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1.
浅成-次火山岩黑云母Cu,Au成矿示踪意义   总被引:4,自引:3,他引:4  
浅成-次火山岩是许多斑岩型和斑岩-浅成低温热液型铜、金矿床矿质和流体的重要来源,斑岩体初始岩浆的Cu,Au丰度,CI,F含量及岩浆结晶时的氧逸度是其能否最终形成含Cu,Au流体的关键因素。黑云母是浅成-次火山中酸性侵入体中最常见的铁镁矿物,含有较丰富的Cu,Au及挥发分CI,F其Fe^3 /Fe^3 (Fe^3 Fe^2 )比值可以反映其结晶时岩浆的氧化还原状态,尤其是斑晶黑云母往往形成于岩浆流体出溶和去气作用发生之前,它能灵敏地指示其母岩浆的初始Cu,Au丰度和CI,F含量及氧化还原状态,因此,可以作为成矿物质、成矿流体来源的理想示踪矿物,并可用于浅成-次火山侵入人体的成矿潜力。在一些斑岩型铜、金矿床和斑岩-浅成低温热液型金、铜矿床分布区开展浅成-次火山侵入体黑云母的成矿示踪研究,对于解决矿床成因和指导找矿实践均具有重要意义。  相似文献   

2.
3.
The Igarapé Bahia gold deposit has developed from weathering of a near-vertical hydrothermal Cu (Au) mineralization zone. The unweathered bedrock composed of chlorite schists is mainly metamorphosed basalts, pyroclastic and clastic sedimentary rocks and iron formation. Contents and Fe/(Fe + Mg) ratios of chlorites increase from distal country rock towards the mineralization zone, which can be attributed to different water/rock ratios and locations in a hydrothermal system. In the hydrothermal system high salinity fluids convected through basin-floor rocks, stripping metals from the recharge zones with precipitation in discharge zones. The chlorite with lower Fe/(Fe + Mg) ratios indicates alteration by relatively unreacted Mg-rich fluids, occurring within recharge zones. By contrast, the chlorite with higher Fe/(Fe + Mg) ratios in the mineralization zone formed from solutions rich in Fe, Mn, Au, Cu, H2S and SiO2 within a discharge zone. The iron formation could also be formed within the discharge zone or on the basin floor from the Fe-rich fluids. The distal country rock with less chlorite content is a hydrothermal product at low water/rock ratios whereas the proximal country rock and the host rock with more chlorite content formed at high water/rock ratio conditions. The Al(IV) contents of chlorites indicate that the formation temperatures of these rocks range from 204 to 266 °C, with temperatures slightly increasing from distal country rock towards the mineralization zone.  相似文献   

4.
1∶5万水系沉积物测量显示,平然地区矿化异常是一个以Cu、Ni、Co异常为主,伴随有Cr、V、Ti等的多元素组合异常,体现了基性—超基性岩石的成矿专属性。对元素分布特征、单元素异常特征、异常元素组合特征进行了研究,得出该区异常主要受区域性NW向断裂构造和基性—超基性岩石控制。对平然地区水系沉积物测量数据聚类分析表明,15种元素可以分为三类:Ni、Cr、Cu、V、Co、Zn、Ti为一类,反映了与基性—超基性岩有关的元素分布、富集特征和相关矿化信息;As、Sb、Pb为一类,反映了与中低温热液作用有关的矿化信息;剩余元素的相关性差,归为一类。平然地区F1主因子可能代表了与基性—超基性有关的Cu、Ni、Co矿化。对平然地区3806个样品分别计算F1因子得分,得分大于2的607个样品分布特征与Cu、Ni、Co异常分布特征大致吻合。因此,Cu、Ni、Co异常区域及F1因子得分大于2的样品所在区域的重叠处应该是以Cu、Ni、Co为主的重点找矿区域。  相似文献   

5.
王强  许继峰  赵振华 《地学前缘》2003,10(4):561-572
文中概述了强烈亏损重稀土元素的中酸性火成岩(或埃达克质岩)的研究历史、现状和意义,列出了扬子地块东部、青藏高原以及新疆北部与铜金成矿有关的同类岩石的一些特征,重点分析了当前强烈亏损重稀土元素的中酸性火成岩(或埃达克质岩)的研究中所存在的问题,并提出了一些初步的设想。强烈亏损重稀土元素的中酸性火成岩(或埃达克质岩)不仅具有重要的地球动力学意义(可能与俯冲、拆沉、底侵、板片窗或地幔交代等深部过程有关),而且具有极其重要的Cu、Au成矿意义。俯冲洋壳熔融形成的埃达克岩及其成矿作用已有相当深入的研究,但是来自大陆内部的强烈亏损重稀土元素的中酸性火成岩的成因、岩石组合及其成矿作用是否类似于俯冲洋壳熔融形成的埃达克岩,还需要深入的研究。一些强烈亏损重稀土元素的中酸性火成岩(或埃达克质岩)的所表现出的高钾特征很可能与高压(>1 GPa)条件下的熔融或源岩的高钾有关。文中提出了一个有别于俯冲洋壳熔融+埃达克岩+Cu、Au成矿的新工作模型——拆沉洋壳或下地壳熔融+强烈亏损重稀土元素的中酸性火成岩(或埃达克质岩)+Cu、Au成矿。拆沉洋壳或下地壳熔融形成熔体的Fe_2O_3对地幔的交代(氧化)作用可能是Cu、Au从地幔迁出并最终成矿的一个重要原因,但是增厚下地壳环境中流体的作用也不?  相似文献   

6.
新疆若羌县长沙沟一带的基性-超基性岩位于阿尔金陆缘地块和祁漫塔格早古生代岛弧带结合部位,沿阿尔金断裂带状展布,为镁铁质-超镁铁质岩带。岩石主要由橄榄岩、辉橄岩和辉石岩和辉长岩等组成;上部镁铁质岩主要由辉长岩(部分为橄榄辉长岩和辉石岩)组成,下部辉橄岩、橄榄岩、辉石岩相互过渡(且成堆晶结构)。1∶20万、1∶5万化探资料显示,沿基性-超基性杂岩带有Cu、N i、Co、C r、W等异常,异常重现性较好,特别是Cu、N i、Co、C r元素套合较好,极值较大,浓集中心显著;1∶5万地面高精度磁测显示区内有较好的磁异常8处,异常规模较大,并与基性-超基性岩体吻合。对部分高磁异常区激电中梯剖面扫面,发现高激电异常,极化率在3%左右,最高达17.8%。经野外初步检查,发现了大量的铜镍矿化和磁铁矿化体,并圈出了阿克萨依镍矿和长清磁铁矿,表明长沙沟基性-超基性杂岩带具有较好的铜、镍、铁找矿潜力。  相似文献   

7.
PGE-rich disseminated zones with discrete platinum-group minerals (Pd, Pt and Rh mineral phases) have been discovered in three thick (80–130 m), differentiated (peridotite-gabbro) mafic-ultramafic flows of the Archean Abitibi greenstone belt, Ontario. Three mineralization zones (whole-rock ∑PGE + Au = up to 1000 ppb) occur along four stratigraphic cross sections through a 2 km strike-length of the Boston Creek Flow ferropicritic basalt. Their occurrence most strikingly correlates with lenticular-podiform concentrations of disseminated chalcopyrite (1 %) and clinopyroxene + interstitial magnetite-ilmenite intergrowths (15–20% oxide), high concentrations of related metals (3000 ppm Cu, 3000 ppm S, 1200 ppb Ag, and 1000 ppm V), strong PGE depletion in adjacent rocks and along strike, and lithological and textural complexity in the margins of the central gabbro-diorite layer. The mineralization zone (whole-rock Ir + Pt + Pd + Au = 110 ppb) within Theo's Flow tholeiitic basalt is somewhat similar in occurrence, style, and composition to those within the Boston Creek Flow. In contrast, the mineralization zone (whole-rock Ir + Pt + Pd + Au = 340 ppb) in Fred's Flow komatiitic basalt most strikingly correlates with vesicle-filling intergrowths of pyrrhotite + pentlandite ± chalcopyrite (2 modal %) and high whole-rock concentrations of Ni (2500 ppm), Cu (700 ppm), and S (1.1%) in the upper chilled margin of the flow.Although apparently uneconomic, these flow-hosted PGE mineralization zones are of interest in exploration, because they are more similar in stratigraphie setting, style, and composition to PGE-rich disseminated Fe-Cu sulfide mineralization zones within thick differentiated intrusions than to mineralization zones in other Archean volcanic rocks. The characteristics of the mineralization zones and their host rocks, especially high degrees of PGE enrichment, vertical and horizontal patterns of PGE depletion, and accumulation of clinopyroxene + magnetite-ilmenite intergrowths, indicate a critical genetic role for variations in the regime of melt flowage. The mineralization zones in the Boston Creek and Theo's Flows are interpreted to have formed by simultaneous in situ formation of PGE-rich Fe-Cu sulfide and Fe-Ti oxide from flowing silicate liquid in the margins of internal lava channels. The mineralization zone in Fred's Flow is interpreted to have formed by ponding and coalescence of PGE-enriched sulfurous vapor bubbles in the upper chilled margin during olivine accumulation on the base of a dynamic lava channel. The relative abundance of PGE mineralization zones and high degree of PGE enrichment in the Boston Creek Flow suggest that the most favorable exploration targets are rocks crystallized from late-stage, highly fractionated derivative liquids in large differentiated terropicritic units.  相似文献   

8.
The Yinshan deposit in the Jiangnan tectonic belt in South China consists of Pb‐Zn‐Ag and Cu‐Au ore bodies. This deposit contains approximately 83 Mt of the Cu‐Au ores at 0.52% Cu and 0.8 g/t Au, and 84 Mt of the Pb‐Zn‐Ag ores at 1.25% Pb, 1.02% Zn and 33.3 g/t Ag. It is hosted by low‐grade metamorphosed sedimentary rocks and mafic volcanic rocks of the lower Mesoproterozoic Shuangqiaoshan Group, and continental volcanic rocks of the Jurassic Erhuling Group and dacitic subvolcanic rocks. The ore bodies mainly consist of veinlets of sulfide minerals and sulfide‐disseminated rocks, which are divided into Cu‐Au and Pb‐Zn‐Ag ore bodies. The Cu‐Au ore bodies occur in the area close to a dacite porphyry stock (No. 3 stock), whereas Pb‐Zn‐Ag bodies occur in areas distal from the No. 3 stock. Muscovite is the main alteration mineral associated with the Cu‐Au ore bodies, and muscovite and chlorite are associated with the Pb‐Zn‐Ag ores. A zircon sensitive high‐resolution ion microprobe U‐Pb age from the No. 3 dacite stock suggests it was emplaced in Early Jurassic. Three 40Ar‐39Ar incremental‐heating mineral ages from muscovite, which are related to Cu‐Au and Pb‐Zn‐Ag mineralization, yielded 179–175 Ma. These muscovite ages indicate that Cu‐Au mineralization occurred at 178.2±1.4 Ma (2σ), and Pb‐Zn‐Ag mineralization at 175.4±1.2 Ma (2σ) and 175.3±1.1 Ma (2σ), which supports a restricted period for the mineralization. The Early Jurassic ages for the mineralization at Yinshan are similar to that of the porphyry Cu mineralization at Dexing in Jiangnan tectonic belt, and suggest that the polymetallic mineralization occurred in a regional transcompressional tectonic regime.  相似文献   

9.
吉林夹皮沟成矿带金成矿作用与太古宇变质岩系、幔源岩浆活动、韧性剪切带密切相关.成矿流体以地幔流体为主,成矿物质主要来源于地幔,地幔活动形成的韧性剪切带及其伴生的次一级断裂构造不仅是成矿流体的运移通道,而且是矿体就位的有利空间.论述了新立屯-马家店、大朝阳沟地区具有金矿成矿的基本地质条件——太古宇变质岩系广泛分布,幔源岩浆、韧性-脆性构造活动强烈;金矿化体(石英脉)受韧性剪切带两侧的次一级断裂控制,伴随金矿化有黄铁矿化、黄铜矿化、方铅矿化及闪锌矿化等,金品位与金属硫化物含量呈正相关;与矿化关系密切的围岩蚀变是硅化(-钾长石化).金矿化、围岩蚀变特征与矿带内已知金矿床相似.找矿研究表明,新立屯矿化点深部具有较强烈的主成矿期热液活动,且围岩条件、构造条件适宜金矿成矿作用;马家店矿点、大朝阳沟地区的矿化点同样具有较大的成矿潜力.因此,夹皮沟成矿带南东部外围具有良好的成矿远景.  相似文献   

10.
研究区属含古老地块并经中生代改造的中古生代造山带,存在金、锡等丰度较高的锡林浩特元古宙杂岩、古生代蛇绿岩及板块缝合带、二叠系火山岩、中生代伸展构造背景下的大规模火山-侵入活动及锡多金属成矿作用.本区金矿化类型主要有:韧性剪切带中的石英脉型、蚀变岩型金矿,产于幔源中基性侵入岩中的铜金矿,燕山晚期斑岩型铜金矿,与燕山期次火山岩浆活动有关的脉状铜矿床中的伴生金矿化,微细浸染型金矿化,浅成低温热液型金矿化等.研究区金矿成矿时代可分为242~229Ma、169~161.8Ma、132~159Ma (可能以130~140Ma为主)、127~109.2Ma四个区间.认识到存在印支期成矿、燕山期多阶段成矿等特点对于区内金矿勘查有重要意义.新发现7个矿床(点)的伴生金矿化.毛登、大井等多金属矿床的伴生金矿化具有重要的潜在工业意义.  相似文献   

11.
1. The division of main tectonic regions and their minerogenetic belts. In quite a few fold zones of geosynclinal systems, such as Altay, Junggar, Tianshan, Kunlun and Beishan Mountains, there exist ore zones of rare metals, muscovite, Fe, Cr, Mn, Au, P, asbestos, nonferrous metals, etc., whereas in Tarim platform, Fe, Al, Zn, Cr, P, S, Cu and coal minerogenetic belts have already been found. 2. Minerogenetic relations between major types of ore deposits and magmatic series, sedimentary formation, or metamorphic facies. Cr, Cu, Ni, Co, Fe and rare metals of magmatic type are related to magnesian ultrabasic, ferruginous basic-ultrabasic or acid-alkaline rocks, nonferrous and noble metals, Fe and asbestos of hydrothermal type are found associated with acid, intermediate-acid intrusive rocks generally rich in alkali; rare metals and muscovite of pegmatitic type are genetically in connection with acid-alkaline rocks, Fe of volcanic type has to do with alkali-rich acid to basic eruptive rocks, coal, Fe, Mn, Al, Cu, Pb, Zn, P and S of sedimentary type occur mostly in clastic carbonate-rocks, siliceous carbonate rocks, detrital rocks, red beds, salt-bearing or coal-bearing formations, Fe, P of sedimentary-metamorphic type are preserrt: within such metamorphic facies as ferro-siliceous hornblendite, green schist-marble or siliceous-magnesian carbonatite. 3. Regularity of the formation and distribution of ore deposits. The formation and distribution of ore deposits are generally characterued by zoning, fault-controlling, polycycles, stratabinding, inheritance, regeneration, ore combination, equidistance, migration and superimposition, with individual ore deposit having its specific characteristics.  相似文献   

12.
Olivine/melt partitioning of ΣFe, Fe2+, Mg2+, Ca2+, Mn2+, Co2+, and Ni2+ has been determined in the systems CaO-MgO-FeO-Fe2O3-SiO2 (FD) and CaO-MgO-FeO-Fe2O3-Al2O3-SiO2 (FDA3) as a function of oxygen fugacity (fO2) at 0.1 MPa pressure. Total iron oxide content of the starting materials was ∼20 wt%. The fO2 was to used to control the Fe3+/ΣFe (ΣFe: total iron) of the melts. The Fe3+/ΣFe and structural roles of Fe2+ and Fe3+ were determined with 57Fe resonant absorption Mössbauer spectroscopy. Changes in melt polymerization, NBO/T, as a function of fO2 was estimated from the Mössbauer data and existing melt structure information. It varies by ∼100% in melts coexisting with olivine in the FDA3 system and by about 300% in the FD system in the Fe3+/ΣFe range of the experiments (0.805-0.092). The partition coefficients ( in olivine/wt% in melt) are systematic functions of fO2 and, therefore, NBO/T of the melt. There is a -minimum in the FDA3 system at NBO/T-values corresponding to intermediate Fe3+/ΣFe (0.34-0.44). In the Al-free system, FD, where the NBO/T values of melts range between ∼1 and ∼2.9, the partition coefficients are positively correlated with NBO/T (decreasing Fe3+/ΣFe). These relationships are explained by consideration of solution behavior in the melts governed by Qn-unit distribution and structural changes of the divalent cations in the melts (coordination number, complexing with Fe3+, and distortion of the polyhedra).  相似文献   

13.
新疆阿克陶县恰尔隆一带1:5万区调工作中曾在库科西力克一带发现数个具有一定工业价值的矿点,这些矿点位于西昆仑铜钼多金属元素富集带,其矿种齐全,涉及Au、Ag、Cu、Pb—Zn、M0、W和Fe等,分布较为集中,资源前景较好,找矿潜力巨大。本文从矿床地质及元素地球化学的角度对一些典型矿点进行了系统调查、采样、分析及研究,发现库尔尕斯金铜矿点主成矿元素中Ag、Cu和Pb具有一致的成矿阶段,而Au受后期构造作用可能滞后富集成矿。同时各矿点间REE含量及分布模式存在较大的差异。除库尔尕斯金铜矿点外,各矿点中矿石和围岩REE总量和分布模式差别也较为明显。认为库科西力克一带各矿点在成矿地质条件上具有一定的联系,成矿物质可能主要来源于深部,主要受区域性断裂(库科西力克断裂)及岩浆活动的影响,但各矿点之间具有各自的成矿特点,这与各矿点不同的矿床类型相关。  相似文献   

14.
Many metallic ore deposits of the Late Cretaceous to Early Tertiary periods are distributed in the Gyeongsang Basin. Previous and newly analyzed sulfur isotope data of 309 sulfide samples from 56 ore deposits were reviewed to discuss the genetic characteristics in relation to granitoid rocks. The metallogenic provinces of the Gyeongsang Basin are divided into the Au–Ag(–Cu–Pb–Zn) province in the western basin where the sedimentary rocks of the Shindong and Hayang groups are distributed, Pb–Zn(–Au–Ag–Cu), Cu–Pb–Zn(–Au–Ag), and Fe–W(–Mo) province in the central basin where the volcanic rocks of the Yucheon Group are dominant, and Cu(–Mo–W–Fe) province in the southeastern basin where both sedimentary rocks of the Hayang Group and Tertiary volcanic rocks are present. Average sulfur isotope compositions of the ore deposits show high tendencies ranging from 2.2 to 11.7‰ (average 5.4‰) in the Pb–Zn(–Au–Ag–Cu) province, ?0.7 to 11.5‰ (average 4.6‰) in the Cu–Pb–Zn(–Au–Ag) province, and 3.7 to 11.4‰ (average 7.5‰) in the Fe–W(–Mo) province in relation to magnetite‐series granitoids, whereas they are low in the Au–Ag(–Cu–Pb–Zn) province in relation to ilmenite‐series granitoids, ranging from ?2.9 to 5.7‰ (average 1.7‰). In the Cu(–Mo–W–Fe) province δ34S values are intermediate ranging from 0.3 to 7.7‰ (average 3.6‰) and locally high δ34S values are likely attributable to sulfur derived from the Tertiary volcanic rocks during hydrothermal alteration through faults commonly developed in this region. Magma originated by the partial melting of the 34S‐enriched oceanic plate intruded into the volcanic rocks and formed magnetite‐series granitoids in the central basin, which contributed to high δ34S values of the metallic deposits. Conversely, ilmenite‐series granitoids were formed by assimilation of sedimentary rocks rich in organic sulfur that influenced the low δ34S values of the deposits in the western and southeastern provinces.  相似文献   

15.
赵善仁  吴悦斌 《现代地质》1996,10(4):478-484
五台山—恒山绿岩带Au、Ag、Cu矿床可分为二大类型:(1)再生型金银铜矿,产在包括岩浆岩在内的各类岩石断裂构造中,与岩浆期后热液有关;(2)变生型金银铜矿,产于各类变质岩中,具有层控特征(即绿岩型金矿)。在地球化学特征上,再生型矿床与变生型矿床相比,矿体及围岩中Mo、Ag、Pb、Zn、Cd等成矿及伴生元素明显富集;K2O、Rb、Sr、Ba、Th、U也明显富集,是后期岩浆热液作用的结果;Hg、F的明显富集则与后期构造活动有关;Zn/Cd比值较低,说明受到后期岩浆侵入影响;Th/U比值低,可能指示富钙的酸性岩环境。再生型Au矿化的元素组合为Cd、As、Ni、Ag、Sb、Au、Hg(Bi),再生型Ag矿化的元素组合为As、Sb、Ag、Cd、Cu、Ni(Mo、Pb、Zn、Bi),变生型Au矿化的元素组合较简单,只为Au、Hg、As或Au、Cu。上述地球化学特征不仅可以有效地区分矿化类型,而且可以作为地球化学找矿和评价的指标  相似文献   

16.
澳大利亚Cloncurry地区大部分被元古宙地层所覆盖,其中赋存有大量世界级的成矿热液系统。大型热液系统大都与含磁铁矿或赤铁矿等铁氧化物的铁矿化岩石密切相关。铁氧化物和铜金矿化的矿物学、地球化学及年代学特征反映出成矿过程可能涉及到多种流体间的作用和水岩反应。对Cloncurry地区典型矿床和区域Na-Ca热液系统的研究表明,含铁氧化物的铁矿化岩石与铜金矿化之间的关系可分为4类:①贫磁铁矿或赤铁矿的"Kiruna-型"铁矿化岩石;②铜金矿化赋存于含铁氧化物的铁矿化岩石中;③与铁氧化物有关的铜金矿化;④少量或者不含铁氧化物的铜金矿化。该分类提供了一些与铁氧化物有关的铜金矿化成因联系、矿物学和矿化类型信息。  相似文献   

17.
The Bystrinskoe skarn-porphyry Cu–Au–Fe deposit (Eastern Trans-Baikal Region) is confined to skarn zones, which were formed along the contact of granitoids referred to the Shakhtama intrusive complex (J2–3), with terrigenous–carbonate sedimentary rocks. Commercial (Cu–Au–Fe ± W, Mo) mineralization was formed due to the regional postcollision development involving the intrusion of porphyritic granitoids, the derivatives of oxidized adakite highly magnesian magmas enriched in water, sulfur, and metals, which could develop under melting of garnet-bearing amphibolite in the mafic lower crustal arc.  相似文献   

18.
刘斌  马启波  张哲 《地质与资源》2000,9(3):149-154
延边东北部地区中生代陆相火山断陷盆地处于吉黑褶皱系延边优地槽褶皱带延边复向斜内;区内中生代以来不同方向的断裂发育,火山活动强烈,岩浆侵入频繁;与中生代火山-岩浆活动有成因联系的金、铜金金属矿床多处,矿化蚀变线索也较多,构成了著名的五凤-小西南岔近东西向火山-岩浆期后低温热液型金、铜多金属成矿带;区内中生代火山-岩浆岩的形成是太平洋板块俯冲作用使大陆边缘拉张活动不断加剧,造成上地幔岩浆上侵的结果;并伴有成矿作用的发生,在岩浆岩体内外接触带的有利部位形成金、金铜或铜金多金属矿床;从远源至近源的成矿分带为Au-Ag→Au-Cu-Ag→Cu-Au-Pb-Zn→Cu(-Mo-Au);成矿作用表现出从低温至高温、从低硫到高硫的变化.  相似文献   

19.
牛鼻子梁地区位于柴达木盆地西北缘,属于典型的高原荒漠景观,开展大比例尺的地球化学测量,能获取更为真实地球化学信息,大大提高了地球化学信息的收集和地质找矿的效果。通过对牛鼻子梁地区的成矿地质特征及重要地球化学异常特征进行分析研究,发现与成矿密切相关的是晚泥盆世基性-超基性岩,断裂构造有一定的控制作用;地球化学异常中Cr、Co、Ni、La、Au等元素异常特征明显,结合内已有的成矿事实,表明寻找与基性-超基性岩体相关的铜镍矿、与韧性剪切带相关的金矿及稀有稀土矿的潜力较大,建议下一步优先对此类异常区进行详细查证和工程勘查。  相似文献   

20.
熔体结构对岩浆的物理和热力学性质起着重要的制约作用。本文以镜泊湖全新世火山为例,讨论了熔体结构和某些火山喷发机制的关系。熔体结构的NBO/T值(每个四次配位阳离子所含有的非桥氧数)是基于岩浆的主要元素和挥发分含量的计算获得的。研究结果表明,NBO/T值越高的岩浆,喷发时溢流出的熔岩比例越高,熔岩流流动的距离越长,越有利于熔岩隧道的形成,H2O^ 和F也更富集。  相似文献   

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