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1.
Degradation of isoprene, m-xylene, n-octane, propene, and methacrolein by hydroxyl radicals has been studied in the simulation chamber SAPHIR under burden of trace gases as they are typical for the moderately polluted planetary boundary layer. Measured time series of the hydrocarbon mixing ratios and the OH concentrations were used to determine the rate constants. The hydrocarbons were measured with gas chromatography and proton transfer reaction mass spectrometry. OH was measured with the Jülich DOAS (differential optical absorption spectroscopy) instrument. In all cases except methacrolein good agreement was found with the reference rate constants taken from the Master Chemical Mechanism (MCM3.1). The data for methacrolein are consistent with the results of Karl et al. (J. Atmos. Chem 55, 2006, doi:) who reported a 12% smaller value. The degradation of hydrocarbons provides an independent method to analyse precision and accuracy of the OH measurements. A precision of better than 4% over a period of nearly 4 months was found. The accuracy is within the limitations given by the light absorption cross section of OH. Both results are consistent with earlier results by Hausmann et al. (J. Geophys. Res. 102:16011–16022, 1997).  相似文献   

2.
A new version of an atmospheric pressure chemical ionisation mass spectrometer has been developed for ground based in situ atmospheric measurements of OH and total peroxy (HO2 + organic peroxy) radicals. Based on the previously developed principle of chemical conversion of OH radicals to H2SO4 in reaction with SO2 and detection of H2SO4 using an ion molecule reaction with NO3─, the new instrument is equipped with a turbulent chemical conversion reactor allowing for measurements in moderately polluted atmosphere at NO concentrations up to several ppb. Unlike other similar devices, where the primary NO3─ ions are produced using radioactive ion sources, the new instrument is equipped with a specially developed corona discharge ion source. According to laboratory measurements, the overall accuracy and detection limits are estimated to be, respectively, 25% and 2 × 105 molecule cm-3 for OH and 30% and 1 × 105 molecule cm-3 for HO2 at 10 min integration times. The detection limit for measurements of OH radicals under polluted conditions is 5 × 105 molecules cm-3 at 10 min integration times. Examples of ambient air measurements during a field campaign near Paris in July 2007 are presented demonstrating the capability of the new instrument, although with reduced performance due to the employment of non isotopic SO2.  相似文献   

3.
张仁健 《气象学报》2002,60(5):620-624
应用作者建立的全球二维大气化学模式 ,采用 2种CH4 排放源的长期增长方案 ,同时考虑了CH4 排放源以及对OH自由基浓度有重要影响的CO和NOx 排放源的长期变化 ,模拟了CH4 和OH从 1840～ 2 0 2 0年的长期变化趋势。考虑了世界人口增长的排放源方案可以更好地模拟CH4 的长期变化 ,模拟结果表明 ,工业革命前的大气CH4 浓度和年排放总量分别为 76 0× 10 -9(V/V)和 2 80× 10 9kg ,1991年大气CH4 的浓度和年排放总量分别为16 11.9× 10 -9(V/V)和 5 33 .9× 10 9kg ,对流层OH自由基数浓度从 1840年的 7.17× 10 5分子数 /cm3 下降到 1991年的 5 .79× 10 5分子数 /cm3,降低了 19%。工业革命以来大气CH4 的增长一方面是由于CH4 排放源的增长 ,另一方面是由于大气OH浓度的下降。  相似文献   

4.
An open-path cavity ring-down spectroscopy (CRDS) instrument for measurement of atmospheric iodine monoxide (IO) radicals has been tested in the laboratory and subsequently deployed in Roscoff on the north-west coast of France as part of the Reactive Halogens in the Marine Boundary Layer (RHaMBLe) project in September 2006. In situ measurements are reported of local IO mixing ratios in the marine boundary layer. To obtain these mixing ratios, accurate absorption cross sections of IO are required at the selected wavelengths used for spectroscopic measurements. Absorption cross sections at the bandheads of the IO A2Π3/2–X2Π3/2 (3,0) and (2,0) vibronic bands were thus verified by a combination of spectral simulation methods, inter-comparison of prior determinations of cross-sections at high and low spectral resolution, and by measurement of rates of loss of IO by its self-reaction. The performance of the open-path CRDS instrument was tested by measuring concentrations of NO2 in ambient air, both within and outside the laboratory, with results that were in excellent agreement with a previously validated continuous wave CRDS apparatus for NO2 detection. During the RHaMBLe campaign, the open-path CRDS instrument was located within a few metres of the shoreline and operated at wavelengths close to 435 nm to detect the absorption of light by trace levels of IO. The IO mixing ratios were obtained on two days, peaked close to low tide, and were approximately 5–10 times higher than values calculated from column densities previously reported by long-path, differential optical absorption spectroscopy (DOAS) in coastal regions. The typical detection limit of the instrument was estimated to be 10 pptv of IO, with some fluctuation around this value depending on the conditions of wind and atmospheric aerosol particles, and the total accumulation time was 30 s for each data point. The observations of relatively high concentration of IO, compared to the values previously reported by DOAS, are consistent with the concurrent observations using a LIF (Laser induced Fluorescence) instrument (Whalley et al. in press). The first such measurements of localized IO by CRDS and LIF should contribute to an improved understanding of the chemistry of halogen compounds and the formation of iodine oxide aerosol particles in the marine boundary layer.  相似文献   

5.
Free Radicals and Fast Photochemistry during BERLIOZ   总被引：4，自引：0，他引：4  
The free radicals OH, HO2, RO2, and NO3 are known to be the driving force for most chemical processes in the atmosphere. Since the low concentration of the above radicals makes measurements particularly difficult, only relatively few direct measurements of free radical concentrations have been reported to date.We present a comprehensive set of simultaneous radical measurements performed by Laser Induced Fluorescence (LIF), Matrix Isolation –Electron spin Resonance (MI-ESR), Peroxy Radical Chemical Amplification (PERCA), and Differential Optical Absorption Spectroscopy (DOAS) during the BERLIner OZonexperiment (BERLIOZ) during July and August of 1998 near Berlin, Germany. Most of the above radical species were measured by more than one technique and an intercomparison gave good agreement. This data set offered the possibility to study and quantify the role of each radical at a rural, semi-polluted site in the continental boundary layer and to investigate interconnections and dependencies among these free radicals.In general (box) modelled diurnal profiles of the different radicals reproduced the measurements quite well, however measured absolute levels are frequently lower than model predictions. These discrepancies point to disturbing deficiencies in our understanding of the chemical system in urban air masses.In addition considerable night-time peroxy radical production related to VOC reactions with NO3 and O3 could be quantified.  相似文献   

6.
A study of the oxidation mechanism of N-methyl pyrrolidinone (C5H9NO, NMP) initiated by hydroxyl radicals was made at EUPHORE at atmospheric pressure (1000 ± 10) mbar of air and ambient temperature (T = 300 ± 5 K). The main products were N-methyl succinimide (NMS) (52 ± 4)% and N-formyl pyrrolidinone (FP) (23 ± 9)%. The relative rate technique was used to determine the rate constants of OH with NMP, NMS and FP, the measured values were (in units of cm3 molecule − 1 s− 1): kNMP = (2.2 ± 0.4) × 10− 11, kNMS = (1.4 ± 0.3) × 10− 12 and kFP = (6 ± 1) × 10− 12. The results are presented and discussed in terms of the atmospheric impact.  相似文献   

7.
A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A2Π3/2 ← X2Π3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N2O/CF3I/N2 mixtures with O3 actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.  相似文献   

8.
Rate constants for the reaction of OH radicals with some branched alkyl nitrates have been measured applying a competitive technique. Methyl nitrite photolysis in synthetic air was used as OH radical source at 295±2 K and 1000 mbar total pressure. Using a rate constant of 2.53×10-12 cm3 s-1 for the reaction of OH radicals with n-butane as reference, the following rate constants were obtained (units: 10-12 cm3 s-1): isopropyl nitrate, 0.59±0.22; isobutyl nitrate, 1.63±0.20; 3-methyl-2-butyl nitrate, 1.95±0.15; 2-methyl-1-butyl nitrate, 2.50±0.15; 3-methyl-1-butyl nitrate, 2.55±0.35. These values have been combined with the literature data to recalculate the substituent factors F(X) for the different nitrate groups which can be used to predict OH rate constants for organic nitrates for which experimental data are not available.Preliminary measurements of the photolysis frequency of isopropyl nitrate have shown that for this nitrate as a model substance, OH reactions and direct photolysis are of equal importance under tropospheric conditions.  相似文献   

9.
Simulations of polar ozone losses were performed using the three-dimensional high-resolution (1∘ × 1∘) chemical transport model MIMOSA-CHIM. Three Arctic winters 1999–2000, 2001–2002, 2002–2003 and three Antarctic winters 2001, 2002, and 2003 were considered for the study. The cumulative ozone loss in the Arctic winter 2002–2003 reached around 35% at 475 K inside the vortex, as compared to more than 60% in 1999–2000. During 1999–2000, denitrification induces a maximum of about 23% extra ozone loss at 475 K as compared to 17% in 2002–2003. Unlike these two colder Arctic winters, the 2001–2002 Arctic was warmer and did not experience much ozone loss. Sensitivity tests showed that the chosen resolution of 1∘ × 1∘ provides a better evaluation of ozone loss at the edge of the polar vortex in high solar zenith angle conditions. The simulation results for ozone, ClO, HNO3, N2O, and NO y for winters 1999–2000 and 2002–2003 were compared with measurements on board ER-2 and Geophysica aircraft respectively. Sensitivity tests showed that increasing heating rates calculated by the model by 50% and doubling the PSC (Polar Stratospheric Clouds) particle density (from 5 × 10−3 to 10−2 cm−3) refines the agreement with in situ ozone, N2O and NO y levels. In this configuration, simulated ClO levels are increased and are in better agreement with observations in January but are overestimated by about 20% in March. The use of the Burkholder et al. (1990) Cl2O2 absorption cross-sections slightly increases further ClO levels especially in high solar zenith angle conditions. Comparisons of the modelled ozone values with ozonesonde measurement in the Antarctic winter 2003 and with Polar Ozone and Aerosol Measurement III (POAM III) measurements in the Antarctic winters 2001 and 2002, shows that the simulations underestimate the ozone loss rate at the end of the ozone destruction period. A slightly better agreement is obtained with the use of Burkholder et al. (1990) Cl2O2 absorption cross-sections.  相似文献   

10.
A coupled atmosphere-ocean model developed at the Institute for Space Studies at NASA Goddard Space Flight Center (Russell et al., 1995) was used to verify the validity of Haney-type surface thermal boundary condition, which linearly connects net downward surface heat flux Q to air / sea temperature difference △T by a relaxation coefficient k. The model was initiated from the National Centers for Environmental Prediction (NCEP) atmospheric observations for 1 December 1977, and from the National Ocean Data Center (NODC) global climatological mean December temperature and salinity fields at 1° ×1° resolution. The time step is 7.5 minutes. We integrated the model for 450 days and obtained a complete model-generated global data set of daily mean downward net surface flux Q, surface air temperature TA,and sea surface temperature To. Then, we calculated the cross-correlation coefficients (CCC) between Q and △T. The ensemble mean CCC fields show (a) no correlation between Q and △T in the equatorial regions, and (b) evident correlation (CCC≥ 0.7) between Q and △T in the middle and high latitudes.Additionally, we did the variance analysis and found that when k= 120 W m-2K-1, the two standard deviations, σQ and σk△T, are quite close in the middle and high latitudes. These results agree quite well with a previous research (Chu et al., 1998) on analyzing the NCEP re-analyzed surface data, except that a smaller value of k (80 W m-2K-1) was found in the previous study.  相似文献   

11.
A preliminary study was carried out toexamine the feasibility of measuring tropospherichydroxyl radicals (OH) by liquidphase scrubbing andhigh performance liquid chromatography (HPLC). Thepotential advantages of this approach are itssimplicity, portability, and low expense. Thesampling system employs glass bubblers to trapatmospheric OH into a buffered solution of salicylicacid (o-hydroxybenzoic acid, OHBA). Rapidreaction of OH with OHBA produces a stable fluorescentproduct, 2,5-dihydroxybenzoic acid (2,5-DHBA), whichis determined by reverse-phase HPLC and fluorescencedetection. Our preliminary field results indicatethat this method is most suitable for OH measurementsin clean tropospheric air, where interferences fromother atmospheric species appear to be negligible orminor relative to polluted air. In clean air, thesampling period is about 45–90 minutes, which yieldsa detection limit of approximately 3–6 ×105 radicalscm-3. During an OHintercomparison experiment at the Caribou samplingsite in Colorado, our liquidphase scrubber method wascompared with the ion-assisted mass spectrometry (MS)method. Our results were within the same range asthose of the ion-assisted MS method (1–5 ×106 radicals cm-3) within our precision atthat time (about ±30–50%). Preliminary testsin Pullman, WA indicated that the method might alsofunction in moderately polluted air by acidifying thescrubbing solution or by adding a scavenger tosuppress interferences. In Pullman, mid-day OHconcentrations were usually in the range of 2–20 ×106 radicals cm-3. Nighttime OHconcentrations were always low, either at or slightlyabove the detection limit.  相似文献   

12.
In-situ OH measurements by laser-induced fluorescence (LIF) spectroscopy and folded long-path differential optical absorption spectroscopy (DOAS) were carried out in a rural environment in North-East Germany as part of the field experiment POPCORN in August 1994. The large set of OH data obtained allowed an intercomparison of both techniques based on relative diurnal profiles and simultaneously measured absolute concentrations. Most of the time the two OH instruments encountered the same air and agreed well in the measured relative diurnal variations. Only on a few occasions the measurements significantly disagreed due to a perturbation of the DOAS measurements by a local OH source in the north-western wind sector. Excluding data from this wind direction, the statistical analysis of 137 data pairs yields a correlation coefficient of r = 0.90 and a weighted linear fit with a slope of 1.09 ± 0.12. The correlations are carefully analyzed. The comparison of both instruments is discussed in the light of newly published effective absorption cross-sections for H2O and O2 that affect the calibration of LIF.  相似文献   

13.
It is essential to quantify the background reactivity of smog-chambers, since this might be the major limitation of experiments carried out at low pollutant concentrations typical of the polluted atmosphere. Detailed investigation of three chamber experiments at zero-NO x in the European Photoreactor (EUPHORE) were carried out by means of rate-of-production analysis and two uncertainty analysis tools: local uncertainty analysis and Monte Carlo simulations with Latin hypercube sampling. The chemical mechanism employed was that for methane plus the inorganic subset of the Master Chemical Mechanism (MCMv3.1). Newly installed instruments in EUPHORE allowed the measurement of nitrous acid and formaldehyde at sub-ppb concentrations with high sensitivity. The presence of HONO and HCHO during the experiments could be explained only by processes taking place on the FEP Teflon walls. The HONO production rate can be described by the empirical equation W(HONO)EUPHORE dry = a × j NO 2× exp (− T 0/T) in the low relative humidity region (RH < 2%, a = 7.3×1021 cm−3, T 0 = 8945K), and by the equation W(HONO)EUPHORE humid = W(HONO)EUPHORE dry+ j NO 2× b × RH q in the higher relative humidity region (2% < RH < 15%, b = 5.8×108 cm−3 and q = 0.36, and RH is the relative humidity in percentages). For HCHO the expression W(HCHO)EUPHORE = c × j NO 2exp (− T′0/T) is applicable (c = 3.1×1017 cm−3 and T′0 = 5686 K). In the 0–15% relative humidity range OH production from HONO generated at the wall is about a factor of two higher than that from the photolysis of 100 ppb ozone. Effect of added NO2 was found to be consistent with the dark HONO formation rate coefficient of MCMv3.1.  相似文献   

14.
The results of an intercomparison campaign of eight different long path UV-visible DOAS instruments measuring NO2, O3 and SO2 concentrations in a moderately polluted urban site are presented. For effective optical path lengths of 230 and 780 m the overall spread of these measurements (±1) are 5×1010, 6×1010 and 1×1010 molec·cm-3 (2.0, 2.4, and 0.4 ppb) for these molecules respectively when all instruments used a common set of absorption cross sections. The remaining differences are not completely random and the systematic differences are attributed to the different retrieval methods used for each instrument.  相似文献   

15.
This article presents a complete study of the diurnal chemical reactivity of the biogenic volatile organic compound (BVOC), 2-methyl-3-buten-2-ol (MBO) in the troposphere. Reactions of MBO with OH and with ozone were studied to analyse the respective parts of both processes in the global budget of MBO atmospheric reactivity. They were investigated under controlled conditions for pressure (atmospheric pressure) and temperature (298 ± 2 K) using three complementary European simulation chambers. Reaction with OH radicals was studied in the presence of and in the absence of NO x . The kinetic study was carried out by relative rate study using isoprene as a reference. The rate constant found for this reaction was molecule−1 cm3 s−1. FTIR spectroscopy, DNPH- and PFBHA-derivatisation analyses were performed for reactions with both OH radicals and ozone. In both reactions, the hydroxycarbonyl compound, 2-hydroxy-2-methylpropanal (HMPr) was positively identified and quantified, with a yield of in the reaction with OH, and a yield of and 0.84 ± 0.08 in the reaction with ozone under dry (HR < 1%) and humid conditions (HR = 20%–30%). A primary production of two other carbonyl compounds, acetone , and formaldehyde was found in the case of the dry ozonolysis experiments. Under humid conditions, only formaldehyde was co-produced with HMPr as a primary carbonyl compound, with a yield of . For the reaction with OH, three other carbonyl compounds were detected, acetone , formaldehyde and glycolaldehyde . In addition some realistic photo-oxidation experiments were performed to understand in an overall way the transformations of MBO in the atmosphere. The realistic photo-oxidation experiments were conducted in the EUPHORE outdoor simulation chamber. It was found that this compound is a weak secondary aerosol producer (less than 1% of the carbon balance). But it was confirmed that it is a potentially significant source of acetone, Δ[Acetone]/Δ[MBO] = 0.45. With our experimental conditions ([MBO]0 = 200 ppb, [NO]o = 50 ppb), an ozone yield of Δ[O3]/Δ[MBO] = 1.05 was found.  相似文献   

16.
Atmospheric hydroxyl (OH), hydroperoxy (HO2), total peroxy (HO2 and organic peroxy radicals, RO2) mixing ratios and OH reactivity (first order OH loss rate) were measured at a rural site in central Pennsylvania during May and June 2002. OH and HO2 mixing ratios were measured with laser induced fluorescence (LIF); HO2 + RO2 mixing ratios were measured with chemical ionization mass spectrometry (CIMS). The daytime maximum mixing ratios were up to 0.6 parts per trillion by volume (pptv) for OH, 30 pptv for HO2, and 45 pptv for HO2 + RO2. A parameterized RACM (Regional Atmospheric Chemistry Mechanism) box model was used to predict steady state OH, HO2 and HO2 + RO2 concentrations by constraining the model to the measured OH reactivity and previously measured volatile organic compound (VOC) distributions. The averaged model calculations are generally in good agreement with the observations. For OH, the model matched the observations for day and night, with an average observed-to-modeled ratio of 0.80. In previous studies such as PROPHET98, nighttime NO was near 0 pptv and observed nighttime OH was significantly larger than modeled OH. In this study, nighttime observed and modeled OH agree to within measurement and model uncertainties because the main source of the nighttime OH was the reaction HO2 + NO → OH + NO2, with the NO being continually emitted from the surrounding fertilized corn field. The observed-to-modeled ratio for HO2 is 1.0 on average, although daytime HO2 is underpredicted by a factor of 1.2 and nighttime HO2 is over-predicted by a factor of ∼2. The average measured and modeled HO2 + RO2 agree well during daytime, but the modeled value is about twice the measured value during nighttime. While measured HO2 + RO2 values agree with modeled values for NO mixing ratios less than a few parts per billion by volume (ppbv), it increases substantially above the expected value for NO greater than a few ppbv. This observation of the higher-than-expected HO2 + RO2 with the CIMS technique confirms the observed increase of HO2 above expected values at higher NO mixing ratios in HO2 measurements with the LIF technique. The maximum instantaneous O3 production rate calculated from HO2 and RO2 reactions with NO was as high as 10–15 ppb h−1 at midday; the total daily O3 production varied from 13 to 113 ppbv d−1 and was 48 ppbv d−1 on average during this campaign.  相似文献   

17.
A chemical substance being in a high-disperse state (fine aerosol particles and very thin films) in the environment reveals specific chemical and physicochemical features which differ from the processes in a relatively coarse disperse object and, even more, in ordinary liquid and solid “test-tube” assays. The kinetics and the mechanism of the direct and sensitized photochemical destruction of pesticide compound fipronil C12H4Cl2F6N4OS have been experimented as applied to the aerosol particles ≈0.12–1.3 μm in diameter and thin films ≈0.02–0.6 μm thick on the glass plates. A non-photochemical (“dark”) reaction of fipronil molecules with the OH radicals which spontaneously proceeds in the ambient air was also observed. Quantitative estimations based on experimental results show that the fipronil pollutant, observed in the atmosphere in the form of levitated aerosols, can convert chemically in the above reaction with the OH radicals for a very short time (from several minutes for a particle 2 μm in diameter to 12–24 h for a particle of 20–30 μm). The fipronil residues presented on foliage either in the form of 1–20 μm films or as a group of deposited 2–30 μm aerosols react under sunlight by two photochemical pathways (photooxidation and photodecay). The lifetime of these residues in the ambient conditions is expected to be 11–25 days. Besides, adding a small amount of the Shirvanol 2 sensitizer to the fipronil formulation, one can increase the overall decomposition rate to 8–12 days.  相似文献   

18.
A global two-dimensional chemistry model is developed to study long-term trends of CH4 since industrial revolution.The sources of CH4,CO and NOx are parameterized as functions of latitude and time.With two long-term emission scenarios,long-term trends of CH4 are simulated.The results have a good agreement with observation from ice cores.The modeled CH4 increased from 760 ppbv in 1840 to 1611.9 ppbv in 1991, while the modeled number concentration of tropospheric OH decreased from 7.17×105 cm-3 in 1840 to 5.79×105 cm-3 in 1991.The increase of atmospheric CH4 can be explained by the increase of emission of CH4 and build-up because of decrease of OH radicals that remove CH4 from the atmosphere.The model is also used to simulate the distribution of CH4.Comparisons between the model results and observations show that the model can simulate both latitudinal distribution and seasonal variation of CH4 well.  相似文献   

19.
An analysis was performed of the turbulent data obtained from Yucheng experimental station in the Shandong Province in 1984. [t is shown that at variant wind speed, the spectra of streamwise velocity remain similar and the intensity of wind fluctuations is proportional to wind speed in the downwind area of shelter belt. Therefore, we may decide the similarity of wind fluctuations by a speed scale and a length scale which is not correlated with stability, σu /V0 = F(X / H). The -5/3 power range of temperature spectra extends to lower frequency. The variation of ratio σ0 /T. with stability becomes σ0 / T . = C(X / H)( - Z / L)-1/3 . There is not such an extension of -5 / 3 power range in the humidity spectra.  相似文献   

20.
The uptake of water vapor on MgCl2×6H2O and NaCl salt dry solid films was studied over the temperature range 240 to 340 K and at 1 Torr pressure of helium using a flow reactor coupled to a modulated molecular beam mass spectrometer. The H2O to salt uptake data were obtained from the kinetics of H2O loss on salt coated Pyrex rods. The following Arrhenius expression was obtained for the initial uptake coefficient of H2O on MgCl2×6H2O films: γ 0 (MgCl2) = (6.5 ± 1.0) × 10−6 exp[(470 ± 40)/T] (calculated with specific BET surface area, quoted uncertainties are 1σ statistical). The rate of H2O adsorption on NaCl was found to be much lower than on MgCl2×6H2O, and only an upper limit was determined for the corresponding uptake coefficient: γ (NaCl) ≤ 5.6 × 10−6 at T = 300 K. The results show that the rate of H2O adsorption to salt surfaces is drastically dependent on the salt sample composition.  相似文献   

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