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1.
《Gondwana Research》2002,5(2):453-465
The Kunduru Betta Ring Complex (KRC), at the southern margin of Dharwar craton, South India, comprises metaluminous sub-solvus syenites and quartz monzonite with a concentric disposition younging towards the center. An outer mafic syenite (of lamprophyric affinity) is followed by porphyritic monzonite, quartz monzodiorite and finally a quartz monzonitic stock at the centre.SiO2, Al2O3 and Na2O increase from the primitive lamprophyric mafic syenite to the quartz monzonite through the intermediate members, while CaO, MgO, Fe2O3T, TiO2, P2O5 and MnO show an opposite trend suggesting fractionation of hornblende, clinopyroxene, biotite, apatite, sphene, and iron oxide minerals. Rb, Th and U increase with a complementary decrease in Sc, V, Cr, Co, Cu, Sr and Ba from the outer mafic syenite to the inner quartz monzonite. Y, Zr and Hf decrease from lamprophyric mafic syenite to quartz monzodiorite and the trend is reversed in the final quartz monzonite phase. However, the suite is characterised by a compositional gap between quartz monzodiorite and quartz monzonite. Total REE gradually decrease from the mafic syenite to quartz monzonite and the REE distribution patterns show LREE-enriched and HREE-depleted parallel distributions with negligible Eu anomalies.The geochemical data suggest that the rock types were formed as products of progressive differentiation by crystal fractionation of calc-alkaline lamprophyric parent magma which was derived by partial melting of metasomatically enriched mantle in the Kabini lineament. Although the quartz monzonites conform to the trend of differentiated Kunduru Betta suite, the compositional gap between them and the quartz monzodiorite precludes their origin by simple differentiation. It is suggested that convective liquid fractionation might have resulted in the discrete body of quartz monzonite.  相似文献   

2.
The Boziguoer A-type granitoids in Baicheng County,Xinjiang,belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks.The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite,an aegirine or arfvedsonite alkali feldspar granite,and a biotite alkali feldspar syenite.The major rock-forming minerals are albite,K-feldspar,quartz,arfvedsonite,aegirine,and siderophyllite.The accessory minerals are mainly zircon,pyrochlore,thorite,fluorite,monazite,bastnaesite,xenotime,and astrophyllite.The chemical composition of the alkaline granitoids show that SiO2 varies from 64.55% to 72.29% with a mean value of 67.32%,Na2O+K2O is high (9.85%-11.87%) with a mean of 11.14%,K2O is 2.39%-5.47% (mean =4.73%),the K2O/Na2O ratios are 0.31-0.96,Al2O3 ranges from 12.58% to 15.44%,and total FeOT is between 2.35% and 5.65%.CaO,MgO,MnO,and TiO2 are low.The REE content is high and the total SREE is (263-1219) ppm (mean =776 ppm),showing LREE enrichment and HREE depletion with strong negative Eu anomalies.In addition,the chondrite-normalized REE patterns of the alkaline granitoids belong to the "seagull" pattern of the right-type.The Zr content is (113-1246) ppm (mean =594 ppm),Zr+Nb+Ce+Y is between (478-2203) ppm with a mean of 1362 ppm.Furthermore,the alkaline granitoids have high HFSE (Ga,Nb,Ta,Zr,and Hf) content and low LILE (Ba,K,and Sr) content.The Nb/Ta ratio varies from 7.23 to 32.59 (mean =16.59) and the Zr/Hf ratio is 16.69-58.04 (mean =36.80).The zircons are depleted in LREE and enriched in HREE.The chondrite-normalized REE patterns of the zircons are of the "seagull" pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly.The Boziguoer A-type granitoids share similar features with A1-type granites.The average temperature of the granitic magma was estimated at 832-839℃.The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature,anhydrous,and low oxygen fugacity conditions.  相似文献   

3.
A unique type of Nb–Zr–REE–Ga-enriched alkali tonstein of pyroclastic origin occurs exclusively within the late Permian coal measures of southwest China. The alkali tonsteins are located within the lowest Xuanwei or Longtan formations of Wuchiapingian age, indicating that their age is later than the main episode of Emeishan Large Igneous Province (ELIP) magmatism. The alkali tonsteins have intermediate–felsic Al2O3/TiO2 values (12.6–34.2, mean 22.0), light rare earth element-enriched chondrite-normalised patterns, negative δEu and incompatible element ratios similar to those of ELIP alkaline Nb–Ta-enriched syenites. All available evidence shows that the alkali tonsteins from southwest China originated from coeval ELIP alkaline magmatism. The enrichment of Nb–Zr–REE–Ga in alkali tonsteins is derived from the ELIP alkaline Nb–Ta-enriched volcanic ashes and may represent the last stage of mineralisation associated with the Emeishan mantle plume activity.  相似文献   

4.
The Mogou syenite intruded into the Mesoproterozoic Xiong’er Group is the main lithostratigraphic unit, along the southern margin of the North China Craton (NCC). This paper reports zircon LA-ICP-MS data, whole-rock major and trace element compositions of late Triassic magmatic rocks in the Mogou syenite, in order to constrain the formation age of the Mogou syenite, research the origin and evolution of the magma and analyse the geodynamic setting of the Qinling Orogen (QO) in Late Triassic. These rocks consist of medium- to coarse-grained syenite and fine-grained quartz syenite. Zircon U–Pb dating yields a crystallization age of 226.5±2.7 Ma. The syenites are characterized by high SiO2 (63.49–72.17%), alkali (K2O+Na2O of 11.18–15.38%) and potassium (K2O/Na2O of 2.88–28.11), are peralkaline or metaluminous (molar A/CNK of 0.87–1.02) and belong to shoshonite series. The syenites have ΣREE of 33.01–191.30 ppm, LREE/HREE of 14–20, (La/Yb)N of 11–24, with LREE-rich distribution pattern and obvious differentiation between HREE and LREE. Eu anomalies are positive for the medium- to coarse-grained syenite and weakly negative for the fine-grained quartz syenite. In addition, the syenites are enriched in large-ion lithophile elements (Ba, K, Sr, and Pb) but depleted in high strength field elements (Ti, Ta, Nb, Zr, and Hf), and have high differentiation indices of 91.69–97.06. These geochemical features indicate that the primary magma of the Mogou syenite most likely originated from a mantle source with minor crustal component, and underwent a fractional crystallization process during its emplacement. The late Triassic A-type Moguo syenite along the southern margin of the NCC was generated in the late stage of the syn-collision event of QO, recording a transition period from compression to extension at around 227 Ma.  相似文献   

5.
The Sharang porphyry Mo deposit is the first discovered Mo porphyry‐type deposit in the Gangdese Metallogenic Belt. The orebody is hosted by the Eocene multi‐stage composite intrusive complex which is emplaced in the Upper Permian Mengla Formation and cut by the Miocene dykes. Granite porphyry is recognized as the ore‐bearing porphyry in the complex, which consists of quartz diorite, quartz monzonite, granite, prophyritic granite and post‐mineral lamprophyre. Granodiorite porphyry and dacite porphyry intrude the granite porphyry. Geochemical data indicate that Sharang complex has a High‐K calc‐alkalinc to shoshonitic, metaluminous to slightly peraluminous composition. The Sharang complex rocks are enriched in large ion lithophile elements, depleted in high‐field strength elements, Nb, Sr, P and Ti. REE patterns show slight enrichments in light REE relative to heavy REE and weak negative Eu anomalies. All rocks in this complex have a wide range of initial 87Sr/86Sr ratios (0.705605~0.712496) and lower εNd(t) values (?0.61~?7.80). The geochemical data suggest highly oxidized‐evolved magma and old continental materials may have been the magma source for the Sharang intrusive complex that host porphyry Mo mineralization. Eocene pre‐ore and ore‐forming rocks at Sharang may have formed by partial melting of mantle wedge and by mixing with old continental crust at the lower crust level. In contrast the post‐ore rocks may have formed by partial melting of enriched lithospheric mantle.  相似文献   

6.
I. A. Andreeva 《Petrology》2016,24(5):462-476
Melt inclusions were studied by various methods, including electron and ion microprobe analysis, to determine the compositions of melts and mechanisms of formation of rare-metal peralkaline granites of the Khaldzan Buregtey massif in Mongolia. Primary crystalline and coexisting melt inclusions were found in quartz from the rare-metal granites of intrusive phase V. Among the crystalline inclusions, we identified potassium feldspar, albite, tuhualite, titanite, fluorite, and diverse rare-metal phases, including minerals of zirconium (zircon and gittinsite), niobium (pyrochlore), and rare earth elements (parisite). The observed crystalline inclusions reproduce almost the whole suite of major and accessory minerals of the rare-metal granites, which supports the possibility of their crystallization from a magmatic melt. Melt inclusions in quartz from these rocks are completely crystallized. Their daughter mineral assemblage includes quartz, microcline, aegirine, arfvedsonite, polylithionite, a zirconosilicate, pyrochlore, and a rare-earth fluorocarbonate. The melt inclusions were homogenized in an internally heated gas vessel at a temperature of 850°C and a pressure of 3 kbar. After the experiments, many inclusions were homogeneous and consisted of silicate glass. In addition to silicate glass, some inclusions contained tiny quench zircon crystals confined to the boundary of inclusions, which indicates that the melts were saturated in zircon. In a few inclusions, glass coexisted with a CO2 phase. This allowed us to estimate the content of CO2 in the inclusion as 1.5 wt %. The composition of glasses from the homogeneous melt inclusions is similar to the composition of the rare-metal granites, in particular, with respect to SiO2 (68–74 wt %), TiO2 (0.5–0.9 wt %), FeO (2.2–4.6 wt %), MgO (0.02 wt %), and Na2O + K2O (up to 8.5 wt %). On the other hand, the glasses of melt inclusions appeared to be strongly depleted compared with the rocks in CaO (0.22 and 4 wt %, respectively) and Al2O3 (5.5–7.0 and 9.6 wt %, respectively). The agpaitic index is 1.1–1.7. The melts contain up to 3 wt % H2O and 2–4 wt % F. The trace element analysis of glasses from homogenized melt inclusions in quartz showed that the rare-metal granites were formed from extensively evolved rare-metal alkaline melts with high contents of Zr, Nb, Th, U, Ta, Hf, Rb, Pb, Y, and REE, which reflects the metallogenic signature of the Khaldzan Buregtey deposit. The development of unique rare metal Zr–Nb–REE mineralization in these rocks is related to the prolonged crystallization differentiation of melts and assimilation of enclosing carbonate rocks.  相似文献   

7.
ABSTRACT

The Boein–Miandasht Complex (BMC) is a part of the Sanandaj–Sirjan metamorphic basement and is cut by gabbroic to granitoid bodies. These intrusive bodies comprise gabbro, gabbro–diorite associated with fine-grained, in part porphyritic leucocratic granitoids. Zircon U–Pb dating of representative gabbro–diorite samples yielded ages of 166.4 ± 1.8 Ma and 163.5 ± 6.3 Ma (Callovian, the latest stage of the Middle Jurassic). Mineral chemistry of the gabbro–diorites shows a homogeneous composition of the main minerals, main augite to diopside clinopyroxene and plagioclase (~An17–59). Moreover, low AlZ/TiO2 ratios of the clinopyroxene grains suggest that the rocks were generated in a within-plate tectonic regime. The SiO2 contents of the gabbro-diorite rocks are between 46.36 and 55.61 wt. %, Al2O3 ranges from 7.57 to 17.98 wt. %. The TiO2 contents vary from 1.18 to 3.65 wt. %, Fe2O3 from 7.41 to 12.95 wt. %, the MgO ranges between 3.49 and 15.75 wt. %, Na2O from 0.65 to 5.08 wt. % and K2O from 0.48 to 1.08 wt. %. These rocks mostly plot in the alkali-gabbro field. Compared to chondrite are characterized by enrichment of LREEs over HREE, enrichment of LIL elements (e.g. Rb, Sr and Ba) and obvious positive anomalies of Nb and Ti. Based on the chemical composition, and mineral composition, this complex was generated in an extensional tectonic regime by partial melting of the hot asthenospheric mantle which is not more consistent with previous models which have suggested for SaSZ evolution in before.  相似文献   

8.
刘园园  马昌前  吕昭英  黄卫平 《岩石学报》2012,28(10):3287-3305
长江中下游贵池地区燕山期侵入岩发育,与成矿关系密切.本文对该区侵入岩开展了详细的锆石U-Pb年代学、地球化学及Sr-Nd-Hf同位素研究.结果表明,马头花岗闪长斑岩形成于147±2Ma,而花园巩石英二长岩形成于127±1Ma,比花岗闪长斑岩晚约20Ma.早期的花岗闪长斑岩(147 ~ 145Ma)为高钾钙碱性系列,具有高Al2O3、Sr含量和Sr/Y、La/Yb比值,以及低的Y、Yb含量,与埃达克质岩的地球化学特征一致;而晚期石英二长岩(127Ma)和石英正长岩为钾玄岩系列,具有高的(Na2O+ K2O)、Zr、Nb、Y含量和Y/Nb、Yb/Ta比值,与造山带A2型花岗岩地球化学特征相似;碱长花岗岩(125~124Ma)同样具有A型花岗岩的地球化学特征,但与石英二长岩、石英正长岩相比,碱长花岗岩的Y/Nb、Yb/Ta比值相对较低,具板内环境A1型花岗岩的地球化学特征.因此,贵池地区岩浆岩从早期的埃达克质岩变为晚期的A型花岗岩,反应了晚中生代时期长江中下游地区的构造环境由大陆边缘环境向伸展环境的转变.  相似文献   

9.
ABSTRACT

The Mesozoic tectonic transition from the Palaeo-Tethys tectonic regime to the Palaeo-Pacific tectonic regime in the eastern South China Block has long been debated. Geochemical and zircon U–Pb–Hf isotopic studies were conducted on the Dashuang complex in the eastern Zhejiang Province. The Dashuang complex consists mainly of quartz syenite in the northwestern part and quartz monzonite in the southeastern part. New laser ablation inductively coupled plasma mass spectrometry zircon U–Pb data show that the quartz syenite, the quartz monzonite, and its chilled margin (fine-grained granite) crystallized at 235 ± 4 Ma, 232 ± 3 Ma, and 230 ± 1 Ma, respectively. The Dashuang complex intrudes into the Chencai Group gneiss that postdated ~646 Ma and underwent anatexis at 443 ± 14 Ma. The quartz monzonite shows A-type granite affinity, characterized by high K2O + Na2O and Zr + Nb + Ce + Y, high FeOT/(MgO + FeOT) and Ga/Al ratios, an enrichment in light rare earth elements, and depletions in Ba, Sr, and Eu. The quartz monzonite has zircon εHf(t) values of ?14.2 to –11.9 and two-stage model ages of 1788–1922 Ma. Zircon εHf(t) values of the chilled margin (fine-grained granite) and wall rock (gneiss) are scattered (?18.2 to –6.3 and ?19.5 to 10.2). The corresponding two-stage model ages are 1482–2133 Ma and 1184–2471 Ma, respectively. The Dashuang complex was derived mainly from partial melting of Neoproterozoic clastic rocks in the Cathaysia Block. Geochemical data indicate that the quartz monzonite formed in a post-collision extensional environment. These results, considered with previous data, indicate that the transition from the Palaeo-Tethys to the Palaeo-Pacific tectonic regimes of the eastern South China Block occurred during the Late Triassic (225–215 Ma).  相似文献   

10.
The South Platte pegmatite district is well known for its significant enrichment in the rare earth elements (REE), Y, Nb, F, and for the exceptionally well-developed internal zonation of the complex pegmatites located within a reversely zoned portion of the Pikes Peak batholith. Chemical trends both within and between pegmatites define the behavior of major and trace elements and the role of F in the fractionation of the granitic magma and pegmatitic fluids, suggesting a new model for the evolution of the granite-pegmatite system.Whole-rock XRF and INAA analyses of the host Pikes Peak granite and quartz monzonite and pegmatite wall zones provide strong evidence that all three are related by differentiation. With increasing SiO2, there is systematic enrichment in K2O, Na2O, and Rb, and depletion in CaO, MgO, FeO1, TiO2, P2O5, Ba, Sr, and Sc. REE, Y, Zr, and Th were strongly partitioned out of the wall zone into the final residual fluids where they were concentrated up to an order of magnitude over levels in the granite.Within the district, there is also chemical zonation of F, Nb, Th, U, and REE between groups of pegmatites. Polyzonal quartz-core types typically contain more fluorite, samarskite, HREE-zircon, and yttrian-fluorite than their bizonal composite-core counterparts, which contain only sparse fluorite and allanite.The sequence of magmatic evolution involved: (1) a process of diffusive differentiation and fractional crystallization which produced a chemically stratified magma chamber with a hotter more mafic quartz monzonitic base and a more felsic, granitic top enriched in H2O, F, HREE, Nb, and Y; (2) resurgence of the more mafic lower level crystal mush in to the upper more felsic part of the pluton; and (3) separation of pegmatitic fluids from the juxtaposed magmas giving rise to two compositionally distinct groups of pegmatites.  相似文献   

11.
Whole-rock major and trace element and Sr-Nd isotopic data, together with zircon LA ICPMS in-situ U-Pb and Hf isotopic data of the syenites and granites in the Tengchong Block are reported in order to understand their petrogenesis and tectonic implications. Zircon U-Pb data gives the emplacement ages of ca. 115.3±0.9 Ma for syenites and 115.7±0.8 Ma for granites, respectively. The syenites are characterized by low SiO_2 content(62.01–63.03 wt%) and notably high Na_2O content(7.04–7.24 wt%) and Na_2O/K_2O ratios(2.02–2.10), low MgO, Fe_2O_3 T and TiO_2, enrichment of LILEs(large-ion lithophile element) such as Rb, Th, U, K, and Pb) and obvious depletion HFSE(high field strength element; e.g. Nb, Ta, P, and Ti) with clearly negative Eu anomalies(d Eu=0.53–0.56). They also display significant negative whole-rock εNd(t) values of-6.8 and zircon εHf(t) values(-9.11 to-0.27, but one is +5.30) and high initial ~(87) Sr/~(86) Sr=0.713013. Based on the data obtained in this study, we suggest that the ca. 115.3 Ma syenites were possibly derived from a sodium-rich continental crustal source, and the fractionation of some ferro-magnesian mineral and plagioclase might occur during the evolution of magma. The granites have high SiO_2 content(71.35–74.47 wt%), metaluminous to peraluminous, low Rb/Ba, Rb/Sr, and Al_2O_3/(MgO+FeOT+TiO_2) ratios and moderate(Al_2O_3+MgO+FeOT+TiO_2) content. They show low initial ~(87) Sr/~(86) Sr(0.703408 to 0.704241) and εNd(t) values(-3.8 to-3.5), plotted into the evolutionary trend between basalts and lower crust. Hence, we suggest that the granites were derived from the melting of mixing sources in the ancient continental crust involving some metabasaltic materials and predominated metasedimentary greywackes. Together with data in the literatures, we infer that the Early Cretaceous magmatism in the Tengchong block was dominated by magmas generated by the partial melting of ancient crustal material, which represent the products that associated to the closure of Bangong-Nujiang Meso-Tethys.  相似文献   

12.
Diverse models have been proposed for the role of the Tarim Craton within the Paleoproterozoic Columbia supercontinent assembly. Here we report a suite of-1.71 Ga Nb-enriched meta-gabbro lenses in the eastern Quanji Massif, within the Tarim Craton in NW China. The meta-gabbroic rocks have Nb contents of 11.5-16.4 ppm with Nb/La ratios varying from 0.84 to 1.02((Nb/La)_N = 0.81-0.98) and Nb/U ratios from 38.0 to 47.2. They show low SiO_2(45.1-48.5 wt.%) and MgO(5.96-6.81 wt.%) and Mg#(Mg# = Mg/(Mg + Fe) = 43.5-47.7), high FeO~t(13.0-15.7 wt.%) and moderate Ti02(1.70-2.51 wt.%).with tholeiitic affinities. These rocks possess low fractionated REE patterns without obvious Eu anomalies(Eu/Eu~* = 0.87-1.02). Their primitive mantle-normalized elements patterns display significant Zr-Hf troughs, positive Nb anomalies, weak negative Ti and P anomalies, and high contents of Rb and Ba,resembling Nb-enriched basalts generated in arc-related tectonic settings. Their arc-like geochemical signatures together with whole rock εNd(t) values of 0.4-2.1 and corresponding old T_(DM)(2.22-2.37 Ga)as well as(~(143)Nd/~(144)Nd)_t and(~(87)Sr/~(86)Sr)t(t = 1712 Ma) values of 0.5104-0.5105 and 0.7030-0.7058,respectively, suggest that their precursor magma originated from mantle wedge peridotite metasomatised by subduction-derived melts. The results from our study reveal subduction along the eastern periphery of the Tarim Craton and marginal outgrowth continuing to ~1.7 Ga within the Columbia supercontinent.  相似文献   

13.
浙北地区位于扬子陆块东南缘,中生代岩浆侵入活动强烈,发育有何村石英二长岩、康山、沈家墈、泗岭花岗岩和凤凰山正长花岗岩等岩体。锆石LA-ICP-MS U-Pb定年结果表明,何村石英二长岩侵位时间为149.2±1.1 Ma,康山花岗岩形成于137.4±1.2 Ma,沈家墈、泗岭花岗岩和凤凰山正长花岗岩的成岩年龄在133.6±0.95 Ma~131.3±1.7 Ma之间。地球化学分析结果显示,何村石英二长岩为高钾钙碱性系列准过铝质I型花岗岩,高Rb、Th、U、K,贫Nb、Ta、Ti,中等的Eu负异常(δEu=0.78~0.79),具有类似岛弧岩浆岩的特征,锆石饱和温度为826~830℃。康山、沈家墈、泗岭花岗岩及凤凰山正长花岗岩地球化学特征相似,岩石富Si O2,高Ga、Zr、Nb和Y,贫Al2O3、Sr、Ba、Ti和P,强烈的Eu负异常(δEu=0.02~0.12);区别在于前者Fe2O3T含量为0.63%~0.89%,母岩浆温度为788~814℃,显示高分异I型特征;后三者Fe2O3T含量为1.02%~1.57%,母岩浆温度为847~868℃,属铝质A型花岗岩。锆石Hf同位素研究表明,何村石英二长岩和康山花岗岩εHf(t)变化范围分别集中在-3.79~-1.67和-6.59~-5.23之间,二阶段模式年龄(tDM2)变化范围对应于1162~1279 Ma和1350~1423 Ma,说明其源区物质可能主要来自中元古代地壳;沈家墈、泗岭花岗岩和凤凰山正长花岗岩εHf(t)主要集中在-4.24~2.48之间,tDM2主要集中于915~1161 Ma之间,说明岩体的源区物质来自于中-新元古代江南火山岛弧,εHf(t)值逐渐增大,表明越来越多的幔源物质或新生地壳参与成岩。浙北地区三类岩体分别形成于晚侏罗世古太平洋板块俯冲的挤压、早白垩世板块撤离挤压向伸展背景的转换和后造山拉张背景下岩石圈减薄等3个阶段。  相似文献   

14.
Epidote-bearing porphyritic dikes (whole rock analysis: SiO2?=?55–65 wt. %, MgO <2.1 wt. %, K2O <2.5 wt. %, Al2O3 >17 wt. %, Na2O + K2O?=?5.7–9.4 wt. %) situated in the continental margin zone, the Middle Urals, Russian Federation have been dated using SHRIMP U-Pb zircon techniques and give a Middle Devonian age of 388?±?2 Ma and 389?±?6 Ma. The porphyries contain phenocrysts of magmatic epidote (Ps?=?17–25 %), Ca- and Mn-rich (CaO >9 wt. %; MnO >6 wt. %) almandine garnet, Al-rich (Al2O3?=?12–16 wt. %) amphibole, titanite, plagioclase, biotite, muscovite, apatite, and quartz. 60 to 70 % groundmass of the porphyritic dikes consists of fine-grained albite, quartz, and K-feldspar. A variety of thermobarometric estimations, plus comparison with published experimental data indicate that the phenocryst assemblage was stable between 5 and 11 kbar and 690 to 800 °C. Oxygen fugacity was close to or greater than logfo2 = Ni-NiO + 1. Later stage formation of the quartz-feldspar groundmass took place at hypabyssal conditions, corresponding to 1 to 2 kbar and 660 to 690 °C. The porphyritic dikes are metaluminous to slightly peraluminous (ACNK?=?0.7–1.17). They are enriched in REE and depleted Nb and Ti. They show features typical of subduction-related magmas. Chemical composition and isotopic ratios of 86Sr/87Sri?=?0.709–0.720 suggest that both mantle- and deep crustal-derived materials were involved in their petrogenesis.  相似文献   

15.
安徽庐枞地区位于下扬子断陷带内,区内中生代岩浆活动强烈,壳幔交换频繁,形成了一系列A型花岗岩类,其中产有一些同源岩石包体。这些A型花岗岩类以富碱富钾为特征,为准铝质硅饱和岩石,具有高的104×Ga/Al比值和REE含量,明显富集Rb,Th,K等大离子亲石元素,而Nb,Ta,Ti和Zr等高场强元素和Sr,P相对亏损。与寄主岩相比,岩石包体SiO2和全碱含量偏低,Cr,Co,Sc,V等元素明显偏高,Zr和Eu的负异常不明显。包体和寄主岩的(87Sr/86Sr)i 值为0.7053~0.7089,εNd(t)值为-2.2~-8.66。这些资料表明,庐枞地区中生代A型花岗岩类是起源于富集岩石圈地幔的玄武质岩浆与地壳物质发生轻度同化混染作用,并经历结晶分异作用的产物,在岩浆演化过程中,结晶分异作用发挥着主导作用。从岩石组合来看,庐枞地区的A型花岗岩类主要由石英正长斑岩、正长斑岩、辉石二长岩和碱长花岗岩组成,属于碰撞后准铝质镁铁质-长英质岩套的一部分。岩石样品分析数据在Nb-Y-Ce,Nb-Y-3Ga和Rb/Nb-Y/Nb图上的投影结果表明,庐枞A型花岗岩类为碰撞后环境结束阶段的产物。结合区域地质背景分析,可以认为庐枞地区A型花岗岩类形成于岩石圈伸展背景下的碰撞后岩浆活动的末期,其出现可能标志着碰撞后环境的结束。  相似文献   

16.
The Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide (VMS) deposit occurs within the Surian volcano-sedimentary complex in the Sanandaj–Sirjan zone (SSZ) of southern Iran. The Surian complex is comprised of pelite, sandstone, calcareous shale, basalt, gabbro sills, and thin-bedded limestone. Mineralization occurs as stratiform sheet-like and tabular orebodies hosted mainly by greenschist metamorphosed feldspathic and quartz feldspathic sandstone, basalt, and pelites. The basalts of the Surian complex show predominantly tholeiitic to transitional affinities, with a few samples that are alkalic in composition. Primitive mantle-normalized trace and rare earth element (REE) patterns of the Surian basalts display depletions in light REE, negative anomalies of Nb, Ta, and Ti, and positive anomalies of P. Positive P anomalies are indicative of minor crustal contamination. Furthermore, Th enrichments in the mid-ocean ridge basalt-normalized patterns of the Surian basalts are characteristic of rifted arc basalts emplaced in continental margin subduction zones. The high MgO content (>6?wt.%) of most Surian basalts and low TiO2 content of two samples (0.53 and 0.62?wt.%) are characteristic of boninites. The aforementioned features of the basalts indicate arc tholeiites emplaced in intra-arc rift environments and continental margin subduction zones. U–Pb dating by laser ablation- inductively coupled plasma mass spectrometry of detrital zircons extracted from the host feldspathic and quartz feldspathic sandstone yields various ages that are predominantly Permian and Triassic; however, the youngest zircons give a mean Early Jurassic concordant U–Pb age of 191?±?12?Ma. This age, together with geological and petrochemical data, indicate that VMS mineralization formed in the Early Jurassic in pull-apart basins within the SSZ. These basins and the VMS mineralization may be temporally related to an intra-arc volcano–plutonic event associated with Neo-Tethyan oblique subduction.  相似文献   

17.
Late Cretaceous Bayazeh dyke swarm is situated in the western part of the Central-East Iranian Microcontinent (CEIM). These dykes with a dominant northeast-southwest trend occur in the Eastern margin of the Yazd block. They cross cut the Lower Cretaceous sedimentary rocks. The length of the Bayazeh dykes occasionally reaches up to the 2 km. Rock forming minerals of these dykes are plagioclase (andesine and oligoclase), amphibole (magnesio-hastingsitic hornblende, magnesio-hornblende and tschermakitic hornblende), quartz, K-feldspar (orthoclase), zircon and apatite. Secondary minerals are chlorite (pycnochlorite), albite, magnetite and calcite. The main textures are porphyritic, glomeroporphyritic and poikilitic. The felsic character of the Bayazeh dacitic dykes is shown by their high SiO2 (62.70 to 64.60 wt %) and low [Fe2O3* + MgO + MnO + TiO2] (average 4.64 wt %) contents. These dykes represent the peraluminous to metaluminous nature and their Na2O and K2O values are 5.20–7.14 and 1.51–2.59 wt %, respectively, which reveal their sodic chemistry. The trace element characteristics are the LREE enrichment relative to HREE, [La/Yb]CN = 13.27–22.99, and slightly negative or positive Eu anomaly. These geochemical characteristics associated with low Nb/La (0.16–0.25), Yb/Nd (0.04–0.05) and high Zr/Sm (37.60–58.25) ratios indicate that the melting of a metamorphosed subducted oceanic crust is occurred where the residual mineral assemblage is dominated by garnet amphibolite. The chemical compositions of the Bayazeh dykes resemble those of slab-derived tonalite-trondhjemite-granodiorite (TTG) series. They were formed by subduction of Mesozoic Neo-Tethys -related Nain and Ashin oceanic crusts.  相似文献   

18.
The Qimantagh area of Northwest China lies in the western part of the East Kunlun Orogenic Belt and is characterized by extensive magmatism, particularly in the Triassic. However, recent research has shown that Devonian magmatism was also widespread in this area and has a genetic relationship with mineralization. This article presents a detailed study of three types of Early Devonian intrusions: high-K calc-alkaline granites, A-type granites, and mafic intrusions, all from the Qimantagh region. These rocks were subjected to precise zircon U–Pb dating, major and trace element analyses, and Sr–Nd isotope measurements, focusing on the Lalingzaohuo (eastern Qimantagh) and Yemaquan (central Qimantagh) monzogranites, as well as the coeval Tanbeixuefeng (western Qimantagh) mafic dike swarm. To better understand the Early Devonian igneous activity in the Eastern Kunlun, data for other coeval granitoids were compared with our data. The Yemaquan monzogranite yielded a mean zircon U–Pb age of 400.5 ± 1.4 Ma. These rocks are metaluminous to slightly peraluminous, with Al2O3 contents of 13.10–14.16 wt.%, high alkali contents (total K2O + Na2O) of 6.89–7.68 wt.%, relatively low Sr contents (79–192 ppm), and high (La/Yb)N ratios, all of which indicate an I-type granite affinity. The Lalingzaohuo monzogranites yielded mean zircon U–Pb ages of 396.2–402.2 Ma. These rocks have higher SiO2 and alkali contents than the Yemaquan monzogranite, with high 10,000 Ga/Al ratios, high Zr + Nb + Ce + Y contents, high Fe2O3T/MgO ratios, and high Y contents, indicating an A-type granite affinity. These two monzogranites have initial 87Sr/86Sr ratios of 0.703–0.706 and εNd(t) values of –0.1 to –0.7. The Sr–Nd isotopic data require a significant input of a mantle component in the petrogenesis of these granites. The Tanbeixuefeng diabase dikes formed at ~396 Ma and have a continental tholeiitic affinity, as evident from small Ti–Nb–Ta anomalies and high contents of light rare earth and large-ion lithophile elements. We propose that post-collisional slab break-off was responsible for the generation of these Early Devonian intrusions in the Qimantagh area.  相似文献   

19.
在野外地质调查的基础上,结合室内显微镜观察及电子探针分析测试,对新疆拜城波孜果尔碱性岩中的副矿物的矿物学特征和化学成分进行了研究.发现这些副矿物常以共生组合的形式产在碱性岩中,主要分布在石英二长闪长岩和石英二长岩中.烧绿石中U、Th和REE替代Ca、Na.独居石富含LREE,Th和LREE相互替代;根据独居石中w(La+ Ce) >40%和La/Nd比值在1.6~4.5,推断独居石为热液成因.磷钇矿中富含REE,且以HREE为主;w(Th)>w(U).锆石中Zr/Hf比值在60%以上,符合碱性岩特征;其Th/U比值为0.6,属于岩浆锆石.星叶石中w(Rb2O)、w(Cs2O)较高.萤石中Y、Ce替代Ca.锆石中的钍石w(U)明显高于磁铁矿中钍石w(U).在石英二长岩中,烧绿石的w(CaO)、w(TiO2)、w(ZrO2)、w(U3O8),磷钇矿的w(Y2O3),星叶石的w(TiO2),萤石的w(Ca),氟碳铈镧矿的w(CaO)较丰富;而在石英二长闪长岩中,烧绿石的w(Ce2O3),磷钇矿的REE含量,星叶石的w(Nb2O5)、w(Rb2O),萤石w(Ce)、w(Y)和氟碳铈镧矿的w(La2O3)较高.  相似文献   

20.
The petrography, mineral chemistry and geochemical features of the Sabongari alkaline complex are presented and discussed in this paper with the aim of constraining its petrogenesis and comparing it with other alkaline complexes of the Cameroon Line. The complex is mainly made up of felsic rocks: (i) granites predominate and include pyroxene–amphibole (the most abundant), amphibole–biotite, biotite and pyroxene types; (ii) syenites are subordinate and comprise amphibole–pyroxene and amphibole–biotite quartz syenites; (iii) pyroxene–amphibole–biotite trachyte and (iv) relatively abundant rhyolite. The minor basic and intermediate terms associated with felsic rocks consist of basanites, microdiorite and monzodioites. Two groups of pyroxene bearing rocks are distinguished: a basanite–trachyte–granite (Group 1) bimodal series (SiO2 gap: 44 and 63 wt.%) and a basanite–microdiorite–monzodiorite–syenite–granite (Group 2) less pronounced bimodal series (reduced SiO2 gap: 56–67 wt.%). Both are metaluminous to peralkaline whereas felsic rocks bare of pyroxene (Group 3) are metaluminous to peraluminous. The Group 1 basanite is SiO2-undersaturated (modal analcite in the groundmass and 11.04 wt.% normative nepheline); its Ni (240 ppm) and Cr (450 ppm) contents, near mantle values, indicate its most primitive character. The Group 2 basanite is rather slightly SiO2-saturated (1.56 wt.% normative hypersthene), a marker of its high crustal contamination (low Nb/Y-high Rb/Y). The La/Yb and Gd/Yb values of both basanites (1: 19.47 and 2.92; 2: 9.09 and 2.23) suggest their common parental magma composition, and their crystallization through two episodes of partial melting (2% and 3% respectively) of a lherzolite mantle source with <4% residual garnet. The effects of crustal contamination were selectively felt in the values of HFSE/LREE, LREE/LILE and LREE/HFSE ratios, known as indicators. Similar features have been recently obtained in the felsic lavas of the Cameroon Volcanic Line.  相似文献   

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