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1.
The Sheepbed mudstone forms the base of the strata examined by the Curiosity rover in Gale Crater on Mars, and is the first bona fide mudstone known on another planet. From images and associated data, this contribution proposes a holistic interpretation of depositional regime, diagenesis and burial history. A lake basin probably received sediment pulses from alluvial fans. Bed cross‐sections show millimetre to centimetre‐scale layering due to distal pulses of fluvial sediment injections (fine‐grained hyperpycnites), fall‐out from river plumes, and some aeolian supply. Diagenetic features include mineralized synaeresis cracks and millimetre‐scale nodules, as well as stratiform cementation. Clay minerals were initially considered due to in situ alteration, but bulk rock chemistry and mineralogy suggests that sediments were derived from variably weathered source rocks that probably contained pre‐existing clay minerals. X‐ray diffraction analyses show contrasting clay mineralogy in closely spaced samples, consistent with at least partial detrital supply of clay minerals. A significant (ca 30 wt%) amorphous component is consistent with little post‐depositional alteration. Theoretical modelling of diagenetic reactions, as well as kinetic considerations, suggest that the bulk of diagenetic clay mineral formation occurred comparatively late in diagenesis. Diagenetic features (synaeresis cracks and nodules) were previously thought to reflect early diagenetic gas formation, but an alternative scenario of synaeresis crack formation via fabric collapse of flocculated clays appears more likely. The observed diagenetic features, such as solid nodules, hollow nodules, matrix cement and ‘raised ridges’ (synaeresis cracks) can be explained with progressive alteration of olivine/glass in conjunction with centrifugal and counter diffusion of reactive species. Anhydrite‐filled fractures in the Sheepbed mudstone occurred late in diagenesis when fluid pressures built up to exceed lithostatic pressure. Generating fluid overpressure by burial to facilitate hydraulic fracturing suggests a burial depth of at least 1000 m for the underlying strata that supplied these fluids.  相似文献   

2.
Shrinkage-crack morphotypes in the Libby Formation (upper Belt Supergroup) are confined to distinct environmental facies. The lower facies is characterized by flat rip-up clasts, stromatolites, oolites, small-scale symmetrical ripples, and fenestral fabric. These rocks were deposited above fair-weather wave base on a periodically exposed mudflat. Shrinkage cracks in this facies are predominantly branching, incompletely connected features in plan view, except for local examples of completely connected polygonal cracks on purple argillite bed tops and rare, long spindle-shaped cracks on bed tops of dark grey argillite. The upper facies was deposited below fair-weather wave base and contains mainly unconnected, short spindle-shaped shrinkage cracks, and rare slightly branching cracks. Restriction of some crack types to certain facies better constrains interpretation of the origin of these shrinkage cracks. The cracks in the upper facies were strongly influenced by sediment loading, and may have formed by compaction-induced expulsion of water from pore space, resulting in synaeresis cracks. In the underlying shallower facies, polygonal cracks formed by desiccation. Elsewhere in this facies, incomplete, partially connected cracks and long spindle-shaped cracks on the same bedding plane are interpreted as having formed by desiccation. Shrinkage cracks are an under-used source of environmental information, but confusion as to their origin sometimes restricts their potential. More intensive analysis of properties of host sediment and crack fills may further our understanding of depositional and diagenetic influence on crack morphology. Crack cross-sections, which are often more commonly exposed than bedding plane cracks, may provide critical additional information on crack genesis. Better understanding of crack genesis will strengthen our ability to interpret unfossiliferous muddy sequences common in Precambrian and lacustrine settings.  相似文献   

3.
4.
Septarian concretions in the Staffin Shales Formation (Kimmeridgian, Isle of Skye) allow controls on concretion rheology and septarian cracking to be investigated. Stratabound concretions consist of anhedral ferroan calcite microspar enclosing clay and minor pyrite. Intergranular volumes range from 77% to 88%, and calcite δ13C and δ18O values in most concretion bodies range from ?10·0‰ to ?17·3‰ and +0·3‰ to ?0·6‰ respectively, consistent with rapid and pervasive cementation in marine pore fluids. Septarian rupture occurred during incipient cementation, with a sediment volume reduction of up to 43%. Crack‐lining brown fibrous calcite records pore fluid re‐oxygenation during a depositional hiatus, followed by increasing Fe content and δ13C related to bacterial methanogenesis. Brown colouration results from an included gel‐like polar organic fraction that probably represents bacterially degraded biomass. A new hypothesis for concretion growth and septarian cracking argues that quasi‐rigid ‘proto‐concretions’ formed via binding of flocculated clays by bacterial extracellular polysaccharide substances (EPS). This provided rheological and chemical conditions for tensional failure, subcritical crack growth, volume contraction, calcite nucleation, and incorporation of degraded products into crack‐lining cements. Bacterial decay of EPS and syneresis of host muds provided internal stresses to initiate rupture at shallow burial. Development of septarian (shrinkage) cracks in muds is envisaged to require pervasive in situ bacterial colonization, and to depend on rates of carbonate precipitation versus EPS degradation and syneresis. Subsequent modification of septarian concretions included envelopment by siderite and calcite microspar, hydraulic fracturing associated with Cretaceous shallow burial or Palaeogene uplift; and cementation by strongly ferroan, yellow sparry calcite that records meteoric water invasion of the host mudrocks. An abundance of fatty acids in these spars indicates aqueous transport of organic breakdown products, and δ13C data suggest a predominantly methanogenic bicarbonate source. However, the wide δ18O range for petrographically identical cement (?1·3‰ to ?15·6‰) is difficult to explain.  相似文献   

5.
辽宁兴城中元古界常州沟组砂岩中微生物成因沉积构造   总被引:2,自引:1,他引:1  
辽宁兴城夹山中元古界常州沟组潮间带相砂岩层面产出裂隙状构造。这些构造由0.8~3 cm长的纺锤状短裂隙和超过7 cm的长延伸裂隙组成,孤立为主,部分相连。通过与类似的层面裂隙和现代微生物席干缩裂隙的比较分析,将其解释为微生物成因沉积构造分类体系中的收缩裂隙(Shrinkage crack),并参考席裂多边形(Mat-crack polygon)的术语称其为席裂(Mat-crack)。微生物席在脱水不充分的情况下形成纺锤状席裂,脱水充分的情况下形成席裂多边形。这些构造在常州沟组的出现,表明微生物生态系统在华北克拉通中元古代海侵初期已经开始影响古海岸带的地质作用,这对于恢复燕山裂陷槽盆地的生物—沉积作用和环境演化具有重要意义。  相似文献   

6.
Ancient evaporite deposits are geological archives of depositional environments characterized by a long‐term negative precipitation balance and bear evidence for global ocean element mass balance calculations. Here, Cretaceous selenite pseudomorphs from western Anatolia (‘Rosetta Marble’) — characterized by their exceptional morphological preservation — and their ‘marine’ geochemical signatures are described and interpreted in a process‐oriented context. These rocks recorded Late Cretaceous high‐pressure/low‐temperature, subduction‐related metamorphism with peak conditions of 1·0 to 1·2 GPa and 300 to 400°C. Metre‐scale, rock‐forming radiating rods, now present as fibrous calcite marble, clearly point to selenitic gypsum as the precursor mineral. Stratigraphic successions are recorded along a reconstructed proximal to distal transect. The cyclical alternation of selenite beds and radiolarian ribbon‐bedded cherts in the distal portions are interpreted as a two type of seawater system. During arid intervals, shallow marine brines cascaded downward into basinal settings and induced precipitation. During more humid times, upwelling‐induced radiolarian blooms caused the deposition of radiolarite facies. Interestingly, there is no comparable depositional setting known from the Cenozoic world. Meta‐selenite geochemical data (δ13C, δ18O and 87Sr/86Sr) plot within the range of reconstructed middle Cretaceous seawater signatures. Possible sources for the 13C‐enriched (mean 2·2‰) values include methanogenesis, gas hydrates and cold seep fluid exhalation. Spatially resolved component‐specific analysis of a rock slab displays isotopic variances between meta‐selenite crystals (mean δ13C 2·2‰) and host matrix (mean δ13C 1·3‰). The Cretaceous evaporite‐pseudomorphs of Anatolia represent a basin wide event coeval with the Aptian evaporites of the Proto‐Atlantic and the pseudomorphs share many attributes, including lateral distribution of 600 km and stratigraphic thickness of 1·5 to 2·0 km, with the evaporites formed during the younger Messinian salinity crisis. The Rosetta Marble of Anatolia may represent the best‐preserved selenite pseudomorphs worldwide and have a clear potential to act as a template for the study of meta‐selenite in deep time.  相似文献   

7.
The Tandilia Belt in northeast Argentina includes a Neoproterozoic sequence of sediments (Sierras Bayas Group), in which the Cerro Largo Formation, ca. 750 Ma in age, forms a siliciclastic, shallowing upward succession of subtidal nearshore to tidal flat deposits. Trace fossils Palaeophycus isp. and Didymaulichnus isp. have been described from the upper part of this succession. Specific sedimentary structures consisting of round-crested bulges, arranged in a reticulate pattern, and networks of curved cracks are associated with the trace fossils. These structures are considered to be related to epibenthic microbial mats that once colonized the sediment surface. They reflect stages of mat growth and mat destruction, if compared to analogous structures in modern cyanobacterial mats of peritidal, siliciclastic depositional systems. Also the trace fossils are interpreted as mat-related structures, partly forming components of networks of shrinkage cracks, partly representing the upturned and involute margins of shrinkage cracks or circular openings in desiccating and shrinking, thin microbial mats.

The definition of Didymaulichnus miettensis Young as a Terminal Proterozoic trace fossil is questioned, and it may be considered to interpret the ‘bilobate’ structure as the upturned, opposite margins of microbial shrinkage cracks which have been brought back into contact by compaction after burial.  相似文献   


8.
Calcite septarian concretions from the Permian Beaufort Group in the Maniamba Graben (NW Mozambique) allow controls on the composition and nature of diagenetic fluids to be investigated. The concretions formed in lacustrine siltstones, where they occur in spherical (1 to 70 cm in diameter) and columnar (up to 50 cm long) forms within three closely spaced, discrete beds totalling 2·5 m in thickness. Cementation began at an early stage of diagenesis and entrapped non‐compacted burrows and calcified plant roots. The cylindrical concretions overgrew calcified vertical plant roots, which experienced shrinkage cracking after entrapment. Two generations of concretionary body cement and two generations of septarian crack infill are distinguished. The early generation in both cases is a low‐Mn, Mg‐rich calcite, whereas the later generation is a low‐Mg, Mn‐rich calcite. The change in chemistry is broadly consistent with a time (burial)‐related transition from oxic to sub‐oxic/anoxic conditions close to the sediment–water interface. Geochemical features of all types of cement were controlled by the sulphate‐poor environment and by the absence of bacterial sulphate reduction. All types of cement present have δ13C ranging between 0‰ and −15‰(Vienna Peedee Belemnite, V‐PDB), and highly variable and highly depleted δ18O (down to 14‰ Vienna Standard Mean Ocean Water, V‐SMOW). The late generation of cement is most depleted in both 13C and 18O. The geochemical and isotopic patterns are best explained by interaction between surface oxic waters, pore waters and underground, 18O‐depleted, reducing, ice‐meltwaters accumulated in the underlying coal‐bearing sediments during the Permian deglaciation. The invariant δ13C distribution across core‐to‐rim transects for each individual concretion is consistent with rapid lithification and involvement of a limited range of carbon sources derived via oxidation of buried plant material and from dissolved clastic carbonates. Syneresis of the cement during an advanced stage of lithification at early diagenesis is considered to be the cause of development of the septarian cracks. After cracking, the concretions retained a small volume of porosity, allowing infiltration of anoxic, Ba‐bearing fluids, resulting in the formation of barite. The results obtained contribute to a better understanding of diagenetic processes at the shallow burial depths occurring in rift‐bound, lacustrine depositional systems.  相似文献   

9.
Results of a detailed petrographic and stable isotope study illustrate that sedimentological differences and eogenetic dissolution/precipitation processes controlled porosity distribution within carbonate turbidites of the Ionian basin (central Albania). Based on lithology characteristics and porosity distribution observed in outcrop, individual turbidite beds can be subdivided into four distinct intervals, i.e. from base to top: (A) a non‐porous wackestone/floatstone or packstone followed by (B) porous packstone–grainstone that grades into (C) wackestone and (D) non‐porous mudstone with pelagic foraminifera. Wackestone interval C is characterized by an alternation of porous and non‐porous laminae. Changes in turbidity current flow regime controlled the initial presence of matrix micrite giving rise to both matrix‐ and grain‐supported lithologies within turbidite sequences. These are non‐porous and porous, respectively. Four eogenetic diagenetic processes (dissolution, cementation, neomorphism and compaction) acted shortly after deposition and modified primary porosity characteristics and distribution. Alteration by meteoric water is excluded based on the continuous burial until the Oligocene of the studied deep marine carbonates. Moreover, the stable isotope data with values between −2·1‰ and +0·7‰ for δ18OV‐PDB and between +1‰ and +3‰ for δ13CV‐PDB, favour alteration by marine‐derived pore‐waters. Compaction and aggrading neomorphism occurred dominantly in intervals characterized by higher matrix micrite content, i.e. the floatstone base and the wackestone–mudstone upper turbidite part. Framework‐stabilizing cementation occurred dominantly in the packstone–grainstone middle part of the turbidite beds. In the latter porous lithologies, matrix micrite was not compacted because of the grain fabric and the framework‐stabilizing cements. Here, neomorphism of micrite into microrhombic euhedral calcite occurred and microporosity was preserved.  相似文献   

10.
A variety of unusual early post‐depositional deformation structures exist in grainstone and flat‐pebble conglomerate beds of Upper Cambrian strata, western Colorado, including slide scarps, thrusted beds, irregular blocks and internally deformed beds. Thrusted beds up to tens of centimetres thick record thrust movement of a part of a bed onto itself along a moderate to steeply inclined (15° to 40°) ramp, locally producing hanging wall lenses with fault‐bend geometries. Thrust plane orientations are widely distributed, and in some cases nearly oppositely oriented in close proximity, indicating that they did not form as failures acted upon by gravity forces. Irregular bedded to internally deformed blocks are isolated on generally flat upper bedding surfaces. These features represent parts of beds that detached, moved up onto and some distances across, the laterally adjacent undisturbed bed surfaces. Deformation of thin intervals of mud on the ocean floor by moving blocks rules out the possibility of storm‐induced deformation, because the mud was not eroded by high shear stresses that would accompany the extremely large forces required to produce and move the blocks. Finally, internally deformed beds are characterized by large blocks, fitted fabrics of highly irregular fragments and contorted lamination, which represent heterogeneous deformation, such as brecciation and liquefaction. The deformation structures were produced by earthquakes linked to the reactivation of Mesoproterozoic, crustal‐scale shear zones in the central Rockies during the Late Cambrian. Analysis of the deformation structures indicates very large body forces and calculated earthquake‐generated ground motion velocities of ca 1·6 m sec?1. These correspond to moment magnitudes of ca 7·0 or more and a Mercalli Intensity of X+. These are the only known magnitude estimates of Phanerozoic (other than Quaternary) large‐intensity earthquakes for the Rocky Mountain region, and they are as large as, or larger than, previous estimates of Proterozoic earthquakes along these major shear zones of the central Rockies.  相似文献   

11.
Drying of deformable porous media results in their shrinkage, and it may cause cracking provided that shrinkage deformations are hindered by kinematic constraints. Herein, we focus on slow drying of an initially water‐saturated sample of a microheterogeneous poroelastic material damaged by parallel mesocracks. The cracking risk is analyzed by means of the thermodynamics‐based microporoelasticity model described in the companion paper (Part I), which is extended toward consideration of the hierarchical organization of cracked argillite. Drying of a material sample is studied in a framework where macrodisplacements in direction of the crack normal are blocked, while elsewise macrostress‐free boundary conditions prevail. The model implies that the opening/closure behavior of the cracks is governed by an effective pressure, in which the average crack (under)pressure, making the crack opening smaller, competes with the average micropore (under)pressure that makes the crack opening larger. The driving force for crack propagation is a quadratic function of this effective pressure. The model proposes that if drying shrinkage deformations are hindered by kinematic constraints, onset of cracking becomes possible once air entry into the cracks is observed. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

12.
Lower Messinian stromatolites of the Calcare di Base Formation at Sutera in Sicily record periods of low sea‐level, strong evaporation and elevated salinity, thought to be associated with the onset of the Messinian Salinity Crisis. Overlying aragonitic limestones were precipitated in normal to slightly evaporative conditions, occasionally influenced by an influx of meteoric water. Evidence of bacterial involvement in carbonate formation is recorded in three dolomite‐rich stromatolite beds in the lower portion of the section that contain low domes with irregular crinkly millimetre‐scale lamination and small fenestrae. The dominant microfabrics are: (i) peloidal and clotted dolomicrite with calcite‐filled fenestrae; (ii) dolomicrite with bacterium‐like filaments and pores partially filled by calcite or black amorphous matter; and (iii) micrite in which fenestrae alternate with dark thin wispy micrite. The filaments resemble Beggiatoa‐like sulphur bacteria. Under scanning electron microscopy, the filaments consist of spherical aggregates of dolomite, interpreted to result from calcification of bacterial microcolonies. The dolomite crystals are commonly arranged as rounded grains that appear to be incorporated or absorbed into developing crystal faces. Biofilm‐like remains occur in voids between the filaments. The dolomite consistently shows negative δ13C values (down to ?11·3‰) and very positive δ18O (mean value 7·9‰) that suggest formation as primary precipitate with a substantial contribution of organic CO2. Very negative δ13C values (down to ?31·6‰) of early diagenetic calcite associated with the dolomite suggest contribution of CO2 originating by anaerobic methane oxidation. The shale‐normalized rare earth element patterns of Sutera stromatolites show features similar to those in present‐day microbial mats with enrichment in light rare earth elements, and M‐type tetrad effects (enrichment around Pr coupled to a decline around Nd and a peak around Sm and Eu). Taken together, the petrography and geochemistry of the Sutera stromatolites provide diverse and compelling evidence for microbial influence on carbonate precipitation.  相似文献   

13.
ABSTRACT The middle Miocene sedimentary fill of the Calatayud Basin in north‐eastern Spain consists of proximal to distal alluvial fan‐floodplain and shallow lacustrine deposits. Four main facies groups characteristic of different sedimentary environments are recognized: (1) proximal and medial alluvial fan facies that comprise clast‐supported gravel and subordinate sandstone and mudstone, the latter exhibiting incipient pedogenic features; (2) distal alluvial fan facies, formed mainly of massive mudstone, carbonate‐rich palaeosols and local carbonate pond deposits; (3) lake margin facies, which show two distinct lithofacies associations depending on their distribution relative to the alluvial fan system, i.e. front (lithofacies A), comprising massive siliciclastic mudstone and tabular carbonates, or lateral (lithofacies B) showing laminated and/or massive siliciclastic mudstone alternating with tabular and/or laminated carbonate beds; and (4) mudflat–shallow lake facies showing a remarkable cyclical alternation of green‐grey and/or red siliciclastic mudstone units and white dolomitic carbonate beds. The cyclic mudflat–shallow lake succession, as exposed in the Orera composite section (OCS), is dominantly composed of small‐scale mudstone–carbonate/dolomite cycles. The mudstone intervals of the sedimentary cycles are interpreted as a result of sedimentation from suspension by distal sheet floods, the deposits evolving either under subaerial exposure or water‐saturated conditions, depending on their location on the lacustrine mudflat and on climate. The dolomite intervals accumulated during lake‐level highstands with Mg‐rich waters becoming increasingly concentrated. Lowstand to highstand lake‐level changes indicated by the mudstone/dolomite units of the small‐scale cycles reflect a climate control (from dry to wet conditions) on the sedimentation in the area. The spatial distribution of the different lithofacies implies that deposition of the small‐scale cycles took place in a low‐gradient, shallow lake basin located in an interfan zone. The development of the basin was constrained by gradual alluvial fan aggradation. Additional support for the palaeoenvironmental interpretation is derived from the isotopic compositions of carbonates from the various lithofacies that show a wide range of δ18O and δ13C values varying from ?7·9 to 3·0‰ PDB and from ?9·2 to ?1·7‰ PDB respectively. More negative δ18O and δ13C values are from carbonate‐rich palaeosols and lake‐margin carbonates, which extended in front of the alluvial fan systems, whereas more positive values correspond to dolomite beds deposited in the shallow lacustrine environment. The results show a clear trend of δ18O enrichment in the carbonates from lake margin to the centre of the shallow lake basin, thereby also demonstrating that the lake evolved under hydrologically closed conditions.  相似文献   

14.
Septarian concretions are abundant in many Phanerozoic marine and marginal‐marine shales and mudstones. They range from a few centimetres to several metres in size and are spherical or ellipsoidal in morphology. In general, formation by localized calcite or siderite cementation in argillaceous sediments began under less than a few metres of burial. Septarian cracks vary widely in shape and configuration: included are networks of wide, vertically, radially and sometimes concentrically oriented, lenticular shrinkage cracks; and narrower, parallel‐sided, straight to irregular tension cracks locally accompanied by brecciation, and plumose and en échelon sigmoidal cracks indicative of shear stresses. Crack types are intergradational; many concretions exhibit multiple cracking events. Enclosed macrofossils and isopachous fibrous calcite cement that lines earlier formed cracks are commonly broken and displaced. In some cases, cracks contain injected lime mud and silt. These features, taken together, testify that cracking involved a spectrum of responses in concretion interiors, from loss of shear strength, dewatering and shrinkage to brittle failure, demonstrating variations in, and contrasts between, the rheological properties of the matrix and enclosed objects. Localization to interiors and outward tapering of lenticular cracks make a case for fracture partitioning and indicate that interiors were softer than exteriors at the time of shrinkage. Parallel‐sided cracks point to greater stiffness, and evolving crack shape in multiply cracked concretions shows that rigidity increased with time. Crack orientations indicate highly variable tensile and shear stress directions within individual concretions. Rupture, brecciation, displacement of fragments, loss of shear strength, liquefaction and injection of unconsolidated granular sediment suggest that deformation events were rapid, if not virtually instantaneous. Previous explanations for the internal cracking, such as gas generation, spontaneous chemical dehydration or localized overpressuring due to compaction, seem either untenable or fail to account for the spectrum of observed features. However, syndepositional earthquake‐induced shaking of cementing bodies of varying rigidity at shallow burial depths seems to be a plausible source for the requisite short‐lived, variable to anisotropic, high‐stress regime inside the concretions. Septarian concretions may thus preserve a signature of basin seismicity as it relates to their cementation history.  相似文献   

15.
Abundant scratching traces are described from the Early Triassic Kockatea Shale Formation in the Northampton area of the northern Perth Basin, Western Australia. Except for the Radichnus trace that represents grazing of a possible decapod mecochirids, Scalpoichnus minchinensis igen. and isp. nov. is established to accommodate other scratching sculptures, which might have been produced by arthropods that share similar feeding behaviours to those of decapods. These arthropod traces occurred on a mat‐bound substratum defined by wrinkle structures. Microbial mats may have served as food resources for trace‐makers feeding on the substratum. Furthermore, microbial envelopes functioning as a sole veneer in early diagenesis acted as a crucial role for the preservation of those shallow‐tiered engraving traces. Abundant arthropod traces indicate frequent grazing activities probably by decapods or organisms having similar feeding habits upon microbial mat‐bound substratum, implying that the deposit‐feeders or omnivores survived on the matgrounds in the aftermath of the end‐Permian mass extinction in Gondwanaland. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

16.
This paper describes and interprets the mineral and facies assemblages that occur in carbonate–evaporite shallow lacustrine deposits, considering the importance of the processes pathway (i.e. dolomitization, gypsum calcitization and silicification). The Palaeogene deposits of the Deza Formation (Almazán Basin, central‐northern Spain) are selected as a case study to determine the variety of physicochemical processes taking place in carbonate–evaporite shallow lakes and their resulting diagenetic features. Dolostones are the predominant lithology and are composed mainly of dolomite with variable amounts of secondary calcite (5 to 50%), which mainly mimic lenticular gypsum (pseudomorphs). Five morphological types of dolomite crystal were identified as follows: dolomite tubes, dolomite cylinders, rhombohedral dolomite, spheroidal and quasi‐rhombohedral dolomite, and cocoon‐shaped dolomite. The dolomite cylinders and tubes are interpreted as the dolomitized cells of a widespread microbial community. The sequence of diagenetic processes started with growth of microlenticular interstitial gypsum in a calcareous mud deposited on the playa margin mudflats, and that sometimes included microbial sediments. Immediately following growth of gypsum, dolomite replaced the original calcite (or possibly aragonite) muds, the microbial community and the gypsum. Partial or total replacement of gypsum by dolomite was related mainly to the biomineralization of endolithic microbial communities on gypsum crystals. Later calcitization took place under vadose, subaerial exposure conditions. The development of calcrete in distal alluvial settings favoured the release of silica and subsequent silicification on the playa margin mudflats. Stable isotope compositions of calcite range from ?9·02 to ?5·83‰ δ13CPDB and ?7·10 to 1·22‰ δ18OPDB; for the dolomite, these values vary from ?8·93 to ?3·96‰ δ13CPDB and ?5·53 to 2·4‰ δ18OPDB. Quartz from the cherts has δ18OSMOW values ranging from 27·1 to 31·1‰. Wide variation and relatively high δ18OSMOW values for dolomite indicate evaporitic and closed hydrological conditions; increased influx of meteoric waters reigned during the formation of secondary calcite spar.  相似文献   

17.
《Sedimentology》2018,65(6):1918-1946
In southern Patagonia, outcrops of the Upper Cretaceous Cerro Toro Formation preserve a >150 km long deep‐water axial channel belt in the Magallanes–Austral Basin, providing a unique opportunity to investigate longitudinal variations in the depositional characteristics of a deep‐water channel system. This study documents sedimentological, stratigraphical and geochronological data from the Cerro Toro Formation in the Argentine sector of the basin. New results are integrated with previous work from the Chilean basin sector to conduct a basin‐scale comparison of the timing of deposition, provenance and lithofacies proportions. The Cerro Toro channel belt includes a nearly 1000 m thick section characterized by high‐density turbidites and mass‐wasting deposits. Two ash beds from the base of the section yield U–Pb zircon ages of 90·4 ± 2 Ma and 88·0 ± 3 Ma, indicating similar initiation ages as documented in the Chilean sector. The U–Pb detrital zircon age spectra from samples in the study area reveal similar provenance trends to samples from the Chilean basin sector, with peak age populations at 310 to 260 Ma, 160 to 135 Ma and 110 to 82 Ma. The maximum depositional age of the channel belt in the Argentine sector is 87·8 ± 1·5 Ma and all new geochronology data corroborate an 86 to 80 Ma depositional age for the main Cerro Toro channel belt. Statistical analyses of 7370 beds from nearly 8000 m of new and previously published stratigraphic sections along the entire outcrop belt suggest progressive variations in the down‐system proportion of lithofacies. In the up‐slope region, lithofacies representing mass wasting processes (for example, debris‐flow and mass‐transport deposits) account for ca 29% of the stratigraphic thickness, as opposed to 5% in the down‐slope region of the channel belt, where turbidity current deposits are more prevalent. The proportion of beds >1 m thick also decreases systematically down slope, particularly for conglomeratic turbidite deposits. This work highlights that: (i) the proportion of thick beds and distribution of lithofacies are key down‐system changes in the stratigraphic fill of this deep‐water channel belt; (ii) detrital zircon trends suggest a relatively well‐mixed longitudinal depositional system; and (iii) geochronology of the main Cerro Toro outcrop belt supports but does not necessitate the model of a single, roughly age‐equivalent, channel system. This study has implications for understanding the downslope variability in depositional processes, stratigraphic architecture and reservoir quality of submarine channel systems.  相似文献   

18.
In this paper, the interaction of double‐periodical cracks is accurately solved based on the isolating analysis procedure, superposition principle, pseudo‐traction method, Chebyshev polynomial expansion and crack‐surface collocation technique. The jump displacement crossing crack faces, the average additional strain and therefore the effective compliance of the double‐periodically cracked plate are directly determined. The numerical results for axial‐symmetrically distributed double‐periodical cracks, general double‐periodical cracks with one collinear direction as well as two sets of double‐periodical cracks with same size and square distribution are given in this paper. And the partial typical numerical results are compared with the previous works. The analysis shows that the anisotropy induced by the general double‐periodical cracks is generally not orthogonal anisotropy. Only when the double‐periodical cracks are axial‐symmetrically distributed, is the anisotropy orthogonal. In this special cases, the effective engineering constants (consist of effective elastic modulus, the effective Poisson's ratio, the effective shear modulus) of cracked plate versus crack spacing, in the plane stress and plane strain conditions, respectively, are analysed. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

19.
Microbial mats, mainly dominated by filamentous algae Calothrix and Oscillatoria, are well developed in Tibetan hot springs. A great number of fossil microorganisms, which existed as algae lamination in thermal depositional cesium-bearing geyserite in this area, are identified as Calothrix and Oscillatoria through microexamination and culture experiments. These microbial mats show the ability to accumulate cesium from spring water to the extent of cesium concentration of 0.46–1.03% cell dry weight, 900 times higher than that in water, and capture large numbers of cesium-bearing opal grain. Silicon dioxide colloid in spring water replaces and fills with the organism and deposits on it to form algae laminated geyserite after dehydration and congelation. Cesium in the microbial mats and opal grain is then reserved in the geyserite. Eventually, cesium-bearing algae laminated geyserite is formed. Study on cesium distribution in geyserite also shows that cesium content in algae lamination, especially in heavily compacted algae lamination, is higher than in the opal layer. For geyserite with no algae lamination or other organism structure, which is generally formed in spring water with low silicon content, cesium accumulation and cesium-bearing opal grain assembled by the microbial mats are also indispensable. After the microbial mats accumulating cesium from spring water, silicon dioxide colloid poorly replaces and fills with the organism to form opal grain-bearing tremellose microbial mats. The shape and structure of the organisms are then destroyed, resulting in cesium-bearing geyserite with no algae lamination structure after dehydration and congelation. It is then concluded that microbial mats in the spring area contribute to the enrichment of cesium in the formation of cesium-bearing geyserite, and a biological genesis of the geyserite, besides of the physical and chemical genesis, is likely.  相似文献   

20.
The study focuses on the formation of lacustrine dolomite in late Miocene lakes, located at the East Mediterranean margins (Northern Israel). These lakes deposited the sediments of the Bira (Tortonian) and Gesher (Messinian) formations that comprise sequences of dolostone and limestone. Dolostones are bedded, consist of small‐sized (<7 μm), Ca‐rich (52 to 56 mol %) crystals with relatively low ordering degrees, and present evidence for replacement of CaCO3 components. Limestones are comprised of a wackestone to mudstone matrix, freshwater macrofossils and intraclasts (mainly in the Bira Formation). Sodium concentrations and isotope compositions differ between limestones and dolostones: Na = ~100 to 150 ppm; ~1000 to 2000 ppm; δ18O = ?3·8 to ?1·6‰; ?2·0 to +4·3‰; δ13C = ?9·0 to ?3·4‰; ?7·8 to 0‰ (VPDB), respectively. These results indicate a climate‐related sedimentation during the Tortonian and early Messinian. Wet conditions and positive freshwater inflow into the carbonate lake led to calcite precipitation due to intense phytoplankton blooms (limestone formation). Dry conditions and enhanced evaporation led to precipitation of evaporitic CaCO3 in a terminal lake, which caused an increased Mg/Ca ratio in the residual waters and penecontemporaneous dolomitization (dolostone formation). The alternating lithofacies pattern reveals eleven short‐term wet–dry climate‐cycles during the Tortonian and early Messinian. A shift in the environmental conditions under which dolomite formed is indicated by a temporal decrease in δ18O of dolostones and Na content of dolomite crystals. These variations point to decreasing evaporation degrees and/or an increased mixing with meteoric waters towards the late Messinian. A temporal decrease in δ13C of dolostones and limestones and appearance of microbial structures in close association with dolomite suggest that microbial activity had an important role in allowing dolomite formation during the Messinian. Microbial mediation was apparently the main process that enabled local growth of dolomite under wet conditions during the latest Messinian.  相似文献   

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