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1.
在t≥600℃的温度条件下,通过硅酸盐和方解石之间的无水交换,用实验测定了石英、钠长石、钙长石、方解石中的乎衡氧同位素分馏.这些体系中的氧同位素交换就象硅酸盐和水之间的交换那么快.分馏系数可概括为的△Q-Cc=×0.8310~6/t~2;△Ab-Cc=－0.57×10~6/t~2;△An-Cc=－1.59×10~6/t~2.从这些方程式很容易得到硅酸盐矿物对的分馏系数。将这些结果与热液实验所得到 相似文献
2.
《矿物岩石地球化学通报》2017,(1)
水是地球岩浆中的一种主要挥发分。水的存在导致岩石的熔融温度降低,其根本原因在于水易溶于硅酸盐熔体。本文总结了在地球岩石圈温压条件下,水在硅酸盐熔体中的赋存形式、溶解度与水对熔体物理性质的影响。熔体中溶解的水以H_2O分子和OH形式存在。水在熔体中的溶解度随压力的升高而增大。当温压条件位于含水硅酸盐体系的临界曲线之上时,甚至可能形成成分介于硅酸盐熔体和富水流体之间的超临界流体。水使熔体的密度和黏度降低,更易于脱离源区向上运移。水使元素扩散加快,有利于晶体和气泡的生长。水导致熔体的电导率升高,使部分熔融造成的电导率异常更加显著。水对硅酸盐熔体迁移性质的影响以及水的溶解行为都与水的种型分异反应密切相关。在研究与熔融有关的地质过程时必须充分考虑水的作用。 相似文献
3.
100MPa、850℃和800℃条件下锡在流体与富磷过铝质熔体相间分配的实验研究 总被引：1，自引：0，他引：1
利用江西宜春414岩体中的钠长石花岗岩作为实验初始物,制备含不同1〉20s含量（0．27％－7．71％）的实验玻璃,本次实验研究了100MPa、850℃和800℃条件下Sn在流体与富磷过铝质熔体相间的分配。实验结果显示,Sn在流体与熔体相间的分配系数（Dsofluid/mclt）变化于2．10×10^-4－1．36×10^3之间,指示Sn强烈趋向于在富磷过铝质熔体中富集。随体系中P2Os含量从0．27％增至1．91％,Sn在流体与熔体相间的分配系数逐渐增加,当体系中R2O5含量进一步增加时,Sn在两相间的分配系数呈降低的趋势。本次实验结果表明,P可能不是Sn以流体相形式进行搬运的主要络合剂。 相似文献
4.
电气石和水之间的氢同位素分馏 总被引：1，自引：0，他引：1
作者对电气-水体系氢同位素平衡分馏和动力学分馏和动力学分馏开展了实验研究，丰富了羟基矿物氢同位素分馏资料。本文对该研究的实验技术、分析方法作了介绍，并对实验结果进行讨论与国外已有的该方面的资料作了对比。在800-650℃时电气石和水之间氢同位素平衡分馏系数与温度间线性关系为103lna电气石-水=-28.24（106/T2）+2.60；交换速率常数与温度间关系为lnk2=-0.19-6.70（103/T） 相似文献
5.
针对长江中下游形成中性和中酸性岩浆岩的岩浆成因和Ｆｅ、Ｃｕ成矿作用问题，完成了一系列壳幔物质混合物、下地壳物质混合物及中性－中酸性岩浆岩在１０００－２０００ＭＰａ和９００－１５５０℃的水不饱和条件下熔融实验研究。实验结果表明，本地区中性和中酸性岩浆岩可能主要由适当比例的壳幔物质混合物熔化而得的岩浆结晶而成。硅酸盐玻璃的电子探针分析数据没有显示出Ｋ与Ｃｕ和Ｆｅ与Ｎａ的相关关系。在含硫体系中，铜在中性－中酸性硅酸盐熔体中的溶解度介于０．０２％－０．２３％之间，但多数铜分析值在０．１％以上（大致相当于初始物中１５％的铜溶解在硅酸盐熔体中）。余下的部分铜则以Ｃｕ、Ｆｅ、Ｓ组成的小球粒形式不均匀地散布在硅酸盐熔体中。实验结果还表明，中性－中酸性硅酸盐熔体的不混溶性普遍存在。 相似文献
6.
水在硅酸盐熔体中的溶解度及研究意义 总被引：2，自引：0，他引：2
水是岩浆中主要的挥发份 ,而且其溶解作用强烈影响着熔体的物理和化学性质 ,因此对水在硅酸盐熔体中溶解度及溶解机制的研究是非常重要的。近年来研究表明 ,水在硅酸盐熔体中溶解度与压力、温度及熔体组分密切相关。具体而言 ,压力升高可使水的溶解度增大 ,而温度对溶解度的影响则与熔体组成有关。对于AbOrQ体系 ,在压力低于 4 0 0MPa时 ,溶解度与温度呈反相关 ;而在压力高于 50 0MPa时 ,则呈现出正相关。但是 ,温度对溶解度的影响要明显弱于压力的影响。至于水的溶解度与熔体组分的关系 ,通过对碱金属组分的研究表明水的溶解度按K ,Na ,Li的次序而增加。此外 ,根据碱金属组分对水在硅酸盐熔体中溶解度的影响对水的溶解机制进行了论述 ,这与Sykes等通过分子轨道计算和拉曼、红外光谱研究得出的水在铝硅酸盐熔体中的溶解机理是一致的。 相似文献
7.
在0．5－5千巴、775－1000℃条件下，实验测定了水流体与细岗岩、黄玉流纹岩成分的熔融体之间F和CI的分配。F和CI的分配系数Di已经计算出来。DC1为0．8－85；然而，在典型的地质条件下，相对于含F花岗质熔融体来说，CI更强烈地分配进入水流体。由于流体和岩浆中的F减少而H2O^fl（流体中H2O／（H2O＋CO2）体积摩尔数）、温度、压力以及流体和熔融体中的CI增加，因此愈来愈有利于CI分配进入流体。在1000℃和2千巴条件下，CI有利于分配进入含F＞7wt%和CI≤1200ppm的细岗岩熔融体中。DF为0．2－1．0；但是相对于水流体来说，F在花岗质熔融体中更富集。由于压力及熔融体中的F、温度以及XH2O^fl减少，F在黄玉流纹岩熔融体中更强烈地富集。然而，在800℃和2千巴条件下，如果熔融体含F≥7wt%，那么相对于黄玉流纹岩熔融体来说，F有利于分配进入水流体。计算结果表明，如果岩浆中初始H2O、CaO和铁镁含量低，而所产生的水饱和压力高。那么在黄玉流纹岩岩浆及与克莱马克斯（Climax)型钼矿床有关的岩浆结晶作用的最后阶段，在岩浆以及共生的岩浆热液流体中可以出现F（＞4wt%)和CI（＞5000ppm)的极大富集。 相似文献
8.
利用增量方法对云母族矿物的氧同位素分馏进行了系统的理论计算。结果表明，不同化学成分和结构状态的云母之间存在一定的氧同位素分馏，其１８Ｏ富集顺序在热力学同位素平衡时为：多硅白云母＞钠云母＞锂云母＞白云母＝珍珠云母＞海绿石＞铁云母＞金云母＞黑云母。在４００℃以上的高温条件下，云母－水体系的氧同位素分馏与温度之间的相关性不明显，并且云母相对于水亏损１８Ｏ达１‰－２．５‰。石英－云母体系的氧同位素分馏与温度之间具有显著的负相关性，因此，能够作为灵敏的同位素地质温度计。不过，石英－黑云母对的氧同位素地质测温往往给出岩石冷却过程中的退化再平衡温度，而不是岩石形成温度。 相似文献
9.
热扩散在地质过程中是否发挥重要作用一直存有争议。本文回顾了热扩散的研究历史和现状,重点总结了热扩散驱动的元素和同位素行为规律,并探讨了温度、硅酸盐组分、压力和氧逸度等因素对热扩散行为的影响。已有的研究表明,稳定热梯度下的硅酸盐热扩散效应类似于结晶分异或AFC过程,可以造成轻、重同位素分别在高温端和低温端富集,而主、微量元素的扩散方向则取决于两端化学势的高低和熔体中的电价平衡。从基性岩浆到酸性岩浆,熔体聚合度增大,黏度增加,热扩散速率明显降低,成网元素的热扩散效应减弱,变网元素则反之;水、氟、氯和硫化氢等挥发组分能增加熔体的非桥氧比例,降低熔体聚合度,因而能显著增强硅酸盐熔体中元素和同位素的热扩散效应。在此基础上,本文提出了当前硅酸盐体系热扩散研究中存在的五个亟需解决的问题,即:1)对不同硅酸盐体系的热扩散规律的研究还不够全面;2)对微量元素的热扩散行为认识不足;3)硅酸盐体系热扩散作用的影响因素及尺度还不够明确;4)热扩散作用的地质与地球化学关键识别标志有待确立;5)硅酸盐体系热扩散作用的理论模型有待建立。尽管硅酸盐体系热扩散的研究还存在诸多不足,但越来越多的证据表明,热扩散是地质过程中不容忽视的一种成分分异机制。这种机制会造成岩浆房或岩浆通道中的元素分异和同位素分馏,可能对于一些成分分异的岩石和矿床的形成具有重要的意义。 相似文献
10.
应用统计力学方法和较精确的非谐性校正，文章计算了硅烷在不同温度下的还原配分函数比，方程为：ｌｎβ＝－０．１６５９＋０．３６０３ｘ＋０．０４８９ｘ２以及硅烷与水和甲烷的氢同位素分馏方程：ｌｎαＳｉＨ４－Ｈ２Ｏ＝０．１５２３－０．４０６０ｘ＋０．０３１０ｘ２ｌｎαＣＨ４－ＳｉＨ４＝－０．１１５１＋０．２５８８ｘ－０．００２５ｘ２由于硅烷、甲烷中心原子电价相同，构型一致，对它们氢同位素分馏性质的对比讨论是很有意义的；同时，对增量法在氢同位素分馏计算中的应用进行了讨论 相似文献
11.
Lynn A. Silver Phillip D. Ihinger Edward Stolper 《Contributions to Mineralogy and Petrology》1990,104(2):142-162
Infrared spectroscopy was used to determine the concentrations of molecular water and hydroxyl groups in hydrous rhyolitic, orthoclasic, jadeitic, and Ca–Al-silicate glasses synthesized by quenching of melts from elevated presure and temperature. The rhyolitic glasses and some of the Ca–Al-silicate glasses were quenched from water-vapor-saturated melts and used to determine the solubility of water in melts of these compositions. For all compositions studied, hydroxyl groups are the dominant hydrous species at low total water contents, whereas molecular water dominates at elevated water contents. Although the trends in species concentrations in all these compositions are similar, the proportions of the two hydrous species are influenced by silicate chemistry: increasing silica content and K relative to Na both favor molecular water over hydroxyl. Results on rhyolitic glass demonstrate that molecular water is also favored by decreasing temperature at T<850°C. For rhyolitic glasses quenched from vapor-saturated melts, the mole fraction of molecular water is proportional to water fugacity for P(H2O)1500 bars, demonstrating that the behavior of molecular water is approximately Henrian at total water contents up to at least several weight percent. Data on water solubility for albitic, orthoclasic, and Ca–Al-silicate melts to higher pressures can also be fit by assuming Henrian behavior for molecular water and can be used to set constraints on the partial molar volume of water in these melts. The demonstration of Henry's law for molecular water in these liquids provides a link between spectroscopic measurements of microscopic species concentrations and macroscopic thermodynamic properties. 相似文献
12.
Jan A. Schuessler Ronny Schoenberg Harald Behrens Friedhelm von Blanckenburg 《Geochimica et cosmochimica acta》2007,71(2):417-433
A first experimental study was conducted to determine the equilibrium iron isotope fractionation between pyrrhotite and silicate melt at magmatic conditions. Experiments were performed in an internally heated gas pressure vessel at 500 MPa and temperatures between 840 and 1000 °C for 120-168 h. Three different types of experiments were conducted and after phase separation the iron isotope composition of the run products was measured by MC-ICP-MS. (i) Kinetic experiments using 57Fe-enriched glass and natural pyrrhotite revealed that a close approach to equilibrium is attained already after 48 h. (ii) Isotope exchange experiments—using mixtures of hydrous peralkaline rhyolitic glass powder (∼4 wt% H2O) and natural pyrrhotites (Fe1 − xS) as starting materials— and (iii) crystallisation experiments, in which pyrrhotite was formed by reaction between elemental sulphur and rhyolitic melt, consistently showed that pyrrhotite preferentially incorporates light iron. No temperature dependence of the fractionation factor was found between 840 and 1000 °C, within experimental and analytical precision. An average fractionation factor of Δ 56Fe/54Fepyrrhotite-melt = −0. 35 ± 0.04‰ (2SE, n = 13) was determined for this temperature range. Predictions of Fe isotope fractionation between FeS and ferric iron-dominated silicate minerals are consistent with our experimental results, indicating that the marked contrast in both ligand and redox state of iron control the isotope fractionation between pyrrhotite and silicate melt. Consequently, the fractionation factor determined in this study is representative for the specific Fe2+/ΣFe ratio of our peralkaline rhyolitic melt of 0.38 ± 0.02. At higher Fe2+/ΣFe ratios a smaller fractionation factor is expected. Further investigation on Fe isotope fractionation between other mineral phases and silicate melts is needed, but the presented experimental results already suggest that even at high temperatures resolvable variations in the Fe isotope composition can be generated by equilibrium isotope fractionation in natural magmatic systems. 相似文献
13.
Hejiu Hui Youxue Zhang Piero Del Gaudio Harald Behrens 《Geochimica et cosmochimica acta》2009,73(12):3680-3693
Viscosity of silicate melts is a critical property for understanding volcanic and igneous processes in the Earth. We investigate the pressure effect on the viscosity of rhyolitic melts using two methods: indirect viscosity inference from hydrous species reaction in melts using a piston cylinder at pressures up to 2.8 GPa and direct viscosity measurement by parallel-plate creep viscometer in an internally-heated pressure vessel at pressures up to 0.4 GPa. Comparison of viscosities of a rhyolitic melt with 0.8 wt% water at 0.4 GPa shows that both methods give consistent results. In the indirect method, viscosities of hydrous rhyolitic melts were inferred based on the kinetics of hydrous species reaction in the melt upon cooling (i.e., the equivalence of rheologically defined glass transition temperature and chemically defined apparent equilibrium temperature). The cooling experiments were carried out in a piston-cylinder apparatus using hydrous rhyolitic samples with 0.8-4 wt% water. Cooling rates of the kinetic experiments varied from 0.1 K/s to 100 K/s; hence the range of viscosity inferred from this method covers 3 orders of magnitude. The data from this method show that viscosity increases with increasing pressure from 1 GPa to 3 GPa for hydrous rhyolitic melts with water content ?0.8 wt% in the high viscosity range. We also measured viscosity of rhyolitic melt with 0.13 wt% water using the parallel-plate viscometer at pressures 0.2 and 0.4 GPa in an internally-heated pressure vessel. The data show that viscosity of rhyolitic melt with 0.13 wt% water decreases with increasing pressure. Combining our new data with literature data, we develop a viscosity model of rhyolitic melts as a function of temperature, pressure and water content. 相似文献
14.
The influence of melt composition and structure on the oxygen isotope fractionation was studied for the multicomponent (SiO2 ± TiO2 + Al2O3 ± Fe2O3 + MgO ± CaO) system at 1500°C and 1 atm. The experiments show that significant oxygen isotope effects can be observed in silicate melts even at such high temperature. It is shown that the ability of silicate melt to concentrate 18O isotope is mainly determined by its structure. In particular, an increase of the NBO/T ratio in the experimental glasses from 0.11 to 1.34 is accompanied by a systematic change of oxygen isotope difference between melt and internal standard by values from–0.85 to +1.29‰. The obtained data are described by the model based on mass-balance equations and the inferred existence of O0, O–, and O2– (bridging, non-bridging, and free oxygen) ions in the melts. An application of the model requires the intra-structure isotope fractionation between bridging and non-bridging oxygens. Calculations show that the intra-structure isotope fractionation in our experiments is equal to 4.2 ± 1.0‰. To describe the obtained oxygen isotope effects at the melts relatively to temperature and fraction of non-bridging oxygen a general equation was proposed. 相似文献
15.
矿物水体系氢同位素平衡分馏系数和动力分馏系数是同位素地球化学研究中的重要参数。这些参数大多由实验测定。氢同位素分馏的实验研究主要包括矿物水体系氢同位素交换实验,交换实验前后矿物、水的氢同位素分析及分馏机理、平衡分馏、动力分馏理论研究。为确保氢同位素分馏系数和一系列动力学参数的准确可靠,实验中防止氢透过容器壁扩散,避免空气中水汽污染样品,正确控制实验温度等都很重要。本研究以石英管代替前人常用的金（银、铂）管作反应容器,建立了一套实验研究羟基矿物水体系氢同位素平衡分馏和动力分馏的新方法,并开展了电气石水、黑柱石水体系氢同位素分馏的实验研究。所得一系列参数的精度明显好于国外报道的资料。此研究方法可广泛应用于羟基矿物水体系的氢同位素分馏的实验研究。 相似文献
16.
Diffusion of water was experimentally investigated for melts of albitic (Ab) and quartz-orthoclasic (Qz29Or71, in wt %) compositions with water contents in the range of 0 to 8.5 wt % at temperatures of 1100 to 1200 °C and at pressures
of 1.0 and 5.0 kbar. Apparent chemical diffusion coefficients of water (D
water) were determined from concentration-distance profiles measured by FTIR microspectroscopy. Under the same P-T condition and water content the diffusivity of water in albitic, quartz-orthoclasic and haplogranitic (Qz28Ab38 Or34, Nowak and Behrens, this issue) melts is identical within experimental error. Comparison to data published in literature
indicates that anhydrous composition only has little influence on the mobility of water in polymerized melts but that the
degree of polymerization has a large effect. For instance, Dwater is almost identical for haplogranitic and rhyolitic melts with 0.5–3.5 wt % water at 850 °C but it is two orders of magnitude
higher in basaltic than in haplogranitic melts with 0.2–0.5 wt % water at 1300 °C. Based on the new water diffusivity data,
recently published in situ near-infrared spectroscopic data (Nowak 1995; Nowak and Behrens 1995), and viscosity data (Schulze et al. 1996) for hydrous
haplogranitic melts current models for water diffusion in silicate melts are critically reviewed. The NIR spectroscopy has
indicated isolated OH groups, pairs of OH groups and H2O molecules as hydrous species in polymerized silicate melts. A significant contribution of isolated OH groups to the transport
of water is excluded for water contents above 10 ppm by comparison of viscosity and water diffusion data and by inspection
of concentration profiles from trace water diffusion. Spectroscopic measurements have indicated that the interconversion of
H2O molecules and OH pairs is relatively fast in silicate glasses and melts even at low temperature and it is inferred that
this reaction is an active step for migration of water. However, direct jumps of H2O molecules from one cavity within the silicate network to another one can not be excluded. Thus, we favour a model in which
water migrates by the interconversion reaction and, possibly, small sequences of direct jumps of H2O molecules. In this model, immobilization of water results from dissociation of the OH pairs. Assuming that the frequency
of the interconversion reaction is faster than that of diffusive jumps, OH pairs and water molecules can be treated as a single
diffusing species having an effective diffusion coefficient . The shape of curves of Dwater versus water content implies that increases with water content. The change from linear to exponential dependence of Dwater between 2 and 3 wt % water is attributed to the influence of the dissociation reaction at low water content and to the modification
of the melt structure by incorporation of OH groups.
Received: 26 March 1996 / Accepted: 23 August 1996 相似文献
17.
To assess the effect of the melt composition on bromine concentrations in magmas, we have investigated bromide solubility for water-saturated, iron-free silicic melts with variable Na+K/Al and Si/Al molar ratios (albite, haplogranite, rhyolite, and pantellerite). The experiments were performed in rapid quench cold-seal autoclaves over a range of pressure (1, 1.5, and 2 kbar) and temperature (900, 1000, and 1080 °C) with run durations from 5 to 7 days. A series of natural volcanic glasses and melt inclusions hosted in magmatic minerals were analysed together with the synthetic glasses by PIXE (proton-induced X-ray emission). The Br concentrations range from 5360 to 7850 ppm for albite, from 2800 to 3900 ppm for haplogranite, from 4300 to 5900 ppm for rhyolite, and from 9745 to 11,250 ppm for pantellerite. Br concentrations are negatively correlated with pressure in H2O-saturated silicic melts and vary with (Na+K)/Al molar ratio with a minimum value at the ratio close to unity. Br behaves similarly to chlorine for all of these melt compositions. The bromide solubility is similar in albitic and rhyolitic melts, which implies that Df/m is nearly the same for both compositions and is applicable for natural rhyolites as suggested in our previous study (Bureau et al., 2000). This means that the volcanic Br contribution to the atmosphere may be significant. In natural obsidian samples and MI hosted in quartz, olivine, and leucite, the Br concentration varies from < 3 to 28 ppm, with the highest concentrations in pantelleritic melts. We attribute the low Br concentrations of natural melts to a low initial abundance of this halogen in the Earth mantle. However, because Br behaves as an incompatible element before water exsolution, our results imply that magmas could contain much more dissolved Br before eruption and water degassing than the few ppm usually measured in volcanic rocks. Br behaviour during magma crystallisation is controlled by its partitioning into the H2O-rich fluid phase when this occurs. In addition, its potential high solubility in silicate melts makes it a very sensitive chemical tracer of magma contamination by seawater and Br-rich material. This infers that the investigation of Br behaviour in subduction-zone samples may help for a better understanding of volatiles cycling between the Earth reservoirs. 相似文献
18.
Water in Albitic Glasses 总被引：2，自引：1，他引：2
Infrared spectroscopy has been calibrated to provide a preciseand accurate method for determining the concentrations of molecularwater and hydroxyl groups in hydrous albitic glasses. At totalwater contents less than 4 wt.%, most of the water is dissolvedas hydroxyl groups; at higher total water contents, molecularwater becomes the dominant species. For total water contentsabove 4 wt.%, the amount of water dissolved as hydroxyl groupsis nearly constant at about 2 wt.% and additional water is incorporatedas molecular water. These trends in the concentrations of theH-bearing species are similar to those observed in other silicateglasses using infrared and NMR spectroscopies. The ratio ofmolecular water to hydroxyl groups at a given total water contentis independent of the pressure and only weakly dependent onthe temperature of equilibration. Molecular water and hydroxyl group concentrations in glassesprovide constraints on the dissolution mechanisms of water insilicate liquids. Several mixing models involving homogeneousequilibria of the form H2O+O2– = 2OH– among meltspecies in albitic melts have been developed. These models canaccount for the measured species concentrations if the effectsof non-ideal behavior or mixing of polymerized units are included,or by allowing for several different anhydrous species. We used two thermodynamic models of hydrous albitic melts tocalculate phase equilibria. The first assumes that Henry's lawholds for molecular water in albitic liquids; i.e. that theactivity of molecular water in the melt is proportional to itsmole fraction as determined by infrared spectroscopy. The seconddescribes the speciation and thermodynamics of hydrous albiticmelts using the formalism of a strictly regular solution. Thesemodels can account reasonably well for the position of the vapor-saturatedsolidus of high albite and the pressure and temperature dependenceof the solubility of water in albitic melts. To the extent thatthese models are successful, our approach provides a directlink between measured species concentrations in hydrous albiticglasses and the macroscopic thermodyn amic properties of theNaAlSi3O8-H2O system. 相似文献
19.
In this study, we used first-principles calculations based on density functional theory to investigate silicon and oxygen isotope fractionation factors among the most abundant major silicate minerals in granites, i.e., quartz and plagioclase (including albite and anorthite), and an important accessory mineral zircon. Combined with previous results of minerals commonly occurring in the crust and upper mantle (orthoenstatite, clinoenstatite, garnet, and olivine), our study reveals that the Si isotope fractionations in minerals are strongly correlated with SiO4 tetrahedron volume (or average Si–O bond length). The 30Si enrichment order follows the sequence of quartz > albite > anorthite > olivine ≈ zircon > enstatite > diopside, and the 18O enrichment follows the order of quartz > albite > anorthite > enstatite > zircon > olivine. Our calculation predicts that measurable fractionation of Si isotopes can occur among crustal silicate minerals during high-temperature geochemical processes. This work also allows us to evaluate Si isotope fractionation between minerals and silicate melts with variable compositions. Trajectory for δ30Si variation during fractional crystallization of silicate minerals was simulated with our calculated Si isotope fractionation factors between minerals and melts, suggesting the important roles of fractional crystallization to cause Si isotopic variations during magmatic differentiation. Our study also predicts that δ30Si data of ferroan anorthosites of the Moon can be explained by crystallization and aggregation of anorthite during lunar magma ocean processes. Finally, O and Si isotope fractionation factors between zircon and melts were estimated based on our calculation, which can be used to quantitatively account for O and Si isotope composition of zircons crystallized during magma differentiation. 相似文献
20.
Anat Shahar Valerie J. Hillgren Yingwei Fei Liwei Deng 《Geochimica et cosmochimica acta》2011,75(23):7688-7697
The Si stable isotope fractionation between metal and silicate has been investigated experimentally at 1800, 2000, and 2200 °C. We find that there is a significant silicon stable isotope fractionation at high temperature between metal and silicate in agreement with Shahar et al. (2009). Further we find that this fractionation is insensitive to the structure and composition of the silicate as the fractionation between silicate melt and olivine is insignificant within the error of the analyses. The temperature-dependent silicon isotope fractionation is Δ30Sisilicate-metal = 7.45 ± 0.41 × 106/T2. We also demonstrate the viability of using laser ablation MC-ICPMS as a tool for measuring silicon isotope ratios in high pressure and temperature experiments. 相似文献