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1.
An anomalous isotope effect exists in many heavy element isotope systems(e.g., Sr, Gd, Zn, U). This effect used to be called the ‘‘odd–even isotope effect'because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-independent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is currently denoted as the nuclear field shift effect(NFSE). It is found that the NFSE can drive isotope fractionation of some heavy elements(e.g., Hg, Tl, U) to an astonishing degree, far more than the magnitude caused by the conventional mass-dependent effect(MDE). For light elements, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore,the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T2, while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE,including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect(KIE) and heavy isotope geochronology.  相似文献   

2.
The Archean atmospheric oxygen concentration and sulfur cycle was long debated. The banded iron formation (BIF) is a special type of the sedimentary formation, which has truly recorded the atmospheric and oceanic conditions at that time. In this study, the composition of multiple sulfur isotope (δ 34S/δ 33S/δ 32S) for sulfides bedded in the Archean (~2.7 Ga) BIFs, in Anshan-Benxi area of Liaoning Province has been measured. The value of △33S varies from -0.89‰ to 1.21‰, which shows very obvious mass-independent fractionation (MIF) signatures. These non-zero △33S values indicate that the Archean sulfur cycles are different from what it is today, which have been deeply influenced by gas phase photochemical reactions. Algoma-type BIFs which are closely related to the volcanic activity have negative △33S value, however, Superior-type BIFs which are far away from the volcanic center have positive △33S value. The δ 34S varies in a large range from -22.0‰ to 11.8‰, which indicates that the bacteria reduction activity has already existed at that time, and that the oceanic sulfate concentration has at least reached 1 mmol/L in local areas. Combined with the contemporaneous existence of the hematite, magnetite and the occurrence and preservation of the sulfur MIF, it can be inferred that the Archean atmospheric oxygen level must be at 10-2―10-3 of the present atmospheric level (PAL).  相似文献   

3.
Natural nitrogen isotope composition(δ~(15)N) is an indicator of nitrogen sources and is useful in the investigation of nitrogen cycling in organisms and ecosystems. δ~(15)N is also used to study assimilation of inorganic nitrogen. However, the foliar δ~(15)N of intact plants, which is a consequence of nitrate assimilation occurring in the roots and shoots, is not suited for studying nitrate assimilation in cases where nitrate is the sole nitrogen source. In this study, Orychophragmus violaceus(Ov) and Brassica napus(Bn) plantlets, in which nitrate assimilation occurred in the leaves, were used to study the relationship between foliar δ~(15)N and nitrate assimilation.The plantlets were grown in vitro in culture media with different nitrate concentrations, and no root formation occurred for the plantlets during the multiplication stage.Nitrogen isotope fractionation occurred in both the Ov and the Bn plantlets under all treatments. Furthermore, the foliar nitrogen content of both the Ov and Bn plantlets increased with increasing nitrate concentration. Foliar nitrogen isotope fractionation was negatively correlated with foliar nitrogen content for both the Ov and Bn plantlets. Our results suggest that the foliar nitrogen isotope fractionation value could be employed to evaluate nitrate assimilation ability and leaf nitrate reductase activity.Moreover, high external nitrate concentrations couldcontribute to improved foliar nitrogen content and enhanced nitrate assimilation ability.  相似文献   

4.
Hydrogen isotopes in lipid biomarkers can trace past changes in the hydrologic cycle. Recent studies have revealed the potential of hydrogen isotopes in microalgal lipids for quantitatively reconstructing water δ~2H(δD) values and salinity. In this study we collected suspended particles along a salinity gradient from the Changjiang River Estuary(CRE), and measured δD values in fatty acids in these particles. The results indicated that δD values of water were correlated highly with salinity from the CRE, in agreement with the results from other estuaries. δD values in palmitic acid and stearic acid had a positive correlation with δD values of water from the CRE. Nevertheless, in the CRE, hydrogen isotope fractionation in fatty acids relative to water increased as salinity increased, opposite the trend in hydrogen isotope fractionation with salinity found in microalgal culture and field studies. We attribute the increase in hydrogen isotope fractionation as salinity increased to light availability, which was likely lower in the particle rich mixing zone at the end of the estuary, and potentially as well to multiple sources of fatty acids in the CRE.  相似文献   

5.
The Rayleigh distillation isotope fractionation(RDIF) model is one of the most popular methods used in isotope geochemistry. Numerous isotope signals observed in geologic processes have been interpreted with this model. The RDIF model provides a simple mathematic solution for the reservoir-limited equilibrium isotope fractionation effect. Due to the reservoir effect, tremendously large isotope fractionations will always be produced if the reservoir is close to being depleted. However, in real si...  相似文献   

6.
Shales are a major sink for K into seawater delivered from continental weathering,and are potential recorders of K cycling.High precision K isotope analyses reveal a[0.6%variation in δ^41K values(41K/39K relative to NIST SRM 3141a)from a set of well characterized postArchean Australian shale(PAAS)samples.By contrast,loess samples have relatively homogenous δ^41K values(-0.5±0.1%),which may represent the average K composition of upper continental crust.Most of the shales analyzed in this study have experienced K enrichment relative to average continental crust,and the majority of them define a trend of decreasing δ^41K value(from-0.5to-0.7%)with increasing K content and K/Na ratio,indicating cation exchange in clays minerals is accompanied by K isotope fractionation.Several shale samples do not follow the trend and have elevated δ^41K values up to-0.1%,and these samples are characterized by variable Fe isotope compositions,which reflect post-depositional processes.The K isotope variability observed in shales,in combination with recent findings about K isotope fractionation during continental weathering,indicates that K isotopes fractionate during cycling of K between different reservoirs,and K isotopes in sediments may be used to trace geological cycling of K.  相似文献   

7.
Several important equilibrium Si isotope fractionation factors among minerals,organic molecules and the H_4SiO_4 solution are complemented to facilitate the explanation of the distributions of Si isotopes in Earth's surface environments.The results reveal that,in comparison to aqueous H_4SiO_4,heavy Si isotopes will be significantly enriched in secondary silicate minerals.On the contrary,quadra-coordinated organosilicon complexes are enriched in light silicon isotope relative to the solution.The extent of ~(28)Si-enrichment in hyper-coordinated organosilicon complexes was found to be the largest.In addition,the large kinetic isotope effect associated with the polymerization of monosilicic acid and dimer was calculated,and the results support the previous statement that highly ~(28)Sienrichment in the formation of amorphous quartz precursor contributes to the discrepancy between theoretical calculations and field observations.With the equilibrium Si isotope fractionation factors provided here,Si isotope distributions in many of Earth's surface systems can be explained.For example,the change of bulk soil δ~(30)Si can be predicted as a concave pattern with respect to the weathering degree,with the minimum value where allophane completely dissolves and the total amount of sesquioxides and poorly crystalline minerals reaches their maximum.When,under equilibrium conditions,the well-crystallized clays start to precipitate from the pore solutions,the bulk soil δ~(30)Si will increase again and reach a constant value.Similarly,the precipitation of crystalline smectite and the dissolution of poorly crystalline kaolinite may explain the δ~(30)Si variations in the ground water profile.The equilibrium Si isotope fractionations among the quadracoordinated organosilicon complexes and the H_4SiO_4solution may also shed light on the Si isotope distributions in the Si-accumulating plants.  相似文献   

8.
Equilibrium Si isotope fractionation factors among orthosilicic acid(i.e.,H4 Si O4(aq)), quartz and the adsorption complexes of H4 Si O4(aq)on Fe(III)-oxyhydroxide surface were calculated using the full-electron wave-function quantum chemistry methods [i.e., B3LYP/6-311G(2df,p)]with a new cluster-model-based treatment. Solvation effects were carefully included in our calculations via water-droplet method combined with implicit solvent models(e.g., PCM).The results revealed that, if it is under equilibrium conditions,heavy Si isotopes would be significantly enriched in quartz in comparison to H4 Si O4(aq). However, most of the field observations suggested that quartz would have identical or even depleted d30 Si values compared to that of H4 Si O4(aq). To explain this discrepancy between the equilibrium calculation results and the field observations, the kinetic isotope effect(KIE) associated with the formation of amorphous silica,which usually is the precursor of crystalline quartz, was investigated using quantum chemistry methods. The KIE results showed that amorphous silica would be significantly enriched in light Si isotopes during its formation. Our equilibrium fractionation results, however, matched a special type of quartz(i.e., Herkimer ‘‘diamond') very well, due to its nearly equilibrated precipitation condition. Opposite to the case of precipitated quartz, a large equilibrium Si isotope fractionation(i.e.,-3.0 %) was found between the absorbed bidentate Si surface complexes(i.e.,2C [ Fe2O2Si(OH)2) and H4 Si O4(aq). This calculated equilibrium Si isotope fractionation factor largely differed from a previous experimental result(ca.-1.08 %). We found that the formation of transient or temporary surface complexes [e.g.,1V [ Fe2OSi(OH)3] may have accounted for the smaller net fractionation observed.With the equilibrium and kinetic Si isotope fractionation factors provided here, the distributions and changes of Si isotope compositions in the Earth's surface systems can be better understood.  相似文献   

9.
Sedimentary environment and distribution of brachiopods during the Changhsingian in Xingwen, Si-chuan Province of the upper Yangtze region, are statistically analyzed. Changing regularity in diversity of brachiopod is synthetically investigated based on qualitative and quantitative analysis of transgres-sion-regression cycles. The results show that the diversity of brachiopods in this region in the trans-gression (aggradation) sequence is higher than that in the regression (progradation) sequence. The brachiopods in this area began to diversify in the early Changhsingian. And the species diversity had four peak stages which are respectively in the middle Early Changhsingian, late Early Changhsingian, early Late Changhsingian and late Late Changhsingian. The species diversity reached its highest in the late Late Changhsingian but this is followed by a sharp decrease at the end-hanghsingian, indicating the mass extinction of most brachiopod species which were prosperous in the Late Paleozoic.  相似文献   

10.
The Baiyangping Cu-Ag polymetallic ore district is located in the northern part of the Lanping-Simao foreland fold belt,between the Jinshajiang-Ailaoshan and Lancangjiang faults,and the deposit can be divided into eastern and western ore zones.Based upon microscope observation of ore minerals and analysis of zinc,copper,and strontium isotope composition,we conclude that:(1)the zinc isotopic compositions of sphalerite from the eastern and western ore belt of the Baiyangping polymetallic ore deposits are enriched in both the heavy(-0.09‰ to+0.15‰) and light(-0.19‰ to-0.01‰)zinc isotopes.Rayleigh fractionation is likely the additional factor controlling the observed temporal and spatial variations in zinc isotopes in the two studied ore zones.The zinc isotopic composition in the Baiyangping polymetallic Pb-Zn deposits may have the same fractionation as that of magmatic-hydrothermal,VHMS,SEDEX,and MVT deposits,as demonstrated by geological and other geochemical evidence;(2) the range of δ~(65)Cu in massive tetrahedrite is from-0.06‰ to+0.12 ‰ that relates to the early stages of ore-formation,which are higher than that of venial chalcopyrite(from-0.72‰ to-0.07‰)formed at a late ore-forming stage in the western ore belt.Different ore-forming stages and alteration or leaching processes are likely the main factors controlling the observed variations in copper isotopes in the western ore zone;(3) the ~(87)Sr/~(86)Sr value of hydrothermal calcite in eastern(0.7080-0.7093) and western(0.7085-0.7113) ore belt suggested that mineralization of early calcite,with~(87)Sr/~(86)Sr values much higher than in ancient Late Triassic seawater,may be related to recrystallization from a radiogenic Sr-rich or silicifying fluid,either from the strata that the ore-forming fluid flows through or from other fluids.  相似文献   

11.
Compared with the measureable but limited K isotope variation in geological samples,biological samples have much larger variations in δ~(41)K values:from-1.3‰ to+1.1‰ relative to the international K standard NIST SRM 3141a.Notably,higher plants generally have δ~(41)K values that are lower than igneous rocks,whereas sea plants(algae)have δ~(41)K values that are higher than seawater;the range in δ~(41)K values of plants encompasses the δ~(41)K values of both igneous rocks and seawater.Plant cells utilize different K uptake mechanisms in response to highand low-K conditions.In a low-K environment,plant cells use energy-consuming ion pumps for active uptake of K;plant cells in high-K environments use non-energy-consuming ion channels.Based on these facts and on K isotope data from sea and land plants,it is hypothesized that the different K uptake mechanisms are accompanied by distinct K isotope fractionation behaviors or vital effects.The enrichment of light K isotopes in terrestrial plants could be attributed to preferential transport of isotopically light K in the energy-consuming active uptake process by K ion pumps in the membranes of plant root cells.On the other hand,the enrichment of heavy K isotopes in algae may be caused by a combination of the lack of K isotope fractionation during K uptake from seawater via ion channels and the preferential efflux of light K isotopes across the cell membrane back to the seawater.The large variation of K isotope compositions in biological samples therefore may reflect the diversity of isotopic vital effects for K in organisms,which implies the great potential of K isotopes in biogeochemical studies.  相似文献   

12.
In this paper, based on the results of tomographic image of Tangshan and Xingtai areas, the relations between the characteristics of the two strong earthquake sequences and their three-dimensional velocity structures are studied. The research results indicate that:① Mosaic distribution of low-velocity bodies and high-velocity bodies, especially the existence of high-velocity bodies with large size in crust are the common basis of development of the two earthquake sequences. ②Scale, depth, and heterogeneity of high-velocity and low-velocity bodies are the important factors to effect the characteristic of earthquake sequences.③ The depth of the high-velocity body in Tangshan area is less than that in Xingtai area, which is the principal reason why the dominant focal depth and the biggest focal depth of Tangshan earthquake sequence are less than Xingtai's.④The depth of the high-velocity bodies in Ninghe area is more than that in Tangshan-Luanxian area, which lead to the biggest magnitude and epicentral intensity are lower. These results could be helpful for predicting the main shock of strong swarm-type earthquakes and later strong aftershocks.  相似文献   

13.
Carbon stable isotope techniques were extensively employed to trace the dynamics of soil organic carbon(SOC)across a land-use change involving a shift to vegetation with different photosynthetic pathways.Based on the isotopic mass balance equation,relative contributions of new versus old SOC,and SOC turnover rate in corn fields were evaluated world-wide.However,most previous research had not analyzed corn debris left in the field,instead using an average corn plant δ~(13)C value or a measured value to calculate the proportion of corn-derived SOC,either of which could bias results.This paper carried out a detailed analysis of isotopic fractionation in corn plants and deduced the maximum possible bias of SOC dynamics study.The results show approximately 3‰ isotopic fractionation from top to bottom of the corn leaf.The ~(13)C enrichment sequence in corn plant was tassel﹥stalk or cob﹥root﹥leaves.Individual parts accounting for the total dry mass of corn returned distinct values.Consequently,the average δ~(13)C value of corn does not represent the actual isotopic composition of corn debris.Furthermore,we deduced that the greater the fractionation in corn plant,the greater the possible bias.To alleviate bias of SOC dynamics study,we suggest two measures:analyze isotopic compositions and proportions of each part of the corn and determine which parts of the corn plant are left in the field and incorporated into SOC.  相似文献   

14.
The pseudospectral method has been applied to the simulation of seismic wave propagation in 2-D global Earth model.When a whole Earth model is considered,the center of the Earth is included in the model and then singularity arises at the center of the Earth where r=0 since the 1/r term appears in the wave equations.In this paper,we extended the global seismic wavefield simulation algorithm for regular grid mesh to staggered grid configuration and developed a scheme to solve the numerical problems associated with the above singularity for a 2-D global Earth model defined on staggered grid using pseudospectral method.This scheme uses a coordinate transformation at the center of the model,in which the field variables at the center are calculated in Cartesian coordinates from the values on the grids around the center.It allows wave propagation through the center and hence the wavefield at the center can be stably calculated.Validity and accuracy of the scheme was tested by compared with the discrete wavenumber method.This scheme could also be suitable for other numerical methods or models parameterized in cylindrical or spherical coordinates when singularity arises at the center of the model.  相似文献   

15.
Based on the earthquake catalog reported by the Chinese digital seismic network in recent years, we select the earthquakes with both surface wave magnitude and local magnitude and fit them into a relationship between the two magnitudes. The systematic difference is found from the formula which has been used for 30 years. Because of a large dynamic range and wide frequency range of the current digital observation system, in addition to a larger number of stations and earthquakes being used compared to before, the relation obtained in this paper seems more reliable. Our calculation shows that there is no significant difference before and after magnitude conversion so we suggest the abandonment of magnitude conversion. The site response of a station consists of amplification at different frequencies. The amplification is equal to about 1 and changes little with frequency at stations located on basement rock, and it is greater than 1 at low frequency ranges and less than 1 at high frequency ranges at stations located on sediment layers. The difference between magnitudes from single station located on sediment layer and the average magnitude from the whole network increases from negative to positive with period. It seems that there is no fixed station correction factor and the station correction method does not work to improve the accuracy and magnitude estimates.  相似文献   

16.
Abundant natural gas inclusions were found in calcite veins filled in fractures of Central Fault Belt across the centre of Ordos Basin. Time of the calcite veins and characteristics of natural gas fluid inclusion were investigated by means of dating of thermolum luminescence (TL) and analyzing stable isotope of fluid inclusion. Results show that natural gas inclusion formed at 130―140℃ with salinity of 5.5 wt%―6.0 wt% NaCl. It indicates that natural gas inclusion is a kind of thermal hydrocarbon fluid formed within the basin. Method of opening inclusion by heating was used to analyze composition of fluid inclusion online, of which the maximal hydrocarbon gas content of fluid inclusion contained in veins is 2.4219 m3/t rock and the maximal C1/Σci ratio is 91%. Laser Raman spectroscopy (LRS) was used to analyze chemistry of individual fluid inclusion in which the maximal hydrocarbon gas content is 91.6% compared with little inorganic composition. Isotope analysis results of calcite veins show that they were deposited in fresh water, in which the δ13CPDB of calcite veins is from -5.75‰ to 15.23‰ andδ18OSMOW of calcite veins is from 21.33‰ to 21.67‰. Isotope results show thatδ13C1 PDB of natural gas fluid inclusion is from -21.36‰ to -29.06‰ and δDSMOW of that is from -70.89‰ to -111.03‰. It indicates that the gas of fluid inclusion formed from coal source rocks and it is the same as that of natural gas of Mizhi gas reservoir. Results of TL dating show that time of calcite vein is (32.4±3.42)×104 a, which is thought to be formation time of gas inclusion. It indicated that natural gas inclusion contained in calcite veins recorded natural gas leakage from Mizhi gas reservoir through the Central Fault Belt due to Himalayan tectonic movement.  相似文献   

17.
Following the theory and definition of the Corioli force in physics, the Corioli force at the site of the M=8.1 Kunlun Mountain Pass earthquake on November 14, 2001, is examined in this paper on the basis of a statistical research on relationship between the Corioli force effect and the maximum attershock magnitude of 20 earth-quakes with M≥7.5 in Chinese mainland, and then the variation tendency of attershock activity of the M=8.1 earthquake is discussed. The result shows: a) Analyzing the Corioli force effect is an effective method to predict maximum attershock magnitude of large earthquakes in Chinese mainland. For the sinistral slip fault and the reverse fault with its hanging wall moving toward the right side oftbe cross-focus meridian plane, their Corioli force pulls the two fault walls apart, decreasing frictional resistance on fault plane during the fault movement and releasing elastic energy of the mainshock fully, so the maximum magnitude of aftershocks would be low. For the dextral slip fault, its Corioli force presses the two walls against each other and increases the frictional resistance on fault plane, prohibiting energy release of the mainshock, so the maximum magnitude of attershocks would be high.b) The fault of the M--8. l Kunlun Mountain earthquake on Nov. 14, 2001 is essentially a sinistral strike-slip fault,and the Corioli force pulled the two fault walls apart. Magnitude of the induced stress is about 0.06 MPa. Alter a comparison analysis, we suggest that the attershock activity level will not be high in the late period of this earth-quake sequence, and the maximum magnitude of the whole aftershocks sequence is estimated to be about 6.0.  相似文献   

18.
According to the joint probabilistic distribution model of magnitude and space,the author discusses the relationship between the probabilistic distribution of magnitude in a seismic province and that in an area with potential seismic sources.The results show that if the magnitude probabilistic distribution follows the truncated exponential form in a seismic province,there must be some potential source in which the magnitude probabilistic distribution does not conform to that form.The result is consistent with the concept of "characteristic earthquake" derived from the study of actual records of seismicity and the study of geology.The author suggests that the relationship between the probabilistic distribution of magnitude in a seismic province and that in a seismic potential area must be considered in the study of the analysis of seismicity,seismic zonation and engineering seismology,for the purpose of the evaluation of the probabilistic distribution of magnitude correctly in every area with potential s  相似文献   

19.
The Early Triassic was a period of ecological restoration for the earth's system after the end-Permian mass extinction.Geochemical records linked to the variations in marine ecosystems during this period have attracted the interest of geologists for many years.Based on petrographic analysis of samples and evaluations of their reliability as proxies for original seawater,this study investigated the carbon and oxygen isotopic compositions of 350 carbonate rock samples from the Lower Triassic(and adjacent strata)in the southern Longmenxia section of Guang'an,eastern Sichuan Basin.The results indicate that the Triassic carbonate rocks from the southern Longmenxia section favorably preserved the original seawater'sδ~(13)C signal.Furthermore,carbon and oxygen isotopic compositions are found to be poorly correlated,with a determination coefficient as low as 0.0205 and only 44 rock samples show results of Mn/Sr2 and/orδ~(18)0-6.5‰.The complete carbon isotopic curve for the Lower Triassic is established using the data from the remaining 306 samples with Mn/Sr2 and/orδ~(18)O-6.5‰.This curve presents favorable comparability on a global scale,specifically in theδ~(13)C minima near the Permian-Triassic boundary,at the top of the Jia1 and within the the Jia3,as well as in theδ~(13)C maxima at the tops of the Ye1 and Ye4,at the base of the Jia2 and at the top of the Ye3.The peaks and troughs corresponding to these maxima and minima all reflect global signals.By comparing these results to previous research on coeval carbon isotopic curves established within the chronostratigraphic framework,the ages of these critical evolution points are determined.The results show that the Ye1 roughly corresponds to the Griesbachian substage;the Ye2 through Ye4 correspond to the Dienerian substage;Jial corresponds to the Smithian substage;from the Jia2 to the lower part of the Jia4 correspond to the Spathian substage;and the middle and upper parts of the Jia4 belongs to the Aegean Substage of the Middle Triassic.Around the boundary between the Jial and Jia2(which represents the Smithian-Spathian boundary(SSB)),the value ofδ~(13)C increases rapidly from-0.911‰to 3.679‰.The span during which the seawater's carbon isotope experiences this drastic change may be less than36 kyr.The oxygen isotope,which is more sensitive to sedimentary environmental changes,exhibits changes prior to the carbon isotope near the SSB,indicating a significant increase in the salinity of the seawater before a sharp rise in the carbon isotope;this event leads to the formation of evaporites and dolomites.  相似文献   

20.
Lying on the west edge of Dongting Lake, the Taiyangshan area in Hunan Province is part of a hilly region which has uplifted since the Late Cenozoic. According to field investigation of the six existing faults in the Taiyangshan area, we found that four of them are not active in the Quaternary, and that the Gangshi-Hefu fault is likely to have been active in the early Mid- Pleistocene. The geological evidence derived suggests that the Xiaowupu fault was active from the late Mid-Pleistocene to the early late-Pleistocene. It cut the stratum with a TL age of 123 ± 10ka BP and has the property of thrusting. The research results are of great significance for understanding the seismogenic structure of the Changde earthquake with M63/4 in 1631.  相似文献   

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