction. Furthermore, different Bragg peak widths have been detected as an indication of microscopic strain. The observed residual strain values in the samples are related with the grain shape and texture properties. 相似文献
4.
The bowing potential of granitic rocks: rock fabrics, thermal properties and residual strain 总被引：1，自引：0，他引：1
The bowing of natural stone panels is especially known for marble slabs. The bowing of granite is mainly known from tombstones
in subtropical humid climate. Field inspections in combination with laboratory investigations with respect to the thermal
expansion and the bowing potential was performed on two different granitoids (Cezlak granodiorite and Flossenbürg granite)
which differ in the composition and rock fabrics. In addition, to describe and explain the effect of bowing of granitoid facade
panels, neutron time-of-flight diffraction was applied to determine residual macro- and microstrain. The measurements were
combined with investigations of the crystallographic preferred orientation of quartz and biotite. Both samples show a significant
bowing as a function of panel thickness and destination temperature. In comparison to marbles the effect of bowing is more
pronounced in granitoids at temperatures of 120°C. The bowing as well as the thermal expansion of the Cezlak sample is also
anisotropic with respect to the rock fabrics. A quantitative estimate was performed based on the observed textures. The effect
of the locked-in stresses may also have a control on the bowing together with the thermal stresses related to the different
volume expansion of the rock-forming minerals. 相似文献
5.
Enrico Sassoni Serena Andreotti George W. Scherer Elisa Franzoni Siegfried Siegesmund 《Environmental Earth Sciences》2018,77(10):387
Bowing of thin marble slabs is a phenomenon affecting both historic monuments and modern buildings. In spite of the ubiquity and destructiveness of this phenomenon, no fully satisfactory treatment is currently available to arrest and/or prevent bowing. In this study, a treatment based on formation of hydroxyapatite (HAP) was investigated as a possible route to arrest and possibly prevent bowing of Carrara marble slabs. Four different formulations of the HAP treatment were tested and compared to ammonium oxalate and ethyl silicate (widely used in the practice of marble conservation). The treatments were applied onto pre-weathered and unweathered specimens to investigate their ability to arrest and prevent bowing, respectively. Marble behavior was studied in terms of residual strain and bowing after thermal cycles up to 90 °C in dry and wet conditions. Marble cohesion was assessed before and after the thermal cycles by ultrasound. The HAP treatments exhibited promising results, as the residual strain and the bowing after the cycles were always lower or equal to the untreated references, while marble cohesion was always higher. Surprisingly, ammonium oxalate caused marked worsening of marble thermal behavior. In the case of ethyl silicate, most of the initial benefit after consolidation was lost after the thermal cycles. In general, the results of the study point out the importance of evaluating marble thermal behavior to assess the suitability of any conservation treatment and suggest that treatments able to strengthen marble without causing excessive pore occlusion and stiffening are preferable to enhance durability to thermal cycles. 相似文献
6.
为了探讨温度周期变化与高围压对大理岩变形、强度特性及破坏断裂损伤劣化的影响,采用MTS815.03电液伺服刚性岩石试验系统,选取四川凉山雅砻江大河湾锦屏二级水电站引水隧洞围岩大理岩试样分别进行不同温度变化（100～ 600 ℃）,周期次数为8次。进行高围压（60 MPa）作用下全应力应变过程三轴压缩与单轴压缩对比试验,系统分析比较了温度循环与高围压作用对大理岩应力-应变关系曲线、峰值应力、残余应力,峰值应变、残余应变以及弹性模量等的影响。试验结果表明,大理岩随着温度升高,峰值强度、残余强度、弹性模量下降,峰值应变和残余应变随之增大;在同一温度下,随着循环次数增加,其弹性模量、峰值强度、残余强度降低,温度越高,降低越明显;多次循环后,岩石的脆性变大,应力-应变曲线峰后段不再平滑,残余应变变小,其研究成果为锦屏二级水电站引水隧洞围岩稳定性分析提供理论依据。 相似文献
7.
Victoria Shushakova Edwin R. Fuller Jr. Florian Heidelbach David Mainprice Siegfried Siegesmund 《Environmental Earth Sciences》2013,69(4):1281-1297
Thermoelastic behavior of different marble types was analyzed using computational modeling and experimental measurements. Eight marble samples with different composition, grain size, grain boundary geometry, and texture were investigated. Calcitic and dolomitic marbles were considered. The average grain size varies from 75 μm to 1.75 mm; grain boundary geometry differs from nearly equigranular straight grain boundaries to inequigranular-interlobate grain boundaries. Four typical marble texture types were observed by EBSD measurements: weak texture; strong texture; girdle texture and high-temperature texture. These crystallographic orientations were used in conjunction with microstructure-based finite element analysis to compute the thermoelastic responses of marble upon heating. Microstructural response maps highlight regions and conditions in the marble fabric that are susceptible to degradation phenomena. This behavior was compared to the measured thermal expansion behavior, which shows increasing residual strains upon repetitive heating–cooling cycles. The thermal expansion behavior as a function of temperature changes can be classified into four categories: (a) isotropic thermal expansion with small or no residual strain; (b) anisotropic thermal expansion with small or no residual strain; (c) isotropic thermal expansion with a residual strain; and (d) anisotropic thermal expansion with residual strain. Thermal expansion coefficients were calculated for both simulated and experimental data and also modeled from the texture using the MTEX software. Fabric parameters control the amount and directional dependence of the thermal expansion. Marbles with strong texture show higher directional dependence of the thermal expansion coefficients and have smaller microstructural values of the maximum principal stress and strain energy density, the main precursors of microcracking throughout the marble fabric. In contrast, marbles with weak texture show isotropic thermal expansion behavior, have a higher propensity to microcracking, and exhibit higher values of maximum principal stress and strain energy density. Good agreement between the experimental and computational results is observed, demonstrating that microstructure-based finite-element simulations are an excellent tool for elucidating influences of rock fabric on thermoelastic behavior. 相似文献
8.
S. Siegesmund K. Ullemeyer T. Weiss E. K. Tschegg 《International Journal of Earth Sciences》2000,89(1):170-182
Marbles as building stones as well as in their natural environments show complex weathering phenomena. The most important
damage scenario is based on the highly anisotropic thermal expansion coefficient α of calcite, i.e. extreme expansion parallel and contraction normal to the crystallographic c-axis. Therefore, the rock fabric
and especially the lattice-preferred orientation (texture) of calcite and/or dolomite as the predominant mineral phases in
marbles have a significant influence on the mechanical weathering. The textures of marbles from five different locations vary
from a more or less perfect prolate to moderate oblate shape of the [006] pole figure tensor. Accordingly, the texture-derived
bulk thermal dilatation anisotropy covers a broad range from –0.048 to 0.680. The modelled thermal dilatations correlate with
those obtained from experimental measurements. The difference in magnitude is basically explained by the microcrack fabrics
which was not considered in the computations. All samples show a deterioration due to thermal treatment regardless of the
strength of texture. The directional dependence of (a) the total magnitude of the thermal dilatation coefficient and (b) of
the residual strain is highest in marbles with a strong texture, whereas the Carrara marble with a weak texture exhibits a
uniform crack formation. The progressive loss of cohesion along grain boundaries due to dilatancy may serve as an example
for the initial stage of physical weathering.
Received: 10 February 1999 / Accepted: 16 October 1999 相似文献
9.
The thermal rock properties are particularly important for natural stones whenever a temperature change may occur, which becomes particularly important when different materials are combined on any architectural structure. The thermal expansion of a rock is dependent on the coefficients of the expansion of the individual rock-forming minerals and the rock fabric. A systematic study on 65 different stones, mostly granitoids and others magmatic rocks, most of them are often used as dimensional building stones, was performed. Temperature and moisture are very important parameters in the natural environment. Therefore, the thermal expansion, and in addition the thermohygric expansion on selected examples, was measured. The data were also discussed considering the effect of the mineralogy and the temperature. A modeling approach was introduced to show how the mineralogy and the related single crystal properties affect the thermal properties and how good a simple calculation can help to characterize the measured thermal expansion of a rock. The directional dependence of the thermal expansion was also discussed and explained based on detailed rock fabric measurements. In this study, the bowing of granitoid samples was tested and compared with bowing phenomena of granitoid facade panels. The slabs were cut in different directions and were studied under different conditions of temperatures and water saturation. It could be clearly documented that the temperature and the moisture have a control on the bowing behavior. The implication of our data is that thermal expansion depends greatly on wetting and drying, i.e., the thermal cracking is characterized by the residual strain observed after cooling to room temperature. The sensitivity to the thermal cracking has a significant control on the application in architectural constructions. 相似文献
10.
Kai Chen Martin Kunz Nobumichi Tamura Hans-Rudolf Wenk 《Physics and Chemistry of Minerals》2011,38(6):491-500
Microstructures of deformed calcite in marble from the Bergell Alps are studied by using a microfocused polychromatic synchrotron
X-ray beam. The high spatial resolution, together with orientation and strain resolutions, reveals twin plane orientation,
multiple twin lamellae, and strain distributions associated with the twins. Single and multiple mechanical twins on e = { 01[`1] 8 } e = \left\{ {01\overline{1} 8} \right\} systems are confirmed. Residual stresses are derived from the strain tensor that is derived from Laue diffraction patterns.
Average lattice strains from several hundred to over one thousand microstrains are detected in a deformed marble from the
Bergell Alps. Such strains suggest 60–120 MPa residual stresses. A detailed study of strain components shows that shear stresses
on twin planes are completely released. 相似文献
11.
Bowing of dimensional granitic stones 总被引：1，自引：1，他引：0
Bowing is a well-known phenomenon seen in marbles used as building veneers. This form of rock weathering occurs as a result of external factors such as temperature, humidity, the system for anchoring the marble slabs or the panel dimensions. Under the same external conditions, many factors will determine the degree of deformation including petrography, thermal properties and residual locked stresses. The usual way to solve the problem of bowed marble slabs is to replace them with other materials, such as granites, in which the deformation still exists but is less common. In this study, eight ornamental granites with different mineralogy, grain size, grain shape, porosity and fabric were tested in a laboratory to assess their susceptibility to bowing. Three slabs of granite, each cut with a different orientation, were studied under different conditions of temperature (90 and 120°C) and water saturation (dry and wet) to investigate the influence of these factors together with that of anisotropy. At 90°C, only the granite with the coarsest grain size and low porosity exhibited deformation under wet conditions. At 120°C and wet conditions, three of the granites showed evident signs of bowing. Again, the granite with the coarsest grain size was the most deformed. It was concluded that the wide grain size distribution influences microcracking more than other expected factors, such as the quartz content of the rock. Also, mineral shape-preferred orientation and porosity play an important role in the bowing of the studied granites. 相似文献
12.
13.
Christoph Spötl Yuri Dublyansky Michael Meyer Augusto Mangini 《International Journal of Earth Sciences》2009,98(3):665-676
The area south of the prominent east–west trending Salzach Valley at the northern rim of the Central Alps of Austria has long
been known to host anomalously warm springs emerging from a highly deformed calcite marble (Klammkalk). This unit also hosts
cavities whose shapes suggest a hydrothermal karst origin and which are lined by calcite spar. We report here petrographic
and isotopic evidence suggesting that dissolution by ascending low-temperature thermal waters also played an important role
in the origin of a large cave in this region, Entrische Kirche. A paleo cave wall, preserved behind a thick flowstone in the
interior of this cave, revealed a brownish bleaching zone which contrasts to the medium grey colour of the unaltered marble
beneath. Across this zone the C and O isotope values gradually decrease by 3 and 11‰, respectively. These compositions are
very different from those of the speleothem above but are similar to phreatic calcite spar from hydrothermal karst cavities
in other outcrops in the area, where the absence of two-phase fluid inclusions suggests a low-temperature (less than ca. 50°C)
hydrothermal origin. U/Th dating of the flowstone capping the alteration zone yielded a minimum age of the thermal water invasion
in Entrische Kirche of ca. 240 kyr. There is no evidence in Entrische Kirche that these palaeowaters reached the point of
calcite precipitation, but it is physically conceivable that higher and as yet unexplored parts of this deep (ca. 900 m) cave
contain cavities lined by phreatic cave spar. 相似文献
14.
The deformation history of a monophase calcite marble shear zone complex on Thassos Island, Northern Greece, is reconstructed by detailed geometric studies of the textural and microstructural patterns relative to a fixed reference system (shear zone boundary, SZB). Strain localization within the massive marble complex is linked to decreasing P–T conditions during the exhumation process of the metamorphic core complex. Solvus thermometry indicates that temperatures of 300–350°C prevailed during part of the shear zone deformation history. The coarse-grained marble protolith outside the shear zone is characterized by symmetrically oriented twin sets due to early coaxial deformation. A component of heterogeneous non-coaxial deformation is first recorded within the adjacent protomylonite. Enhanced strain weakening by dynamic recrystallization promoted strong localization of plastic deformation in the ultramylonite of the calcite shear zone, where high strain was accommodated by non-coaxial flow. This study demonstrates that both a pure shear and a simple shear strain path can result in similar crystallographic preferred orientations (single c-axis maximum perpendicular to the SZB) by different dominant deformation mechanisms. Separated a-axis pole figures (+a- and −a-axis) show different density distributions with orthorhombic texture symmetry in the protolith marble and monoclinic symmetry in the ultramylonite marble consistently with the observed grain fabric symmetry. 相似文献
15.
Graphite deformation in marble and mylonitic marble, Grenville Province, Canadian Shield 总被引：2，自引：0，他引：2
R. KRETZ 《Journal of Metamorphic Geology》1996,14(4):399-412
In the southern Grenville Province of the Canadian Shield (Otter Lake area), high-grade marble, gneiss and amphibolite have been folded about north- to north-east-trending axes; mylonite zones, parallel to layering and 0.1–10 cm wide, are locally present in marble.
In nonmylonitic marble, graphite occurs as c . 1–mm hexagonal prisms, which are commonly accompanied by a relatively few crystals that have been deformed, resulting in cleavage separation and the formation of folds and kink bands. Fracture-filled calcite contains less Mg and Fe than surrounding calcite (e.g. <0.30 compared with 1.8–2.7 wt% MgO, and 0.02–0.12 compared with 0.13–0.18 wt% FeO); the composition of fracture-filled dolomite is similar to that of the surrounding dolomite. In semimylonite, graphite forms elongate streaks of fragmented crystals and, in mylonite, further fragmentation has occurred to produce extremely small particles. The fragmentation has not destroyed the atomic structure (hexagonal modification) of graphite.
The behaviour of biotite was similar to that of graphite, but extreme fragmentation did not occur. Dolomite was more rigid than calcite, and in mylonite it occurs more commonly as relics. Amphibole and pyroxene crystals remained undeformed but are locally replaced by calcite.
The numerous microprocesses that have evidently occurred in marble and mylonitic marble of the study area are: coarsening (calcite, graphite), twinning (calcite, dolomite), slip (calcite, dolomite, graphite, biotite), strain-induced recrystallization (calcite), microfolding and kink-band formation (graphite, biotite), fragmentation (graphite) and the pressure-induced transport of calcite and dolomite to voids in graphite and biotite. 相似文献
In nonmylonitic marble, graphite occurs as c . 1–mm hexagonal prisms, which are commonly accompanied by a relatively few crystals that have been deformed, resulting in cleavage separation and the formation of folds and kink bands. Fracture-filled calcite contains less Mg and Fe than surrounding calcite (e.g. <0.30 compared with 1.8–2.7 wt% MgO, and 0.02–0.12 compared with 0.13–0.18 wt% FeO); the composition of fracture-filled dolomite is similar to that of the surrounding dolomite. In semimylonite, graphite forms elongate streaks of fragmented crystals and, in mylonite, further fragmentation has occurred to produce extremely small particles. The fragmentation has not destroyed the atomic structure (hexagonal modification) of graphite.
The behaviour of biotite was similar to that of graphite, but extreme fragmentation did not occur. Dolomite was more rigid than calcite, and in mylonite it occurs more commonly as relics. Amphibole and pyroxene crystals remained undeformed but are locally replaced by calcite.
The numerous microprocesses that have evidently occurred in marble and mylonitic marble of the study area are: coarsening (calcite, graphite), twinning (calcite, dolomite), slip (calcite, dolomite, graphite, biotite), strain-induced recrystallization (calcite), microfolding and kink-band formation (graphite, biotite), fragmentation (graphite) and the pressure-induced transport of calcite and dolomite to voids in graphite and biotite. 相似文献
16.
Onimisi A. Jimoh Kamar S. Ariffin Hashim B. Hussin Toyin Abdulkareem 《Journal of the Geological Society of India》2017,89(4):413-418
Metacarbonate deposit occurring in Emiworo area, northcentral Nigeria are low grade marble associated with Proterozoic basement complex rocks. Integrated inorganic geochemical, physical and thermal characteristics of the samples were investigated with the aim of revealing their economic viability. The phase characteristics of the metacarbonate show that dolomite is the dominant phase with calcite and phlogopite as minor phases, while silicates, graphites and pyrites constitute the accessories. Reactivity of the quicklime measured after calcination at different temperatures revealed that only the quicklime produced in 1 hour at 950°C and 1000°C was found to be reactive. Physical properties and comparative data show that the Emiworo marble displays lower water absorption and higher compressive strength, loss on ignition and bulk specific gravity, compared to other metacarbonate rocks occurring in other parts of Nigeria and elsewhere. These attributes makes the deposit suitable for many conventional industrial applications. 相似文献
17.
X射线粉晶衍射仪在大理岩鉴定与分类中的应用 总被引：2，自引：2，他引：0
大理岩主要有方解石大理岩、白云石大理岩和菱镁矿大理岩三种。以往大理岩是依据偏光显微镜下观察岩石结构构造及矿物成分进行分类定名,由于方解石、白云石、菱镁矿都属于三方晶系,具有闪突起、高级白干涉色、一轴晶负光性和菱形解理等相同晶体光学特征,偏光显微镜下区分十分困难。为了准确鉴定大理岩中碳酸盐矿物种类及其相对含量,本文利用岩石薄片偏光显微镜和X射线粉晶衍射技术对32件大理岩岩石样品进行分析测试。岩石薄片鉴定结果表明:大理岩造岩矿物主要有方解石、白云石、菱镁矿、石英、斜长石、白云母、黑云母、绿泥石、黏土和金属矿物。根据岩石结构构造及矿物组分特征,可把32件大理岩样品划分为方解石大理岩、长英质方解石大理岩、石英绿泥白云石大理岩、白云石大理岩、云英质白云石大理岩和菱镁矿大理岩等15个类型。X射线粉晶衍射分析表明:大理岩造岩矿物主要有方解石、白云石、菱镁矿、石英、斜长石、钾长石、云母、绿泥石、滑石和蒙脱石。综合分析认为:岩石薄片偏光显微镜鉴定技术很难区分方解石、白云石和菱镁矿等碳酸盐矿物,以及细小的石英、钾长石和斜长石、滑石和白云母等鳞片状硅酸盐矿物;X射线粉晶衍射分析技术不仅能准确检测出大理岩中方解石、白云石和菱镁矿等碳酸盐矿物种类及相对含量(方解石、白云石和菱镁矿的X射线衍射主峰有明显差异,d值分别为0.303 nm、0.288 nm和0.274 nm),而且能够有效鉴别岩石中粉砂级斜长石、钾长石与石英(三种矿物的X射线衍射主峰d值分别为0.319 nm、0.324 nm、0.334 nm);且能区分蒙脱石、绿泥石、云母和滑石等层状硅酸盐矿物(四种硅酸盐矿物的X射线衍射主峰d值分别为1.400 nm、0.705 nm、0.989 nm、0.938 nm)。综合岩石薄片偏光显微镜鉴定和X射线粉晶衍射分析结果,最终确定32件大理岩样品划分为22个岩石类型。研究认为:仅根据岩石薄片偏光显微镜鉴定或X射线粉晶衍射技术其中一种方法不能准确鉴定大理岩岩石,应将大理岩岩石野外观察、岩石薄片鉴定和X射线粉晶衍射技术结合起来,才能准确确定大理岩岩石类型。 相似文献
18.
Weathering and weathering rates of natural stone 总被引：3，自引：0，他引：3
Erhard M. Winkler 《Environmental Geology》1987,9(2):85-92
Physical and chemical weathering were studied as separate processes in the past. Recent research, however, shows that most
processes are physicochemical in nature. The rates at which calcite and silica weather by dissolution are dependent on the
regional and local climatic environment. The weathering of silicate rocks leaves discolored margins and rinds, a function
of the rocks' permeability and of the climatic parameters. Salt action, the greatest disruptive factor, is complex and not
yet fully understood in all its phases, but some of the causes of disruption are crystallization pressure, hydration pressure,
and hygroscopic attraction of excess moisture.
The decay of marble is complex, an interaction between disolution, crack-corrosion, and expansion-contraction cycies triggered
by the release of residual stresses. Thin spalls of granites commonly found near the street level of buildings are generally
caused by a combination of stress relief and salt action. To study and determine weathering rates of a variety of commercial
stones, the National Bureau of Standards erected a Stone Exposure Test Wall in 1948. Of the many types of stone represented,
only a few fossiliferous limestones permit a valid measurement of surface reduction in a polluted urban environment. 相似文献
19.
Petrographic investigations on the light yellow marble outcrops in the Griesscharte, Tyrol, Austria/Italy revealed them to be dolomite. The white to blue-grey veins in these marbles were those of calcite. Inside these calcites and along the calcite-dolomite phase boundaries minute and microscopically unidentifiable crystallites (? 10 μ) were observed. These crystallites were recognised by X-ray diffractometry as dolomite and their form and distribution were established by scanning electron microscopy. Trace-element distributions on the calcite-dolomite neighbours were studied by neutron-activation method to elucidate the formation mechanism of these calcites in the marble.Genetic relationships of the dolomite crystallites, the calcite host and the surrounding dolomite marble have been discussed in the light of the petrographic and chemical studies. These findings substantiate a deposition of a new formed vein of calcite from the solution circulating in the fissures of the dolomite marble during prograde metamorphism rather than a simple deposition of mobilized sedimentary calcite. The dolomite crystallites in the calcite seem to have been formed post-tectonically, partly by the nucleation in the calcite cleavage planes during Mg-metasomatism and partly from the exsolutions during retrograde metamorphism. 相似文献
20.
Quartz and calcite microfabric transitions in a pressure and temperature gradient,Sivrihisar, Turkey
Nicholas C.A. Seaton Christian Teyssier Donna L. Whitney Matthew T. Heizler 《Geodinamica Acta》2013,26(3-4):191-206
Interlayered quartzite and marble in the southern Sivrihisar Massif, Turkey, record metamorphic conditions ranging from high-pressure/low-temperature through a Barrovian overprint from chlorite- to sillimanite-zone conditions. This sequence was exhumed under transtension, producing macroscopic constrictional fabrics (L-tectonites) during crustal thinning. Quartz microstructures consist of dynamically recrystallized aggregates in the dislocation creep regime dominated by grain boundary migration. Quartz microstructures are relatively constant across the high metamorphic gradient, and crystallographic fabric patterns transition from plane strain to constriction strain. Calcite fabrics are characterized by progressive overprinting of a columnar texture inherited from the high-pressure polymorph aragonite. In the low-temperature Barrovian domain (<400?°C), shearing of calcite rods produced a very strong c-axis point maximum. At moderate temperature, calcite rods were partially to totally recrystallized and the strong preferred orientation maintained. At temperature >500?°C and high constriction strain, marble has no crystallographic fabric, likely reflecting a transition from dislocation creep to diffusion creep. Phengite in high-pressure/low-temperature marble and quartzite yields relatively simple age spectra with Late Cretaceous (88–82 Ma) 40Ar/39Ar ages. Barrovian muscovite records significantly younger ages (63–55 Ma). The transtension system and associated metamorphism may have occurred above a subduction zone in Paleocene–Eocene time as a precursor to intrusion of Eocene (~53 Ma) arc plutons. 相似文献