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文石—水体系氧同位素分馏机理的实验研究 总被引：4，自引：1，他引：3
采用“附晶生长法”分别在５０和７０℃下合成文石下矿物,获得了两种不同的文石与水之间的氧同位素分馏关系。结果证明,文石与水之间氧同位素分馏的化学动力学机 为两步：（１）碳酸根与水之间进行氧同位素交换和平衡,即：「Ｃ＾１６Ｏ３」＾＾３－＋２Ｈ２＾１８Ｏ＝「Ｃ＾１８Ｏ３＾１６Ｏ」＾２－＋２Ｈ２Ｏ１６Ｏ;（２）与水平衡以后的「ＣＯ２」＾２－离子与Ｃａ＾２＋结合生成文石,即：Ｃａ＾２＋＋＿「Ｃ＾１８Ｏ２＾１ 相似文献
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娘子关泉域岩溶地下水SO^2—4,Ca^2＋,Mg^2＋污染分析 总被引：2，自引：0，他引：2
分析了娘子关泉域岩溶地下水ＳＯ＾２－４,Ｃａ＾２＋,Ｍｇ＾２＋等组分含量增多的原因,并定量地探讨了ＳＯ＾２－４,Ｃａ＾２＋,Ｍｇ＾２＋的各种来源比例。研究表明,含水层中石膏溶解及硫化物氧化是ＳＯ＾２－４,Ｃａ＾２＋,Ｍｇ＾２＋高含量的主要原因,控制硫化物氧化水进入含水层,对水质改良有显著效果。 相似文献
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对江汉盆地Ｔ油田主要的工业储层－下第三系新光沟嘴组沉积岩石的成岩流体进行了热力学研究。实测的成岩矿物流体包裹体的均一温度为１１０－１３９℃，属于该区中成岩阶段的温度范围（６７－１５５℃）。成岩流体的压力为１０．２－５６ＭＰａ。成岩流体中阳离子的活度出现Ｃａ＾２＋＞Ｍｇ＾２＋＞Ｎａ＾＋＞Ｋ＾＋＞Ｆｅ＾３＋＞Ｆｅ＾２＋；阴离子的活离出现ＨＣＯ３＾－＞ＳＯ４＾２－＞Ｆ＾－＞Ｃｌ＾－＞ＣＯ３＾２－；气相成 相似文献
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河台韧性剪切带金矿床成矿物理化学条件研究及熔融包裹体的发现 总被引：7，自引：0，他引：7
河台韧性切带金矿床产于震旦系－志留为质岩系深大断裂糜棱岩带中,本研究首次在矿床含矿石英脉及糜棱岩中发现熔融包裹体,流体－熔融包裹体及有机包裹体。不同类型包裹体均一温度,有机包裹体为１６０℃,成矿流体属Ｋ＾＋－Ｃａ＾２＋－Ｍｇ＾２＋－Ｎａ＾＋－ＳＯ４＾２－ＨＣＯ＾２－４－ＨＣＯ３＾－４－Ｃｌ＾－体系,具中偏碱性,微量气体特征：Ｈ２Ｏ〉ＣＯ２〉ＣＨ４〉（或〈）Ｈ２〉ＣＯ〉Ｃ２Ｈ２〉Ｃ２Ｈ６〉Ｏ２〉ＨＪ 相似文献
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论湖南石门砷—（金）矿床的古热泉成因 总被引：4，自引：0，他引：4
湖南石门砷－（金）矿床属古热泉成因,具有典型的三层结构模式,矿体呈筒状;矿床中硅质体属热泉沉积的硅华,矿石中微量元素间该区现代热泉体系沉积物的类似;成矿溶液富Ｎａ＾２＾＋,Ｃａ＾２＾＋,Ｃｌ＾－,ＨＣＯ３＾－和ＳＯ４＾２＾－,也与该区现代热泉水成分相似。泉水的氢,氧,氩,氦同位素研究表明,成矿溶液中水主要为大气降水。提出了热泉型砷－（金）矿床的成矿模式：下渗的大气降水被深部热流体加热,在地层中循环 相似文献
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本文通过钢铁工业废水淋溶钢铁工业渗漏区土壤，不同ｐＨ值，不同含Ｃａ＾２＋，Ｆ＾－浓度与放心水与工业淋溶各种土壤，以及电厂冲灰水淋溶粉煤灰的三种试验，讨论废水中Ｃ６Ｈ５ＯＨ、ＣＮ＾－ＡＳ、Ｃｒ，Ｐｂ，Ｚｎ，Ｈ２Ｓ，ＢＯＤ，ＣＯＤ，Ｆ＾－，Ｃｌ＾－，ＳＯ＾２－Ｒ，ＮＯ＾－３，ＮＨ＾＋４，Ｎａ＾＋和硬度等的污染与自净规律，并提出了防治地下水污染的措施。 相似文献
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西天山阿希金矿流体包裹体研究 总被引：37，自引：0，他引：37
西天山阿希金矿含金石英脉仙流体包裹体粒度细小,形态多样,以单一液相为主。化学成分上属Ｋ＾＋（Ｎａ＾＋）－ＳＯ４＾２－（Ｃｌ＾－）型,其中阳离子成分以Ｋ＾＋为主,Ｎａ＾＋次之;阴离子成分以ＳＯ４＾２－为主,Ｃｌ＾－次之;气相成分以Ｈ２Ｏ、ＣＯ为主,富含Ｏ２、Ｎ２等气候,还原性气体（Ｈ２、ＣＨ４、ＣＯ等）含量亦较高。成矿作用发生于浅成（３００￣９００ｍ）、低温（１２０￣１８０℃）和较封闭的还原环境。成 相似文献
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对云南、海南、江西、湖北、河南、新疆、浙江、山东、辽宁等27个省185个典型金矿床的自然重砂矿物进行统计分析,发现自然重砂矿物对金矿具有良好的响应,自然金、黄铁矿、方铅矿、黄铜矿、白铅矿、辰砂等对寻找金矿具有指示意义。不同成因类型的金矿床反映出的自然重砂矿物组合不同,斑岩型金矿床的标型指示矿物组合为自然金+黄铁矿+方铅矿+重晶石+闪锌矿+白铅矿+金红石,卡林型—类卡林型金矿床的标型指示矿物组合为自然金+黄铁矿+方铅矿+辉锑矿+毒砂+雄(雌)黄,而造山型+矽卡岩型+热液型+构造蚀变岩型金矿床的标型指示矿物组合为自然金+黄铁矿+方铅矿+辰砂。不同区域的金矿床反映出的自然重砂矿物组合也各有差异,闪锌矿为南方各省金矿床的特征矿物,辰砂和白钨矿为北方地区金矿床的特征矿物,重晶石和白铅矿为西部地区金矿的特征矿物。综合研究认为,自然重砂具有直接找矿和指导找矿的作用,按照特定成因类型和区域金矿床所建立的自然重砂矿物组合对建立矿床找矿模型具有重要的意义。 相似文献
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Ralf E. Krupp 《Geochimica et cosmochimica acta》2005,69(17):4283-4299
The evolution of magnesium chloride brines with high bromide contents via a multistage reaction and dissolution process has been studied in brine seeps of a German potash mine. The observed chemical trends and phase equilibria can be modeled and interpreted in terms of a NaCl solution (cap rock brine) infiltrating into a potash zone characterized by the metamorphic mineral assemblage kieserite + sylvite + halite + anhydrite. Establishment of a persistent, stable equilibrium assemblage and constant fluid composition in the invariant point IP1 of the six component (Na-K-Mg-Ca-Cl-SO4-H2O) system of oceanic salts is prevented by the perpetually renewed input of NaCl-brine and by the intermittent exposure of incompatible kieserite. Instead, the solutions develop towards the metastable invariant point IP1(gy), with the mineral assemblage carnallite + polyhalite + sylvite + halite + gypsum, where gypsum takes the place of anhydrite (stage I). The temporary exposure of kieserite and the ensuing formation of polyhalite effectively buffer the solutions along the metastable polyhalite phase boundary during stages II and III. Eventually, in stage IV, polyhalite becomes depleted and admixture of more NaCl brine leads to low sulfate solution compositions, which are now only constrained by carnallite + sylvite + halite, and the once hexary system degenerates to a quaternary one (Na-K-Mg-Cl-H2O) in point E. Bromide in brines shows equilibrium partitioning with respect to the wall rock minerals. The pattern of evolving brine compositions may serve as a model for similar brine occurrences, which in some cases may have been misinterpreted as remains of fossil, highly concentrated and chemically modified seawater. Similar magnesium chloride brines of salt lakes (e.g., Dead Sea, Dabusun Lake) show subtle differences and are constrained by fewer mineral equilibria (more degrees of freedom), and their low sulfate contents are due to gypsum precipitation, driven by calcium chloride input from dolomitization reactions. Finally, the observed reaction sequence is generalized, and a model for the formation of magnesium sulfate depleted, chloride-type potash salts and bischofite deposits by leaching of sulfate-type evaporites is proposed. 相似文献
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Archaean lode gold deposits in the Coolgardie Goldfield, Western Australia, occur in mafic and ultramafic rocks which have
been metamorphosed to the amphibolite facies. Mineralisation was broadly synchronous with peak metamorphism, the main phase
of granitoid emplacement, and regional deformation. Several different structural styles are represented by the deposits of
the Coolgardie Goldfield. Mineralisation occurs along sheared felsic porphyry-ultramafic rock contacts, in gabbro-hosted quartz-vein
sets, in fault-bounded quartzvein sets, and in laminated quartz reefs sited in brittleductile shear zones. The structures
hosting mineralisation formed in response to a progressive deformation event, related to granitoid emplacement in an east-west
compressional far-field stress régime, but with local heterogeneous stress orientations. This occurred after an earlier period
of thrust-stacking, with probable north-south directed tectonic transport. Two contrasting styles of goldrelated wallrock
alteration are associated with the auriferous lodes of the Coolgardie Goldfield. A high-temperature assemblage (formation
temperature >500°C), characterised by the proximal alteration assemblage garnet+ hornblende + plagioclase + pyrrhotite, contrasts
with a medium-temperature assemblage (formation temperature <500°C), consisting of calcic amphibole + biotite + plagioclase
+ calcite + arsenopyrite + pyrrhotite. The distribution of the two styles of gold-related alteration is controlled by distance
from voluminous syntectonic granitoids located to the west of the Coolgardie Goldfield, with the high-temperature style of
alteration more proximal to the granitoid-greenstone contact than the medium-temperature style. The occurrence of gold deposits
that formed under amphibolite facies conditions throughout the Coolgardie Goldfield supports a crustal continuum model for
Archaean lode-gold deposits, which proposes that gold is deposited in metamorphic environments that range from the sub-greenschist
to granulite facies. In addition, the data from Coolgardie suggest that syntectonic, synmineralisation granitic plutons may
play a significant role in controlling the style of gold associated wallrock-alteration at deep crustal levels. 相似文献
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滇西地区地质构造演化复杂，成矿地质条件优越，经历了多期次、多类型成矿作用，形成了多条各具特色的金多金属成矿带。文章通过对区内金沙江-哀牢山金多金属成矿带内北衙、马厂箐、姚安、长安等典型矿床的解剖和对比研究，发现带内金多金属矿床与经典的斑岩型矿床相比具有显著的差异性，主要表现是：成矿岩体岩性以碱性系列为特征，w(K2O+Na2O)超过8%；成矿流体碱质含量偏高，流体阳离子（K++Na+）含量约占流体总量的87%~95%；成矿过程中，除岩浆热液参与成矿外，岩浆气水热液与围岩间的水岩反应，是导致矿质沉淀的主体；自成矿岩体向外依次发育裂隙脉型、矽卡岩型、构造破碎带型和石英硫化物脉型矿化，组成多位一体。文章基于典型矿床特征的系统总结，提出了“碱质热液型”金多金属矿床的概念，并对其成矿作用过程进行了初步探讨。最终，文章构建了滇西地区碱质热液型金多金属矿地物化遥综合找矿模型，并指导相关矿床找矿勘查取得了重要进展。 相似文献
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The common occurrence of olivine, clinopyroxene and plagioclase in natural basalts may suggest that crystallization of these
phases exerts important controls on the evolution of natural basalts at low pressure. In order to understand the effects of
such an assemblage on the evolution of basalt, an experimental study of the divariant assemblage 1+an+cpx+ol in the system
CMAS + FeO was undertaken at 1 bar and under very reducing conditions. Experiments have been performed along three isothernal
sections. Detailed electron microprobe data have been collected on all the coexisting phases. Combining these data with available
data in the system CMAS, the compositions of all the coexisting phases have been described as functions of temperature and
CaO content in the melt by applying a multiple linear regression method. This allows a quantitative characterization of the
divariant assemblage 1+an+epx+ol in the system CMAS + FeO, from 1275°C to 1160°C, with liquid compositions ranging from mg#=1
to mg#=0.28. Knowing the composition-temperature relationships, the basic T-X configuration of the assemblage 1+an+cpx+ol has been analysed, and mass balance calculations have been performed to examine
the FeO effect on different crystallization processes. Addition of FeO to the system CMAS transforms the thermal divide in
the assemblage 1+an+cpx+ol to a thermal ridge, and shifts the spine of the thermal ridge towards SiO2-poor compositions with decreasing temperature. This indicates that tholeiitic basalts can be relatively silica-poor, and
evolve towards slightly more silica-poor compositions. With increasing FeO content, pigeonite replaces ortheonstatite as a
crystallizing phase along the silica-rich boundary of the assemblage 1+an+cpx+ol. In some iron, and silica rich composition,
olivine possibly terminates its crystallization or even starts resorption prior to pigeonite precipitation; this suppresses
silica enrichment in the melt. Crystallization paths of the assemblage 1+an+cpx+ol are determined by the detailed T-X relations of the thermal ridge with the melt evolving away from the spine. The liquid evolution trend depends strongly on
the initial compositions. A tholeiitic liquid can follow a moderate silica enrichment path at the same very reducing condition
of there is a high modal proportion of olivine. ‘A Fenner mechanism therefore is at work at the same place as a Bowen mechanism’. 相似文献
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青藏高原北部可可西里狮头山含硬玉岩类的基本特征及地质意义 总被引：4，自引：6，他引：4
描述了可可西里山南狮头山含硬玉岩类的岩石学、矿物学特征。含硬玉岩类的原岩为辉长岩，围岩为石炭—二叠系。由于变质作用不彻底，保留有原岩的矿物组合。典型的高压变质矿物组合为：钠长石 硬玉 霓石 蓝闪石 绿帘石 绿泥石。硬玉SiO2、FeO偏低，Al2O3、Na2O明显偏高，变质矿物组合中以富钠矿物为主，缺少石英，与国内外含硬玉岩类的原岩成分、变质矿物组合均不相同，是一种新的高压低温硬玉岩类。狮头山高压变质带向西延至若拉岗日、大横山一带，与北侧的西金乌兰—金沙江板块缝合带(西段)平行产出，以此推测缝合带南侧的羌北—昌都板块向北消减于巴颜喀拉板块之下。 相似文献
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碰撞造山型斑岩铜矿蚀变分带模式--以西藏冈底斯斑岩铜矿带为例 总被引：24，自引：0，他引：24
岛弧环境斑岩铜矿蚀变分带模式已为人们所熟知 ,但碰撞造山环境的斑岩铜矿蚀变分带特征尚不清楚。对此 ,文中以西藏冈底斯斑岩铜矿带为例 ,选择驱龙、冲江、厅宫 3个典型斑岩铜矿 ,对其蚀变系统进行了系统研究。依据蚀变矿物组合可分为 3个蚀变带 ,呈环带状分布。从中心向外依次为钾硅酸盐化带、石英绢云母化带、青磐岩化带。泥化带不太发育 ,通常叠加在其它蚀变带之上。钾硅酸盐化带主要蚀变矿物为钾长石、黑云母、石英、硬石膏 ,伴有大量的黄铜矿与辉钼矿 ,是成矿物质的主要堆积区。石英绢云母化带与钾硅酸盐化带渐变过渡或叠加其上 ,是次于钾硅酸盐化带的储矿部位。蚀变矿物组合为绢云母 +石英 +钾长石 ,金属硫化物有黄铁矿、黄铜矿、辉钼矿、斑铜矿 ,少量的方铅矿、闪锌矿。主要的辉钼矿以石英 +辉钼矿脉的形式出现于本矿带。青磐岩化在斑岩体内不发育 ,矿化极微弱。蚀变岩石组分分析表明 ,岩石蚀变及其分带是岩浆流体 /岩石反应时K ,Na ,Ca ,Mg等组分迁移的结果 ,矿化伴随着蚀变发生。钾硅酸盐化带、石英绢云母化带和青磐岩化带的蚀变岩石与未 (弱 )蚀变斑岩具有一致的稀土配分模式 ,REE含量有规律地变化 ,说明蚀变岩石均经历了源于岩浆的流体的交代 ,不同的蚀变形成于岩浆流体演化的不同阶段。蚀? 相似文献
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SONG Chunhui ZENG Yongyao YAN Maodu FANG Xiaomin FENG Ying PAN Jiaqiu LIU Xifang MENG Qingquan HU Chunhu ZHONG Sirui 《《地质学报》英文版》2017,91(1):156-174
The Qiangtang Basin (QB), located in the central Tibetan Plateau, is a Jurassic marine basin and one of the most important prospective salt resource belts in China. In recent decades, many outcrops of gypsiferous?bed have been found in the Jurassic marine strata in the basin. Salt springs with abnormally high sodium (Na+) contents had been identified in the Late Jurassic Xiali Formation (Fm.) in the basin in the last years. However, to date, no potash or halite deposits have been identified in the QB. Gypsum outcrops and salt springs are very important?signs in the investigation of halite and potash deposits. Therefore, the Xiali Fm. is?a potentially valuable layer to evaluate for the possible presence of halite and potash deposits in the basin. However,?few studies?have explored the formation?conditions of evaporites in the unit. Here, we present detailed geochemical records from the Yanshiping section related to the study of the formation?conditions of evaporites in the Xiali Fm. of the QB. Climate proxies based on the obviously increased anion concentrations of SO42? and Cl? and the significant correlation?coefficients of Ca2+-SO42? (R = 0.985) and Na+-Cl? (R = 0.8974) reveal that the upper member of the Xiali Fm. (the upper Xiali Fm.) formed under an arid climate and evolved into the sulfate phase or early chloride phase. Provenance proxies based on the obviously increased K+ and Na+ ion concentrations and the significant correlation?coefficient of Na+-Cl? (R = 0.8974) suggest that the upper Xiali Fm. featured optimal provenance conditions for the possible formation of halite deposits. The regression and the semi-closed tidal?flat environment in the upper Xiali Fm. were favorable for the formation of potash and halite deposits. The low Mg2+ /Ca2+ values (mean value = 1.82) and significant Na+-Cl? correlation?coefficient (R = 0.8974) also suggest that the upper Xiali Fm. is the layer most likely to contain potential halite deposits. In addition, the macroscopic correlations of tectonism, provenance, paleoclimate, saliferous strata and sedimentary?environment between the QB and the adjoining Amu Darya Basin in Central Asia reveal that the two basins shared similar geologic settings that were favorable for the formation of evaporites during the Late Jurassic. Therefore, the upper Xiali Fm. is a valuable layer to explore for halite deposit and may be potentially valuable in the future exploration for potash deposits in the QB. 相似文献
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A. Yu. Ivantsov 《Doklady Earth Sciences》2017,472(2):143-146
It has been established that terrigenous units of mainly carbonate deposits of the Yudoma Group in the Uchur–Maya Region of the Siberian Platform contain an assemblage of Late Vendian Ediacaran-type macrofossils. The assemblage contains species such as Aspidella terranovica, Beltanelliformis brunsae, Nenoxites curvus, and Palaeopascichnus sp., which had widespread geographic distribution. Finds of Ediacaran fossils in fossil-rich deposits of the Yudoma Group have expanded the possibilities of using the classic biostratigraphic approach applied for subdivision and global correlation of carbonate deposits in Late Precambrian paleobasins. 相似文献