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1.
A basanite dyke in the Kerguelen Archipelago contains abundantcomposite mantle xenoliths consisting of spinel-bearing dunitescross-cut by amphibole-rich veins. Two types of veins (thickand thin) have been distinguished: the thick veins representalmost complete crystallization products of highly alkalinemelts similar to the host basanites, whereas thin veins areprecipitates from fractionates of the parental melts to thethick veins. These fractionated fluids are enriched in H2O relativeto the parental melts. The amphiboles in the thin veins arelower in Ti and higher in Nb, Ta, Zr and Hf than amphibolesin the thick veins. This fractionation of high field strengthelements (HFSE) is consistent with a combination of the changingcomposition of the fractionated fluids and the change in intrinsicamphibole–fluid partition coefficients for HFSE in fluidswith higher aH2O and lower aTiO2. The trace element contentof amphiboles disseminated in dunitic wall-rocks is closelyrelated to the composition of adjacent veins and thus theseamphiboles are precipitates from fluids percolating into thedunite from the veins. Disseminated amphibole reflects the compositionof the percolating melt, which is similar to that of the associatedveins. KEY WORDS: mantle amphibole; Kerguelen; HFSE fractionation; mantle HFSE; mantle xenoliths  相似文献   

2.
NIU  YAOLING 《Journal of Petrology》2004,45(12):2423-2458
This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that DZr/DHf< 1 and DNb/DTa < 1. Given the identical charges (5+ forNb and Ta; 4+ for Zr and Hf) and essentially the same ionicradii (RNb/RTa = 1·000 and RZr/RHf = 1·006–1·026),yet a factor of 2 mass differences (MZr/MHf = 0·511 andMNb/MTa = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H2O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H2O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources  相似文献   

3.
Peridotites in the Ulten Zone (Upper Austroalpine, Eastern Alps),occur as small bodies within lower-crustal rocks (gneisses andmigmatites) subducted at eclogite-facies conditions during theVariscan orogeny. They record a complex metamorphic and deformationevolution as indicated by the transition from coarse-grainedspinel-bearing peridotites to fine-grained garnet + amphibole-bearingperidotites, and are interpreted as portions of mantle wedgethat were incorporated in a downgoing slab of cold continentalcrust. The transition from spinel- to garnet-bearing assemblagewas accompanied by significant input of metasomatic agents,as shown by the crystallization of abundant amphibole. Herewe present trace-element mineral chemistry data for selectedUlten peridotites, with the aim of unravelling the nature ofthe metasomatic processes. Amphiboles display significant lightrare earth element (LREE) enrichment [CeN/YbN = 3·90–11·50;LREE up to (20–50) x C1], high Sr (150–250 ppm),K (1910–7280 ppm) and Ba (280–800 ppm) contents,and low concentrations of high field strength elements (HFSE)(Zr = 14–25 ppm, Y = 6·7–16 ppm, Ti = 1150–2500ppm, Nb = 2–7 ppm). On the basis of (1) the evidence formodal orthopyroxene decrease as a result of the garnet-formingreaction rather than abundant orthopyroxene crystallization,(2) the high modal amounts of amphibole (up to 23%) in the mostmetasomatized peridotites and (3) the strong large ion lithophileelement (LILE)/HFSE fractionation in amphiboles, we infer thatthe metasomatic agent was an H2O–CO2 fluid with a lowCO2/H2O ratio. Petrological investigations and geochronologicaldata indicate that the host metapelites experienced in situpartial melting and migmatization concomitantly with the garnet+ amphibole-facies recrystallization in the enclosed peridotites.We infer that the metasomatizing hydrous fluids could representthe residual fluids left after the crystallization of leucosomes,starting from water-undersaturated melts produced during migmatizationof the host gneisses. KEY WORDS: garnet peridotite; crustal metasomatism; amphibole; hydrous fluids  相似文献   

4.
A survey of global ocean island basalt geochemistry shows aremarkably strong linear correlation (average r2 = 0·95)between Zr and Nb concentrations. Fractional crystallizationexplains neither the range in Zr and Nb concentrations nor thefact that regression lines have intercepts significantly differentfrom zero. A substantial, linearly correlated (average r2 =0·92) variability in Zr and Nb concentrations remainsin the datasets after correction for fractional crystallization.Linear correlation between Zr and Nb concentrations is not expectedfrom variable degrees of melting because the concentration ofNb is significantly more sensitive to the degree of meltingthan that of Zr. Our main conclusion is that the Zr/Nb systematicsof ocean island basalts requires binary mixing, and more specificallymixing of two separate melts. We show that a mid-ocean ridgebasalt melt is the depleted endmember, common to all examinedocean island basalts. The enriched endmember has a very variableZr/Nb ratio. We speculate that, rather than implying the existenceof several distinct enriched reservoirs, the highly variableZr/Nb ratio could reflect intra-mantle processes such as fertilizationby small-degree melts or carbonate–silicate melt immiscibility. KEY WORDS: binary mixing; degree of melting; fractional crystallization; linear concentration relationship; trace element enrichment  相似文献   

5.
Geochemical data from back-arc volcanic zones in the Manus Basinare used to define five magma types. Closest to the New Britainarc are medium-K lavas of the island arc association and back-arcbasin basalts (BABB). Mid-ocean ridge basalts (MORB), BABB andmildly enriched T-MORB (transitional MORB) occur along the ManusSpreading Center (MSC) and Extensional Transform Zone (ETZ).The MSC also erupted extreme back-arc basin basalts (XBABB),enriched in light rare earth elements, P, and Zr. Compared withnormal MORB, Manus MORB are even more depleted in high fieldstrength elements and slightly enriched in fluid-mobile elements,indicating slight, prior enrichment of their source with subduction-relatedcomponents. Chemical variations and modeling suggest systematic,coupled relationships between extent of mantle melting, priordepletion of the mantle source, and enrichment in subduction-relatedcomponents. Closest to the arc, the greatest addition of subduction-relatedcomponents has occurred in the mantle with the greatest amountof prior depletion, which has melted the most. Variations inK2O/H2O indicate that the subduction-related component is bestdescribed as a phlogopite and/or K-amphibole-bearing hybridizedperidotite. Magmas from the East Manus Rifts are enriched inNa and Zr with radiogenic 87Sr/86Sr, possibly indicating crustalinteraction in a zone of incipient rifting. The source for XBABBand lavas from the Witu Islands requires a mantle componentsimilar to carbonatite melt. KEY WORDS: Manus back-arc basin, mantle metasomatism, magma generation  相似文献   

6.
The Honolulu Volcanics comprises small volume, late-stage (post-erosional)vents along rifts cutting the older massive Koolau tholeüticshield on Oahu, Hawaii. Most of these lavas and tuff of theHonolulu Volcanics have geochemical features expected of near-primarymagmas derived from a peridotite source containing Fo87–89olivine; e. g. 100 Mg/(Mg + Fe2+) >65, >250 p. p. m. Ni,and presence of ultramafic mantle xenoliths at 18 of the 37vents. Consequently, the geochemistry of the alkali olivinebasalt, basanite, nephelinite and nepheline melilitite lavasand tuff of the Honolulu Volcanics have been used to deducethe composition of their mantle source and the conditions underwhich they were generated by partial melting in the mantle. Compositional trends in 30 samples establish that the magmaswere derived by partial melting of a garnet (<10 per cent)Iherzolite source, which we infer to have been carbon-bearing,from analogy with experimental results. This source was isotopicallyhomogeneous (Sr, Lanphere & Dalrymple, 1980; Pb, Sun, 1980;Nd, Roden et al., 1981), and we infer that the source was compositionallyuniform in all major-element oxides except TiO2, in compatibletrace elements (Sc, V, Cr, Mn, Co and Ni), and in highly incompatibletrace elements (P, Th, La, Ce). However, the source appearsto have been heterogeneous in TiO2, Zr, Hf, Nb, and Ta, elementsthat were not strongly incompatible during partial melting.Some nepheline melilitite samples may be derived from a sourcewith distinct Sc and heavy-rare-earth-elements (REE) abundances,or which had a phase or phases controlling the distributionof these elements. The relatively limited abundance range for several elements,such as Ti, Zr, Nb, is partly a consequence of the low degreesof melting inferred for the series (2 per cent for nephelinemelilitite, 11 per cent for alkali olivine basalt), which failedto exhaust the source in minor residual phases. We infer thatthese residual phases probably included phlogopite, amphibole,and another Ti-rich phase (an oxide?), but not apatite. In comparison with estimates of a primordial mantle compositionand the mantle source of mid-oceanic-ridge basalt the garnetperidotite source of the Honolulu Volcanics was increasinglyenriched in the sequence heavy REEs, Y, Tb, Ti, Sm, Zr, andHf all <P <Nd <Sr Ce <La <Nb Ta. A multi-stagehistory for the source of the Honolulu Volcanics is requiredbecause this enrichment was superimposed on a mantle that hadbeen previously depleted in incompatible elements, as indicatedby the relatively low 87Sr/86Sr ratio, high 143Nd/144Nd ratioand low contents of K, Rb, Ba, and Th. The composition of thesource of the Honolulu Volcanics differs from the source ofthe previously erupted tholeiitic shield. The modal mineralogyof the source of the Honolulu Volcanics is not represented inthe upper-mantle xenoliths, e. g. the garnet pyroxenite andolivine-poor garnet Iherzolite included within the lavas andtuff of the unit.  相似文献   

7.
. We report major-element, trace-element and isotopic data of volcanic rocks from the late-Neoproterozoic (570 Ma) Agardagh Tes-Chem ophiolite in Central Asia, south-west of Lake Baikal (50.5°N, 95°E). The majority of samples are high-alumina basalts and basaltic andesites having island-arc affinities. They were derived from an evolved parental magma (Mg#̾.60, Cr~180 ppm, Ni~95 ppm) by predominantly clinopyroxene fractionation. The parental magma developed from a primary mantle melt by fractionation of about 12% of an olivine+spinel assemblage. The island-arc rocks have high abundances of incompatible trace elements (light rare-earth element abundances up to 100 times chondritic, chondrite-normalised (La/Yb)n=14.6-5.1) and negative Nb anomalies (Nb/La=0.37-0.62), but low Zr/Nb ratios (7-14). Initial )Nd values are around +5.5, initial Pb isotopic compositions are 206Pb/204Pb=17.39-18.45, 207Pb/204Pb=15.49-15.61, 208Pb/204Pb=37.06-38.05. Enrichment of large-ion lithophile elements within this group is significant (Ba/La=11-130). Another group of samples consists of back-arc basin-related volcanic rocks. They are most likely derived from the same depleted mantle source as the island-arc rocks, but underwent higher degrees of melting (8-15%) and are not influenced by slab components. They have lower abundances of incompatible trace elements, flat rare-earth element patterns [(La/Yb)n=0.6-2.4] and higher )Nd values (+7.8 to +8.5). Negative Nb anomalies are absent (Nb/La=0.81-1.30), but Zr/Nb is high (21-48). At least three components are necessary to explain the geochemical evolution of the volcanic rocks: (1) an enriched (ocean island-like) component characterised by a high Nb concentration (up to 30 ppm), an absent negative Nb anomaly, a low Zr/Nb ratio (~6.5), a low )Nd value (around 0), and radiogenic 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb; (2) a back-arc basin component similar to N-MORB with a flat rare-earth element pattern and a high )Nd value (around +8.5); and (3) an island-arc component from a mantle source which was modified by the downgoing slab. Crystal fractionation superimposed on mixing and source contamination by subducted sediments is suitable to explain the observed geochemical data. The most likely geodynamic environment to produce these characteristics is a young, intra-oceanic island-arc system and an associated back-arc basin.  相似文献   

8.
Experimental Melting of Carbonated Peridotite at 6-10 GPa   总被引：2，自引：0，他引：2  
Partial melting of magnesite-bearing peridotites was studiedat 6–10 GPa and 1300–1700°C. Experiments wereperformed in a multianvil apparatus using natural mineral mixesas starting material placed into olivine containers and sealedin Pt capsules. Partial melts originated within the peridotitelayer, migrated outside the olivine container and formed poolsof quenched melts along the wall of the Pt capsule. This allowedthe analysis of even small melt fractions. Iron loss was nota problem, because the platinum near the olivine container becamesaturated in Fe as a result of the reaction Fe2SiO4Ol = FeFe–Ptalloy + FeSiO3Opx + O2. This reaction led to a gradual increasein oxygen fugacity within the capsules as expressed, for example,in high Fe3+ in garnet. Carbonatitic to kimberlite-like meltswere obtained that coexist with olivine + orthopyroxene + garnet± clinopyroxene ± magnesite depending on P–Tconditions. Kinetic experiments and a comparison of the chemistryof phases occasionally grown within the melt pools with thosein the residual peridotite allowed us to conclude that the meltshad approached equilibrium with peridotite. Melts in equilibriumwith a magnesite-bearing garnet lherzolite are rich in CaO (20–25wt %) at all pressures and show rather low MgO and SiO2 contents(20 and 10 wt %, respectively). Melts in equilibrium with amagnesite-bearing garnet harzburgite are richer in SiO2 andMgO. The contents of these oxides increase with temperature,whereas the CaO content becomes lower. Melts from magnesite-freeexperiments are richer in SiO2, but remain silicocarbonatitic.Partitioning of trace elements between melt and garnet was studiedin several experiments at 6 and 10 GPa. The melts are very richin incompatible elements, including large ion lithophile elements(LILE), Nb, Ta and light rare earth elements. Relative to theresidual peridotite, the melts show no significant depletionin high field strength elements over LILE. We conclude fromthe major and trace element characteristics of our experimentalmelts that primitive kimberlites cannot be a direct productof single-stage melting of an asthenospheric mantle. They rathermust be derived from a previously depleted and re-enriched mantleperidotite. KEY WORDS: multianvil; carbonatite melt; peridotite; kimberlite; element partitioning  相似文献   

9.
Olivine + clinopyroxene ± amphibole cumulates have beenwidely documented in island arc settings and may constitutea significant portion of the lowermost arc crust. Because ofthe low melting temperature of amphibole (1100°C), suchcumulates could melt during intrusion of primary mantle magmas.We have experimentally (piston-cylinder, 0·5–1·0GPa, 1200–1350°C, Pt–graphite capsules) investigatedthe melting behaviour of a model amphibole–olivine–clinopyroxenerock, to assess the possible role of such cumulates in islandarc magma genesis. Initial melts are controlled by pargasiticamphibole breakdown, are strongly nepheline-normative and areAl2O3-rich. With increasing melt fraction (T > 1190°Cat 1·0 GPa), the melts become ultra-calcic while remainingstrongly nepheline-normative, and are saturated with olivineand clinopyroxene. The experimental melts have strong compositionalsimilarities to natural nepheline-normative ultra-calcic meltinclusions and lavas exclusively found in arc settings. Theexperimentally derived phase relations show that such naturalmelt compositions originate by melting according to the reactionamphibole + clinopyroxene = melt + olivine in the arc crust.Pargasitic amphibole is the key phase in this process, as itlowers melting temperatures and imposes the nepheline-normativesignature. Ultra-calcic nepheline-normative melt inclusionsare tracers of magma–rock interaction (assimilative recycling)in the arc crust. KEY WORDS: experimental melting; subduction zone; ultra-calcic melts; wehrlite  相似文献   

10.
Ultramafic xenoliths from alkali basalts in the Perjani Mountainsin the Eastern Transylvanian Basin (ETB) of Romania are mainlyspinel Iherzolites, although spinel harzburgites, websterites,clinopyroxenites and amphibole pyroxenites are also present.Amphibole veins cut some spinel peridotite samples. All arederived from the shallow lithospheric upper mantle. In general,textural variations are restricted to protogranular and porphyroclastictypes, compared with the more varied textures found in mantlexenoliths from the alkali basalts of the neighbouring PannonianBasin. Also, ETB peridotites are richer in amphibole. Thus,the mantle beneath the edge of the ETB is less deformed butmore strongly metasomatized than the mantle closer to the centreof the Pannonian Basin.Mineralogical and bulk-rock geochemicalvariations resemble those of spinel Iherzolites from other sub-continentalshallow mantle xenolith suites. There is no apparent correlationbetween deformation and geochemistry, and much of the majorand trace element variation is due to variable extraction ofpicritic melts. The REE patterns of separated clinopyroxenesfrom the peridotite xenoliths are mostly LREE depleted, althoughclinopyroxenes from regions adjacent to amphibole veins haveexperienced an enrichment in La and Ce and a change in theirSr and Nd isotopic values towards those of the vein, while stillretaining an overall LREE depletion. Clinopyroxenes from thewebsterites and clinopyroxenites are more variable. Amphibolein the hydrous pyroxenites and amphibole veins is strongly LREEenriched and is considered to be metasomatic in origin. 87Sr/86Srand 143Nd/l44Nd isotopic ratios of the xenoliths vary between07018 and 07044, and 051355 and 0 51275, respectively. Thesevalue are more depleted than those obtained for xenoliths fromthe Pannonian Basin. The lower l43Nd/l44Nd and higher 87Sr/Sr86values are found in anhydrous pyroxenites, metasomatic amphibolesin veins and amphibole pyroxenites, and in the only exampleof an equigranular spinel Iherzolite in the suite.The ETB xenolithswere brought to the surface in alkaline vokanism which post-dateda period of Miocene to Pliocene subduction-related cak-alkalinevolcanism. However, the effects of the passage of either slab-derivedfluids or cak-alkaline magmas through the ETB lithospheric mantlecannot be discerned in the chemistry of the xenoliths. The metasomaticamphibole has 87Sr/Sr86 and 143Sr/Sr144 ratios similar to thehost alkali basalts, but the least evoked cak-alkaline magmasalso have similar Sr and Nd isotope compositions. The REE patternsof the amphibole resembk those of amphiboles considered to havecrystallized from alkaline melts. No preferential enrichmentin elements typically associated with slab-derivedfluids (K,Rb and Sr) relative to elements typically depleted in cak-alkalinemagmas (Ti, 2jr and Nb) has been observed in the vein amphiboles,although some interstitial amphibole is depleted in all incompatibletrace elements, including LREE. Thus, despite its position closeto the calc-alkaline volcanic arc of the Eastern Carpathians,we cannot readily detect any interaction between the lithosphericupper mantle beneath the ETB and subduction-related magmas orfluids. Metasomatism in the lithospheric mantle is instead largelyrelated to the passage of a primitive alkaline magma similarto the host alkali basal *corresponding author  相似文献   

11.
The effects of source composition and source evolution duringprogressive partial melting on the chemistry of mantle-derivedmid-ocean ridge basalt (MORB) melts were tested using a comprehensivegeochemical and Sr–Nd–Pb isotopic dataset for fresh,magnesian basaltic glasses from the Miocene Macquarie Islandophiolite, SW Pacific. These glasses: (1) exhibit clear parent–daughterrelationships; (2) allow simple reconstruction of primary meltcompositions; (3) show exceptional compositional diversity (e.g.K2O/TiO2 0·09–0·9; La/Yb 1·5–22;206Pb/204Pb 18·70–19·52); (4) preserve changesin major element and isotope compositions, which are correlatedwith the degree of trace element enrichment (e.g. La/Sm). Conventionalmodels for MORB genesis invoke melting of mantle that is heterogeneouson a small scale, followed by binary mixing of variably lithophileelement-enriched melt batches. This type of model fails to explainthe compositions of the Macquarie Island glasses, principallybecause incompatible element ratios (e.g. Nb/U, Sr/Nd) and Pbisotope ratios vary non-systematically with the degree of enrichment.We propose that individual melt batches are produced from instantaneous‘parental’ mantle parageneses, which change continuouslyas melting and melt extraction proceeds. This concept of a ‘dynamicsource’ combines the models of small-scale mantle heterogeneitiesand fractional melting. A dynamic source is an assemblage oflocally equilibrated mantle solids and a related melt fraction.Common MORB magmas that integrate the characteristics of numerousmelt batches therefore tend to conceal the chemical and isotopicidentity of a dynamic source. This study shows that isotoperatios of poorly mixed MORB melts are a complex function ofthe dynamic source evolution, and that the range in isotoperatios within a single MORB suite does not necessarily requiremixing of diverse components. KEY WORDS: mid-ocean ridge basalt; Macquarie Island; radiogenic isotopes; mantle; geochemistry  相似文献   

12.
We report the first estimates of primary kimberlite melt compositionfrom the Slave craton, based on samples of aphanitic kimberlitefrom the Jericho kimberlite pipe, N.W.T., Canada. Three samplesderive from the margins of dykes where kimberlite chilled againstwall rock (JD51, JD69 and JD82) and are shown to be texturallyconsistent with crystallization from a melt. Samples JD69 andJD82 have geochemical characteristics of primitive melts: theyhave high MgO (20–25 wt %), high mg-numbers (86–88),and high Cr (1300–1900 ppm) and Ni (800–1400 ppm)contents. They also have high contents of CO2 (10–17 wt%). Relative to bulk macrocrystal kimberlite, they have lowermg-numbers and lower MgO but are enriched in incompatible elements(e.g. Zr, Nb and Y), because the bulk kimberlite compositionsare strongly controlled by accumulation of mantle olivine andother macrocrysts. The compositions of aphanitic kimberlitefrom Jericho are similar to melts produced experimentally bypartial melting of a carbonate-bearing garnet lherzolite. Onthe basis of these experimental data, we show that the primarymagmas from the Jericho kimberlite could represent 0·7–0·9%melting of a carbonated lherzolitic mantle source at pressuresand temperatures found in the uppermost asthenosphere to theSlave craton. The measured CO2 contents for samples JD69 andJD82 are only slightly lower than the CO2 contents of the correspondingexperimental melts; this suggests that the earliest hypabyssalphase of the Jericho kimberlite retained most of its originalvolatile content. As such these samples provide a minimum CO2content for the primary kimberlite magmas from the Slave craton. KEY WORDS: kimberlite; melt; primitive; primary magma; Slave craton  相似文献   

13.
Several spinel peridotite xenoliths from Spitsbergen have Sr–Ndisotopic compositions that plot to the right of the ‘mantlearray’ defined by oceanic basalts and the DM end-member(depleted mantle, with low 87Sr/86Sr and high 143Nd/144Nd).These xenoliths also show strong fractionation of elements withsimilar compatibility (e.g. high La/Ce), which cannot be producedby simple mixing of light rare earth element-depleted peridotiteswith ocean island basalt-type or other enriched mantle melts.Numerical simulations of porous melt flow in spinel peridotitesapplied to Sr–Nd isotope compositions indicate that thesefeatures of the Spitsbergen peridotites can be explained bychemical fractionation during metasomatism in the mantle. ‘Chromatographic’effects of melt percolation create a transient zone where thehost depleted peridotites have experienced enrichment in Sr(with a radiogenic isotope composition) but not in Nd, thusproducing Sr–Nd decoupling mainly controlled by partitioncoefficients and abundances of Sr and Nd in the melt and theperidotite. Therefore, Sr–Nd isotope decoupling, earlierreported for some other mantle peridotites worldwide, may bea signature of metasomatic processes rather than a source-relatedcharacteristic, contrary to models that invoke mixing with hypotheticalSr-rich fluids derived from subducted oceanic lithosphere. Pbisotope compositions of the Spitsbergen xenoliths do not appearto be consistently affected by the metasomatism. KEY WORDS: Spitsbergen; lithospheric mantle; metasomatism; radiogenic isotopes; theoretical modelling  相似文献   

14.
High Field Strength Element Anomalies in Arc Lavas: Source or Process?   总被引：12，自引：5，他引：12  
An understanding of the origin of depletion in the high fieldstrength elements (HFSE), Nb, Zr and Ti, relative to rare earthelements (REE) in arc lavas is critical to models both for magmagenesisin ares and for the relationship between are magmatism and growthof the continental crust. The presence of HFSE depletion inboth are lavas and in the bulk continental crust constitutessome of the strongest evidence that continental crust is/wasgenerated in subduction zones, especially if the HFSE are retainedrelative to REE in the subducting slab (Saunders et al., 1980;McDonough, 1991). Recently, however, it has been proposed thatHFSE depletion develops during the main are magma melting eventin the mantle wedge (McKenzie & O'Nions, 1991), during meltascent to the surface (Kelemen et al., 1990), or even that aworld-wide shallow mantle reservoir with HFSE depletion exists(Salters & Shimizu, 1988). If so, it is possible that HFSEdepletion may have developed in magmas unrelated to subductionzones during crust-generation processes in the Precambrian.The common presence of high-MgO lavas in the Southern LesserAntilles provides a rare opportunity to test these models, becausetheir chemistry is essentially unmodified since derivation fromthe mantle. We show that depletion (relative to REE) in theHFSE Ti, Zr, and Nb exists in the mantle wedge before melting,and is probably produced by an REE-rich slab flux. In contrastto many other arcs (Woodhead et al., 1993), there is no evidencethat the Lesser Antilles mantle source is more depleted in HFSEthan the source of mid-ocean ridge basalts. Relative to REE,Ti depletion in melts is enhanced during melting, requiringa Ti-rich phase in the residue at low melt fractions. Ti depletionis also enhanced during fractionation of magnetite and amphibole,whereas relative Zr depletion is reduced during fractionation.In most arc magmas (usually <6% MgO), fractionation is probablya major control on the extent of Ti and Zr depletion. In theLesser Antilles, the extent of Nb depletion relative to La islargely unaffected by melting or crystal fractionation processes.  相似文献   

15.
Peak metamorphism (800–850°C, 8–10 kbar) inthe Harts Range Meta-Igneous Complex (Harts Range, central Australia)was associated with localized partial melting by the reactionhornblende + plagioclase + quartz + H2O = garnet + clinopyroxene+ titanite + melt. In situ trace-element determinations of prograde,peak and retrograde minerals in migmatitic metabasites and associatedtonalitic melts using laser-ablation ICP–MS has allowedmonitoring of a range of partial-melting processes (melting,melt segregation and back-reaction between crystallizing meltand restitic minerals). Mass balance calculations indicate thattitanite is a major carrier of trace elements such as Ti, Nb,Ta, Sm, U and Th, and therefore may be an important accessoryphase to control the redistribution of these elements duringthe partial melting of amphibolites. Titanite preferentiallyincorporates Ta over Nb and, hence, residual titanite mightassist in the formation of melts with high Nb/Ta. The fact thatsingle minerals record different rare earth element (REE) patterns,from prograde to peak to retrograde conditions, demonstratesthat REE diffusion is not significant up to 800°C. Therefore,trace-element analysis in minerals can be a powerful tool toinvestigate high-grade metamorphic processes beyond the limitsgiven by major elements. KEY WORDS: Harts Range; laser-ablation ICP–MS; metabasites; partial melting; trace elements  相似文献   

16.
Metasomatism-induced Melting in Mantle Xenoliths from Mongolia   总被引：29，自引：10，他引：19  
Mantle xenoliths from two locations in Mongolia contain patchesof glass-phenocryst aggregates (‘melt pockets’)up to 1 cm in diameter, including one ‘composite’xenolith, which shows a complete transition from unaltered spinelIherzolite to a zone containing melt pockets surrounded by acpx and spinel-free peridotite matrix. We have analyzed majorelements by wet chemistry, X-ray fluorescence (XRF), and electronmicroprobe, trace elements by ion microprobe and inductivelycoupled plasma mass spectrometry (ICP-MS) techniques, and Srand Nd isotopes by mass spectrometry, to elucidate the originof these melt pockets. Petrographic and chemical evidence shows that the melt pocketswere formed neither by infiltration of the host basalt nor bydehydration melting of hydrous phases, such as amphibole. Instead,melting was induced by the interaction of a metasomatic fluidwith clinopyroxene and spinel. The reaction produced melts ofvariable composition, with SiO2 ranging from 52 to 68% and MgOfrom 4.5 to 0.5%. The melts contain euhedral grains of olivine,clinopyroxene, and spinel, and a large number of (now empty)vugs. The melt shows no sign of having invaded the Iherzolitematrix surrounding the pockets. There is some evidence for fractionalcrystallization, but some of the major element chemical trends,such as the negative correlation between Na2O and SiO2, cannotbe accounted for by such a mechanism. The glasses and clinopyroxenephenocrysts are very rich in light rare earth elements (LREE)and Sr, and completely dominate the bulk contents of these andsome other incompatible elements in the rocks with melt pockets.The invading fluid introduced high concentrations of LREE, Th,U, Pb, and Sr, but was relatively depleted in Ba, Rb, Nb, Ta,Zr, Hf, and Ti, and had unusually high Zr/Hf and Nb/Ta ratios. Ion microprobe analyses of fresh glass directly adjacent toclinopyroxene microphenocrysts yield a series of cpx-melt partitioncoefficients for REE and several other trace elements. DYb (cpx-melt)varies between 0–3 and 1.6 and is positively correlatedwith the A12O3+SiO2 and Na2O contents of the glass, and negativelycorrelated with MgO, FeO, and CaO contents. These correlationsare consistent with qualitative predictions from considerationsof silicate melt structure. The clinopyroxenes in the unaltered zones of the composite xenolithshow evidence of an earlier phase of metasomatism which enrichedCe, La, and Sr, but did not affect the other REE. Clinopyroxenesfrom these zones have high Nd values of + 14 and +19, indicatinga history of low Nd/Sm ratios. At the same time, 87Sr/86Sr ratiosare high (>0.704), indicating infiltration of relativelyradiogenic Sr during the early stage of metasomatism. Ion microprobetraverses show no zoning of La/Nd ratios. Therefore, there wasenough time to equilibrate the metasomatic effects in the graininteriors, and we estimate the time required for this equilibrationto be of the order of 105 years. In sharp contrast, the second, or main, metasomatic event thatcaused the formation of the melt pockets must have been extremelyshort-lived and probably lasted only hours or days before thexenolith was captured by the magma and erupted at the surface.This short duration is required by the preservation of freshglass and by the lack of equilibration of the melt pockets withtheir surrounding matrix. The isotopic compositions of Sr and Nd are identical betweenmelt pockets and host basalts in both localities. Therefore,we conclude that the metasomatic fluids were probably derivedfrom the same source rocks as the host basalts. We speculatethat the xenoliths originally resided in an upper-mantle regionwhich was intruded by a partially molten diapir. Volatiles wereexpelled from the unmelted margin of the diapir and invadedthe adjacent upper-mantle peridotites. The fluid infiltrationtriggered formation of the melt pockets, whereupon the materialwas picked up by rapidly ascending magma and erupted at thesurface. The fluids appear to have been poor in water, as nohydrous minerals are present among phenocryst or quench phasesin melt pockets. The major component of the fluid may have beenCO2 or liquid carbonate.  相似文献   

17.
A microanalytical trace element and geochronological study wascarried out on mafic amphibole-rich cumulates (quartz diorites)cropping out in northern Victoria Land (Antarctica). Associatedtonalites and basement rocks were also investigated. Rock texturesand major and trace element mineral compositions reveal thepresence in quartz diorites of two mineral assemblages: (1)clinopyroxene-I + brown amphibole ± dark mica; (2) clinopyroxene-II+ green amphibole + plagioclase + quartz. Both mineral assemblagescontain mafic phases with elevated Mg-number, but their traceelement signatures differ significantly. In situ U–Pbzircon geochronology was carried out to support petrogeneticand geological interpretations. Quartz diorites were emplacedin the mid-crust probably at 516 ± 3 Ma. Parental meltsof quartz diorites were computed by applying solid/liquid partitioncoefficients. The melt in equilibrium with the first mineralassemblage (melt-I) is extremely depleted in heavy rare earthelements (HREE), Y, Ti, Zr and Hf (at about 0·2 timesnormal mid-ocean ridge basalt) and enriched in B, Th, U, thelarge ion lithophile elements and light REE (LREE). It sharesmany similarities with sanukitic melts (e.g. Setouchi andesites),which originated by equilibration of subduction-derived sedimentmelts with a refractory mantle. The melt in equilibrium withthe second mineral assemblage (melt-II) is characterized bya steep LREE enrichment (LaN/YbN up to 39), a U-shaped HREEpattern and low Ti, which is depleted relative to HREE. Thetrace element signature of melt-II can be acquired through amphibolecrystallization starting from a sanukitic melt similar to melt-I,probably in a deeper magma chamber. Our results allow us toconstrain that melts from the subducted slab were produced ona regional scale, in accordance with literature data, belowa large sector of the east Gondwana margin during the mid-Cambrian.Implications for the role of amphibole in petrogenesis of subduction-relatedmagmas are also discussed. KEY WORDS: amphibole; sanukite; high-Mg andesites; Ross Orogeny; Antarctica  相似文献   

18.
A wide range of trace elements have been analysed in mantle xenoliths (whole rocks, clinopyroxene and amphibole separates) from alkaline lavas in the Eastern Carpathians (Romania), in order to understand the process of metasomatism in the subcontinental mantle of the Carpatho-Pannonian region. The xenoliths include spinel lherzolites, harzburgites and websterites, clinopyroxenites, amphibole veins and amphibole clinopyroxenites. Textures vary from porphyroclastic to granoblastic, or equigranular. Grain size increases with increasing equilibrium temperature of mineralogical assemblages and results from grain boundary migration. In peridotites, interstitial clinopyroxenes (cpx) and amphiboles resulted from impregnation and metasomatism of harzburgites or cpx-poor lherzolites by small quantities of a melt I with a melilitite composition. Clinopyroxenites, amphibole veins and amphibole clinopyroxenites are also formed by metasomatism as a result of percolation through fracture systems of large quantities of a melt II with a melanephelinite composition. These metasomatic events are marked by whole-rock enrichments, relative to the primitive mantle (PM), in Rb, Th and U associated in some granoblastic lherzolites and in clinopyroxene and amphibole veins with enrichments in LREE, Ta and Nb. Correlations between major element whole-rock contents in peridotites demonstrate that the formation of interstitial amphibole and clinopyroxene induced only a slight but variable increase of the Ca/Al ratio without apparent modifications of the initial mantle composition. Metasomatism is also traced by enrichments in the most incompatible elements and the LREE. The Ta, Nb, MREE and HREE contents remained unchanged and confirm the depleted state of the initial but heterogeneous mantle. Major and trace element signature of clinopyroxene suggests that amphibole clinopyroxenites and some granoblastic lherzolites have been metasomatized successively by melts I and II. Both melts I and II were Ca-rich and Si-poor, somewhat alkaline (Na > K). Melt I differed from melt II in having higher Mg and Cr contents offset by lower Ti, Al, Fe and K contents. Both were highly enriched in all incompatible trace elements relative to primitive mantle, showing positive anomalies in Rb, Ba, Th, Sr and Zr. They contrasted by their Ta, Nb and LREE contents, lower in melt I than in melt II. Melts I and II originate during a two-stage melting event from the same source at high pressure and under increasing temperature. The source assemblage could be that of a metasomatized carbonated mantle but was more likely that of an eclogite of crustal affinity. Genetic relationships between calc-alkaline and alkaline lavas from Eastern Carpathians and these melts are thought to be only indirect, the former originating from partial melting of mantle sources respectively metasomatized by the melts I and II. Received: 17 March 1997 / Accepted: 14 July 1997  相似文献   

19.
Mineral and whole-rock chemical data for peridotite xenolithsin basaltic lavas on Spitsbergen are examined to reassess mechanismsof melt–fluid interaction with peridotites and their relativerole versus melt composition in mantle metasomatism. The enrichmentpatterns in the xenoliths on primitive mantle-normalized diagramsrange from Th–La–Ce ‘inflections’ inweakly metasomatized samples (normally without amphibole) toa continuous increase in abundances from Ho to Ce typical foramphibole-bearing xenoliths. Numerical modelling of interactionbetween depleted peridotites and enriched melts indicates thatthese patterns do not result from simple mixing of the two end-membersbut can be explained by chromatographic fractionation duringreactive porous melt flow, which produces a variety of enrichmentpatterns in a single event. Many metasomatized xenoliths havenegative high field strength element and Pb anomalies and Srspikes relative to rare earth elements of similar compatibility,and highly fractionated Nb/Ta and Zr/Hf. Although amphiboleprecipitation can produce Nb–Ta anomalies, some of thesefeatures cannot be attributed to percolation-related fractionationalone and have to be a signature of the initial melt (possiblycarbonate rich). In general, chemical and mineralogical fingerprintsof a metasomatic medium are strongest near its source (e.g.a vein) whereas element patterns farther in the metasomatic‘column’ are increasingly controlled by fractionationmechanisms. KEY WORDS: Spitsbergen; lithospheric mantle; metasomatism; trace elements; theoretical modelling  相似文献   

20.
Xenoliths from Engeln–Kempenich in the East Eifel volcanicfield (Germany) comprise gabbroic to ultramafic cumulates, andmeta-igneous and meta-sedimentary granulite- to amphibolite-facieslithologies. They provide evidence for Pleistocene heating andmetasomatism of the lower continental crust by mafic magmas.The metamorphic xenoliths were divided into three types: (1)primitive type P, which are little affected by metasomatic replacementstructures; (2) enriched type E1 defined by metasomatic replacementof primary pyroxene and garnet by pargasitic amphibole and biotite;(3) enriched type E2 defined by breakdown of hydrous phases.Type E rocks are geochemically related to type P and cumulatexenoliths by compositional trends. During modal metasomatism,type E rocks were oxidized. Type E1 rocks were typically enrichedin Rb, Th, U, Nb, K, light rare earth elements (LREE) and Zr,and E2 enriched in Rb, Th, U, Nb, K, REE, Zr, Ti and Y, relativeto type P rocks. Formation of the hydrous, chlorine-bearingphases amphibole and scapolite containing glass and fluid inclusionsin the E1 rocks provides evidence for a water and Cl-bearingfluid phase coexisting with silicate melt. Accordingly, we calculated10 mol % H2O back into the CO2-dominated fluid inclusions, inagreement with experimental data on the composition of a fluidphase coexisting with mafic alkaline melts at elevated pressure.Primary CO2-dominated fluid inclusions coexisting with glassinclusions in metamorphic corona phases and neoblasts, and incumulate xenoliths, have overlapping densities. Fluid inclusionbarometry using the corrected densities indicates that bothcumulates and metamorphic xenoliths originated from the samedepth at 22–25 km (650 ± 50 MPa). This is interpretedas being a main magma reservoir level within the upper partof the lower crust close to the Conrad discontinuity, wherethe xenoliths represent wall-rocks. The Conrad discontinuityseparates an upper-crustal layer, consisting of preferentiallyductile granodioritic and tonalitic gneisses, and more brittlelower-crustal mafic granulites. The brittle–ductile transitionappears to be a preferred level of magma stagnation. KEY WORDS: continental lower crust; fluids; magma chamber; metasomatism; xenoliths  相似文献   

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