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1.
2.
Abstract. We have constructed a chemical reaction system in a contracting interstellar cloud. In paper (I) we have presented the details of the physical and chemical scheme and the method of solution. The results of our chemical model produce fractional abundances of H2CO, CO, OH, H2O, SO and OCS which are in good agreement with the results of observations. On the other hand, the results of chlorine-bearing species are not in agreement with those of the observations. The calculated abundances of H2CO, CO, OH, H2O, SO, OCS and Cl+ are in agreement with the results of previous theoretical studies. 相似文献
3.
D. D. S. Mackay 《Astrophysics and Space Science》1995,224(1-2):507-508
The gas phase chemistry of hot molecular cores is thought to depend upon the composition of evaporated ice mantle material and its subsequent gas phase reactions. We have modelled the silicon chemistry in these conditions from an SiH4 precursor and find substantial fractional abundances of SiO, H2SiO and HNSi on a timescale of a few 104 yr. 相似文献
4.
Chemical differences between cores in the dark ridge TMC-1 have been attributed to the cores being in different stages of chemical evolution with those having high NH3 to cyanopolyyne abundance ratios being the most evolved. We suggest several alternative models including one in which the highest NH3 to cyanopolyyne abundance ratio obtains in the youngest TMC-1 core; in this and in one of the other models the evolution of the chemistry as depletion increases is supposed to lead to a lower NH3 to cyanopolyyne ratio. The possibility that the cyanopolyynes exist primarily in an interface between dark core material and the wind of a low mass star is considered; this wind interface model may account for the sharp cyanopolyyne emission gradient on the side of the ridge away from the star. Implosion of the cores by the ram pressure of the wind may have caused them to collapse more rapidly than gravity could and more rapidly than chemistry evolves so that the chemistry reflects a core's state at a lower density. 相似文献
5.
The effects of the production on dust grain surfaces of molecular hydrogen in excited states have been investigated. On the
assumption that all of the H2 formed on the surface of grains has a sufficient level of excitation too vercome the energy barriers in the formation reactions
for the important OH and CH+ radicals, we consider the likely abundances of excited H2 (H2
*), OH and CH+ in various situations. Two different models are employed; the first links the H2
* abundance directly to that of H2 using a steady-state approximation, whilst the second considers the time-dependence of H2
*. The second model is applied to gas that has been subjected to a strong isothermal shock (specifically, the shock-induced
collapse of a diffuse cloud), which results in an extreme (high density, high atomic hydrogen abundance) environment. In general,
it is found that the presence of the excited H2 has only marginal effects on the chemistry of interstellar clouds. However, in the isothermal shock model, the abundances
of CH+ are significantly enhanced, but only on short timescales, whilst the effects on the OH abundances are smaller, but last longer.
We conclude that other than in such exceptional environments there are no obvious chemical signatures of the formation of
H2
*.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
6.
In this paper we study the effect of shock waves on the chemical structure of the interstellar clouds. A model of molecular cloud has been assumed. The chemistry is investigated in a time dependent model. Our chemical network contains 56 species in 251 reactions to including molecules of the elements H, O, C, N, S, and Si.The results indicate that the calculated fractional abundance of the molecules NS, H2O, CN, NH, CO, and SO agrees well with the observations. The molecules OH, H2S, CS, H2CS, HS, NO, SiO, CH, CH2, CH3, HCO, C2, and HCN reach high post-shock abundances. 相似文献
7.
A set of samples of 13 massive star-forming cores were observed in SiO (2-1), CH3OH (2-1) and C34S (2-1) thermal lines. Nine of these cores were detected in all three lines. Among the nine SiO detections, three were new detections, and relatively faint. Most of the lines have wide wings, which might be interpreted as the evidence of ongoing energetic out?ows in the cores. The line widths of SiO are generally the broadest, which might further suggest that the SiO emissions are due to higher velocity out?ow, and closer to the excited source. We derive the rotational temperatures, column densities and chemical relative abundances of the cores. There is a strong correlation between SiO and CH3OH abundances, with correlation coeffcient R = 0.77, but no correlation is observed between SiO and C34S. 相似文献
8.
One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H2O, OH, O, CN, C2, C3, CH, and NH2. Whole-coma abundances are presented for NH2, CH, C2, C3, CN, OH, CO+, H2O+, CH+, N2+, and CO2+. 相似文献
9.
Deborah P. Ruffle Eric Herbst 《Monthly notices of the Royal Astronomical Society》2001,322(4):770-778
The photodissociation of surface species, caused by photons from the cosmic-ray-induced and background interstellar radiation fields, is incorporated into our combined gas-phase and grain-surface chemical models of quiescent dense interstellar cores. For the cores studied here, only cosmic-ray-induced photons are important. We find that photodissociation alters gas-phase and surface abundances mainly at large cloud ages (≳ 106–7 yr). The abundances of those surface species, such as H2 O, that are readily reproduced on the surface following photodissociation are not strongly affected at any time. The abundances of surface species that are, on the other hand, reformed slowly via surface reactions possessing activation energy (e.g. CH3 OH) are reduced, while the abundances of associated surface photoproducts (e.g. CO) increase. In the gas phase, inclusion of surface photodissociation tends to increase molecular abundances at late times, slightly improving the agreement with observation for TMC-1. 相似文献
10.
We present gas-phase abundances of species found in the organic-rich hot core G327.3-0.6. The data were taken with the Swedish-ESO Submillimetre Telescope (SEST). The 1-3 mm spectrum of this source is dominated by emission features of nitrile species and saturated organics, with abundances greater than those found in many other hot cores, including Sgr B2 and OMC-1. Population diagram analysis indicates that many species (CH3CN, C2H3CN, C2H5CN, CH3OH, etc.) have hot components that originate in a compact (~2") region. Gas-phase chemical models cannot reproduce the high abundances of these molecules found in hot cores, and we suggest that they originate from processing and evaporation of icy grain mantle material. In addition, we report the first detection of vibrationally excited ethyl cyanide and the first detection of methyl mercaptan (CH3SH) outside the Galactic center. 相似文献
11.
S. A. Lamzin 《Astronomy Letters》2006,32(3):176-184
We have determined the atomic hydrogen column density N HI toward all of the young stars from the Taurus-Auriga-Perseus star-forming complex for which the corresponding spectra are available in the Hubble Space Telescope archive (nine stars) by analyzing the Lyα line profile. We show that the stars studied, except DR Tau, lie not far from the edge of the gaseous cloud of the star-forming region closest to us or, more precisely, inside the outer H I shell of the cloud. This shell with a column density of N HI ? 6 × 1020 cm?2 surrounds the molecular gas of the cloud composed of a diffuse component (the so-called diffuse screen) in which dense, compact TMC-1 cores are embedded. The properties of the dust grains toward the stars that lie at the front edge of the cloud most likely differ only slightly from those of the interstellar dust outside star-forming regions. This casts doubt on the validity of the hypothesis that the extinction curve toward young stars has an anomalously low amplitude of the 2175 Å bump—such an extinction curve is observed for the field stars HD 29647 and HD 283809 toward which the line of sight passes through the TMC-1 core. 相似文献
12.
We report the first detection of interstellar nitrogen sulfide (NS) in cold dark clouds. Several components of the 2 pi 1/2, J = 3/2 --> 1/2 and J = 5/2 --> 3/2 transitions were observed in TMC-1 and L134N. The inferred column density for TMC-1 is NNS approximately 8 x 10(12)cm-2 toward the NH3 peak in that cloud, and in L134N is NNS approximately 3 x 10(12)cm-2 toward the position of peak NH3 emission. These values correspond to fractional abundances relative to molecular hydrogen of fNS approximately 8 x 10(-10) for TMC-1, and fNS approximately 6 x 10(-10) for L134N. The NS emission is extended along the TMC-1 ridge and is also extended in L134N. The measured abundances are significantly higher than those predicted by some recent gas phase ion-molecule models. 相似文献
13.
A critical analysis of CH, NH, OH, C2, and CN molecules/radicals has been made in twenty-four F- and early G-type dwarfs at different effective temperature as well as in new constructed model atmosphere. Molecular indices of bandheads ofA-X system of CH, NH, OH, C2, and CN have been obtained by using the data available in the literature (thirteen-colour and eight-colour photometry).Besides, some interesting plots of the molecular indices vs eff, molecular abundances and molecular indices vs dissociation energy, reduced equivalent widths and FCF's vs dissociation energy for respective molecules have also been enumerated. It is found that the molecular indices at bandheads ofA-X system of CH, NH, OH, C2, and CN are approximately constant (5810–6570 K). It is to be noted that the molecular indices decrease in the order OH, NH, CH, C2, and CN at a given temperature.The dissociation equilibrium of CH, NH, OH, C2, and CN is considered at 5810, 6570, and 7160 K phases in model atmosphere. At standard scale of abundance the molecular abundance and molecular index decrease in the order OH, NH, CH, C2, and CN at any given phase, however, CN abundance and index increase (eff=0.867-0.767). The amplitude of abundance and index variation decrease in the order NH, OH, CH, C2, and CN (eff=0.767-0.704).The reduced equivalent width decrease in the order OH, NH, CH, and C2 and FCF's decrease in the order CH, OH, NH, CN, and C2.The confrontation of models and observations of spectra of F- and early G-type dwarfs of parent molecules is of primary importance to investigate the physical conditions within atmospheres. Reliable excitation models are also requisite for interpreting spectroscopic observations of parent molecules and deriving molecular abundances. 相似文献
14.
Karen Magee-Sauer Michael J. Mumma Neil Dello Russo Boncho P. Bonev G.L. Villanueva 《Icarus》2008,194(1):347-356
We used the NIRSPEC instrument on the Keck-2 telescope atop Mauna Kea, HI to observe Comet C/2001 A2 (LINEAR) in a Target of Opportunity campaign on UT 2001 July 9.5, 10.5 August 4.4, 10.5. We measured seven organic parent volatiles (C2H6, C2H2, HCN, CH4, CO, CH3OH, H2CO) simultaneously with H2O. We obtained absolute production rates and relative abundances for parent volatiles, and also measured rotational temperatures for several of these species. The chemical composition of C/2001 A2 differs substantially from any comet we have observed to date. The abundances we measure (relative to H2O) for C2H6, C2H2, HCN, and CH3OH are enriched by a factor of ∼2 to 3 in C/2001 A2 compared with most comets in our database. Other molecular species were detected within the typical range of measured abundances. C/2001 A2 presented a unique opportunity to study the chemistry of a fragmenting comet where pristine areas are exposed to the Sun. 相似文献
15.
D.P. Ruffle T.W. Hartquist P. Caselli J.M.C. Rawlings D.A. Williams 《Astrophysics and Space Science》1998,262(2):177-185
We have investigated the dependences of the fractional abundances of a number of species on the selective depletions of elemental carbon, nitrogen, oxygen and sulphur, as well as metals. Of the most commonly observed species, HCO+ is the one having the fractional abundance that is least sensitive to the selective elemental depletions and for this reason is a particularly appropriate species to study in efforts to diagnose collapse dynamics in star formation from the analysis of infall signatures in spectral line profiles. We suggest that a combination of molecules could be the focus of observations aimed at the investigation of collapse dynamics. Comparisons of the profiles of spectral features of these species would also give insight into the behaviours of the selective depletions of the different elements in the infalling gas. 相似文献
16.
We have constructed a reaction system containing the chemical families of H, C, O, N, S, Si, Cl, metals (Me) and grains. A total of 104 species have been included and a network of 557 reactions has been studied. The chemical kinetic equations were integrated as a function of time by using gear program. The chemical reaction system was followed at low, intermediate and high cloud densities i.e. from 10–107 particles cm-3. The calculated fractional abundances of N2, CN, HCN, and CH which are in good agreement with the results of observations and with those of previous theoretical studies. 相似文献
17.
R. Ruiterkamp S. B. Charnley H. M. Butner H.-C. Huang S. D. Rodgers Y.-J. Kuan P. Ehrenfreund 《Astrophysics and Space Science》2007,310(3-4):181-188
We have observed emission from both ortho and para spin states of ketene (CH2CO) towards several deeply-embedded protostars. The low CH2CO fractional abundances (∼10−10) and the rotation temperatures (∼20 K) are consistent with emission from the cooler envelope. We compare our results with
previous studies and discuss possible production pathways to interstellar ketene. We suggest that, if low observed excitation
temperatures of CH2CO, CH3CHO and H2CO are indicative of their absence from the hot core region, then this may be due to the extensive hydrogenation of pre-existing
grain mantles prior to evaporation into the inner envelope, leading to lower abundances of these compounds and to mantles
rich in alcohols. 相似文献
18.
A variety of models are explored to study the photochemistry of CO2 in the Martian atmosphere with emphasis on reactions involving compounds of carbon, hydrogen, and oxygen. Acceptable models are constrained to account for measured concentrations of CO and O above 90 km, with an additional requirement that they should be in accord with observations of CO, O2, and O3 in the lower atmosphere. Dynamical mixing must be exceedingly rapid at altitudes above 90 km, with effective eddy diffusion coefficients in excess of 107 cm2 sec?1. If recombination of CO2 is to occur mainly by gas phase chemistry, catalyzed by trace quantities of H, OH, and HO2, mixing must be rapid over the altitude interval 30 to 40 km. The value implied for the diffusion coefficient in this region is a function of assumptions made regarding the rates for reaction of OH with HO2 to form H2O and of the rate for reaction of HO2 with itself to form H2O2. If rates for these reactions are taken to have values similar to rates used in current models for the Earth's stratosphere, the eddy diffusion coefficient at 40 km on Mars should be about 5 × 107 cm2 sec?1, consistent with Zurek's (1976) estimate for this parameter inferred from tidal theory. Surface chemistry could have an influence on the abundances of atmospheric CO and O2, but a major effect would imply sluggish mixing at all altitudes below 50 km and in addition would carry implications for the magnitude of the rates for reaction of OH with HO2 and HO2 with itself. 相似文献
19.
The paper deals with massive fluid spheres with an isothermal core (having finite central density) and a polytropic envelope in terms of the General Relativity. The matching of the solutions in the core and envelope has been done using Bondi's condition,H=0 and also without it. The study reveals that since this condition does not correspond to any particular physical situation the maximum values of fractional core size, fractional core mass and the redshift do not occur atH=0, but that they occur at some other point. Within the permissible physical conditions (dP/dρ≤1) the maximum values ofM core/M,R core/R and the surface redshift, for an isothermal coreP=ρ/3, are respectively 0.473, 0.554, and 0.565. Using the conditionH=0, it has been shown that for isothermal cores corresponding to the equation of the stateP≥0.6ρ, the configurations are pulsationally unstable. 相似文献
20.
Yuri Aikawa 《Astrophysics and Space Science》2008,313(1-3):35-40
We review molecular evolution in low-mass star-forming regions and discuss what we can observe with ALMA. Recent observations have revealed chemical fractionation, i.e. spatial variation of molecular abundances, in dense prestellar cores. In the central regions of cold prestellar cores, CO is heavily depleted, while the depletion of N-bearing species are rare. Models show that CO is frozen onto grains, while N-bearing species survive because of the CO depletion and slow formation of N2 in the gas phase. CO depletion also enhances the molecular D/H ratio. Chemical fractionation and its variation among cores can be an indicator of evolutionary stage and/or accumulation process of cores. As the core contracts, central region of the core is eventually heated by compressional heating and a new-born protostar. CO is sublimated back to the gas phase, if the temperature reaches 20 K. Warm temperature enhances the endothermic reactions which were negligible in the prestellar core stage, and also enhances grain-surface reactions among heavy-element species to form large organic molecules, which sublimate when the temperature reaches ～100 K. Warm regions with high abundances of the gaseous organic species are called hot corinos or low-mass hot cores. Adopting a theoretical model of core contraction, we present the temporal variation of the radius inside which CO and large organic species are sublimated. We also investigate the molecular evolution in infalling shells to derive molecular distribution in a protostellar core. 相似文献