首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 356 毫秒
1.
Aeolian sand and dust in polar regions are transported offshore over sea ice and released to the ocean during summer melt. This process has long been considered an important contributor to polar sea floor sedimentation and as a source of bioavailable iron that triggers vast phytoplankton blooms. Reported here are aeolian sediment dispersal patterns and accumulation rates varying between 0·2 g m?2 yr?1 and 55 g m?2 yr?1 over 3000 km2 of sea ice in McMurdo Sound, south‐west Ross Sea, adjacent to the largest ice free area in Antarctica. Sediment distribution and the abundance of southern McMurdo Volcanic Group‐derived glass, show that most sediment originates from the McMurdo Ice Shelf and nearby coastal outcrops. Almost no sediment is derived from the extensive ice free areas of the McMurdo Dry Valleys due to winnowed surficial layers shielding sand‐sized and silt‐sized material from wind erosion and because of the imposing topographic barrier of the north‐south aligned piedmont glaciers. Southerly winds of intermediate strength (ca 20 m sec?1) are primarily responsible for transporting sediment northwards and offshore. The results presented here indicate that sand‐sized sediment does not travel more than ca 5 km offshore, but very‐fine sand and silt grains can travel >100 km from source. For sites >10 km from the coast, the mass accumulation rate is relatively uniform (1·14 ± 0·57 g m?2 yr?1), three orders of magnitude above estimated global atmospheric dust values for the region. This uniformity represents a sea floor sedimentation rate of only 0·2 cm kyr?1, well below the rates of >9 cm kyr?1 reported for biogenic‐dominated sedimentation measured over much of the Ross Sea. These results show that, even for this region of high‐windblown sediment flux, aeolian processes are only a minor contributor to sea floor sedimentation, excepting areas proximal to coastal sources.  相似文献   

2.
Research on colluvial depositional systems has recently emphasized periglacial and high‐altitude settings, and the relations between Quaternary slope stratigraphy and climate change. This article examines the role of variable slope morphology, surface hydrology and microclimate in controlling colluvial sedimentation along a coastal tract of the hyperarid Atacama Desert in northern Chile. Direct accessibility of active surfaces is accompanied by uninterrupted stratigraphic exposures along the base of slopes, allowing direct comparisons between surface processes and the resulting sedimentary record. Four slope sectors are identified, based on differences in morphology and processes over active surfaces. Colluvial sedimentation is controlled by complex interactions of slope gradients and profiles, exposure to dominant winds, and potential runoff pathways, which vary considerably between different sectors. Major differences are evident between these hyperarid deposits and slope sedimentation in periglacial and temperate settings, including the complete absence of pedogenic activity and clay minerals; the volume of aeolian deposits and their role in controlling processes which redistribute sediment downslope, extending colluvial aprons; and the occurrence of runoff processes only where favoured by particular topographic configurations. Depositional surfaces range from steep talus cones, to debris‐flow‐dominated and aeolian‐dominated colluvial aprons, to an aeolian ramp subject to reworking by mass flows and flash floods. Consequently, facies associations and architectures at outcrop are highly variable and highlight the importance of spatial variations in slope morphology and processes in producing distinct, coeval colluvial stratigraphies within a single environmental context. Discrepancies between active processes and the corresponding stratigraphic signatures are also evident in some sectors; for example, preservation of alluvial and aeolian facies in stratigraphic sections does not always reflect the dominant processes over active slopes. Together with the spatial variability in processes and deposits along these slopes, this suggests that caution is required when extracting palaeoenvironmental information from analyses of colluvial successions.  相似文献   

3.
The deposition of natural dust in an area of 53 ha, situated in the northern Negev desert, is investigated in detail both in the wind tunnel (dust storm simulations over a topographic scale model) and in the field. The wind tunnel results and the field results show a high degree of agreement, indicating that scale-model simulation may be considered an important technique for future loess and desert research. More dust settles on windward slopes than on leeward slopes, which is in contradistinction with the widespread wind shadow concept. Air-flow separation zones immediately downwind of steep windward slopes have an important impact on dust deposition too. In the case of dust deposition on topographic scale models, a restricted height distortion of the model will not necessarily lead to serious problems. In addition, wind tunnel blockage percentages up to 13% may be allowed in order to obtain acceptable dust deposition patterns for the scale model. A mean gross dust deposition of about 200–250 g m?2 year?1 is calculated for the northern Negev desert for 1987. Thus, if the settled dust can be protected against erosion in the cultivated areas in the Negev, the dust content of the top soil will markedly increase with time. However, it has to be borne in mind that cultivation activities themselves may also contribute to a higher soil erosion and, hence, to a higher dust content in the atmosphere. At any rate, a higher dust content in the top soil will unquestionably have an important positive effect on agricultural yields. From the air dust concentration data and the dust deposition data, a deposition velocity of 4.7cms?1 can be calculated for Avdat dust.  相似文献   

4.
A significant portion of calcium carbonate is deposited in lake sediments as a result of biological processes related to the photosynthetic activity of phytoplankton in the pelagic realm and, in addition, macrophytes in the littoral zone. Lake Wigry, one of the largest lakes in Poland (north‐east Poland), is characterized by: (i) carbonate sediments with a CaCO3 content exceeding 80% within the littoral zone; and (ii) large areas of submerged vegetation dominated by charophytes (macroscopic green algae, Characeae family). It is claimed that charophytes are highly effective in utilizing HCO3? and forming thick CaCO3 encrustations. Thus, this study was aimed at evaluating the CaCO3 production by dense Chara stands overgrowing the lake bottom reaching a depth of 4 m. In late July 2009, the fresh and dry mass of plants, the percentage contribution of calcium carbonate and the production of CaCO3 per 1 m2 were investigated along three transects at three depths (1 m, 2 m and 3 m, with each sample area equal to 0·0625 m2) per transect. The composition and structure of phytoplankton and the physico‐chemical properties of the water analysed in both the littoral and pelagic zones served as the environmental background and demonstrated moderately low fertility in the lake. The greatest dry plant mass exceeded 1000 g m?2 and CaCO3 encrustations constituted from 59% to over 76% of the charophyte dry weight. Thus, the maximum and average values of carbonates precipitated by charophytes were 685·5 and 438 g m?2, respectively, which exceeded previously reported results. A correlation of carbonate production with the depth of Chara stands was detected, and intermediate depths offered the most favourable conditions for carbonate precipitation (589 g m?2 on average). As precipitated carbonates are ultimately stored in bottom deposits, the results highlight the significance of charophytes in lacustrine CaCO3 sedimentation.  相似文献   

5.
A natural smoky quartz crystal from Shandong province, China, was characterised by laser ablation ICP‐MS, electron probe microanalysis (EPMA) and solution ICP‐MS to determine the concentration of twenty‐four trace and ultra trace elements. Our main focus was on Ti quantification because of the increased use of this element for titanium‐in‐quartz (TitaniQ) thermobarometry. Pieces of a uniform growth zone of 9 mm thickness within the quartz crystal were analysed in four different LA‐ICP‐MS laboratories, three EPMA laboratories and one solution‐ICP‐MS laboratory. The results reveal reproducible concentrations of Ti (57 ± 4 μg g?1), Al (154 ± 15 μg g?1), Li (30 ± 2 μg g?1), Fe (2.2 ± 0.3 μg g?1), Mn (0.34 ± 0.04 μg g?1), Ge (1.7 ± 0.2 μg g?1) and Ga (0.020 ± 0.002 μg g?1) and detectable, but less reproducible, concentrations of Be, B, Na, Cu, Zr, Sn and Pb. Concentrations of K, Ca, Sr, Mo, Ag, Sb, Ba and Au were below the limits of detection of all three techniques. The uncertainties on the average concentration determinations by multiple techniques and laboratories for Ti, Al, Li, Fe, Mn, Ga and Ge are low; hence, this quartz can serve as a reference material or a secondary reference material for microanalytical applications involving the quantification of trace elements in quartz.  相似文献   

6.
Sediment data from the Bahamian Santaren carbonate drift reveal the variability of trans‐Atlantic Saharan dust transport back to about 100 ka bp (Marine Isotope Stage 5·3) and demonstrate that carbonate drifts are a valuable pelagic archive of aeolian dust flux. Carbonate drift bodies are common around tropical carbonate platforms; they represent large‐scale accumulations of ocean‐current transported material, which originates from the adjacent shallow‐water carbonate factory as well as from pelagic production, i.e. periplatform ooze. Subordinately, there is a clay‐size to silt‐size non‐carbonate fraction, which typically amounts to less than 10% of the sediment volume and originates from aeolian and fluvial input. Sedimentation rates in the 5·42 m long core GeoHH‐M95‐524 recovered 25 km west of Great Bahama Bank in the Santaren Channel ranges from 1·5 to 24·5 cm ka?1 with lowest values during the last glacial lowstand and highest values following platform re‐flooding around 8 ka bp . These sedimentation rates imply that carbonate drifts have not only the potential to resolve long‐term environmental changes on orbital timescales, but also millennial to centennial fluctuations during interglacials. The sediment core has been investigated with the aim of characterizing the lithogenic dust fraction. Laboratory analyses included X‐ray fluorescence core scanning, determination of carbonate content and grain‐size analyses (of bulk and terrigenous fraction), as well as visual inspections of the lithogenic residue; the age model is based on oxygen isotopes and radiocarbon ages. Data show that the input of aeolian dust in the periplatform ooze as indicated by Ti/Al and Fe/Al element ratios abruptly increases at 57 ka bp , stays elevated during glacial times, and reaches a Holocene minimum around 6·5 ka bp , contemporary to the African Humid Period. Subsequently, there is a gradual increase in dust flux which almost reaches glacial levels during the last centuries. Grain‐size data show that the majority of dust particles fall into the fine silt range (below 10 μm); however, there is a pronounced coarse dust fraction in the size range up to 63 μm and individual ‘giant’ dust particles are up to 515 μm in size. Total dust flux and the relative amounts of fine and coarse dust are decoupled. The time‐variable composition of the grain‐size spectrum is interpreted to reflect different dust transport mechanisms: fine dust particles are delivered by the trade winds and the geostrophic winds of the Saharan Air Layer, whereas coarse dust particles travel with convective storm systems. This mode of transport ensures continuous re‐suspension of large particles and results in a prolonged transport. In this context, grain‐size data from the terrigenous fraction of carbonate drifts provide a measure for past coarse dust transport, and consequently for the frequency of convective storm systems over the dust source areas and the tropical Atlantic.  相似文献   

7.
Heavy aeolian deposition is one of the most threatening natural hazards to oases in arid areas. How an oasis affects aeolian deposition is tightly related to the local ecological environments. To examine the effects of oasis on aeolian deposition under different weather conditions, monthly aeolian deposition from April 2008 to March 2009 and additional samples during dust storms in April and May 2008 were collected at four sites along the Qira oasis. The monthly ADRs (aeolian deposition rates) varied greatly with seasons and sites, ranging from 19.4 to 421.2 g/m2/month and averaging 198.8 g/m2/month. Aeolian deposition in the oasis was composed dominantly of sand and silt. Based on the variations of ADRs from the four sites, it can be found that the oasis exhibits two different effects on aeolian deposition under different weather conditions. During dust storms, the oasis demonstrates a significantly shielding effect due to the obstruction of the oasis-protection systems, resulting in most aeolian particles being deposited at the windward side of the oasis. While during non-dust storm periods with weak winds, the oasis exhibits an “attracting” effect on aeolian deposition, leading to a higher ADR inside the oasis. Owing to the annual ADR is dominated by the non-dust storm ADR in Qira, the oasis seems to become an important aeolian deposition area caused by the “attracting” effect of the oasis.  相似文献   

8.
The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al2O3 content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses.  相似文献   

9.
Creep and saltation are the primary modes of surface transport involved in the fluid‐like movement of aeolian sands. Although numerous studies have focused on saltation, few studies have focused on creep, primarily because of the experimental difficulty and the limited amount of theoretical information available on this process. Grain size and its distribution characteristics are key controls on the modes of sand movement and their transport masses. Based on a series of wind tunnel experiments, this paper presents new data regarding the saltation flux, obtained using a flat sampler, and on the creeping mass, obtained using a specifically designed bed trap, associated with four friction velocities (0·41, 0·47, 0·55 and 0·61 m sec?1). These data yielded information regarding creeping and saltating sand grains and their particle size characteristics at various heights, which led to the following conclusions: (i) the creeping masses increased as a power function (q = ?1·02 + 14·19u*3) of friction wind velocities, with a correlation (R2) of 0·95; (ii) the flux of aeolian sand flow decreases exponentially with increasing height (q = a exp(–z/b)) and increases as a power function (q = ?26·30 + 428·40 u*3) of the friction wind velocity; (iii) the particle size of creeping sand grains is ca 1·15 times of the mean diameter of salting sand grains at a height of 0 to 2 cm, which is 1·14 times of the mean diameter of sand grains in a bed; and (iv) the mean diameter of saltating sand grains decreases rapidly with increasing height whereas, while at a given height, the mean diameter of saltating sand grains is positively correlated with the friction wind velocity. Although these results require additional experimental validation, they provide new information for modelling of aeolian sand transport processes.  相似文献   

10.
Abstract: The distribution, optically stimulated luminescence dating and granulometric properties suggest that the loess on the northern flank of Tian Shan should be divided into two types. One which is like mantle and is named type A, is located on the windward slopes and dated to about 54.5±5.73?Ka. The other, called type B, lies flatly on the terraces of the rivers or low hills and penetrated 30.8±2.05?Ka ago. Here we study the origin and the age of two types of loess, and a model of loess formation is proposed. The dust was entrained from the Gobi Desert located to the north of Tian Shan by the monsoon from Mongolia, obstructed by the high mountains and deposited on the windward slopes of the mountains. The rivers and flows then transported the aeolian loess to low terraces and piedmont alluvial plains.  相似文献   

11.
Sedimentary and meteorological characteristics of easterly dust storms causing severe damage in the Negev in November 1958 are analysed. Though the heavy storm originated in weather conditions outside of the affected area, the intense dustiness was of a more local nature. The sedimentological character of the dust indicates that the largest portion was of local origin, picked up by the turbulent current in the loess area of the northern Negev on its passage westward. Total quantity of sediment transported in the Beersheba Basin is estimated to be 10–20 million tons. The analysis of climatic data and of sedimentary characteristics of several other dust samples indicates that though severe dust storms can produce dramatic effects in transporting and deposition of aeolian dust, the rare occurrence of easterly dust storms does not make it likely that they were responsible for the import of aeolian sediments found in the northern Negev.  相似文献   

12.
We derive a slip rate for a frontal thrust in the western Hexi Corridor along the northern Qilian Shan by combining topographic profiling and 10Be exposure dating. The active Yumen‐Beidahe thrust fault offsets late Pleistocene alluvial‐fan deposits, and a prominent north‐facing scarp is well preserved. To quantify the slip rate, we surveyed the uplifted terraces and sampled quartz‐rich pebbles on terrace surfaces and river channels to determine surface exposure ages and pre‐depositional inheritance. The minimum vertical slip rate of the fault is 0.73 ± 0.09 mm a?1. This represents a horizontal shortening rate of 1.26 ± 0.31 mm a?1 for a fault dip of 30 ± 5°. This estimated slip rate supports the inference made from previous geological and GPS constraints that NNE‐directed shortening across the western Qilian Shan and the Hexi Corridor is distributed on several active faults with a total shortening rate of 4–10 mm a?1.  相似文献   

13.
Mass fractions of Sn and In were determined in sixteen geological reference materials including basaltic/mafic (BCR‐2, BE‐N, BHVO‐1, BHVO‐2, BIR‐1, OKUM, W‐2, WS‐E), ultramafic (DTS‐2b, MUH‐1, PCC‐1, UB‐N) and felsic/sedimentary reference materials (AGV‐2, JA‐1, SdAR‐M2, SdAR‐H1). Extensive digestion and ion exchange separation tests were carried out in order to provide high yields (> 90% for Sn, > 85% for In), low total procedural blanks (~ 1 ng for Sn, < 3 pg for In) and low analytical uncertainties for the elements of interest in a variety of silicate sample matrices. Replicate analyses (n = 2–13) of Sn–In mass fractions gave combined measurement uncertainties (2u) that were generally < 3% and in agreement with literature data, where available. We present the first high‐precision In data for reference materials OKUM (32.1 ± 1.5 ng g?1), DTS‐2b (2.03 ± 0.25 ng g?1), MUH‐1 (6.44 ± 0.30 ng g?1) and PCC‐1 (3.55 ± 0.35 ng g?1) as well as the first Sn data for MUH‐1 (0.057 ± 0.010 μg g?1) and DTS‐2b (0.623 ± 0.018 μg g?1).  相似文献   

14.
Halogen contents for the widely distributed reference glasses BHVO‐2G, BIR‐1G, BCR‐2G, GSD‐1G, GSE‐1G, NIST SRM 610 and NIST SRM 612 were investigated by pyrohydrolysis combined with ion chromatography, total reflection X‐ray fluorescence analysis, instrumental neutron activation analysis, the noble gas method, electron probe microanalysis and laser ablation‐inductively coupled plasma‐mass spectrometry. Glasses BHVO‐2G, GSD‐1G and GSE‐1G have halogen contents that can be reproduced at the 15% level by all bulk techniques and cover a significant range in halogen mass fractions for F (~ 20–300 μg g?1), Cl (~ 70–1220 μg g?1) and Br (~ 0.2–285 μg g?1) and I (~ 9–3560 ng g?1). The BIR‐1G glass has low F (< 15 μg g?1), Cl (~ 20 μg g?1), Br (15 ng g?1) and I (3 ng g?1). The halogen contents for the silica‐rich NIST SRM 610 and 612 glasses were poorly reproduced by the different techniques. The relatively high Cl, Br and I abundances in glasses GSD‐1G and GSE‐1G mean that these glasses are well suited for calibrating spatially resolved micro‐analytical studies on silicate glasses, melt and fluid inclusions. Combined EPMA and laser ablation‐inductively coupled plasma‐mass spectrometry data for glass GSE‐1G demonstrate homogeneity at the 10% level for Cl and Br.  相似文献   

15.
Optically stimulated luminescence (OSL) dating is widely applied to sediments in paleoenvironmental sciences. However, there are only limited examples determining the age of archaeological stone structures by OSL using dust deposits. The age of dust deposits associated with ancient buildings may be used to date the onset of settlement (sediment below structures), settlement activity (occupation layer), or the time after a settlement had been abandoned or destroyed (sediment between collapsed roofs and walls). In this study, OSL dating is applied to establish numerical dates for settlement structures situated in the Negev Highlands, Israel. Two archaeological sites are investigated to identify their occupation history, by dating nine samples of aeolian dust trapped within the remains of ancient buildings. The OSL dating technique is applied using coarse grain quartz and a standard single‐aliquot regenerative‐dose (SAR) protocol. It was possible to date the onset of sedimentation in a later phase of the human occupation or shortly after the sites were abandoned, to 3.7 ± 0.3 ka (Intermediate Bronze Age) at the central site and to 2.7 ± 0.2 ka (Iron Age) at the ephemeral site. These results are supported by archaeological evidence gained from pottery finds and the architecture of the ancient buildings.  相似文献   

16.
The time at which deserts established their current arid or hyper-arid conditions remains a fundamental question regarding the history of Earth. Cosmogenic isotope exposure ages of desert pavement and welded, calcic–gypsic–salic Reg soils that developed on relatively flat alluvial surfaces ～2 Ma ago in the Negev Desert indicate long geomorphic stability under extremely dry conditions. Over a short interval during their initial stage of development between 1–2 Ma, these cumulative soils are characterized by calcic soils reaching maximum stage III of carbonate morphology. This interval is the only period when calcic soil horizons formed on stable abandoned alluvial surfaces in the southern Negev Desert. Since ～1 Ma pedogenesis changed toward more arid soil environment and the formation of gypsic–salic soil horizons that were later followed by dust accumulation. The dichotomy of only moderately-developed calcic soil (stages II–III) during a relatively long time interval (105–106 years) indicates an arid environment that does not support continuous development but only occasional calcic soil formation. The very low δ18O and relatively high δ13C values of these early pedogenic carbonates support soil formation under arid climatic conditions. Such an environment was probably characterized by rare and relatively longer duration rainstorms which occasionally allowed deeper infiltration of rainwater and longer retention of soil moisture. This, in turn enabled the growth of sparse vegetation that enhanced deposition of pedogenic carbonate. At ～1 Ma these rare events of slightly wetter conditions ceased and less atmospheric moisture reached the southern Negev Desert leading to deposition of soluble salts and dust deposited in the soils. The combination of long-term hyperaridity, scarcity of vegetation and lack of bioturbation, salts cementation, dust accumulation and tight desert pavement cover, has protected the surfaces from erosion forming one of the most remarkably stable landscapes on Earth, a landscape that essentially has not eroded, but accumulated salt and dust for more than 106 yr.  相似文献   

17.
A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.  相似文献   

18.
Experimental determination of the pressure and temperature controls on Ti solubility in quartz provides a calibration of the Ti‐in‐quartz (TitaniQ) geothermometer applicable to geological conditions up to ~ 20 kbar. We present a new method for determining 48Ti mass fractions in quartz by LA‐ICP‐MS at the 1 μg g?1 level, relevant to quartz in HP‐LT terranes. We suggest that natural quartz such as the low‐CL rims of the Bishop Tuff quartz (determined by EPMA; 41 ± 2 μg g?1 Ti, 2s) is more suitable than NIST reference glasses as a reference material for low Ti mass fractions because matrix effects are limited, Ca isobaric interferences are avoided, and polyatomic interferences at mass 48 are insignificant, thus allowing for the use of 48Ti as a normalising mass. Average titanium mass fraction from thirty‐three analyses of low temperature quartz from the Czech Erzgebirge is 0.9 ± 0.2 μg g?1 (2s) using 48Ti as a normalising mass and Bishop Tuff quartz rims as a reference material. The 2s average analytical uncertainty for individual analyses of 48Ti is 8% for 50 μm spots and 7% for 100 μm spots, which offers much greater accuracy than the 21–41% uncertainty (2s) incurred from using 49Ti as an analyte.  相似文献   

19.
This study describes two methods (Procedures‐1 and ‐2) for the direct extraction of Au by an inorganic acid mixture (HClO4‐HBr‐HI‐aqua regia) from complex sample matrices. Standard PTFE jars at 200 °C were used to decompose test portions of 0.5–1 g, with subsequent precise and accurate analysis by ICP‐MS without any other preconcentration or separation. Procedure‐1 decomposed samples effectively without the necessity of leaching with HF and was developed for dust samples from e‐waste (electronic waste) processing; however, testing on geological reference materials showed very good results. The analyses of replicate decompositions (n = 5) from both procedures yielded very good precision (< 5% RSD) for most of the reference materials. The accuracy achieved was better than ± 10%, with the exception of NIST SRM 2782 data from Procedure‐1. Two unknown samples of dust from e‐waste processing (P‐1 and VM‐1) exhibited elevated concentrations of Au (21.31–61.64 μg g?1) with precision better than 10% (n = 5). The proposed techniques are simple, sensitive and sparing in the use of chemicals, and are designed for a variety of e‐waste dust samples. No significant influences were observed for the predicted spectral interferences on mass 197Au.  相似文献   

20.
Thick bay‐fill sequences that often culminate in strandplain development serve as important sedimentary archives of land–ocean interaction, although distinguishing between internal and external forcings is an ongoing challenge. This study employs sediment cores, ground‐penetrating radar surveys, radiocarbon dates, palaeogeographic reconstructions and hydrodynamic modelling to explore the role of autogenic processes – notably a reduction in wave energy in response to coastal embayment infilling – in coastal evolution and shoreline morphodynamics. Following a regional 2 to 4 m highstand at ca 5·8 ka, the 75 km2 Tijucas Strandplain in southern Brazil built from fluvial sediments deposited into a semi‐enclosed bay. Holocene regressive deposits are underlain by fluvial sands and a Pleistocene transgressive–regressive sequence, and backed by a highstand barrier‐island. The strandplain is immediately underlain by 5 to 16 m of seaward‐thickening, fluvially derived, Holocene‐age, basin‐fill mud. Several trends are observed from the landward (oldest) to the seaward (youngest) sections of the strandplain: (i) the upper shoreface and foreshore become finer and thinner and shift from sand‐dominated to mud‐dominated; (ii) beachface slopes decrease from >11° to ca 7°; and (iii) progradation rates increase from 0·4 to 1·8 m yr?1. Hydrodynamic modelling demonstrates a correlation between progressive shoaling of Tijucas Bay driven by sea‐level fall and sediment infilling and a decrease in onshore wave‐energy transport from 18 to 4 kW m?1. The combination of allogenic (sediment supply, falling relative sea‐level and geology) and autogenic (decrease in wave energy due to bay shoaling) processes drove the development of a regressive system with characteristics that are rare, if not unique, in the Holocene and rock records. These findings demonstrate the complexities in architecture styles of highstand and regressive systems tracts. Furthermore, this article highlights the diverse internal and external processes and feedbacks responsible for the development of these intricate marginal marine sedimentary systems.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号