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文章以水口山矿田内的3个典型铅锌多金属矿床——康家湾铅锌金银矿床、老鸦巢铅锌金矿床和鸭公塘铅锌铁铜矿床的矿石为研究对象,通过野外地质调查、室内显微鉴定、电子探针分析和LA-ICPMS微量元素分析测试,研究了本区稀散元素的赋存状态、分布规律以及与主成矿元素(Pb、Zn、S、Fe)的关系等,总结出稀散元素在本区的富集规律.研究表明:本区矿石中闪锌矿、黄铁矿、黄铜矿、方铅矿主要富集Cd、In、Te3种稀散元素.康家湾铅锌金银矿床In/Zn比值为0.86,老鸦巢铅锌金矿床In/Zn比值为5.10,而鸭公塘铅锌铁铜矿床In/Zn比值为611.20,且w(In)为33.83×10-6～365.62×10-6,因此,康家湾铅锌金银矿床和老鸦巢铅锌金矿床矿石中的In是以类质同象赋存于闪锌矿和黄铜矿的晶格中,而鸭公塘铅锌铁铜矿床矿石中的In可能以硫铟铜矿的形式赋存.水口山矿田的Te主要有2种赋存形式:一种以类质同象形式赋存于硫化物(黄铁矿)中;另一种以矿石中形成其独立矿物辉碲铋矿(分子式为Bi2TeS2)和碲银矿(分子式为Ag2Te)存在. 相似文献
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C. Trepka-Bloch 《Mineralium Deposita》1985,20(1):23-29
The Näsliden and Rävliden deposits in the Skellefte field consist of stratiform massive sulfide ores associated with submarine volcanic and clastic rocks. The ores are pretectonic. Consequently, the orebodies are considered to have formed syngenetically with deposition of the host rocks. Banding and interlayering with host sediments are common features. Cu : Zn and Zn : Pb ratios of the ores show stratigraphically and laterally defined trends. Cu : Pb : Zn ratios correspond with those found in other deposits of volcanogenic origin. Nonstratiform breccia Cu mineralizations occur directly under the massive stratiform ores in the footwall rocks where hydrothermal alteration is strongest. Ore formation took place intermittently resulting in clusters of ore systems occurring at slightly different stratigraphical levels within each deposit. 相似文献
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All varieties of base metal sulphide deposits may be classified using base metal ratios viz. Copper Ratio (CR=100Cu/{Cu+Zn}), Zinc Ratio (ZR=100Zn/{Zn+Pb}) and Lead Ratio (PR=100Pb/{Pb+Cu}). Based on this ore group classification an attempt has been made to identify ore groups present in the late Archaean volcanic associated Ingaldhal Sulphide Deposit (ISD) of Karnataka Craton. Using base metal ratios (CR, ZR and PR) five distinct fields are suggested: Cu, Cu-Zn, Cu-Zn-Pb, Zn-Cu and Zn-Cu-Pb/Zn-Pb-Cu with their associated geological and geochemical characteristics. A transitional change in the ore groups is observed from the North Block (Cu rich groups; CR>50) to South Block (Zn and Pb dominated groups; CR<50) and the Main Block is represented by all the five ore groups.This classification may be useful as a pointer in the exploration of polymetallic base metal deposits. Copper rich groups (Cu, Cu-Zn and Cu-Zn-Pb) exhibit high concentration of Bi and Co, and low CaO and Cd whereas the Zn rich groups (Zn-Cu and Zn-Cu-Pb/Zn-Pb-Cu) show high CaO and Cd, and low Bi and Co. The CR of most of the ore groups exhibit a sympathetic relation with Co and Ag. A preliminary attempt has been made for better understanding of ore group genesis of ISD by integrating ore group characteristics with deduced geothermometry. 相似文献
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闽中梅仙丁家山铅锌矿床硫化物微量元素地球化学特征及其成矿意义 总被引：1，自引：1，他引：0
梅仙丁家山铅锌矿床是闽中新元古代马面山群中多个大中型铅锌多金属矿床的典型代表.本文以丁家山铅锌矿床两类矿石(含磁黄铁矿矿石和含磁铁矿矿石)内的闪锌矿和黄铁矿为研究对象,通过电子探针及LA-ICP-MS微量元素分析技术,揭示二者的微量元素组成和赋存状态,探讨成矿温度及矿床成因方面的重要信息.分析结果显示:闪锌矿内Fe、Mn、Cd、Cu、In、Pb、Bi元素较为富集,两类矿石内的闪锌矿除Fe元素含量相差较大以外(平均值分别为9.3％和1.7％),其他元素含量并无明显差异;电子探针面扫描和LA-ICP-MS剥蚀图像显示元素Mn、Cd、In以类质同象形式存在,而Fe、Cu、Pb、Bi则有类质同象和显微包体2种存在形式.黄铁矿微量元素含量整体较低,元素Co、Ni、Pb、Bi相对富集,Ni、Mn主要以类质同象形式存在,Cu、Co有类质同象替换和显微包体2种形式,Pb、Bi主要以方铅矿包体形式存在.两类矿石中的闪锌矿Zn/Cd比值分别在120～150之间和93～210之间,均指示中温成矿条件.两类闪锌矿内Fe、Cd、Mn元素含量特征与典型矽卡岩型矿床内的闪锌矿相吻合;矿床内硫化物硫同位素组成揭示成矿物质来自于岩浆岩.上述证据共同支持梅仙丁家山铅锌矿矿床属矽卡岩型矿床. 相似文献
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Song Xuexin 《Mineralium Deposita》1984,19(2):95-104
The Fankou Pb-Zn deposit occurs in the Middle-Upper Devonian and Lower Carboniferous carbonate and argillaceous carbonate formations. In principle, the deposit can be classified as a carbonate-hosted strate-bound deposit. Representative sphalerite, galena, and pyrite separates from Fankou have been analysed. For the purpose of comparison a literature survey on minor elements of other districts have been carried out. The comparison of determined data with the quoted data shows that the Fankou sphalerites are rich in Ga, Ge and Ag, but poor in Se and Te; the Fankou galenas are rich in Ag, Hg, Sb and As, but poor in Se, Te, Tl and Bi; the Fankou pyrites are rich in As, Cd and In, but poor in Se, Te, Co and Ni. Zn/Cd and Se/S×10–4 ratios for sphalerites, Sb/Ag, Sb/Bi and Se/S×10–4 ratios for galenas and Co/Ni ratios for pyrites from Fankou and other districts have been calculated. Ga-Ge-Ag atomic ratios in sphalerites, Sb-Bi-Ag atomic ratios in galenas and Co-Ni relations in pyrites have been plotted. The average value (311) of Zn/Cd ratios for sphalerites from Fankou is similar to values of sphalerites from Gaobanhe, Heqing, Accesa and Broken Hill. The average Sb/Ag ratio (0.74) and the Sb-Bi-Ag atomic ratios in Fankou galenas are similar to those in the syngenetic galena from the British Island. The Ga-Ge-Ag atomic ratios for Fankou sphalerites are similar to those for the syngenetic sphalerites and Gorno sphalerites. The average Co/Ni ratio (1.1) for micro to fine-grained pyrites from Fankou laminated-bedded pyrite ore is similar to that (0.8) for the sedimentary pyrites from other districts. As to the fine to medium-grained pyrites from Fankou massive pyritic ores, their higher Co/Ni ratios (1.6–1.8) may relate to the fact that more Ni is lost than Co, during the reformation or recrystallization. Sphalerite, galena and pyrite from Fankou all are rather poor in Se and have very low values of Se/S×10–4, so they may bear no genetic relation to volcanism. To sum up, the following conclusions can be reached: (1) The Fankou deposit possesses some syngenetic features. (2) Evidently it differs from skarn type, hydrothermal type, and volcanogenic type deposits. (3) Surely it is a reformed sedimentary Pb-Zn deposit. 相似文献
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分散元素在地壳中的含量很低,很难形成独立矿物和独立矿床,因此对矿床中伴生的分散元素的研究有重要的理论和现实意义。本文利用常规显微镜、电子探针和等离子质谱分析等手段,对大梁子铅锌矿床中的分散元素镉、锗、镓进行了研究。镉在闪锌矿中的含量随着闪锌矿颜色的变浅逐渐增加,镓则相反。分散元素镉、锗、镓的赋存状态为类质同象形式;矿床主要以富集镉为特征,其中镉主要富集于闪锌矿中,锗和镓主要富集于方铅矿中。 相似文献
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Chuanwei Zhu Hanjie Wen Yuxu Zhang Zhilong Huang Christophe Cloquet Béatrice Luais Tao Yang 《地学前缘(英文版)》2021,12(6):162-170
The Sichuan-Yunnan-Guizhou(SYG)Zn-Pb metallogenic zone in SW China contains＞400 carbonate-hosted hydrothermal Zn-Pb deposits.Some of these,such as the Huize,Tianbaoshan,and Daliangzi deposits,are super-large deposits with significant reserves of Cd,Ge,and Ag.However,the sources of these metals remain controversial.This study investigated the Cd isotopic geochemistry of the Huize deposit,the largest Zn-Pb deposit in the SYG area.Sphalerites formed at three stages in the deposit have different colors:black or dark brown(Stage Ⅰ),red(Stage Ⅱ),and light-yellow(Stage Ⅲ).The δ114/110Cd values of the sphalerites are in the order Stage Ⅲ＜Stage Ⅰ＜Stage Ⅱ.Kinetic isotopic fractionation is likely the key factor causing the lower δ114/110Cd values in the early formed Stage Ⅰ sphalerites than in later-formed Stage Ⅱ sphalerites,with cooling of ore-forming fluids being responsible for the still lower values of the Stage Ⅲ sphalerites.In galena,the δ114/110Cd values are inversely correlated with Cd contents and tend to be higher in high-Zn galena.We speculate that Cd isotopic fractionation was significant during the precipitation of sphalerite and galena,with light Cd isotopes being enriched in galena rather than sphalerite.Comparison of the Cd isotopic signatures and Zn/Cd ratios of different endmembers suggests that the δ114/110Cd values and Zn/Cd ratios of sphalerite from the Huize deposit,as well as other large-scale deposits from the SYG area,are lie in those range of Emeishan basalts and sedimentary rocks and the mean δ114/110Cd values of these deposits show good negative correlation with 1/Cd,suggesting that the ore-forming materials of these deposits were derived from the mixing of Emeishan basalts and sed-imentary rocks.This study demonstrates that Cd isotopes can be useful proxies in elucidating ore genesis in large Zn-Pb deposits. 相似文献
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西太平洋冲绳海槽烟囱硫化物矿床矿石化学特征与分带型式 总被引：12，自引：0，他引：12
西太平洋冲绳海槽烟囱式硫化物矿床分布于琉球弧后扩张盆地、产于尹是名洼陷盆地（深１４００ｍ），其特征与日本黑矿类似。硫化物矿石及烟囱主要有３种化学类型：Ｐｂ－Ｚｎ－Ｂａ型、Ｚｎ－Ｐｂ型和Ｃｕ－Ｚｎ型，三者分别代表温度不断升高的热液体系的早、中、晚３个成矿阶段产物，其中，Ｐｂ－Ｚｎ－Ｂａ矿石及烟囱形成于高ｆｏ２环境和高流速、低温、富Ｐｂ、Ｚｎ、Ｂａ热液体系，Ｃｕ－Ｚｎ矿石及烟囱形成于低流速、高温、富Ｃｕ热液体系，Ｚｎ－Ｐｂ矿石则介于其间。硫化物烟囱显示明显的矿物－化学分带。在Ｐｂ－Ｚｎ－Ｂａ矿石（烟囱），Ｚｎ、Ｃｄ集中于烟囱中央，Ｂａ、Ｆｅ、Ａｓ、Ｓｂ、Ａｇ、Ｐｂ集中于烟囱外带，Ｃｕ则富集于烟囱中外部。在Ｃｕ－Ｚｎ矿石，Ａｓ、Ｓｂ、Ｆｅ、Ａｇ、Ａｕ仍富集于烟囱外带，Ｃｕ、Ｚｎ、Ｐｂ则在烟囱中央富集。依此元素化学分带型式，建立了古代黑矿硫化物矿体分带与硫化物堆积模式。 相似文献
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铂族元素矿床地球化学勘查的战略和技术 总被引：11，自引：1，他引：11
最近10年，PGE地球化学勘查取得许多进展，在此对主要进展作一简短的评述。①通过对已知其它金属矿床的再认识和再评价，发现新类型PGE矿床；②通过对已知PGE矿床的地球化学勘查，发现新的找矿靶区；③在空白区通过PGE地球化学填图，发现规模巨大的PGE地球化学省或巨省，为寻找PGE矿床提供了直接的找矿信息。根据中国的具体情况提出了中国PGE地球化学勘查的战略目标是：采用迅速，掌握全局，逐步缩小靶区的找矿战略，力争用5-10a时间使PGE矿床找矿获得重大突破。部署工作应以西南Pt、Pd地球化学省、新-甘-青Pt 相似文献
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Manganese ore deposits in Koira-Noamundi province of Iron Ore Group, north Orissa, India: In the light of geochemical signature 总被引：1，自引：0，他引：1
Several small Mn–Fe oxide and Mn-oxide ore bodies associated with Precambrian Iron Ore Group of rocks are located within Koira-Noamundi province of north Orissa, India. These deposits are classified into in situ (stratiform), remobilized (stratabound) and reworked categories based on their field disposition. Volcaniclastic/terrigenous shale in large geographic extension is associated with these ore bodies.The in situ ore bodies are characterised by cryptomelane-, romanechite- and hematite-dominating minerals, low Mn/Fe ratio (1.1) and relatively lower abundance of trace (1500–2500 ppm) constituents. In such type of deposits the stratigraphic conformity of oxides with the tuffaceous shale suggests precipitation of Mn and Fe at a time of decreased volcaniclastic/terrigenous contribution. The minor and trace elements were removed from solution by adsorption rather than by precipitation. Both Mn and Fe oxides when precipitated adsorb trace elements strongly but the partitioning of elements takes place during diagenesis. The inter-elemental relationship reveals that Cu, Co, Ni, Pb and Zn were adsorbed on precipitating hydrous Mn oxides and form manganates. Some of these elements probably get desorbed from Fe oxide because of their inability to substitute for Fe3+ in the lattice of its oxide. However, P, V, As and Mo were less partitioned and retained in Fe-oxide phase. Positive correlation between Al2O3 and SiO2, MgO, Na2O, TiO2 and some traces like Li, Nb, Sc, Y, Zr, Th and U points to their contribution through volcaniclastic/terrigenous detritus of both mafic and acidic composition.The remobilized ore bodies are developed in a later stage through dissolution, remobilization and reprecipitation of Mn oxides in favorable structural weak planes under supergene environment. Increase in average Mn/Fe ratio (8) and trace content (5000–8500 ppm) by 5–2.5 orders of magnitude, respectively, or more above its abundance in adjoining/underlying protore is characteristic of these deposits. The newly formed Mn ores constituting lithiophorite, cryptomelane/romanechite and goethite get quantitatively enriched in traces like Cu, Co, Ni, Pb and Zn. Positive correlation between Mn, Li, Co and Zn is due to the formation of mineral of lithiophorite–chalcophanite group during redistribution and reconcentration of Mn oxide. P and V, which were present in Fe oxide, also get dissolved and reprecipitate with Fe oxyhydroxide in these ores. Some other elements like Y, Th and U show positive relation with Fe. This is probably due to leaching of these elements during chemical weathering of associated shale and getting re-adsorbed in Fe-oxyhydroxide phase.However, under oxidizing environment selective cations like Ba, K, etc. resorb from Mn-structure, resulting in the development of pyrolusite (Mn/Fe>20). In such transformation, trace metals from pyrolusitic structure expels out, resulting thereby in a considerable reduction in total trace value (<3000 ppm).The reworked ore bodies are allochthonous in nature and developed through a number of stages during terrain evolution and lateritisation. Secondary processes such as reworking of pre-existing crust; solution and remobilization; precipitation and cementation and transport, etc. are responsible for their development. Such deposits are usually very low in Mn/Fe ratio (3) and trace content (<2000 ppm). 相似文献
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Major minerals (sulfates, sulfides, quartz) are distributed in different parts of submarine hydrothermal ore deposits. For instance, the abundance of barite increases stratigraphically upwards in the massive orebodies of the Kuroko deposits (black and yellow ores), while quartz is abundant in the lower parts (siliceous ore). The different distribution of barite and quartz in the Kuroko deposits can not be accounted for by thermochemical equilibrium calculations based on the precipitation due to mixing of ascending hydrothermal solutions with ambient cold seawater. In the present study, a coupled fluid flow‐precipitation kinetics model was used to calculate the amounts of quartz, barite, and anhydrite precipitated from a hydrothermal solution mixed with seawater, assuming reasonable values for temperature, precipitation rate, fluid flow velocity, mineral surface area/fluid mass ratio (A/M), and initial concentrations of hydrothermal solution and seawater before mixing occurred. The results indicate that barite precipitates more efficiently than quartz from discharging fluids with relatively higher flow velocity, lower temperatures and under the condition of lower A/M ratios on the seafloor (black ore), whereas quartz precipitates more effectively from solutions with lower flow velocity, higher temperatures and higher A/M ratios beneath the seafloor (siliceous ore) and in the orebody (barite ore, ferruginous chert ore). Anhydrite precipitates in shallow sub‐seafloor environments with lower precipitation rates and higher A/M ratios than barite and higher precipitation rates and lower A/M ratios than quartz. These results explain the observed occurrences of barite, anhydrite, and quartz in the Kuroko deposits. Namely, barite is abundant in black ore and barite ore which formed above the seafloor, anhydrite formed in high‐permeability tuff breccias, and quartz formed in low permeability dacite intrusive bodies in the sub‐seafloor environment. 相似文献
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黄岗梁铁锡矿床位于大兴安岭中南段晚古生代增生造山带。矿区内闪锌矿产于矽卡岩中,可分为浸染状和层纹状闪锌矿。本文对两种闪锌矿进行了高精度LA-ICP-MS元素含量测试,结果表明矿区两种闪锌矿具有相同成因特征,闪锌矿中Mn、Cu、As、In较富集,Ga、Ge、Cd含量较低,而As、Sn、Bi、Pb含量变化较大。Cu、Sn、Bi、Pb等元素在闪锌矿中以独立矿物赋存,Mn、Fe、Ga、Ge、Cd、In、Sb以类质同像形式赋存在闪锌矿晶格中。In/Ga、In/Ge比值较低,Zn/Cd比值为233~250,指示闪锌矿形成于中高温环境。Cd/Fe、Cd/Mn比值分别小于0.1和0.5,指示闪锌矿成因与岩浆活动有关,In Ge特征图解也指示其矽卡岩成因。通过与国内外典型矿床闪锌矿微量元素特征对比,结合矿床地质特征认为黄岗梁铁锡矿床中闪锌矿属于与燕山期岩浆作用有关的中高温矽卡型闪锌矿。 相似文献
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上庄坪铅锌银矿床是新一轮国土资源大调查中在北秦岭二郎坪群发现的硫化物矿床。笔者通过对矿床矿石、容矿同岩、重晶石岩的微量、稀土元素地球化学特征分析和地质特征研究,探讨成矿构造环境、成矿物质来源及矿床成因问题。研究表明.矿石和容矿围岩稀土元素球粒陨石标准化组成模式均为右倾型.矿石与围岩在Cu-Pb-Zn判别图解中投点区域一致.矿石Zn/(Zn Pb)与冲绳海槽和上向黑矿矿石特征相似、与TAG和EPR13°N区硫化物存在差异.矿石具较高As、Sb和Pb与低Cu、Cd和Se元素特征.认为该矿床成矿元素来源于壳幔混合、但以壳源为主的围岩变(石英)角斑岩和变细碧岩。矿石稀土元素、微量元素地球化学特征、矿床地质特征及与热水沉积重晶石岩和硅质岩的紧密共生关系说明,上庄坪矿床是弧后盆地构造环境海底热液喷流成岩成矿作用的产物。重晶石岩、硅质岩、矿床纵向和横向分带是寻找和勘探该类矿床的重要标志和依据。 相似文献
15.
PENGRunmin ZHAIYusheng 《《地质学报》英文版》2004,78(2):534-547
Most ore-forming characteristics of the Langshan-Zha‘ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha‘ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical zonation of sulfides; (5) The Cu/(Pb Zn Cu) ratio of the large and thick Pb Zn Cu orebodies gradually decreases from bottom to top; and (6) barite is interbedded with pyrites and sometimes with sphalerite. However, some characteristics such as the Co/Ni radio of the pyrites, the volcanism, for example, of the Langshan-Zha‘ertalshan metallogenic belt, are different from those of the typical SEDEX deposits of the world. The meta-basic volcanic rock in Huogeqi, the sodic bimodal volcanic rocks in the Dongshengmiao and potassic bimodal-volcanic rocks with blastoporphyfitic and blasto-glomeroporphyritic texture as well as blasto-amygdaloidal structure in the Tanyaokou deposits have been discovered in the only ore-bearing second formation of the Langshan Group in the past 10 years. The metallogeny of some deposits hosted in the Langshan Group is closely related to syn-sedimentary volcanism based on the following facts: most of the lead isotopes in sphalerite, galena, pyrite, pyrrhotite and chalcopyrite plot on both sides of the line for the mantle or between the lines for the mantle and lower crust in the lead isotope composition diagram; cobalt content of some pyrites samples is much higher than the nickel content (Co/Ni= 11.91-12.19). Some volcanic blocks and debris have been picked out from some pyritic and pyrrhotitic ores. All Zn-Pb-Cu-Fe sulfide orebodies in these deposits occur in the strata overlying metamorphic volcanic rocks in the only ore-bearing second formation. In the Jiashengpan deposit that lacks syn-sedimentary volcanic rocks in the host succession only Pb and Zn ores occur without Cu ore, but in the Dongshengmiao, Tanyaokou and Huogeqi deposits with syn-sedimentary volcanic rocks in the host succession Cu ores occur. This indicates a relatively higher ore-forming temperature. The process of synsedimentary volcanic eruption directly supplied some ore-forming elements, and resulted in secular geothermal anomaly favorable for the circulation of a submarine convective hydrothermal system, which accounts for the precipitation of deep mineralizing fluids exhaling into anoxidic basins along the syn-sedimentary fault system in the Langshan-Zha‘ertai rift. The Dongshengmiao, Tanyaokou, and Huogeqi deposits hosted in the Langshan Group appear to be a transitional type of mineral deposit between SEDEX and VMS-types but with a bias towards SEDEX, while the Jiashengpan deposit hosted in the Zha‘ertai Group is of a characteristic SEDEX type. This evidence, together with other new discoveries of Mesoproterozoic volcanic rocks and the features of lithogeny and metallogeny of the Bayun Obo deposit in the neighborhood emphasize the diversity, complexity and uniqueness of the Mesoproterozoic Langshan-Zha‘ertal-Bayun Obo ore belt. 相似文献
16.
作为华南大面积低温成矿域的重要组成部分,川滇黔铅锌矿集区是我国重要的铅锌银等资源基地之一,同时该矿集区也是Ge、Cd、Ga和In等稀散元素的超常富集区域。毛坪矿床是该矿集区内第二大铅锌矿床,累计探明铅锌金属储量超过3Mt(Pb+Zn平均品位≥18%),锗(Ge)保有储量182t。本文以新发现的Ⅵ矿带(铅锌金属已探明储量≥60万t,Pb+Zn平均品位≥20%)为研究对象,利用LA-ICPMS对主要矿石矿物闪锌矿和黄铁矿进行了微区原位微量元素组成和Mapping分析。研究结果显示Ⅵ矿带闪锌矿普遍富集Ge(最高580×10^(-6),均值81.1×10^(-6))、Cd(最高3486×10^(-6),均值1613×10^(-6))和Ga(最高190×10^(-6),均值44.4×10^(-6));黄铁矿普遍富集Mn、As、Pb、Cu、Ag和Sb。与Ⅰ和Ⅱ号矿带闪锌矿相比,Ⅵ号矿带闪锌矿更富集Ge和Ga。闪锌矿中Fe和Pb以类质同象为主,偶见黄铁矿和方铅矿显微包体;Cu、Ge、Ag和As赋存形式主要为类质同象,替代方式为Ge^(4+)+2(Cu+,Ag+,As+)↔3Zn^(2+);Cd以类质同象方式赋存为主,替代机制为Cd^(2+)↔Zn^(2+);Ga和In可能主要以类质同象方式存在。黄铁矿中Pb和Mn主要以方铅矿和碳酸盐矿物显微包体为主;Cu、As和Sb以类质同象形式存在于黄铁矿中;Ag和Zn可能以独立矿物形式赋存;Co和Ni以类质同象方式替代Fe进入黄铁矿晶格中,替代方式为Ni^(2+)+Co^(2+)↔2Fe^(2+)。毛坪矿床新发现Ⅵ矿带硫化物相比典型MVT矿床硫化物具有不同的In和Ge含量以及Cd/Fe比值,结合矿床地质特征和其他证据,表明毛坪矿床成因类型特殊,有别于经典MVT铅锌矿床,属于川滇黔型铅锌矿床。 相似文献
17.
Halogen elements play an important role in the metallogenesis of metallic ore deposits and are involved in the whole process of remobilization, transport and precipitation of metallic elements. However, with the exception of fluorine, which, as a component of fluorite and mica minerals, can be occasionally concentrated in ores, Cl, Br and I are hard to enrich in the ores. Investigations have found that the halogen elements tend to diffuse toward country rocks with the development of hydrothermal alteration in the process of their involvement in metallogenesis, especially during the post-ore stage when extensive halogen diffusion halos over orebodies would be formed. Such halogen element diffusion halos over the Chadong As–Ag–Au deposit extend as widely as 200 m. The largest diffusion extent is for I and the diffusion halos of Br are most noticeable 50–130 m away from the orebodies. In areas of ore exposure and the strongly altered zone, the Cl, Br and I contents are close to those of the strata with a V-shaped distribution pattern in the periphery of the mining district. Comparatively speaking, in going away from the altered zone, the major metallic elements Au and Ag in the deposit tend to decrease suddenly to their normal contents in the strata. This variation feature of halogen elements can be used as geochemical indicators for exploring concealed orebodies at depth. In the Chadong ore deposit, halogen element anomalies can be used to predict concealed orebodies at the depth range of 0–200 m. 相似文献
18.
Sajjad Maghfouri Ebrahim Rastad David R. Lentz Fardin Mousivand Flavien Choulet 《Chemie der Erde / Geochemistry》2018,78(1):40-57
The southwestern Sabzevar basin is the north of Central Iranian Microcontinent hosts abundant mineral deposits, including exhalative Mn mineralization and Cu-Zn volcanogenic massive sulfide (VMS) deposits. Amongst them, the Nudeh Besshi-type Cu–Zn volcanogenic massive sulfide (VMS) deposit is hosted within the lower part of a Late Cretaceous volcano-sedimentary sequence composed of alkali olivine basalt flows and tuffaceous silty sandstone. Based on investigations into the ore geometry, mineralogy, and texture, we recognized three different ore facies: (1) a stockwork of sulfide-bearing quartz veins cutting across the footwall volcano-sedimentary rocks and representing the stringer zone; (2) a massive ore type, displaying replacement texture with pyrite, chalcopyrite, sphalerite, friedrichite, and minor magnetite; and (3) a bedded ore type, with laminated to disseminated pyrite and chalcopyrite. EPMA studies indicate a distinctive minor element distribution between the different ore types of the Nudeh deposit. The Fe content in the sphalerite ranges from 0.65–1.80?wt.%, indicating the Fe-poor nature of the sphalerite. However, the Cd content in sphalerite ranged between 0.164–0.278?wt.%. According to the mineral compositions, Zn, Se, and Ag are found in bornite as minor elements. In the bedded ore facies, the pyrite contains higher levels of Se (up to 0.35?wt.%). The Zn content in the friedrichite in all of the ore samples is low. The Co/Ni ratios in pyrite from the Nudeh ore are lower than those of most magmatic deposits, but are similar to those from volcanogenic deposits, and hence support the proposed hydrothermal origin of the deposit. Two generations of quartz, Q1 and Q2 in the stockwork veins, contain primary fluid inclusions and these contain two phases (liquid and vapor). The lack of vapor-rich inclusions or variable liquid/vapor ratios indicate that the fluids did not boil at the site of trapping. Salinity for both Q1 and Q2 fluid inclusions ranges between 2.2–6.8?wt.% eq. NaCl. Homogenization temperatures for inclusions in the Q1 and Q2 veins average at about 296?°C and are similar to the temperatures of hydrothermal fluids discharged through vents in many modern seafloor VMS deposit. The Nudeh Besshi-type VMS deposit appears to have formed on the seafloor and based on the salinity and temperature constraints from the underlying stockwork, a buoyancy plume model is proposed as a mechanism for precipitation. 相似文献
19.
Sedex型矿床成矿系统 总被引：53，自引：0，他引：53
系统总结了Ｓｅｄｅｘ型矿床产出的构造背景、地质环境、矿床地质地球化学特征、矿化流体来源及成矿模式等问题。结合某些最新研究成果,对该类型矿床的Ｐｂ、Ｓｉ、Ｂ同位素地球化学进行了综合研究,并以加拿大科迪勒拉地区页岩容矿的Ｚｎ Ｐｂ矿床、中国大厂锡多金属矿床及澳大利亚布罗肯希尔Ｐｂ Ｚｎ Ａｇ矿床为例,深入讨论了Ｐｂ、Ｓｉ、Ｂ的来源及其对矿床成因的指示意义。对产于不同地质环境下现代海底热液成矿系统的研究证明,有沉积物覆盖和无沉积物覆盖海底成矿热流体的化学组成及Ｐｂ、Ｓｒ、Ｂ稳定同位素地球化学明显不同。前者富含与陆壳物质有关的金属组合及ＮＨ４,并富含放射成因Ｐｂ和Ｓｒ的组分,后者富含与洋壳玄武岩有关的金属组合,但特别贫ＮＨ４。这种不同与古代Ｓｅｄｅｘ型和塞浦路斯型矿床之间化学组成的差别十分相似,它意味着前者成矿物质主要来源于下伏陆壳岩石,并为其富含Ｂ,Ｂａ,Ａｇ,Ａｓ,Ｓｂ,Ｗ,Ｓｎ,Ｈｇ,Ｍｎ等元素提供了合理的解释。在此基础上,笔者指出,在特定地球化学背景下,上述那些元素也能形成独立的Ｓｅｄｅｘ型矿床,同时强调了注意寻找这种新型矿床的重要性 相似文献
20.
Indium Mineralization in Copper–Tin Stratiform Skarn Ores at the Saishitang–Rilonggou Ore Field,Qinghai, Northwest China 
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下载免费PDF全文 Jianping Liu Xiangping Gu Yongjun Shao Yuzhou Feng Jianqing Lai 《Resource Geology》2016,66(4):351-367
The Saishitang–Rilonggou Ore Field (SROF), which includes the Saishitang, Tongyugou, and Rilonggou ore deposits as well as other scattered occurrences, is located in the Elashan region in Qinghai Province, and is a significant Cu–Sn ore field in NW China. These ores are hosted in stratiform skarn deposits with the main metals being Cu and Sn, as well as Zn, Pb, Au, Ag, and trace elements (e.g. Ga, Ge, Se, and In). Bulk‐rock geochemical analyses of 50 ore samples from the three deposits show that In contents in the Saishitang deposit range from 0.03 to 39 ppm (average 12.7 ppm, n = 19), with 1000 In/Zn values that vary from >0.01 to 29.83 (average 4.29). Indium contents in the Tongyugou deposit vary from 7.51 to 131 ppm (average 28.37 ppm, n = 13), with 1000 In/Zn values from 0.74 to 48 (average 17.55). Finally, indium contents in the Rilonggou deposit vary from 0.73 to 120 ppm (average 36.15 ppm, n = 18), with 1000 In/Zn values from 0.33 to 47 (average 8.52). Indium is hosted mainly in sphalerite, while some other In‐bearing minerals (e.g., roquesite, stannoidite, and stannite) are present locally within the ore field. Roquesite, which replace or fill bornite, occurs in bornite‐rich ores in the Saishitang deposit. This is the first reported Chinese locality of roquesite. Based on previously reported Zn resources, a total of 136 tons of In is calculated to be hosted in the SROF, with 30, 66, and 40 tons of In attributed to the Saishitang, Tongyugou, and Rilonggou deposits, respectively. The differences in indium contents among the deposits and their respective geological histories and characteristics suggest that the origin of indium relates to volcanogenic metallogenesis in an early Permian volcano‐sedimentary basin. Based on the evaluation of In resources, future mining operations should include the recovery of indium in the Tongyugou and Rilonggou deposits. 相似文献