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1.
Baerzhe Be–Nb–Zr–REE deposit is hosted in alkaline granite (125 Ma) which intrudes in the late Jurassic Baiyingaolao Formation in the middle of the Great Hinggan Metallogenic Belt in China. The ore‐forming granite consists of three lithological facies: arfvedsonite‐bearing alkaline granite at the bottom, aegirine‐bearing albite aplite in the middle and pegmatite crust on the top. The albite aplite is the main orebody. We recognized three magmatic‐hydrothermal stages: orthomagmatic stage, late‐magmatic stage and hydrothermal stage, with the late‐magmatic stage being divided into two substages, the pegmatite substage and the aplite substage. Petrographic study on the granite, the microthermometric study on fluid inclusions and in situ laser‐ablation inductively coupled plasma mass spectrometry analysis for quartz‐hosted melt inclusions reveal the process of magmatic‐hydrothermal evolution. The finding indicates that primary magma evolved to more peralkaline by fractional crystallization, with synchronously increasing high field strength elements. An extremely high content of Zr and Nb are in the melt inclusions from last stage albite aplite (Zr, min 52 548 ppm, and Nb, min 4104 ppm). This implies that the residual magma directly formed the orebody of rare metal elements. Meanwhile, volatility was increasing during the magma evolution process and F‐bearing aqueous fluid was oversaturated at temperatures higher than 800°C. The separation of fluid from magma caused Li‐REE enrichment in F‐bearing fluid and depletion in residual melt, and led to the difference of the Y/Ho ratio between whole rock compositions and melt inclusion data. Fluid separated into a high‐salinity liquid and a low density vapor phase above 697°C, and enriched REE in the high‐salinity liquid. The oxygen isotope data shows mixing between primary magmatic‐hydrothermal fluid and meteoric water. The ubiquitous pseudo‐secondary fluid inclusions have a wide range of salinity below 462°C, which is similar to the melting temperatures of REE‐bearing daughter minerals. A model involving the mixing by meteoric water could be a mechanism for precipitation of REE minerals. 相似文献
2.
We present two-feldspar thermometry and diffusion chronometry from sanidine, orthopyroxene and quartz from multiple samples of the Bishop Tuff, California, to constrain the temperature stratification within the pre-eruptive magma body and the timescales of magma mixing prior to its evacuation. Two-feldspar thermometry yields estimates that agree well with previous Fe–Ti oxide thermometry and gives a ~80 °C temperature difference between the earlier- and later-erupted regions of the magma chamber. Using the thermometry results, we model diffusion of Ti in quartz, and Ba and Sr in sanidine as well as Fe–Mg interdiffusion in orthopyroxene to yield timescales for the formation of overgrowth rims on these crystal phases. Diffusion profiles of Ti in quartz and Fe–Mg in orthopyroxene both yield timescales of <150 years for the formation of overgrowth rims. In contrast, both Ba and Sr diffusion in sanidine yield nominal timescales 1–2 orders of magnitude longer than these two methods. The main cause for this discrepancy is inferred to be an incorrect assumption for the initial profile shape for Ba and Sr diffusion modelling (i.e. growth zoning exists). Utilising the divergent diffusion behaviour of Ba and Sr, we place constraints on the initial width of the interface and can refine our initial conditions considerably, bringing Ba and Sr data into alignment, and yielding timescales closer to 500 years, the majority of which are then within uncertainty of timescales modelled from Ti diffusion in quartz. Care must be thus taken when using Ba in sanidine geospeedometry in evolved magmatic systems where no other phases or elements are available for comparative diffusion profiling. Our diffusion modelling reveals piecemeal rejuvenation of the lower parts of the Bishop Tuff magma chamber at least 500 years prior to eruption. Timescales from our mineral profiling imply either that diffusion coefficients currently used are uncertain by 1–2 orders of magnitude, or that the minerals concerned did not experience a common history, despite being extracted from the same single pumice clasts. Introduction of the magma initiating crystallisation of the contrasting rims on sanidine, quartz, orthopyroxene and zircon was prolonged, and may be a marker of other processes that initiated the Bishop Tuff eruption rather than the trigger itself. 相似文献
3.
钠长石花岗岩中雪球结构形成机理的研究 总被引：5，自引：0，他引：5
在某些富锂、氟含稀有金属花岗岩的石英和钾长石斑晶中常见 (半 )雪球结构。雪球结构的产出特征、雪球体中钠长石的电子探针分析结果以及其他间接证据都说明 ,雪球结构是在岩浆结晶分异过程中形成的。对矿物结晶顺序、石英和钠长石的生长速率以及固相线温度的研究表明 ,富锂、氟、钠的花岗质残余岩浆完全具备形成雪球结构的条件。岩浆熔体中较高的Na2 O/K2 O比值和F、H2 O含量在雪球结构的形成过程中起着重要的作用 :F的高含量使岩浆固相线温度降低 ,岩浆得以充分分异演化 ,形成接近端员组分的钾长石和钠长石 ;Na2 O/K2 O比值较大使钠长石首先结晶 ;较高的F和H2 O含量使岩浆粘度降低 ,石英的生长速率相对加快并逐渐包裹钠长石形成雪球结构。 相似文献
4.
An Al‐rich, SiO2‐deficient sapphirine–garnet‐bearing rock occurs as a metapelitic boudin within granulite facies Proterozoic charnockitic gneisses and migmatites on the island of Hisøy, Bamble Sector, SE Norway. The boudin is made up of peraluminous sapphirine, garnet, corundum, spinel, orthopyroxene, sillimanite, cordierite, staurolite and biotite in a variety of assemblages. Thermobarometric calculations based on coexisting sapphirine–spinel, garnet–corundum–spinel–sillimanite, sapphirine–orthopyroxene, and garnet–orthopyroxene indicate peak‐metamorphic conditions near to 930 °C at 10 kbar. Corundum occurs as single 200 to 3000 micron sized skeletal crystal intergrowths in cores of optically continuous pristine garnet porphyroblasts. Quartz occurs as 5–60 micron‐sized euhedral to lobate inclusions in the corundum where it is in direct contact with the corundum with no evidence of a reaction texture. Some crystal inclusions exhibit growth zoning, which indicates that textural equilibrium was achieved. Electron Back‐Scatter Diffraction (EBSD) studies reveal that the quartz inclusions share a common c‐axis with the host corundum crystal. The origin of the quartz inclusions in corundum is enigmatic as recent experimental studies have confirmed the instability of quartz–corundum over geologically realistic P–T ranges. The combined EBSD and textural observations suggest the presence of a former silica‐bearing proto‐corundum, which underwent exsolution during post‐peak‐metamorphic uplift and cooling. Exsolution of quartz in corundum is probably confined to fluid‐absent conditions where phase transitions by coupled dissolution–precipitation mechanisms are prevented. 相似文献
5.
Determining the mechanisms involved in generating large-volume eruptions (>100 km3) of silicic magma with crystallinities approaching rheological lock-up (~50 vol% crystals) remains a challenge for volcanologists. The Cenozoic Southern Rocky Mountain volcanic field, in Colorado and northernmost New Mexico, USA, produced ten such crystal-rich ignimbrites within 3 m.y. This work focuses on the 28.7 Ma Masonic Park Tuff, a dacitic (~62–65 wt% SiO2) ignimbrite with an estimated erupted volume of ~500 km3 and an average of ~45 vol% crystals. Near-absence of quartz, titanite, and sanidine, pronounced An-rich spikes near the rims of plagioclase, and reverse zoning in clinopyroxene record the reheating (from ~750 to >800?°C) of an upper crustal mush in response to hotter recharge from below. Zircon U–Pb ages suggest prolonged magmatic residence, while Yb/Dy vs temperature trends indicate co-crystallization with titanite which was later resorbed. High Sr, Ba, and Ti concentrations in plagioclase microlites and phenocryst rims require in-situ feldspar melting and concurrent, but limited, mass addition provided by the recharge, likely in the form of a melt-gas mixture. The larger Fish Canyon Tuff, which erupted from the same location ~0.7 m.y. later, also underwent pre-eruptive reheating and partial melting of quartz, titanite, and feldspars in a long-lived upper crustal mush following the underplating of hotter magma. The Fish Canyon Tuff, however, records cooler pre-eruptive temperatures (~710–760?°C) and a mineral assemblage indicative of higher magmatic water contents (abundant resorbed sanidine and quartz, euhedral amphibole and titanite, and absence of pyroxene). These similar pre-eruptive mush-reactivation histories, despite differing mineral assemblages and pre-eruptive temperatures, indicate that thermal rejuvenation is a key step in the eruption of crystal-rich silicic volcanics over a wide range of conditions. 相似文献
6.
矿物环带结构是岩浆过程的良好记录,而矿物温压计可以定量计算岩浆的物理化学条件。该次研究对邯邢地区中生代侵入岩中两个浅成侵入体中典型的斜长石斑晶进行了电子探针和LA-ICP-MS元素面扫描,同时对其中不同成因的角闪石晶体进行了电子探针分析和物理化学条件计算。通过研究发现这两个样品中的斜长石斑晶属于循环晶。辉石闪长玢岩中的斜长石斑晶主要成分为更长石,而斑状石英二长岩中斜长石斑晶主要成分为中长石和拉长石。两者具有明显不同的环带结构,分别记录了不同的岩浆混合过程:前者记录了基性岩浆多次注入酸性岩浆房,并最终获得体积优势;后者记录了少量基性岩浆注入酸性岩浆房内,两者不断混合,形成均质化岩浆的过程。Fe元素从斜长石中心到边部有富集的趋势,表明岩浆最终向富铁的方向演化。角闪石温压计的计算结果表明,辉石闪长玢岩的岩浆房深度在5.5 km左右,温度大约为850 ℃,氧逸度大约为ΔNNO+1,熔体中的含水量大约为4.0%,其最终侵位于2.1 km的地壳深度。而斑状石英二长岩最终定位于2.0 km的地壳深度,角闪石结晶的平均温度为737 ℃,相对氧逸度为ΔNNO+1.2,熔体含水量为3.9%。 相似文献
7.
Frank S. Spear Kyle T. Ashley Laura E. Webb Jay B. Thomas 《Contributions to Mineralogy and Petrology》2012,164(6):977-986
Quartz inclusions in garnet from samples collected from the staurolite zone in central New England are zoned in cathodoluminescence (CL). The CL intensity is interpreted to be a proxy for Ti concentration and the zoning attributed to Ti diffusion into the quartz grains driven by Ti exchange between quartz and enclosing garnet as a function of changing temperature. The CL zoning has been interpreted using a numerical diffusion model to constrain the time scales over which the diffusion has occurred. Temperature–time histories are sensitive to the presumed peak temperature but not to other model parameters. The total time of the metamorphic heating and cooling cycle from around 450?°C to the peak temperature (550–600?°C) back to 450?°C is surprisingly short and encompasses only 0.2–2 million years for peak temperatures of 600–550?°C. The metamorphism was accompanied by large-scale nappe and dome formation, and it is suggested that this occurred as a consequence of in-sequence thrusting resulting in a mid-crustal ductile duplex structure. 相似文献
8.
Charles J. Hughes 《Lithos》1971,4(4):403-415
Various structural and textural features of a drusy granophyric ring-dyke intrusion can be explained in terms of the behaviour of magmatic water. Initial crystallization of water-rich magma close to ternary eutectic composition resulted in textures grading from granophyric to microgranitic. Eventual entrapment of water-rich pockets resulted in crystallization from a silicate liquid and a hydrothermal liquid simultaneously, probably at magmatic overpressure, to form isolated bodies of pegmatite containing giant euhedral quartz crystals. Later aplite, rhyolite breccia, and tuffisite veins reflect the escape of magma and magmatic gas through the congealed parts of the intrusion, at first permissively, but later with increasingly explosive effects. 相似文献
9.
华南富锂氟含稀有金属花岗岩的成冈分析 总被引：3，自引：0，他引：3
雪球结构的产出特征、钠长石电子探针分析及其它间接证据都说明,雪球结构是在岩浆结晶过程中形成的。雪球结构形成与否主要与岩浆熔体中Ｎａ２Ｏ／Ｋ２Ｏ比值和Ｆ、Ｈ２Ｏ含量有关。较大的Ｎａ２Ｏ／Ｋ２Ｏ比值（〉１）例钠长石首先从熔体中晶出;较高的Ｆ含量使岩浆固相线温度大大降低,有利于岩浆分异演化并形成接近端员组分的钠长石和钾长石同的Ｈ２Ｏ含量有利于石英以较快的速度生长并逐渐包裹钠长石形成雪球结构。自形的α－石英斑晶、接近各自端员组分的甲和工石和钠长石等说明该类花岗岩形成温度较低,众多的地质、地球化学依据都证明了,华南富锂氟含稀有金属花岗岩是从过铝富氟富钠的残余熔体中直接结晶而成的。 相似文献
10.
The Tonglvshan deposit is the largest Cu–Fe (Au) skarn deposit in the Edong district, which is located in the westernmost part of the Middle and Lower Yangtze River metallogenic belt, China. In this study, we performed a detailed in situ analysis of major and trace elements in amphiboles from the ore-related Tonglvshan quartz monzodiorite porphyry using electron microprobe (EMPA) analysis and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Two distinct populations of amphiboles, which can be distinguished by their aluminum content, are found in the quartz monzodiorite porphyry. The low-aluminum (Low-Al) amphiboles are subhedral or anhedral and formed at 46.3–73.5 MPa and 713–763 °C. In contrast, the high-aluminum (High-Al) amphiboles are euhedral and formed at 88–165 MPa and 778–854 °C. Some euhedral amphiboles are partially or completely replaced by Low-Al amphibole. The compositions of parental melts in equilibrium with the High-Al amphibole (Melt 1) and Low-Al amphibole (Melt 2) were computed by applying solid/liquid partition coefficients. This modeling shows that magma in equilibrium with High-Al amphibole (Melt 1) underwent 40% fractional crystallization of amphibole, plagioclase and apatite at a depth of ~5 km to evolve to magma in equilibrium with Low-Al amphibole (Melt 2). Copper enrichment occurred in the magma after undergoing fractional crystallization. The magma had a high oxygen fugacity, increasing from NNO + 1 (Melt 1) through NNO + 2 to HM (Melt 2), which could have prevented the loss of Cu (and possibly Au) to sulfide minerals during crystallization. Finally, the evolved magma intruded to shallower depths, where it presumably exsolved aqueous ore-forming fluids. Therefore, the large Cu–Fe–Au reserves of the Tonglvshan deposit can likely be attributed to a combination of controlling factors, including high oxygen fugacity, fractional crystallization, fluid exsolution, and a shallow emplacement depth. 相似文献
11.
Anna Pietranik Francois Holtz Jürgen Koepke Jacek Puziewicz 《Mineralogy and Petrology》2009,97(1-2):1-21
Crystallization experiments were performed on quartz diorite (~55 wt.% SiO2, 3.1–8.4 wt.% MgO) from the G?siniec Intrusion (Bohemian Massif, SW Poland) at 1?2 kbar, 750–850°C, various mole fractions of water and with fO2 buffered by the NNO buffer. The two natural quartz diorites (leucocratic poikilitic quartz diorite - ‘LPD’ and melanocratic quartz diorite - ‘MD’) differ in whole rock and mineral composition with MD being richer in MgO and poorer in CaO than LPD, probably due to accumulation of mafic minerals or melt removal in MD. LPD represents melt composition and is used to reconstruct crystallization conditions in the G?siniec Intrusion. The crystallization history of LPD magma, deduced from experimental and natural mineral compositions, includes a higher pressure stage probably followed by emplacement at ~2 kbar of partly crystallized magma at temperatures ~850?800°C and quick cooling. The mineral assemblage present in LPD requires water contents in the magma of at least 5 wt% and oxygen fugacity below that controlled by the NNO buffer. The compositions of mafic minerals in the MD composition were equilibrated at temperatures below 775°C and at subsolidus conditions. The equilibration was probably due to the reaction between water-rich, oxidizing residual melt and the cumulatic-restitic mineral assemblage. MD is characterized by occurrence of the euhedral cummingtonite and increasing anorthite content in the rims of plagioclase. A similar reaction was reproduced experimentally in both LPD and MD compositions indicating that cummingtonite may be a late magmatic phase in quartz dioritic systems, crystallizing very close to solidus and only from water saturated magma. 相似文献
12.
对近年来我国"大洋一号"科考船在西南印度洋中脊(SWIR)多金属硫化物调查区4个站位所获得的玄武岩进行了岩石学及元素地球化学研究。其岩相学特征为以斑状结构为主,斑晶矿物主要由斜长石、辉石和橄榄石组成。基质以间隐结构为主,主要由斜长石、橄榄石和辉石微晶组成。全岩元素地球化学分析结果表明样品属于亏损型洋中脊玄武岩。矿物化学成分表明斜长石主要为倍长石和拉长石,橄榄石为贵橄榄石。研究区玄武岩具低的Na8、K/Ti比值和LREE/HREE以及较高的Fe8值,可整体归入SWIR 49°E-70°E区指示岩浆熔融程度最高、熔融深度最深的区域内。本次研究为探索SWIR洋脊玄武岩和岩浆熔融等相关研究提供了49.6°E和50.5°E区的新资料,也指示了区内岩浆活动或成矿围岩物质来源的复杂性。 相似文献
13.
Quartz zoning and the pre-eruptive evolution of the ~340-ka Whakamaru magma systems,New Zealand 总被引：1，自引：1，他引：0
Cathodoluminescence (CL) zoning in quartz crystals from rhyolitic pumices in two ignimbrite members of the ~340-ka Whakamaru
super-eruption deposits, Taupo Volcanic Zone, New Zealand, is investigated in conjunction with the analysis of Ti concentration
in quartz to reconstruct the history of changing magma chamber conditions and to elucidate the eruption-triggering processes.
CL intensity images are taken as a proxy for Ti concentration and thus temperature and/or pressure and/or compositional variations
during crystal growth history. Estimates of the maximum temperature changes (i.e., assuming other factors influencing Ti uptake
remain constant) are made using the TitaniQ geothermometer based on the Ti concentration in quartz. These results are reviewed
in comparison with Fe–Ti oxide, feldspar-melt and amphibole geothermometry. Core-to-rim quartz Ti profiles record a marked
change in conditions (temperature increase and/or pressure decrease and/or change in melt composition) causing and then following
a significant resorption horizon in the outer parts of the crystals. Two alternative models that could explain the quartz
Ti zonation invoke a temperature increase caused by mafic recharge and/or a pressure decrease due to magma ponding and re-equilibration
at shallow crustal levels. Concomitant changes in melt composition and Ti activity may, however, also have strongly influenced
Ti uptake into the quartz. Some crystals also show other marked increases in CL brightness internally, but any accompanying
magmatic changes did not result in eruption. Diffusion modelling indicates that this significant change in conditions occurred
over ~10–85 years prior to caldera-forming eruption. This rapid thermal pulse or pressure change is interpreted as evidence
for open-system processes, and appears to record a magma chamber recharge event that rejuvenated the Whakamaru magma system
(melt-dominant magma plus crystal mush), and potentially acted as a trigger for processes that led to eruption. 相似文献
14.
A previously reported porphyry Cu + Mo deposit in an Eocene pluton within the South Shetland Island magmatic arc has been re-interpreted as three distinct hydrothermal assemblages. The oldest assemblage (1) exsolved under confinement from the deep (～6 km?) cooling magma whereas assemblages (2) and (3) formed during tectonic ± magmatic episodes at depths of < 1.5 km in the late Cenozoic. The three assemblages occur over the 5 × 11 km mapped in Barnard Point tonalite pluton. Assemblage (1) comprises shallowly dipping sheets of aplite, biotite + tourmaline pegmatite, massive ‘grey’ quartz, and quartz + tourmaline + bornite + chalcopyrite + molybdenite veins. Magnetite + tourmaline + chalcopyrite breccias have associated biotite, K-feldspar and muscovite alteration. Fluid inclusions indicate formation from hot (～600°C), saline (40 equivalent weight % NaCl + CaCl2) aqueous-carbonic fluids that exsolved from the partly consolidated magma. The primary control on solution chemistry and nature of fracturing was the depth of pluton emplacement. Assemblage (2) consists of steep, vuggy veins and country-rock breccias, with thick propylitic alteration selvages, cemented by microcrystalline quartz, complex inter-growths of FeMg carbonate, bladed barite and trace amounts of bornite and chalcopyrite. These rocks, previously described as breccia (sensu ‘pebble’) dykes in the porphyry complex, are reinterpreted as an influx of moderately hot (175–330°C), weak to moderately saline (2–21 EWP NaCl), aqueous-carbonic fluids that underwent isobaric boiling at 0.8 to 1.3 km depth. Assemblage (3) consists of thin, hematitic fault infillings formed during a second episode of brittle faulting. 相似文献
15.
The Chandmani Uul deposit is located in Dornogovi province, Southeastern Mongolia. Iron oxide ores are hosted in the andesitic rocks of the Shar Zeeg Formation of Neoproterozoic to Lower‐Cambrian age. Middle‐ to Upper‐Cambrian bodies of granitic rocks have intruded into the host rocks in the western and southern regions of the deposit. The wall rocks around the iron oxide ore bodies were hydrothermally altered to form potassic, epidote, and sericite–chlorite alteration zones, and calcite and quartz veinlets are ubiquitous in the late stage. Since granitic rocks also underwent potassic alteration, the activity of the granitic rocks must have a genetic relation to the ore deposit. The ore mineral assemblage is dominated by iron oxides such as mushketovite, euhedral magnetite with concentric and/or oscillatory zoning textures, and cauliflower magnetite. Lesser amounts of chalcopyrite and pyrite accompany the iron oxides. Among all these products, mushketovite is dominant and is distributed throughout the deposit. Meanwhile, euhedral magnetite appears in limited amounts at relatively shallow levels in the deposit. By contrast, cauliflower magnetite appears locally in the deeper parts of the deposit, and is associated with green‐colored garnet and calcite. Sulfide minerals are ubiquitously associated with these iron oxides. The oxygen isotope (δ18O) values of all types of magnetite, quartz, and epidote were found to be ?5.9 to ?2.8‰, 10.5 to 14.9‰, and 3.6 to 6.6‰, respectively. The δ18O values of quartz–magnetite pairs suggest an equilibrium isotopic temperature near 300°C. The calculated values of δ18O for the water responsible for magnetite ranged from 2 to 10‰. All the data obtained in this study suggest that the iron oxide deposit at the Chandmani Uul is a typical iron oxide–copper–gold deposit, and that this deposit was formed at an intermediate depth with potassic and sericite–chlorite alteration zones under the oxidized conditions of a hematite‐stable environment. The δ18O range estimated implies that the ore‐forming fluid was supplied by a crystallizing granodioritic magma exsolving fluids at depth with a significant contribution of meteoric water. 相似文献
16.
Fan‐shaped polycrystalline staurolite porphyroblasts, 3–4 cm in length and 0.5 cm in width, occur together with centimetre‐sized euhedral prismatic staurolite porphyroblasts in pelitic schists of the Littleton Formation on the western overturned limb of the Bolton syncline in eastern Connecticut. The fans consist of intergrown planar splays of [001] elongated prisms, which are crudely radial from a single apex. The apical angles of the radial groupings range up to 70°. The orientations of the individual staurolite prisms are related by a rigid rotation about an axis perpendicular to the fan plane. The zone axes [001] always lie in the plane of the fan. Although the angle between the [100] zone axes of the individual prisms is uniform in each fan, it ranges from +30° to ?30° in different fans. Internally, the fans display: (i) remnants of a passively captured Si foliation defined by disc‐shaped quartz blebs (type 1 inclusions) and layers of very fine carbonaceous material and tabular ilmenite platelets; (ii) bent staurolite blades and undulose extinction along low‐angle (010) subgrain boundaries near the apex of the fans; (iii) wedge‐shaped dilatational zones containing equigranular inclusion‐free quartz, mica and staurolite, and (iv) growth‐related quartz inclusion trails roughly perpendicular to a crystal face (type 2 inclusions). The Si inclusion trails are typically perpendicular to the fan surface, radiate parallel to the blades, and show little to no curvature except at the very edge of the fans where they abruptly curve through nearly 90° into parallelism with an external Se foliation. Careful examination of the three‐dimensional geometry of fans based on U‐stage measurements, serial sections and two‐circle optical goniometric measurements permits a detailed reconstruction of their sequential development. The origin of a fan involves limited intracrystalline deformation and brittle crack dilation, spalling, rotation, and growth of small marginal fragments and of new staurolite along wedge‐shaped zones along the Si inclusion surfaces. Fans preferentially develop in porphyroblasts in which Si is subparallel to the 010 cleavage. These internal features reflect the rotation and deformation of a brittle porphyroblast relative to syn‐growth shear stresses. 相似文献
17.
Dynamics of magma mixing and degassing recorded in plagioclase at Stromboli (Aeolian Archipelago,Italy) 总被引：12，自引：0，他引：12
Crystal-rich materials (scoriae and lava flows) emitted during the 1985–2000 activity of Stromboli were taken into consideration for systematic study of bulk rock/matrix glass chemistry and in particular for the study of chemical and textural zoning of plagioclase, the most abundant mineral phase. Over the considered time period, bulk rock composition remained fairly constant in both major (SiO2 49.2–50.9 wt% and K2O 1.96–2.18 wt%) and trace elements. The quite constant chemistry of matrix glasses also indicates that the degree of crystallization of magma was maintained at around 50 vol%. Plagioclase ranges in composition between An62 and An88 and is characterized by alternating, <10–100 m thick, bytownitic and labradoritic concentric layers, although the dominant and representative plagioclase of scoriae is An68. The labradoritic layers (An62–70) show small-scale (1–5 µm), oscillatory zoning, are free of inclusions, and appear to record episodes of slow crystal growth in equilibrium with a degassed liquid having the composition of the matrix glass. In contrast the bytownitic layers (An70-An88) are patchy zoned, show sieve structure with abundant micrometric glass inclusions and voids, and are attributed to rapid crystal growth.A key to understanding the origin of bytownitic layers can be retrieved from the texture and composition of the coronas of plagioclase xenocrysts, inherited from crystal-rich magma, in nearly aphyric pumice which are erupted during more energetic events and represent a deep, volatile-rich, HK-basaltic magma. They show a continuum from fine-sieve to evident skeletal texture from the inner to the outer part of the corona associated with normal compositional zoning from An90 to An75. In the light of these observations, we propose that input of H2O-rich melt blobs, and their mixing with the residing magma, causes partial dissolution of the labradoritic layers followed by the growth of bytownitic composition whose sieve texture attests of rapid crystallization occurring under undercooling conditions mainly induced by degassing. As a whole, the zoning of plagioclase in the scoriae records successive and discrete intrusions of volatile-rich magma blobs, its degassing and mixing with the resident degassed magma at shallow level.Editorial responsibility: T.L. GroveAn erratum to this article can be found at 相似文献
18.
Duncan D. Muir Jon D. Blundy Michael C. Hutchinson Alison C. Rust 《Contributions to Mineralogy and Petrology》2014,167(3):1-25
Uturuncu is a dormant volcano in the Altiplano of SW Bolivia. A present day ~70 km diameter interferometric synthetic aperture radar (InSAR) anomaly roughly centred on Uturuncu’s edifice is believed to be a result of magma intrusion into an active crustal pluton. Past activity at the volcano, spanning 0.89 to 0.27 Ma, is exclusively effusive and almost all lavas and domes are dacitic with phenocrysts of plagioclase, orthopyroxene, biotite, ilmenite and Ti-magnetite plus or minus quartz, and microlites of plagioclase and orthopyroxene set in rhyolitic groundmass glass. Plagioclase-hosted melt inclusions (MI) are rhyolitic with major element compositions that are similar to groundmass glasses. H2O concentrations plotted versus incompatible elements for individual samples describe a trend typical of near-isobaric, volatile-saturated crystallisation. At 870 °C, the average magma temperature calculated from Fe–Ti oxides, the average H2O of 3.2 ± 0.7 wt% and CO2 typically <160 ppm equate to MI trapping pressures of 50–120 MPa, approximately 2–4.5 km below surface. Such shallow storage precludes the role of dacite magma emplacement into pre-eruptive storage regions as being the cause of the observed InSAR anomaly. Storage pressures, whole-rock (WR) chemistry and phase assemblage are remarkably consistent across the eruptive history of the volcano, although magmatic temperatures calculated from Fe–Ti oxide geothermometry, zircon saturation thermometry using MI and orthopyroxene-melt thermometry range from 760 to 925 °C at NNO ± 1 log. This large temperature range is similar to that of saturation temperatures of observed phases in experimental data on Uturuncu dacites. The variation in calculated temperatures is attributed to piecemeal construction of the active pluton by successive inputs of new magma into a growing volume of plutonic mush. Fluctuating temperatures within the mush can account for sieve-textured cores and complex zoning in plagioclase phenocrysts, resorption of quartz and biotite phenocrysts and apatite microlites. That Fe–Ti oxide temperatures vary by ~50–100 °C in a single thin section indicates that magmas were not homogenised effectively prior to eruption. Phenocryst contents do not correlate with calculated magmatic temperatures, consistent with crystal entrainment from the mush during magma ascent and eruption. Microlites grew during ascent from the magma storage region. Variability in the proportion of microlites is attributed to differing ascent and effusion rates with faster rates in general for lavas >0.5 Ma compared to those <0.5 Ma. High microlite contents of domes indicate that effusion rates were probably slowest in dome-forming eruptions. Linear trends in WR major and trace element chemistries, highly variable, bimodal mineral compositions, and the presence of mafic enclaves in lavas demonstrate that intrusion of more mafic magmas into the evolving, shallow plutonic mush also occurred further amplifying local temperature fluctuations. Crystallisation and resorption of accessory phases, particularly ilmenite and apatite, can be detected in MI and groundmass glass trace element covariation trends, which are oblique to WRs. Marked variability of Ba, Sr and La in MI can be attributed to temperature-controlled, localised crystallisation of plagioclase, orthopyroxene and biotite within the evolving mush. 相似文献
19.
Partial melting of metapelites at ultrahigh-pressure conditions, Greenland Caledonides 总被引：8，自引：0，他引：8
Eclogite, orthogneiss and, by association, metapelite from an island at 78°N in North‐East Greenland experienced ultrahigh‐pressure (UHP) metamorphism at approximately 970 °C and 3.6 GPa, at the end of the Caledonian collision, 360–350 Ma. Hydrous metapelites contain abundant leucocratic layers and lenses composed of medium‐grained, anhedral, equigranular quartz, antiperthitic plagioclase and K‐feldspar with minor small garnet and kyanite crystals. Leucosomes are generally parallel to the matrix foliation, are interlayered with residual quartz bands, anastomose around residual garnet and commonly cross‐cut micaceous segregations. Textures suggest that the leucosomes crystallized from a syntectonic melt, but crystallized at the end of local high‐grade deformation. The metapelite outcrop is < 1.5 km from kyanite eclogites with confirmed coesite, but the metapelites lack coesite and palisade textures diagnostic of coesite pseudomorphs. They do contain highly fractured garnet megacrysts with polycrystalline quartz inclusions (some surrounded by radial fractures) and Ti‐rich phengite inclusions that suggest the former presence of coesite. Polyphase inclusions in garnet contain reactants and products of the inferred dehydration melting reaction: Phe + Qtz = Ky + Kfs + Rt + melt. The reactants are thought to have been early inclusions of hydrous phases within garnet that melted and then crystallized new phases. Garnet surrounding these inclusions has patchy zoning with elevated Ca, consistent with experiments that produced similar patchy microstructures in garnet around inclusions with an unequivocal melt origin. The peak UHP metamorphic assemblage in these rocks is inferred to have been phengite, coesite, garnet, kyanite, rutile, fluid ± omphacite ± epidote. Phase diagrams indicate that dehydration melting of phengite in this assemblage would have occurred after decompression from peak pressure, but still above the coesite to quartz transition. Unusual crown‐ and moat‐like textures in garnet around some polycrystalline quartz inclusions are also consistent with the inference that melting took place at UHP conditions. 相似文献
20.
普朗斑岩铜矿岩浆混合作用：岩石学及元素地球化学证据 总被引：11，自引：1，他引：10
普朗斑岩铜矿花岗闪长斑岩中存在大量的随机分布的镁铁质微粒包体,包体与寄主岩存在渐变接触关系。包体成分为闪长质,具有岩浆结构,存在针状磷灰石,显示了快速冷却结晶的特征。包体内可见具有暗色矿物镶边的眼球状石英,表明存在岩浆混合作用。寄主岩岩体规模较小,呈岩枝状产出,包体和寄主岩均为似斑状结构,说明两种岩浆侵位和发生岩浆混合作用的深度较浅。元素地球化学特征显示包体与寄主岩的之间有成分交换。包体和寄主岩强不相容元素均富集,高场强元素Nb、Ta、Ti均表现出显著的负异常,具有典型的岛弧岩浆岩的微量元素特征,包体和寄主岩Mg＃较高,在同等Si条件下比玄武岩部分熔融体富K2O和MgO,意味着源区必须有幔源岩浆的贡献。普朗斑岩铜矿蚀变矿化模式反映了其成矿环境偏基性,暗示镁铁质岩浆的加入对成矿具有贡献。 相似文献